Durable PP/EPDM/GF/SiO2 nanocomposites with improved strength and toughness for orthotic applications.

Ankle-foot orthotics need ideal specification of being light-weight, high strength, tough, stiff, and durable. Reinforced polypropylene (PP) composites with enhanced mechanical properties are the most favorable materials being used in this field, but still, it is challenging to achieve balanced blend of strength and toughness in the composites. The present study thus aims to achieve the challenging task of simultaneous improvement in stiffness and toughness in reinforced PP composites exploring the synergistic reinforcement effect of glass fibers (GFs) and nano silica (SiO2) as multiscale fillers and ethylene propylene diene monomer (EPDM) as impact modifier. EPDM is used as toughness modifier, addressing the brittle behavior, but at the cost of the strength of the polymer. Combined use of micro and nanofillers as reinforcement in toughened polypropylene provides a potential approach to balance the strength while maintaining the toughness. GFs could offer high strength and nanofillers offer ductile fracture to the material. PP, PP/GF, PP/EPDM/GF composites and PP/EPDM/GF/SiO2 nanocomposites are fabricated through melt blending technique and are characterized through SEM, mechanical evaluation, nanoindentation and dynamic mechanical analysis. Mechanical properties are evaluated in accordance with ASTM standards. PP/EPDM/GF/SiO2 nanocomposites exhibits remarkable enhancement in Tensile strength, tensile modulus, impact strength and percent elongation at break by 49 MPa (55% increase over PP), 2450 MPa (145% increase), 145 J/m (13% increase) and 156% (160% increase) respectively. The exceptional improvement in reduced modulus and hardness reveals good interfacial properties. Loss factor decrement reveals elastic behavior of nanocomposites suitable for thermoforming of nanocomposites for orthotic device fabrication.

Swift Heavy Ion Irradiation as a Tool for Homogeneous Dispersion of Nanographite Platelets within the Polymer Matrices: Toward Tailoring the Properties of PEDOT:PSS/Nanographite Nanocomposites.

Performance of the polymer nanocomposites is dependent to a great extent on efficient and homogeneous dispersion of nanoparticles in polymeric matrices. The dispersion of nanographite platelets (NGPs) in polymer matrix is a great challenge because of the inherent inert nature of the NGPs, poor wettability toward polymer matrices, and easy agglomeration due to van der Waals interactions. In the present study, attempts have been made to use a new approach involving the irradiation of polymer nanocomposites through swift heavy ion (SHI) to homogeneously disperse the NGPs within the polymer matrices. Poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) ( PEDOT: PSS)/nanographite nanocomposite (NC) films prepared by the solution blending method were irradiated with SHI (Ni ion beam, 80 MeV) at a fluence range of 1 × 10(10) to 1 × 10(12) ions/cm(2). XRD studies revealed that ion irradiation results in delamination and better dispersion of NGPs in the irradiated nanocomposite films compared to unirradiated films, which is also depicted through SEM, AFM, TEM, and Raman studies. In the irradiated polymer nanocomposite films, the conformation of PEDOT chains changes from coiled to extended coiled structure, which, along with homogeneously dispersed NGPs in irradiated NCs, shows an excellent synergistic effect facilitating charge transport. The remarkable improvement in conductivity from 1.9 × 10(-2) in unirradiated NCs to 0.45 S/cm in irradiated NCs is observed with marked improvement in sensing the response toward nitroaromatic vapors at room temperature. The temperature induced conductivity studies have been carried out for PEDOT: PSS/nanographite NCs to comprehend the charge transport mechanism in NC films using the 3D Mott variable range hopping model also. The study reveals SHI as a novel method, addressing the challenge associated with the dispersion of NGPs within the polymer matrix for their enhanced performance toward various applications.