In-Depth Experimental Analysis of Influence of Electroplated Gold Thickness on Thermal and Electro-Optical Properties of mid-IR AlInAs/InGaAs/InP Quantum Cascade Lasers.

In this paper, we have examined the influence of electroplated gold thickness on the thermal and electro-optical properties of mid-IR AlInAs/InGaAs, InP QCLs. The experimental results show a significant reduction of the temperature of QCL active region (AR) with increasing gold layer thickness. For QCLs with 5.0 µm gold thickness, we observed a 50% reduction of the active region temperature. An improvement of key electro-optical parameters, that is, threshold current density and maximum emitted power for structures with thick gold, was observed. The results of micro-Raman characterization show that the electroplated gold layer introduces only moderate compressive strain in top InP cladding, which is well below the critical value for the creation of misfit dislocations.

Visual discrimination of aromatic acid substitution patterns by supramolecular nanocooperativity.

Physicochemical and, in particular, visual recognition of positional isomers, due to their similar appearance and properties, is an extremely challenging task. Here we present an easy-to-prepare assay for the naked-eye differentiation of all possible isomers of phthalic acids. The desired optical response is attained through specific non-covalent interactions between the acids and a cationic macrocyclic host. These interactions are then translated to and amplified by gold nanoparticles which subsequently aggregate to various extents producing a color palette.

Submicron Colloidosomes of Tunable Size and Wall Thickness.

We present a simple method for the fabrication of colloidal capsules of different sizes ranging from below 100 nm up to one micron. The capsules are produced by self-assembling 5 nm gold nanoparticles at the interface of oil-in-water emulsion droplets. The size of the capsules is regulated by tuning the wetting properties of the nanoparticles by changing either the composition of their ligand shell or the composition of the oil phase. The modified wettability affects not only the size but also the thickness of capsule walls. The wall can be thin if it is made of a single layer of the nanoparticles or thick when composed of multilayers. The durability of such capsules is quite high, although it can be improved by chemical cross-linking with UV light. Such capsules have low permeability, so they can store a molecular cargo and then release it on demand.