A Novel Multifunctional Photonic Film for Colored Passive Daytime Radiative Cooling and Energy Harvesting.

Passive daytime radiative cooling (PDRC) materials with sustainable energy harvesting capability is critical to concurrently reduce traditional cooling energy utilized for thermal comfort and transfer natural clean energies into electricity. Herein, a versatile photonic film (Ecoflex@BTO@UAFL) based on a novel fluorescent luminescence color passive radiative cooling with triboelectric and piezoelectric effect is developed by filling the dielectric BaTiO3 (BTO) nanoparticles and ultraviolet absorption fluorescent luminescence (UAFL) powder into the elastic Ecoflex matrix. Test results demonstrate that the Ecoflex@BTO@UAFL photonic film exhibits a maximum passive radiative cooling effect of ∽10.1 °C in the daytime. Meanwhile, its average temperature drop in the daytime is ~4.48 °C, which is 0.91 °C higher than that of the Ecoflex@BTO photonic film (3.56 °C) due to the addition of UAFL material. Owing to the high dielectric constant and piezoelectric effect of BTO nanoparticles, the maximum power density (0.53 W m-2 , 1 Hz @ 10 N) of the Ecoflex@BTO photonic film-based hybrid nanogenerator is promoted by 70.9% compared to the Ecoflex film-based TENG. This work provides an ingenious strategy for combining PDRC effects with triboelectric and piezoelectric properties, which can spontaneously achieve thermal comfort and energy conservation, offering a new insight into multifunctional energy saving.

A Versatile Strategy for Concurrent Passive Daytime Radiative Cooling and Sustainable Energy Harvesting.

Developing versatile systems that can concurrently achieve energy saving and energy generation is critical to accelerate carbon neutrality. However, challenges on designing highly effective, large scale, and multifunctional photonic film hinder the concurrent combination of passive daytime radiative cooling (PDRC) and utilization of sustainable clean energies. Herein, a versatile scalable photonic film (Ecoflex@h-BN) with washable property and excellent mechanical stability is developed by combining the excellent scattering efficiency of the hexagonal boron nitride (h-BN) nanoplates with the high infrared emissivity and ideal triboelectric negative property of the Ecoflex matrix. Strikingly, sufficiently high solar reflectance (0.92) and ideal emissivity (0.97) endow the Ecoflex@h-BN film with subambient cooling effect of ≈9.5 °C at midday during the continuous outdoor measurements. In addition, the PDRC Ecoflex@h-BN film-based triboelectric nanogenerator (PDRC-TENG) exhibits a maximum peak power density of 0.5 W m-2 . By reasonable structure design, the PDRC-TENG accomplishes effective wind energy harvesting and can successfully drive the electronic device. Meanwhile, an on-skin PDRC-TENG is fabricated to harvest human motion energy and monitor moving states. This research provides a novel design of a multifunctional PDRC photonic film, and offers a versatile strategy to realize concurrent PDRC and sustainable energies harvesting.

Sensing-transducing coupled piezoelectric textiles for self-powered humidity detection and wearable biomonitoring.

The performance of chemical sensors is dominated by the perception of the target molecules via sensitive materials and the conduction of sensing signals through transducers. However, sensing and transduction are spatially and temporally independent in most chemical sensors, which poses a challenge for device miniaturization and integration. Herein, we proposed a sensing-transducing coupled strategy by embedding the high piezoresponse Sm-PMN-PT ceramic (d33 = ∼1500 pC N-1) into a moisture-sensitive polyetherimide (PEI) polymer matrix via electrospinning to conjugate the humidity perception and signal transduction synchronously and sympatrically. Through phase-field simulation and experimental characterization, we reveal the principle of design of the composition and topological structure of sensing-transducing coupled piezoelectric (STP) textiles in order to modulate the recognition, conversion, and sensitive component utilization ratio of the prepared active humidity sensors, achieving high sensitivity (0.9%/RH%) and fast response (20 s) toward ambient moisture. The prepared STP textile can be worn on the human body to realize emotion recognition, exercise status monitoring, and physiological stress identification. This work offers unprecedented insights into the coupling mechanism between chemisorption-related interfacial state and energy conversion efficiency and opens up a new paradigm for developing autonomous, multifunctional and highly sensitive flexible chemical sensors.

Biodegradable cotton fiber-based piezoresistive textiles for wearable biomonitoring.

Electronic textiles are fundamentally changing the way we live. However, the inability to effectively recycle them is a considerable burden to the environment. In this study, we developed a cotton fiber-based piezoresistive textile (CF p-textile) for biomonitoring which is biocompatible, biodegradable, and environmentally friendly. These CF p-textiles were fabricated using a scalable dip-coating method to adhere MXene flakes to porous cotton cellulose fibers. The adhesion is made stronger by strong hydrogen bonding between MXene flakes and hierarchically porous cotton cellulose fibers. This cotton-fiber system provides a high sensitivity of 17.73 kPa-1 in a wide pressure range (100 Pa-30 kPa), a 2 Pa subtle pressure detection limit, fast response/recovery time (80/40 ms), and good cycle stability (over 5, 000 cycles). With its compelling sensing performance, the CF p-textile can detect various human biomechanical activities, including pulsation, muscle movement, and swallowing, while still being comfortable to wear. Moreover, the cotton cellulose is decomposed into low-molecular weight cellulose or glucose as a result of the 1,4-glycosidic bond breakage when exposed to acid or during natural degradation, which allows the electronic textile to be biodegradable. This work offers an ecologically-benign, cost-effective and facile approach to fabricating high-performance wearable bioelectronics.

Degradable MXene-Doped Polylactic Acid Textiles for Wearable Biomonitoring.

Degradable wearable electronics offer a promising route to construct sustainable cities and reduced carbon society. However, the difficult functionalization and the poor stability of degradable sensitive materials dramatically restrict their application in personalized healthcare assessment. Herein, we developed a scalable, low-cost, and porosity degradable MXene-polylactic acid textile (DMPT) for on-body biomonitoring via electrospinning. A combination of polydimethylsiloxane templating and MXene flake impregnation methods endows the fabricated DMPT with a sensitivity of 5.37/kPa, a fast response time of 98 ms, and a good mechanical stability (over 6000 cycles). An efficient degradation of as-electrospun DMPTs was observed in 1 wt % sodium carbonate solution. It is found that the incorporation of MXene nanosheets boosts the hydrophilicity and degradation efficiency of active polylactic acid nanofibrous films in comparison with the pristine counterpart. Furthermore, the as-received DMPT demonstrates great capability in monitoring physiological activities of wrist pulse, knuckle bending, swallowing, and vocalization. This work opens up a new paradigm for developing and optimizing high-performance degradable on-body electronics.

High-performance piezoelectric composites via ß phase programming.

Polymer-ceramic piezoelectric composites, combining high piezoelectricity and mechanical flexibility, have attracted increasing interest in both academia and industry. However, their piezoelectric activity is largely limited by intrinsically low crystallinity and weak spontaneous polarization. Here, we propose a Ti3C2Tx MXene anchoring method to manipulate the intermolecular interactions within the all-trans conformation of a polymer matrix. Employing phase-field simulation and molecular dynamics calculations, we show that OH surface terminations on the Ti3C2Tx nanosheets offer hydrogen bonding with the fluoropolymer matrix, leading to dipole alignment and enhanced net spontaneous polarization of the polymer-ceramic composites. We then translated this interfacial bonding strategy into electrospinning to boost the piezoelectric response of samarium doped Pb (Mg1/3Nb2/3)O3-PbTiO3/polyvinylidene fluoride composite nanofibers by 160% via Ti3C2Tx nanosheets inclusion. With excellent piezoelectric and mechanical attributes, the as-electrospun piezoelectric nanofibers can be easily integrated into the conventional shoe insoles to form a foot sensor network for all-around gait patterns monitoring, walking habits identification and Metatarsalgi prognosis. This work utilizes the interfacial coupling mechanism of intermolecular anchoring as a strategy to develop high-performance piezoelectric composites for wearable electronics.

Microstructured PVDF Film with Improved Performance as Flexible Infrared Sensor.

Polyvinylidene fluoride (PVDF) is a very promising material for fabricating flexible infrared sensors due to its ferroelectricity as well as excellent flexibility and low fabrication cost. This work focuses on improving PVDF's pyroelectric performance by creating microstructures in the film. Simulation results suggest that the pyroelectric response of PVDF film can be improved if micro groove, square-pit or sinusoidal patterns are created on the film surface, with the grooved film showing the best pyroelectric performance. Suggested by the simulation results, flexible PVDF samples with groove structure are prepared by casting the precursor solution on the mold with designed patterns. Measurement results demonstrate that the optimal microstructured PVDF film can improve its pyroelectric performance by as high as 146%, which is in good agreement with the simulations. This work provides an innovative way of achieving flexible infrared sensor devices with promoted performance based on pyroelectric polymers.

Optimizing Piezoelectric Nanocomposites by High-Throughput Phase-Field Simulation and Machine Learning.

Piezoelectric nanocomposites with oxide fillers in a polymer matrix combine the merit of high piezoelectric response of the oxides and flexibility as well as biocompatibility of the polymers. Understanding the role of the choice of materials and the filler-matrix architecture is critical to achieving desired functionality of a composite towards applications in flexible electronics and energy harvest devices. Herein, a high-throughput phase-field simulation is conducted to systematically reveal the influence of morphology and spatial orientation of an oxide filler on the piezoelectric, mechanical, and dielectric properties of the piezoelectric nanocomposites. It is discovered that with a constant filler volume fraction, a composite composed of vertical pillars exhibits superior piezoelectric response and electromechanical coupling coefficient as compared to the other geometric configurations. An analytical regression is established from a linear regression-based machine learning model, which can be employed to predict the performance of nanocomposites filled with oxides with a given set of piezoelectric coefficient, dielectric permittivity, and stiffness. This work not only sheds light on the fundamental mechanism of piezoelectric nanocomposites, but also offers a promising material design strategy for developing high-performance polymer/inorganic oxide composite-based wearable electronics.

MXene-Sponge Based High-Performance Piezoresistive Sensor for Wearable Biomonitoring and Real-Time Tactile Sensing.

Electrode microfabrication technologies such as lithography and deposition have been widely applied in wearable electronics to boost interfacial coupling efficiency and device performance. However, a majority of these approaches are restricted by expensive and complicated processing techniques, as well as waste discharge. Here, helium plasma irradiation is employed to yield a molybdenum microstructured electrode, which is constructed into a flexible piezoresistive pressure sensor based on a Ti3 C2 Tx nanosheet-immersed polyurethane sponge. This electrode engineering strategy enables the smooth transition between sponge deformation and MXene interlamellar displacement, giving rise to high sensitivity (1.52 kPa-1 ) and good linearity (r2  = 0.9985) in a wide sensing range (0-100 kPa) with a response time of 226 ms for pressure detection. In addition, both the experimental characterization and finite element simulation confirm that the hierarchical structures modulated by pore size, plasma bias, and MXene concentration play a crucial role in improving the sensing performance. Furthermore, the as-developed flexible pressure sensor is demonstrated to measure human radial pulse, detect finger tapping, foot stomping, and perform object identification, revealing great feasibility in wearable biomonitoring and health assessment.

Precision Glycoproteomics Reveals Distinctive N-Glycosylation in Human Spermatozoa.

Spermatozoon represents a very special cell type in human body, and glycosylation plays essential roles in its whole life including spermatogenesis, maturation, capacitation, sperm-egg recognition, and fertilization. In this study, by mapping the most comprehensive N-glycoproteome of human spermatozoa using our recently developed site-specific glycoproteomic approaches, we show that spermatozoa contain a number of distinctive glycoproteins, which are mainly involved in spermatogenesis, acrosome reaction and sperm:oocyte membrane binding, and fertilization. Heavy fucosylation is observed on 14 glycoproteins mostly located at extracellular and cell surface regions in spermatozoa but not in other tissues. Sialylation and Lewis epitopes are enriched in the biological process of immune response in spermatozoa, while bisected core structures and LacdiNAc structures are highly expressed in acrosome. These data deepen our knowledge about glycosylation in spermatozoa and lay the foundation for functional study of glycosylation and glycan structures in male infertility.

Simultaneous Biomechanical and Biochemical Monitoring for Self-Powered Breath Analysis.

The high moisture level of exhaled gases unavoidably limits the sensitivity of breath analysis via wearable bioelectronics. Inspired by pulmonary lobe expansion/contraction observed during respiration, a respiration-driven triboelectric sensor (RTS) was devised for simultaneous respiratory biomechanical monitoring and exhaled acetone concentration analysis. A tin oxide-doped polyethyleneimine membrane was devised to play a dual role as both a triboelectric layer and an acetone sensing material. The prepared RTS exhibited excellent ability in measuring respiratory flow rate (2-8 L/min) and breath frequency (0.33-0.8 Hz). Furthermore, the RTS presented good performance in biochemical acetone sensing (2-10 ppm range at high moisture levels), which was validated via finite element analysis. This work has led to the development of a novel real-time active respiratory monitoring system and strengthened triboelectric-chemisorption coupling sensing mechanism.

NiWO4 Microflowers on Multi-Walled Carbon Nanotubes for High-Performance NH3 Detection.

NiWO4 microflowers with a large surface area up to 79.77 m2·g-1 are synthesized in situ via a facile coprecipitation method. The NiWO4 microflowers are further decorated with multi-walled carbon nanotubes (MWCNTs) and assembled to form composites for NH3 detection. The as-fabricated composite exhibits an excellent NH3 sensing response/recovery time (53 s/177 s) at a temperature of 460 °C, which is a 10-fold enhancement compared to that of pristine NiWO4. It also demonstrates a low detection limit of 50 ppm; the improved sensing performance is attributed to the porous structure of the material, the large specific surface area, and the p-n heterojunction formed between the MWNTs and NiWO4. The gas sensitivity of the sensor based on daisy-like NiWO4/MWCNTs shows that the sensor based on 10 mol % (MWN10) has the best gas sensitivity, with a sensitivity of 13.07 to 50 ppm NH3 at room temperature and a detection lower limit of 20 ppm. NH3, CO2, NO2, SO2, CO, and CH4 are used as typical target gases to construct the NiWO4/MWCNTs gas-sensitive material and study the research method combining density functional theory calculations and experiments. By calculating the morphology and structure of the gas-sensitive material NiWO4(110), the MWCNT load samples, the vacancy defects, and the influence law and internal mechanism of gas sensitivity were described.

StrucGP: de novo structural sequencing of site-specific N-glycan on glycoproteins using a modularization strategy.

Precision mapping of glycans at structural and site-specific level is still one of the most challenging tasks in the glycobiology field. Here, we describe a modularization strategy for de novo interpretation of N-glycan structures on intact glycopeptides using tandem mass spectrometry. An algorithm named StrucGP is also developed to automate the interpretation process for large-scale analysis. By dividing an N-glycan into three modules and identifying each module using distinct patterns of Y ions or a combination of distinguishable B/Y ions, the method enables determination of detailed glycan structures on thousands of glycosites in mouse brain, which comprise four types of core structure and 17 branch structures with three glycan subtypes. Owing to the database-independent glycan mapping strategy, StrucGP also facilitates the identification of rare/new glycan structures. The approach will be greatly beneficial for in-depth structural and functional study of glycoproteins in the biomedical research.

Optimizing K0.5Na0.5NbO3 Single Crystal by Engineering Piezoelectric Anisotropy.

K0.5Na0.5NbO3 is considered as one of the most promising lead-free piezoelectric ceramics in the field of wearable electronics because of its excellent piezoelectric properties and environmental friendliness. In this work, the temperature-dependent longitudinal piezoelectric coefficient d33* was investigated in K0.5Na0.5NbO3 single crystals via the Landau-Ginzburg-Devonshire theory. Results show that the piezoelectric anisotropy varies with the temperature and the maximum of d33max* deviates from the polar direction of the ferroelectric phase. In the tetragonal phase, d33maxt* parallels with cubic polarization direction near the tetragonal-cubic transition region, and then gradually switches toward the nonpolar direction with decreasing temperatures. The maximum of d33o* in the orthorhombic phase reveals a distinct varying trend in different crystal planes. As for the rhombohedral phase, slight fluctuation of the maximum of d33r* was observed and delivered a more stable temperature-dependent maximum d33maxr* and its corresponding angle θmax in comparison with tetragonal and orthorhombic phases. This work not only sheds some light on the temperature-dependent phase transitions, but also paves the way for the optimization of piezoelectric properties in piezoelectric materials and devices.

Self-Powered Respiration Monitoring Enabled By a Triboelectric Nanogenerator.

In mammals, physiological respiration involves respiratory cycles of inhaled and exhaled breaths, which has traditionally been an underutilized resource potentially encompassing a wealth of physiologically relevant information as well as clues to potential diseases. Recently, triboelectric nanogenerators (TENGs) have been widely adopted for self-powered respiration monitoring owing to their compelling features, such as decent biocompatibility, wearing comfort, low-cost, and high sensitivity to respiration activities in the aspect of low frequency and slight amplitude body motions. Physiological respiration behaviors and exhaled chemical regents can be precisely and continuously monitored by TENG-based respiration sensors for personalized health care. This article presents an overview of TENG enabled self-powered respiration monitoring, with a focus on the working principle, sensing materials, functional structures, and related applications in both physical respiration motion detection and chemical breath analysis. Concepts and approaches for acquisition of physical information associated with respiratory rate and depth are covered in the first part. Then the sensing mechanism, theoretical modeling, and applications related to detection of chemicals released from breathing gases are systemically summarized. Finally, the opportunities and challenges of triboelectric effect enabled self-powered respiration monitoring are comprehensively discussed and criticized.

Walking energy harvesting and self-powered tracking system based on triboelectric nanogenerators.

Due to the extensive energy consumption and high population density in modern cities, the collection and use of scattered walking energy from the stream of people is crucial for the development of a green ecological city. Herein, a flexible undulated electrode-based triboelectric nanogenerator (u-TENG) was integrated to the floor to scavenge walking energy from pedestrians, promoting the ordered collection of disordered and scattered energy. Driven by the steps of human walking, the output of the as-fabricated u-TENG are an open-circuit voltage of 86 V and a short-circuit current of 6.2 µA, which are able to continuously light up 110 light-emitting diode bulbs. In addition, a self-powered location-tracking system was prepared for pedestrian volume counting and passenger tracing with the purpose of reducing energy consumption in public areas. The proposed walking energy harvesting device is flexible, feasible, and unaffected by season, climate, or location. This work not only proposes a strategy for mechanical energy harvesting in public areas, including subway stations, hospitals, shopping malls, and business streets, but also offers a novel solution for smart cities and low-carbon transportation alternatives.

Alveolus-Inspired Active Membrane Sensors for Self-Powered Wearable Chemical Sensing and Breath Analysis.

Fossil fuel internal combustion engines generate and release a huge amount of nitrogen dioxide, leading to respiratory and allergic diseases such as asthma, pneumonia, and possibly tuberculosis. Here we develop an alveolus-inspired membrane sensor (AIMS) for self-powered wearable nitrogen dioxide detection and personal physiological assessment. The bionic AIMS exhibits an excellent sensitivity up to 452.44%, a good linearity of 0.976, and superior selectivity under a NO2 concentration of 50 ppm. Furthermore, the AIMS can also be employed to diagnose human breath behaviors for breath analysis. The fundamental sensing mechanism is established using a combination of thermodynamic analysis, finite-element analysis, and phase-field simulations. It is found that the depolarization field inside the sensitive materials plays a crucial role in the self-powered gas-sensing performance. This work not only provides an efficient, low-cost, portable, and environmentally friendly means for active environmental assessment and personal biomonitoring but also provides a deep understanding of the gas-sensing mechanisms.

Ultraviolet to Long-Wave Infrared Photodetectors Based on a Three-Dimensional Dirac Semimetal/Organic Thin Film Heterojunction.

In this work, high-performance ultraviolet to long-wave infrared (UV-LIR) devices based on an N-type three-dimensional (3D) Dirac semimetal Cd3As2 and P-type organic (small molecules and polymers) heterojunction are prepared. Primarily, the photodetector shows a broadband photoresponse from 365 to 10600 nm. The optimized device responsivity is 729 mA/W, along with a fast response time of 282 µs and a high on-off ratio of 6268, which are 2 orders of magnitude higher than those previously reported for a 3D Dirac semimetal-based device. In the LIR region (10600 nm), the responsivity and on-off ratio can reach 81.3 mA/W and 100, respectively. In addition, the time-resolved femtosecond pump detection technology is used to reveal the relaxation time of Cd3As2/organic thin films (4.30 ps), indicating that Cd3As2/organic thin films have great potential for the manufacture of fast IR devices. These results demonstrate that the 3D Dirac semimetal/organic thin film heterojunction photodetectors will be a feasible solution for high-speed and broadband photodetectors in large-array imaging.

A New Model and Its Application for the Dynamic Response of RGO Resistive Gas Sensor.

An reduced graphene oxide (RGO) resistive gas sensor was prepared to detect ammonia at room temperature, the result indicated that the desorption of gas (NH 3 ) molecules from a graphene-based sensor was difficult, which lead to a baseline drift. The responses of different concentrations were compared and studied. It was found that both the response rate and its acceleration were affected by the gas concentration. An Intermolecular Forces Based Model was established to explain the adsorption and desorption dynamic response curves. A new method was proposed based on this model. The first and second derivative extrema (FSDE) of the response curve can be attained quickly to calibrate the gas concentrations. The experiment results demonstrated that this new method could eliminate the baseline drift and was capable of increasing the efficiency of gas calibration significantly.

Self-Powered, Wireless, Remote Meteorologic Monitoring Based on Triboelectric Nanogenerator Operated by Scavenging Wind Energy.

Meteorologic monitoring plays a key role on weather forecast and disaster warning and deeply relies on various sensor networks. It is an optimal choice that grabbing the environmental energy around sensors for driving sensor network. Here, we demonstrate a self-powered, wireless, remote meteorologic monitoring system based on an innovative TENG. The TENG has been proved capable of scavenging wind energy and can be employed for self-powered, wireless meteorologic sounding. This work not only promotes the development of renewable energy harvesting, but also exploits and enriches promising applications based on TENGs for self-powered, wireless, remote sensing.