Highly Efficient Phosphorescent Organic Light-Emitting Diodes Using Benzo[4',5']imidazo[2',1':2,3]imidazo[4,5,1-jk]carbazole as a Rigid and Effective Electron Acceptor in Bipolar Host.

A novel bipolar host architecture was investigated to improve the external quantum efficiency (EQE) of green phosphorescent organic light-emitting diodes (PhOLEDs). The host was developed by incorporating carbazole as a hole-transport unit and fused rigid benzo[4',5']imidazo[2',1':2,3]imidazo[4, 5, 1-jk]carbazole (BzICz) as a new electron transport unit. The primary goal of the BzICz-based host design was to achieve a high triplet energy and bipolar charge transport characteristics. The green PhOLEDs fabricated using the new BzICz and carbazole-based host demonstrated a high EQE of 26.6% due to their high triplet energy and good bipolar charge transporting characteristics.

Highly efficient and stable deep-blue organic light-emitting diode using phosphor-sensitized thermally activated delayed fluorescence.

Phosphorescent and thermally activated delayed fluorescence (TADF) blue organic light-emitting diodes (OLEDs) have been developed to overcome the low efficiency of fluorescent OLEDs. However, device instability, originating from triplet excitons and polarons, limits blue OLED applications. Here, we develop a phosphor-sensitized TADF emission system with TADF emitters to achieve high efficiency and long operational lifetime. Peripheral carbazole moieties are introduced in conventional multi-resonance-type emitters containing one boron atom. The triplet exciton density of the TADF emitter is reduced by facilitating reverse intersystem crossing, and the Förster resonant energy transfer rate from phosphor sensitizer is enhanced by high absorption coefficient of the emitters. The emitter exhibited an operational lifetime of 72.9 hours with Commission Internationale de L'Eclairage chromaticity coordinate y = 0.165, which was 6.6 times longer than those of devices using conventional TADF emitters.