Characterizations for the photothermal effect of Rhodamine 6G using white-light interferometry and windowed Fourier transform.

Photothermal phenomenon is one of the natural responses in light-matter interactions in which the energy of the incident light is converted into heat, resulting in a temperature increase in the illuminated material. This effect has a direct influence on the refractive index of the material such that its change of spectral dependency with temperature can be exploited for different applications. However, it is also important to separate/identify the thermal effect from the optical/electronic resonance effect to expand potential applications of light-matter interactions. In this work, we demonstrate the use of a white-light interferometry approach combined with a windowed Fourier transform method and a consistency-checking peak-fitting method to obtain the refractive index of an Rh6G-ethanol dye solution with a sensitivity of about ∼10-6 (RIU) for the visible range. Moreover, we also perform both static and dynamic measurements to study the photothermal effect of the Rh6G solution under external excitation. Importantly, we separate the optical and thermal effects due to the external excitation and obtain very good agreement with the experimental results by modeling the relative refractive index of the Rh6G solution with an expression consisting of spectrally a Fano-like resonance term and a linear dependent thermal term. We find that the response due to the optical effect is about ∼0.2 × 10-3 of that due to the thermal effect in the low-light regime. Our approach to separating the optical and thermal effects could shed light on other fields for potential applications through precision measurements of the transmission phase or refractive index.

Polarization coincidence images from metasurfaces with HOM-type interference.

Metasurfaces provide a promising route for structuring light and generating holograms with designed amplitude, phase, and polarization profiles, leading to a versatile platform for integrating and constructing optical components beyond the conventional ones. At the same time, incorporating coincidence in imaging allows a high signal-to-noise ratio for imaging in very low light levels. As beneficial from the recent development in both metasurfaces and single-photon avalanche diode (SPAD) cameras, we combine the polarization-sensitive capability of metasurfaces with Hong-Ou-Mandel (HOM)-type interference in generating images with tailor-made two-photon interference and polarization coincidence signatures. By using orthogonal linear-polarized photons as incidence, correlated, anticorrelated, and uncorrelated polarization coincidence features can be observed within the same image from the pairwise second-order coherence statistics across different pixels of the image. Our work adds polarization to the demonstrated amplitude and phase sensitivity in the domain of "HOM microscopy" and can be useful for biological and security applications.

Tailor-made unitary operations using dielectric metasurfaces.

Qubit operation belonging to unitary transformation is the fundamental operation to realize quantum computing and information processing. Here, we show that the complex and flexible light-matter interaction between dielectric metasurfaces and incident light can be used to perform arbitrary U(2) operations. By incorporating both coherent spatial-mode operation together with two polarizations on a single metasurface, we further extend the discussion to single-photon two-qubit U(4) operations. We believe the efficient usage of metasurfaces as a potential compact platform can simplify optical qubit operation from bulky systems into conceptually subwavelength elements.

Quantitative measurement and mechanism analysis of the high-efficiency laser propulsion of a graphene sponge.

Laser propulsion of a graphene sponge shows tremendous potential in propellant-free flight, photoresponsive actuators and micro opto-electro mechanical systems. However, the mechanism is still in dispute and the propulsion force hasn't been accurately measured, seriously hindering its development. This work develops a quantitative method to measure the propulsion force. It is found that the characteristics of the force agree qualitatively with the Knudsen force due to laser-induced thermal nonequilibrium in rarefied gas, which might be another possible mechanism of laser propulsion of a graphene sponge. Also, this kind of laser propulsion is highly efficient, stable and sustainable.

Exceptional point-based plasmonic metasurfaces for vortex beam generation.

An exceptional point occurring in a tailor-made lossy optical system has been recently found to alter optical properties in counter-intuitive ways. In the context of tunable plasmonic devices, exceptional points can be useful as a driving mechanism to enhance tunability. Here, we experimentally demonstrate how a plasmonic exceptional point can be incorporated in metasurface Q-plates to have the generated vortex beam tuned through a change of structural parameter. We have observed an orbital rotation in the far-field by 45 degrees in crossing the exceptional point. We expect a new generation of tunable plasmonic devices in polarization control, beam structuring and holograms, which can take advantage of the huge sensitivity from exceptional points.

Circular Phase-Dichroism of Chiral Metasurface Using Birefringent Interference.

Circular phase-dichroism (CPD) has been suggested for the characterization of chiral metasurfaces in supplementing the conventional circular dichroism (CD). Conventional CD probes the bulk properties while the CPD, reported recently in 2D chiral metasurfaces using an air-gap Fabry-Perot setup, is based on the surface properties. Here we propose and demonstrate a robust birefringent interference approach to obtain the CPD by replacing the air-gap with a uniaxial birefringent material in which interference is realized by the difference in the refractive indexes for the ordinary and extraordinary components of the material. We measure the transmission phases of metasurfaces fabricated on birefringent sapphire substrates and obtain clear CPDs for chiral metasurfaces but vanishing for achiral metasurfaces. Importantly, our approach can be applied to metasurfaces fabricated on nonbirefringent substrates by add-on birefringent materials. We confirm our results by a Jones matrix method using data obtained from full-wave simulations, and good agreements with experiments are obtained.

Characterization of free-standing 1D photonic crystals using an effective medium approach.

Photonic crystals (PCs) are usually fabricated on bulk substrates which break the symmetry of the PC system for incidence from either side of the PCs. Here we report the fabrication of a free-standing 1D layered dielectric PC by using a two-beam holographic interference method. The free-standing PC exhibits distinct photonic bandgaps as well as Fabry-Perot oscillations in the photonic bands. Furthermore, we show that the PC can be modeled by an effective medium approach and obtain the reflection phase for the photonic bands of the PC. We have also performed full-wave simulations for the PC and obtained very good agreement with the experiment. The free-standing PC enables a better comparison between experiment and simulation, and importantly, it is flexible enabling new applications for PCs.

Characterization of thermal bump due to surface plasmon resonance.

Surface plasmon resonance (SPR) has found wide applications in sensing down to molecular level due to its extreme sensitivity to change of dielectric properties. An unavoidable effect in SPR is surface deformation (thermal bump) due to local heating by incident laser light used in SPR. In addition, changes in the reflection phase from the metal film used in SPR could also contribute to the SPR signal, and thus proper handling of the SPR signal is very important in order to broaden the potential applications of SPR. Here we report a simple Fabry Perot (FP) interference technique for measuring, simultaneously, the thermal bump height as well as the reflection phase shift of gold film used in SPR. We find that the shift of the FP signal is dominated by the effect of the thermal bump while it is small for the effect of the reflection phase shift due to change of dielectric property of the metal. To support our experimental results, we have also performed model simulation for the SPR system and obtain good agreement with the experiment. As both amplitude and phase can be measured, our method could lead to better characterization of SPR and can also be applied to the study of active metasurfaces under external excitation.

Experimental demonstration of angular momentum-dependent topological transport using a transmission line network.

Novel classical wave phenomenon analogs of the quantum spin Hall effect are mostly based on the construction of pseudo-spins. Here we show that the non-trivial topology of a system can also be realized using orbital angular momentum through a coupling between the angular momentum and the wave vector. The idea is illustrated with a tight-binding model and experimentally demonstrated with a transmission line network. We show experimentally that even a very small network cluster exhibits angular momentum-dependent one-way topological edge states, and their properties can be described in terms of local Chern numbers. Our work provides a new mechanism to realize counterparts of the quantum spin Hall effect in classical waves and may offer insights for other systems.

Three dimensional chiral plasmon rulers based on silver nanorod trimers.

The symmetry dependences of plasmon excitation modes are studied in 3D silver nanorod trimers. The degenerate plasmon modes split into chiral modes by breaking the inversion and mirror symmetry of the nanorod trimer through translation and/or rotation of the middle rod. With a translation operation, successive evolution of the circular dichroism (CD) spectrum can be achieved through gradual breaking of the inversion symmetry. An additional rotation operation produces even dramatic spectral changes due to breaking a quasi-mirror symmetry resulted from the same angular distance of the middle rod to the top and bottom rods. Especially, pairs of new chiral modes can be excited due to the contact of the middle rod with the top-bottom rod pair. The spectral changes in the simulations, which are also demonstrated experimentally, envision the 3D chiral nanorod trimer system as plasmon ruler for spatial configuration retrieval and dynamic bio-process analysis at the single molecule level.

Correction of numerical aperture effect on reflection phase measurement using a thick-gap Fabry-Perot etalon.

We propose a method for the measurement of the reflection phase using a thick-gap Fabry-Perot (FP) etalon interferometry technique with correction for the numerical aperture effect of the optical setup. The setup is first calibrated using a known sample by comparing the reflectance from a two-beam interference model for the FP etalon with experimental data. We then apply the correction to a sample of interest and obtain the reflection phase of the sample. Our method can be used to measure the reflection phase of a small sample and could lead to practical applications in optical characterization of metamaterials. Moreover, the principle of our approach could be generalized to other systems in the correction of numerical aperture effect due to microscopic objectives.

Controlling interface states in 1D photonic crystals by tuning bulk geometric phases.

There is no known simple rule that assures the existence of interface states in photonic crystals (PCs). We show here that one can control the existence or absence of interface states in 1D PCs through engineering the bulk geometrical phase such that interface states can be guaranteed in some or all photonic bandgaps. We verify experimentally the interface state design paradigm in 1D multilayered PCs fabricated by electron beam vapor deposition. We obtain the geometrical phases by measuring the reflection phases at the bandgaps of the PCs and achieve good agreement with the theory. Our approach could provide a platform for generating a PC interface state for various applications.

Measurement of reflection phase using thick-gap Fabry-Perot etalon.

We report measurement of the reflection phase of a dielectric (glass)/titanium (Ti) surface in the visible wavelength using a thick-gap Fabry-Perot (FP) interferometry technique. Using a two-beam interference model for the reflection peaks and troughs of the FP etalon, we obtain the air-gap spacing of the etalon and, more importantly, the reflection phase of the etalon substrate. We find systematic dependence of the as-measured reflection phase on the air-gap spacing due to the numerical aperture effect of the measuring objective. However, the relative reflection phase of Ti with respect to glass is independent of the air-gap spacing. As a demonstration of our approach in the optical characterization of small metamaterial samples, we also measure the reflection phase of a micron-sized 2D Au sawtooth nanoarray. The experiment is in good agreement with the model simulation.

Multipolar Effects in the Optical Active Second Harmonic Generation from Sawtooth Chiral Metamaterials.

Based on the facts that chiral molecules response differently to left- and right-handed circular polarized light, chiroptical effects are widely employed for determining structure chirality, detecting enantiomeric excess, or controlling chemical reactions of molecules. Compared to those in natural materials, chiroptical behaviors can be significantly amplified in chiral plasmonic metamaterials due to the concentrated local fields in the structure. The on-going research towards giant chiroptical effects in metamaterial generally focus on optimizing the field-enhancement effects. However, the observed chiroptical effects in metamaterials rely on more complicated factors and various possibilities towards giant chiroptical effects remains unexplored. Here we study the optical-active second harmonic generation (SHG) behaviors in a pair of planar sawtooth gratings with mirror-imaged patterns. Significant multipolar effects were observed in the polarization-dependent SHG curves. We show that the chirality of the nanostructure not only give rise to nonzero chiral susceptibility tensor components within the electric-dipole approximation, but also lead to different levels of multipolar interactions for the two orthogonal circular polarizations that further enhance the nonlinear optical activity of the material. Our results thus indicate novel ways to optimize nonlinear plasmonic structures and achieve giant chiroptical response via multipolar interactions.

[Application Progress of Holographic Lithgraphy in Fabrication of Micro-Nano Photonic Structures].

Micro-nano photonic structures are developing vigorously based on the progress of photonics, semiconductor physics and microfabrication technology. A series of results are achieved in structure characterization, theory, and fabrication of them. Most high quality photonic structures are man-made ones; however, there are still some challenges in fabricating artificial large-area and high-quality photon materials. With the advantages of photonic structure processing technology, holographic lithography, a low-cost, time-saving and high-efficiency microfabrication method, performs superior application potentials in making metamaterials as well as photonic crystal templates. In this article, we introduced the principles of holographic lithography and described the applications in fabricating various micro-nano photonic structures, such as three dimensional face-center-cubic, wood-pile, diamond-like photonic crystals, as well as quasi-crystalline structure, chiral metamaterials and periodic defect-mode structures. Moreover, the applications of some structures in solar cell and optical fiber sensing are discussed. The success of fabricating micro-nano photonic structures by holographic lithography would pave the way for more applications of these structures in wide fields.

Determination of Zak phase by reflection phase in 1D photonic crystals.

For a one-dimensional (1D) periodic system with inherent mirror symmetry, the value of the geometric "Zak" phase in a bulk band is related to the sign of reflection phase for wavelengths inside the bandgaps sandwiching the bulk band. Here, we designed an interference setup which allows us to measure the reflection phase of 1D phonic crystal fabricated for the optical range; this, in turn, enabled us to determine the Zak phases of the bands. We then found interface states whose existence can be traced to the topological properties of the bandgaps and the geometric phases of the bulk bands.

Giant plasmonic circular dichroism in Ag staircase nanostructures.

We demonstrate large circular dichroism (CD) in the visible range resulting from electromagnetic couplings in three-dimensional Ag staircase nanostructures. Analytical calculations using effective constitutive parameters show that the CD originates from chiral resonances of the staircase in which the induced magnetic dipole moment has components parallel or antiparallel to the induced electric dipole moment. The strength of the coupling as well as the CD can be tuned by varying the configuration (e.g. the strip width) of staircase nanostructure. More importantly we are able to realize such chiral resonances with large CD in the visible range in topologically similar chiral nanostructures fabricated using a simple shadowing vapor deposition method. Our simple staircase model demonstrates the effect of couplings between electric and magnetic dipole moments in producing large chiral responses in 3D nanostructures and can enhance the understanding of hybrid chiral optical systems.

Optical activities of large-area SU8 microspirals fabricated by multibeam holographic lithography.

We report on the fabrication of large-area microspirals in SU8 photoresist using a 6+1 beam holographic lithography (HL) technique involving the interference of six linearly polarized side beams and one circularly polarized central beam. In contrast to common photoresist-substrate (glass) configuration, the spirals are fabricated on a substrate with a precured thin SU8 photoresist. This SU8-SU8-glass configuration strengthens the attachment of the spirals to the substrate, and hence enhances the quality of the fabricated spirals. The fabricated SU8 microspirals exhibit large optical activities with a polarization rotation close to 10 deg and a circular dichroism of about 0.5 in the visible range. Our precured substrate method could lift the limitations of the HL method in fabricating large and uniform microstructures or nanostructures.

Direct and seamless coupling of TiO2 nanotube photonic crystal to dye-sensitized solar cell: a single-step approach.

A TiO(2) nanotube layer with a periodic structure is used as a photonic crystal to greatly enhance light harvesting in TiO(2) nanotube-based dye-sensitized solar cells. Such a tube-on-tube structure fabricated by a single-step approach facilitates good physical contact, easy electrolyte infiltration, and efficient charge transport. An increase of over 50% in power conversion efficiency is obtained in comparison to reference cells without a photonic crystal layer (under similar total thickness and dye loading).

Q-factor enhancement in a one-dimensional photonic crystal cavity with embedded planar plasmonic metamaterials.

We report Q-factor enhancement in a one-dimensional (1D) photonic crystal (PC) cavity by embedding electromagnetic-induced-transparency (EIT) planar plasmonic metamaterials in the cavity. Microwave experiments show tenfold Q-factor enhancements, confirming the numerical simulations. More importantly, the Q-factor enhancement is mainly due to both the longitudinal and lateral confinements contributed by the 1D PC cavity and the planar EIT metamaterials, respectively. The combined PC-EIT structure with a prominent cavity figure of merit may find new applications in nonlinear optics, cavity quantum electrodynamics, and low-threshold lasers.