Digital Self-Interference Canceler with Joint Channel Estimator for Simultaneous Transmit and Receive System.

Simultaneous transmit and receive wireless communications have been highlighted for their potential to double the spectral efficiency. However, it is necessary to mitigate self-interference (SI). Considering both the SI channel and remote transmission (RT) channel need to be estimated before equalizing the received signal, we propose two adaptive algorithms for linear and nonlinear self-interference cancellation (SIC), based on a multi-layered joint channel estimator structure. The proposed algorithms estimate the RT channel while performing SIC, and the multi-layered structure ensures improved performance across various interference-to-signal ratios. The M-estimate function enhances the robustness of the algorithm, allowing it to converge even when affected by impulsive noise. For nonlinear SIC, this paper introduces an adaptive algorithm based on generalized Hammerstein polynomial basis functions. The simulation results indicate that this approach achieves a better convergence speed and normalized mean squared difference compared to existing SIC methods, leading to a lower system bit error rate.

A Sparse Shared Aperture Design for Simultaneous Transmit and Receive Arrays with Beam Constraints.

The utilization of efficient digital self-interference cancellation technology enables the simultaneous transmit and receive (STAR) phased array system to meet most application requirements through STAR capabilities. However, the development of application scenario requirements makes array configuration technology for STAR phased arrays increasingly important. Thus, this paper proposes a sparse shared aperture STAR reconfigurable phased array design based on beam constraints which are achieved by a genetic algorithm. Firstly, a design scheme for transmit and receive arrays with symmetrical shared apertures is adopted to improve the aperture efficiency of both transmit and receive arrays. Then, on the basis of shared aperture, sparse array design is introduced to further reduce system complexity and hardware costs. Finally, the shape of the transmit and receive arrays is determined by constraining the side lobe level (SLL), main lobe gain, and beam width. The simulated results indicate that the SLL of the transmit and receive patterns under beam-constrained design have been reduced by 4.1 dBi and 7.1 dBi, respectively. The cost of SLL improvement is a reduction in transmit gain, receive gain, and EII of 1.9 dBi, 2.1 dBi, and 3.9 dB, respectively. When the sparsity ratio is greater than 0.78, the SLL suppression effect is also significant, and the attenuation of EII, transmit, and receive gains do not exceed 3 dB and 2 dB, respectively. Overall, the results demonstrate the effectiveness of a sparse shared aperture design based on beam constraints in producing high gain, low SLL, and low-cost transmit and receive arrays.

Insights into Antiperovskite Ni3 In1-x Cux N Multi-Crystalline Nanoplates and Bulk Cubic Particles as Efficient Electrocatalysts on Hydrogen Evolution Reaction.

Intrinsic hydrogen evolution reaction (HER) activity and the mechanism of antiperovskite Ni3 In1-x Cux N bulk cubic particles and multi-crystalline nanoplates are thoroughly investigated. Stoichiometric Ni3 In0.6 Cu0.4 N reaches the best HER performance, with an overpotential of 102 mV in its multi-crystalline nanoplates obtained from the LDH-derived method, and 143 mV in its bulk cubic particles from the citric method. DFT calculation reveals that Ni-In or Ni-Cu paired on the (100) plane serve as primary active sites. The Ni-Cu pair exhibits stronger OH* and H* affinity that correspondingly reduce OH* and H* adsorption free energy. Introducing specific amounts of the Ni-Cu pair, that is In:Cu = 0.6:0.4 in Ni3 In0.6 Cu0.4 N, can optimize OH* and H* adsorption free energy to facilitate water dissociation in the HER process, while avoiding OH* adsorption getting too strong to block active sites. Besides, Ni3 In0.6 Cu0.4 N turns the water adsorption step spontaneous, which may be attributed to the shifted d-band center and polarizing effect from surface In-Cu charge distribution. This work expands the scope for material design in an antiperovskite system by tailoring the chemical components and morphology for optimal reaction free energy and performance.

Puffing Up Hollow Carbon Nanofibers with High-Energy Metal-Organic Frameworks for Capacitive-Dominated Potassium-Ion Storage.

Nitrogen-doped carbon materials with abundant defects and strong potassium adsorption ability have been recognized as potential anodes for potassium ion batteries (PIBs). However, the limited content and uncontrolled type of nitrogen-doped sites hinder the further performance improvement of PIBs. Herein, this work proposes nitrogen phosphorous co-doped hollow carbon nanofibers (PNCNFs) derived from high-energy metal-organic frameworks (MOFs) with an ultra-high nitrogen content of 19.52 wt% and a high portion of more reactive pyridinic N sites. Furthermore, the highly open architecture exploded by released gases from high-energy MOFs provides sufficient edge sites to settle the N atoms and further form pyridinic N sites induced by phosphorous dopants. The resulting PNCNFs achieve excellent potassium ion storage performance with high reversible capacity (466.2 mAh g-1 ), superb rate capability (244.4 mAh g-1 at 8 A g-1 ), and excellent cycling performance (294.6 mAh g-1 after 3250 cycles). The density functional theory calculation reveals that the N/P defects enhance the potassium adsorption ability and improve the conductivity.

A Metal-Organic Framework Nanorod-Assembled Superstructure and Its Derivative: Unraveling the Fast Potassium Storage Mechanism in Nitrogen-Modified Micropores.

3D carbon-based materials with multiscale hierarchy are promising electrode materials for electrochemical energy storage and conversion applications, but the synthesis in an efficient and large-scale way is still a great challenge. Herein, a carbon nanorod-assembled 3D superstructure is facilely fabricated by morphology-preserving conversion of a metal-organic framework (MOF) nanorod-assembled superstructure. The MOF superstructure can be fabricated in one-pot synthesis with high reproducibility and high yield by precise control of the MOF nucleation and growth. Its derived carbon inherits the nanorod-assembled superstructure and possesses abundant micropores and nitrogen doping, which can serve as a high-performance anode material for fast potassium storage. The superiority of the superstructure and the synergism of micropore capturing and nitrogen anchoring are verified both experimentally and theoretically.

A Robust Design for Aperture-Level Simultaneous Transmit and Receive with Digital Phased Array.

Aperture-level simultaneous transmit and receive (ALSTAR) attempts to utilize adaptive digital transmit and receive beamforming and digital self-interference cancellation methods to establish isolation between the transmit and receive apertures of the single-phase array. However, the existing methods only discuss the isolation of ALSTAR and ignore the radiation efficiency of the transmitter and the sensitivity of the receiver. The ALSTAR array design lacks perfect theoretical support and simplified engineering implementation. This paper proposes an adaptive random group quantum brainstorming optimization (ARGQBSO) algorithm to simplify the array design and improve the overall performance. ARGQBSO is derived from BSO and has been ameliorated in four aspects of the ALSTAR array, including random grouping, initial value presets, dynamic probability functions, and quantum computing. The transmit and receive beamforming carried out by ARGQBSO is robust to all elevation angles, which reduces complexity and is conducive to engineering applications. The simulated results indicate that the ARGQBSO algorithm has an excellent performance, and achieves 166.8 dB of peak EII, 47.1 dBW of peak EIRP, and -94.6 dBm of peak EIS with 1000 W of transmit power in the scenario of an 8-element array.

Fabrication of Hollow CoP/TiOx Heterostructures for Enhanced Oxygen Evolution Reaction.

Transition-metal phosphides have flourished as promising candidates for oxygen evolution reaction (OER) electrocatalysts. Herein, it is demonstrated that the electrocatalytic OER performance of CoP can be greatly improved by constructing a hybrid CoP/TiOx heterostructure. The CoP/TiOx heterostructure is fabricated using metal-organic framework nanocrystals as templates, which leads to unique hollow structures and uniformly distributed CoP nanoparticles on TiOx . The strong interactions between CoP and TiOx in the CoP/TiOx heterostructure and the conductive nature of TiOx with Ti3+ sites endow the CoP-TiOx hybrid material with high OER activity comparable to the state-of-the-art IrO2 or RuO2 OER electrocatalysts. In combination with theoretical calculations, this work reveals that the formation of CoP/TiOx heterostructure can generate a pathway for facile electron transport and optimize the water adsorption energy, thus promoting the OER electrocatalysis.

Passive Location Resource Scheduling Based on an Improved Genetic Algorithm.

With the development of science and technology, modern communication scenarios have put forward higher requirements for passive location technology. However, current location systems still use manual scheduling methods and cannot meet the current mission-intensive and widely-distributed scenarios, resulting in inefficient task completion. To address this issue, this paper proposes a method called multi-objective, multi-constraint and improved genetic algorithm-based scheduling (MMIGAS), contributing a centralized combinatorial optimization model with multiple objectives and multiple constraints and conceiving an improved genetic algorithm. First, we establish a basic mathematical framework based on the structure of a passive location system. Furthermore, to balance performance with respect to multiple measures and avoid low efficiency, we propose a multi-objective optimal function including location accuracy, completion rate and resource utilization. Moreover, to enhance its practicability, we formulate multiple constraints for frequency, resource capability and task cooperation. For model solving, we propose an improved genetic algorithm with better convergence speed and global optimization ability, by introducing constraint-proof initialization, a penalty function and a modified genetic operator. Simulations indicate the good astringency, steady time complexity and satisfactory location accuracy of MMIGAS. Moreover, compared with manual scheduling, MMIGAS can improve the efficiency while maintaining high location precision.

Space-Confined Earth-Abundant Bifunctional Electrocatalyst for High-Efficiency Water Splitting.

Hydrogen generation from water splitting could be an alternative way to meet increasing energy demands while also balancing the impact of energy being supplied by fossil-based fuels. The efficacy of water splitting strongly depends on the performance of electrocatalysts. Herein, we report a unique space-confined earth-abundant electrocatalyst having the bifunctionality of simultaneous hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), leading to high-efficiency water splitting. Outperforming Pt/C or RuO2 catalysts, this mesoscopic, space-confined, bifunctional configuration is constructed from a monolithic zeolitic imidazolate framework@layered double hydroxide (ZIF@LDH) precursor on Ni foam. Such a confinement leads to a high dispersion of ultrafine Co3O4 nanoparticles within the N-doped carbon matrix by temperature-dependent calcination of the ZIF@LDH. We demonstrate that the OER has an overpotential of 318 mV at a current density of 10 mA cm-2, while that of HER is -106 mV @ -10 mA cm-2. The voltage applied to a two-electrode cell for overall water splitting is 1.59 V to achieve a stable current density of 10 mA cm-2 while using the monolithic catalyst as both the anode and the cathode. It is anticipated that our space-confined method, which focuses on earth-abundant elements with structural integrity, may provide a novel and economically sound strategy for practical energy conversion applications.

Highly Enhanced Photoelectrochemical Water Oxidation Efficiency Based on Triadic Quantum Dot/Layered Double Hydroxide/BiVO4 Photoanodes.

The water oxidation half-reaction is considered to be a bottleneck for achieving highly efficient solar-driven water splitting due to its multiproton-coupled four-electron process and sluggish kinetics. Herein, a triadic photoanode consisting of dual-sized CdTe quantum dots (QDs), Co-based layered double hydroxide (LDH) nanosheets, and BiVO4 particles, that is, QD@LDH@BiVO4, was designed. Two sets of consecutive Type-II band alignments were constructed to improve photogenerated electron-hole separation in the triadic structure. The efficient charge separation resulted in a 2-fold enhancement of the photocurrent of the QD@LDH@BiVO4 photoanode. A significantly enhanced oxidation efficiency reaching above 90% in the low bias region (i.e., E < 0.8 V vs RHE) could be critical in determining the overall performance of a complete photoelectrochemical cell. The faradaic efficiency for water oxidation was almost 90%. The conduction band energy of QDs is ∼1.0 V more negative than that of LDH, favorable for the electron injection to LDH and enabling a more efficient hole separation. The enhanced photon-to-current conversion efficiency and improved water oxidation efficiency of the triadic structure may result from the non-negligible contribution of hot electrons or holes generated in QDs. Such a band-matching and multidimensional triadic architecture could be a promising strategy for achieving high-efficiency photoanodes by sufficiently utilizing and maximizing the functionalities of QDs.

Tunable two-color luminescence and host-guest energy transfer of fluorescent chromophores encapsulated in metal-organic frameworks.

Co-assembly of chromophore guests with host matrices can afford materials which have photofunctionalities different from those of individual components. Compared with clay and zeolite materials, the use of metal-organic frameworks (MOFs) as a host structure for fabricating luminescent host-guest materials is still at an early stage. Herein, we report the incorporation of a laser dye, 4-(dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran (DCM), into stilbene-based and naphthalene-based MOF systems. The resulting materials exhibit blue/red two-color emission, and the intensity ratio of blue to red fluorescence varies in different planes within the MOF crystal as detected by 3D confocal fluorescence microscopy. The observed changes in ratiometric fluorescence suggest the occurrence of energy transfer from MOF host to DCM molecules, which can be further confirmed by periodic density functional theoretical (DFT) calculations. Moreover, selective changes in luminescence behavior are observed on treating the guest@MOF samples with volatile organic compounds (methanol, acetone and toluene), indicating that these host-guest systems have potential applications as fluorescence sensors. It can be expected that by rational selection of MOF hosts and guest chromophores with suitable emissive colors and energy levels, a wide variety of multi-color luminescent and energy-transfer systems can readily be prepared in a similar manner.