Development of a tabletop time-of-flight mass spectrometer with an ion attachment ionization technique.

We report a new type of mass spectrometry based on a time-of-flight mass spectrometer combined with an ion attachment ionization technique (IA-TOF). In contrast to electron ionization mass spectra, IA-TOF mass spectra are not complicated by peaks due to fragmentation of the molecular ion; the adduct ion formed in IA does not fragment. We developed a tabletop IA-TOF system and evaluated its performance by analyzing specimens originally in the gas, liquid, and solid phases. We obtained fragment-free spectra covering a mass range up to m/z 3400 with a mass resolution of about 4700. Our IA-TOF system realizes accurate and versatile real-time mass spectrometry.

Direct electron acceleration by stochastic laser fields in the presence of self-generated magnetic fields.

A simple direct acceleration model is proposed, taking into account the stochastic phase disturbance of the coherent driving laser fields. A relativistic single particle simulation shows that plasma electrons are efficiently accelerated far above the ponderomotive energy. The energy and momentum distributions of the accelerated electrons are derived to examine the effects of the self-generated magnetic field on the characteristics of the electron beams. In addition to the beam collimation effect, the magnetic field is found to further enhance the electron acceleration, resulting in the generation of ultrahigh energy electrons.