The regulation of CuSNPs' interface for further enhancing mechanical and photothermal conversion properties of chitosan/@CuSNPs hybrid fibers.

Our previous study has demonstrated that the microstructure of copper sulfide nanoparticles (CuSNPs) can be controlled to enhance mechanical and photothermal conversion properties of chitosan (CS)/CuSNPs hybrid fibers. However, achieving optimal dispersion and compatibility of CuSNPs within a CS matrix remains a challenge, this study aims to improve dispersion and compatibility by modifying the CuSNPs' interface, thereby enhancing mechanical and photothermal conversion properties of hybrid fibers. The interfaces of @CuSNPs (CuS@Xylan NPs, CuS@SA NPs, and CuS@PEG NPs) contain hydroxyl groups, facilitating the hydrogen bonds formation with the CS matrix. The dispersibility is further enhanced by the synergistic effect of xylan and SA's anionic charges with cationic chitosan. Notably, the viscosity of the CS/@CuSNPs hybrid spinning solution is significantly enhanced, resulting in improved breaking strength for initial hybrid fibers. Specifically, the breaking strength of CS/CuS@Xylan NPs hybrid fibers reaches 1.4 cN/dtex, exhibiting a 42.86 % and 20.6 % increase over CS and CS/CuSNPs hybrid fibers. Simultaneously, the CS/CuS@Xylan NPs hybrid fibers exhibit exceptional photothermal conversion performance, surpassing that of CS fibers by 5.2 times and CS/CuSNPs hybrid fibers by 1.4 times. The regulation of interface modification is an efficient approach to enhance the tensile strength and photothermal conversion properties of CS/CuSNPs hybrid fibers.

Chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with improved mechanical and photo-thermal conversion properties via tuning CuSNPs' morphological structures.

Conventional textiles are inadequate for maintaining warmth in extremely cold conditions. Therefore, the development of photo-thermal fibers for personal thermal management textiles has emerged as an urgent need. Herein, novel chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with photo-thermal function were fabricated successfully. Significantly, our study demonstrated that the tensile and photo-thermal conversation properties of the CS/CuSNPs hybrid fibers could be effectively regulated by altering the CuSNPs` morphological structures. Compared with other CuSNPs (tube-like, sphere-like, and flower-like), the plate-like CuSNPs with smooth surfaces and uniform nanometer size played a significant role by scattering incident light in the fibers as a secondary light source for CuSNPs absorbance. Thus, under IR light irradiation at a power density of 1.0 W/cm2, the surface temperature of CS/0.1 wt% plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C, which was more than 4 times of the pure CS fibers. And the breaking strength and initial modulus of CS/0.1 wt% plate-like CuSNPs hybrid fibers increased by more than 18.37 and 6.88 % compared with the nascent CS fibers. This study develops a novel and effective strategy to tune the photo-thermal and tensile properties of CS hybrid fibers without incorporating more content or additives.