Heterogeneity in glacier thinning and slowdown of ice movement in the Garhwal Himalaya, India.

Limited ground-based surveys and extensive remote sensing analyses have confirmed glacier thinning in the Garhwal Himalaya. More detailed studies on specific glaciers and the drivers of reported changes are essential to comprehend small-scale differences in the effects of climatic warming on Himalayan glaciers. We computed elevation changes and surface flow distribution for 205 (≥0.1 km2) glaciers in the Alaknanda, Bhagirathi, and Mandakini basins, all located in the Garhwal Himalaya, India. This study also investigates a detailed integrated analysis of elevation changes and surface flow velocities for 23 glaciers with varying characteristics to understand the impact of ice thickness loss on overall glacier dynamics. We observed significant heterogeneity in glacier thinning and surface flow velocity patterns using temporal DEMs and optical satellite images with ground-based verification. The average thinning rate was found to be 0.07 ± 0.09 m a-1 from 2000 to 2015, and it increased to 0.31 ± 0.19 m a-1 from 2015 to 2020, with pronounced differences between individual glaciers. Between 2000 and 2015, Gangotri Glacier thinned nearly twice as much as the neighbouring Chorabari and Companion glaciers, which have thicker supraglacial debris that protects the beneath ice from melting. The transitional zone between debris-covered and clean ice glaciers showed substantial flow during the observation period. However, the lower reaches of their debris-covered terminus areas are almost stagnant. These glaciers experienced a significant slowdown (~25 %) between 1993-1994 and 2020-2021, and only the Gangotri Glacier was active even in its terminus region during most observational periods. The decreasing surface gradient reduces the driving stress and causes slow-down surface flow velocities and an increase in stagnant ice. Surface lowering of these glaciers may have substantial long-term impacts on downstream communities and lowland populations, including more frequent cryospheric hazards, which may threaten future water and livelihood security.

Emission of greenhouse gases due to anthropogenic activities: an environmental assessment from paddy rice fields.

Paddy rice fields (PRFs) are a potent source of global atmospheric greenhouse gases (GHGs), particularly CH4 and CO2. Despite socio-environmental importance, the emission of GHGs has rarely been measured from Haryana agricultural fields. We have used new technology to track ambient concentration and soil flux of GHGs (CH4, CO2, and H2O) near Karnal's Kuchpura agricultural fields, India. The observations were conducted using a Trace Gas Analyzer (TGA) and Soil Flux Smart Chamber over various parts, i.e., disturbed and undisturbed zone of PRFs. The undisturbed zone usually accounts for a maximum ambient concentration of ~ 2434.95 ppb and 492.46 ppm of CH4 and CO2, respectively, higher than the average global concentration. Soil flux of CH4 and CO2 was highly varied, ranging from 0.18 to 11.73 nmol m-2 s-1 and 0.13-4.98 µmol m-2 s-1, respectively. An insignificant correlation was observed between ambient concentration and soil flux of GHGs from PRFs. Waterlogged (i.e., irrigated and rain-fed) soil contributed slightly lower CH4 flux to the atmosphere. Interestingly, such an agricultural field shows low CO2 and CH4 fluxes compared to the field affected by the backfilling of rice husk ash (RHA). This article suggests farmers not mix RHA to increase soil fertility because of their adverse environmental effects. Also, this study is relevant in understanding the GHGs' emissions from paddy rice fields to the atmosphere, their impacts, and mitigating measures for a healthy ecosystem.

Synthesis of Sulfide Perovskites by Sulfurization with Boron Sulfides.

Chalcogenide perovskites (CPs), with the general composition ABX3, where A and B are metals and X = S and Se, have recently emerged as promising materials for application in photovoltaics. However, the development of CPs and their applications has been hindered by the limitations of available preparation methods. Here we present a new approach for the synthesis of CPs, based on the sulfurization of ternary and binary oxides or carbonates with in situ formed boron sulfides. In contrast to the previously described approaches, the method presented here uses chemically stable starting materials and yields pure-phase crystalline CPs within several hours, under low hazard conditions. CP yields over 95% are obtained at temperatures as low as 600 °C. The generality of the approach is demonstrated by the preparation of CPs with compositions BaZrS3, ß-SrZrS3, BaHfS3, SrHfS3, and EuHfS3. Mechanistic insights about the formation of CPs are discussed.

High-altitude meteorology of Indian Himalayan Region: complexities, effects, and resolutions.

The Himalaya, by virtue of its location and stupendous height, acts as a great climatic divide and regulates meteorological conditions in the subcontinent regions of South Asia. However, the associated complexities and their effects are yet to be resolved to understand the meteorology of the Indian Himalayan Region (IHR). In this review volume, we synthesize the results and inferences of several studies carried out in the IHR using in situ data, remotely sensed data, and model-based meteorological observations. Results provide insights into climate change, scientific gaps, and their causes in deciphering meteorological observations from the last century to recent decades and envisage impacts of climate change on water reservoirs in the future. Warming trend of air temperature, in contrast to global temperature, has been projected in recent decades (after 1990) with a greater warming rate in the maximum temperature than the minimum temperature. This drifting of air temperature from the beginning of last century accelerates the diurnal temperature range of the Himalayas. An elevation-dependent warming trend is mostly perceived in the northwest Himalayan region, implicating an increased warming rate in the Greater Himalaya as compared to the lower and Karakoram Himalaya. No definite trends of precipitation have been observed over different regions of the IHR, suggesting heterogeneous cryosphere-climate interaction between western and central Himalaya. In this review, we have tried to emphasize to the scientific community and policy-makers for enhancing the knowledge of physical and dynamical processes associated with meteorological parameters in the Himalayan terrain.

Evaluating CO2 flux and recharge source in geothermal springs, Garhwal Himalaya, India: stable isotope systematics and geochemical proxies.

Evaluation of geogenic carbon fluxes between solid Earth and its atmosphere is essential to understand the global geological carbon cycle. Some of the key geogenic CO2 suppliers are the magmatic mantle and metamorphic degassing from active and quiescent volcanoes, fault zones, geothermal systems and CO2 rich groundwater. Indian Himalayan geothermal field hosts about 340 geothermal springs in natural as well as artesian condition that eject hot waters and volatiles with varied temperature and chemical composition. These sites provide an opportunity to analyse tectonically driven gas emissions and their impact on regional and global climate. Here we adopt a method for direct measurement of Dissolved Inorganic Carbon (DIC ≈ HCO3) concentration in the geothermal springs to estimate geogenic CO2 flux from an active region based on water discharge and area of geothermal system between the tectonic boundaries of the Main Central Thrust (MCT) and Main Boundary Thrust (MBT) of the Garhwal (Northwest) Himalaya. In the study area, geothermal spring water contain high δ13CDIC ratio (- 8.5‰ to + 4.0‰ VPDB), and among the major ions, bicarbonate (HCO3-) varies by an order of magnitude from 1697 to 21,553 µEq/L; chloride and sodium vary from 90 to 19,171 µEq/L and 436 to 23181 µEq/L. The elevated concentration of Cl- and Na+ in geothermal spring waters suggests affinity towards their deeper origin. These geothermal springs cover a large area of nearly 10,000 km2 of the Garhwal region showing a significant discharge of CO2 rich water with an estimated carbon dioxide degassing flux of ~7.2 × 106 mol/year to the atmosphere. Considering widespread occurrences of geothermal springs in tectonically active areas worldwide, the proposed direct measurement of DIC may be used as a reliable tool to estimate CO2 fluxes in different active orogenic settings within the Earth system. Results of stable isotopes of δ18O (VSMOW) and δD (VSMOW) in these geothermal spring waters follow the Global Meteoric Water Line (GMWL), suggesting affinity of their recharge through the meteoric origin.