Nanocarbon-based sensors for the structural health monitoring of smart biocomposites.

Structural health monitoring (SHM) is a critical aspect of ensuring the safety and durability of smart biocomposite materials used as multifunctional materials. Smart biocomposites are composed of renewable or biodegradable materials and have emerged as eco-friendly alternatives of traditional non-biodegradable glass fiber-based composite materials. Although biocomposites exhibit fascinating properties and many desirable traits, real-time and early stage SHM is the most challenging issue to enable their long-term use. Smart biocomposites are integrated with sensors for in situ identification of the progress of damage and composite failure. The sensitivity of such smart biocomposites is a key functionality, which can be tuned by the introduction of an appropriate filler. In particular, nanocarbons hold promising potential to be incorporated in SHM applications of biocomposites. This review focused on the potential applications of nanocarbons in SHM of biocomposites. The aspects related to fabrication techniques and working mechanism of sensors are comprehensively discussed. Furthermore, their unique mechanical and electrical properties and sustainable nature ensure seamless integration into biocomposites, allowing for real-time monitoring without compromising the material's properties. These sensors offer multi-parameter sensing capabilities, such as strain, pressure, humidity, temperature, and chemical exposure, allowing a comprehensive assessment of biocomposite health. Additionally, their durability and longevity in harsh conditions, along with wireless connectivity options, provide cost-effective and sustainable SHM solutions. As research in this field advances, ongoing efforts seek to enhance the sensitivity and selectivity of these sensors, optimizing their performance for real-world applications. This review highlights the significant advances, ongoing efforts to enhance the sensitivity and selectivity, and performance optimization of nanocarbon-based sensors along with their working mechanism in the field of SHM for smart biocomposites. The key challenges and future research perspectives facing the conversion of nanocarbons to smart biocomposites are also displayed.

3D Porous MoS2-Decorated Reduced Graphene Oxide Aerogel as a Heterogeneous Catalyst for Reductive Transformation Reactions.

The MoS2-based reduced graphene oxide aerogel (MoS2-rGOA)-assisted organic transformation reactions are presented. MoS2-rGOA is used as a heterogeneous catalyst for the reduction of benzene derivatives such as benzaldehyde, nitrobenzene, and benzonitrile to benzyl alcohol, aniline, and benzamide and their derivatives, respectively, in green solvents (water/methanol) and green reducing agents (hydrazine hydrate having N2 and H2 as byproducts). The mechanistic features of the reduction pathway, substrate scope, and the best suitable conditions by varying the temperature, solvent, reducing agent, catalyst loading, time, etc. are optimized. All of the synthesized products are obtained in quantitative yield with purity and well characterized based on nuclear magnetic resonance analysis. Further, it is also observed that our catalyst is efficiently recyclable and works well checked up to 5 cycles.

Sulphonated poly(ethersulfone)/carbon nano-onions-based nanocomposite membranes with high ion-conducting channels for salt removal via electrodialysis.

Herein, we are reporting the carbon nano onions (CNO)-based sulphonated poly(ethersulfone) (SPES) composite membranes by varying CNO content in SPES matrix for water desalination applications. CNOs were cost-effectively synthesized using flaxseed oil as a carbon source in an energy efficient flame pyrolysis process. The physico- and electrochemical properties of nanocomposite membranes were evaluated and compared to pristine SPES. Moreover, the chemical characterisation of composite membranes and CNOs were illustrated using techniques such as nuclear magnetic resonance (NMR), Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscope (FE-SEM), thermogravimetric analysis (TGA) and universal tensile machine (UTM). In the series of nanocomposite membranes, SPES-0.25 composite membrane displayed the highest water uptake (WU), ion exchange membrane (IEC) and ionic conductivity (IC) values that were enhanced by 9.25%, ~ 44.78% and ~ 6.10%, respectively, compared to pristine SPES membrane. The electrodialytic performance can be achieved maximum when membranes possess low power consumption (PC) and high energy efficiency (Ee). Therefore, the value of Ee and Pc for SPES-0.25 membrane has been determined to be 99.01 ± 0.97% and 0.92 ± 0.01 kWh kg-1, which are 1.12 and 1.11 times higher than the pristine SPES membrane. Hence, integrating CNO nanoparticles into the SPES matrix enhanced the ion-conducting channels.

Biomass-derived carbon nano-onions for the effective elimination of organic pollutants and oils from water.

Oil spillage and leakage of organic solvents have caused severe environmental and ecological damages. It is of great significance to develop a cost-efficient and green adsorbent material with high uptake efficiency to separate the oil-water mixture. In this work, biomass-derived CNOs were first time explored in the adsorption of organic pollutants and oils from water. Carbon nano-onions (CNOs) with hydrophobicity and oleophilicity were cost-effectively synthesized in an energy efficient flame pyrolysis process using flaxseed oil as a carbon source. The as-synthesized CNOs without any further surface modification have shown high adsorption efficiency in removing organic solvents and oils from the oil-water mixture. The CNOs could adsorb diverse organic solvents such as pyridine (36.81 mg g-1), dichloromethane (90.95 mg mg-1), aniline (76 mg mg-1), toluene (64 mg mg-1), chloroform (36.25 mg mg-1), methanol (49.25 mg mg-1), and ethanol (42.25 mg mg-1). The uptake capacity for petrol and diesel over CNOs was observed at 36.68 mg mg-1 and 58.1 mg mg-1, respectively. The adsorption of pyridine followed pseudo-second-order kinetics and Langmuir's isotherm model. Moreover, the adsorption efficiency of CNOs towards the remediation of pyridine was almost similar in real-water samples when tested in tap water, dam water, groundwater, and lake water. Similarly, the practical applicability for the separation of petrol and diesel was also verified in the real sample (sea water) and has been proven to be excellent. By simple evaporation, the recovered CNOs can be reused for more than 5 cycles. CNOs exhibit the promising potential to be used in practical applications for oil-polluted water treatment.

Sustainable carbon nano-onions as an adsorbent for the efficient removal of oxo-anions.

The increasing threats of oxo-anions in drinking water have posed a serious threat to human health, aquatic environment, ecology, and sustainability. Accordingly, developments of cost-effective and sustainable nanomaterials for water remediation are on top priority and highly sought in global research community. Carbon nano-onions (CNOs) are one of the emerging nanomaterials for water purification because of its unique morphology, surface reactivity, high density of surface-active sites, and microporous structure. Herein, flaxseed oil-derived CNOs are utilized as efficient adsorbent for the removal of toxic oxo-anions. Aside from the green and economic nature, CNOs provide high adsorption efficiency ~ 806.45 mg g-1 for the removal of [Formula: see text] (99.9%) from aqueous system at ambient temperature, neutral pH in 70 min. The adsorption of [Formula: see text] onto CNOs was well fitted in pseudo-second order kinetics and followed the Langmuir adsorption isotherm model. The adsorption process was determined to be exothermic and spontaneous from the resulting thermodynamic characteristics. Furthermore, the high hydrophobic nature of CNOs make it recycling simpler. The real-life applicability of CNOs towards [Formula: see text] removal was tested in tap water, river water, and dam water. With all these observed results, CNOs show promise for practical water remediation applications.

N-Doped Carbon Nanorods from Biomass as a Potential Antidiabetic Nanomedicine.

Insufficient glucose control remains a critical challenge for type 2 diabetes mellitus (T2DM) patients with currently used therapeutic drugs, which can also have detrimental side effects. The facile synthesis of nitrogen-doped carbon nanorods (N-CNRs) as therapeutic agents in a T2DM transgenic db/db mouse model is reported herein. N-CNRs are synthesized from silkworm powder without the assistance of any template and possess a hollow graphitic nature, rough surface, and good aqueous solubility, which make them ideal candidates for fabricating nanomedicines. N-CNRs are employed to reduce fasting blood glucose and ameliorate serum biomarker levels linked to oxidative stress and inflammation. Interestingly, through the downregulation of enhanced expression of glutathione peroxidase, superoxide dismutase, and catalase as well as inflammatory responses, N-CNRs reverse pancreatic dysfunction and normalize the secretory functions of pancreatic cells. Moreover, hepatic steatosis is attenuated by downregulating lipogenesis and increasing fatty acid oxidation. This finding may help in designing novel therapeutics for T2DM treatment.

Sunlight-promoted photodegradation of Congo red by cadmium-sulfide decorated graphene aerogel.

Herein, a simpler-viable methodology for the surface decoration of pear fruit derived graphene aerogel (GA) via cadmium sulfide (CdS) has been presented. GA can be easily synthesized from bio-mass, which provide an economic advantage. Surface decoration via CdS imparts photocatalytic activities in functionalized graphene aerogels (f-GA). CdS-f-GA is being explored here as a photocatalyst for the degradation of a toxic azo dye named Congo red in the presence of sunlight. The rate and mechanism associated with photodegradation were analyzed by performing kinetics and radical trap-based quenching experiments. Nuclear magnetic resonance and fourier transform infrared spectroscopy analyses of the control and photodegraded products were performed to ensure the degradation of the organic framework of Congo red. Additionally, the real-life applicability of CdS-f-GA was also analyzed by degrading the dye in different types of industrial samples (via the method of external spiking), which can advance its practical relevance.

Thiourea-functionalized graphene aerogel for the aqueous phase sensing of toxic Pb(II) metal ions and H2O2.

A simpler approach of functionalization for the fabrication of thiourea-functionalized-Graphene Aerogel (t-GA) is described here. Graphene Aerogel (GA) was synthesized from bio-mass, which on a simpler oxidative treatment get converted to its water-soluble version due to the impregnation of several oxygenous functionalities like carboxylic, hydroxyl, etc. Further, these carboxylated groups have been functionalized with the molecules of thiourea using the long known dicyclohexylcarbodiimide (DCC) as a coupling agent. The as-synthesized t-GA shows bright yellow fluorescence with a quantum yield of ~3% and holds the high-aqueous solubility and photostability. The fluorescence property of t-GA has been used here for the specific and selective sensing of toxic lead (Pb(II)) metal ions from the used many other metal ions via the fluorescence quenching and showed a limit of detection ~7.3 nM. Further, the mechanism for selective sensing was studied in detail and found to be preferable via ligand to metal charge transfer quenching mechanism. The cyclic voltammetry studies supported the selective sensing of Pb(II). Moreover, t-GA has also been studied for the sensing of hydrogen peroxide and as a yellow fluorescent ink.

N, S, and P-Co-doped Carbon Quantum Dots: Intrinsic Peroxidase Activity in a Wide pH Range and Its Antibacterial Applications.

Nanozymes have drawn significant scientific interest due to their high practical importance in terms of overcoming the instability, complicated synthesis, and high cost of protein enzymes. However, their activity is generally limited to particular pHs, especially acidic ones. Herein, we report that luminescent N, S, and P-co-doped carbon quantum dots (NSP-CQDs) act as attractive peroxidase mimetics in a wide pH range, even at neutral pH, for the peroxidase substrate 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) in the presence of H2O2. The synergistic effects of multiple heteroatoms doping in CQDs boost the catalytic activity in a wide pH range attributed to the presence of high density of active sites for enzymatic-like catalysis and accelerated electron transfer during the peroxidase-like reactions. A possible reaction mechanism for the peroxidase-like activity of CQDs is investigated based on the radical trapping experiments. Moreover, the multifunctional activity of NSP-CQDs was further utilized for antibacterial assays for both Gram-negative and Gram-positive model species, including Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus), respectively. The growths of the employed E. coli and S. aureus were found to be significantly inhibited due to the peroxidase-mediated perturbation of cell walls. The present work signifies the current advance in the rational design of N, S, and P-co-doped CQDs as highly active peroxidase mimics for novel applications in diverse fields, including catalysis, medical diagnostics, environmental chemistry, and biotechnology.

Multifunctional N-P-doped carbon dots for regulation of apoptosis and autophagy in B16F10 melanoma cancer cells and in vitro imaging applications.

Rationale: The present study reports the multifunctional anticancer activity against B16F10 melanoma cancer cells and the bioimaging ability of fluorescent nitrogen-phosphorous-doped carbon dots (NPCDs). Methods: The NPCDs were synthesized using a single-step, thermal treatment and were characterized by TEM, XPS, fluorescence and UV-Vis spectroscopy, and FTIR analysis. The anticancer efficacy of NPCDs was confirmed by using cell viability assay, morphological evaluation, fluorescent live-dead cell assay, mitochondrial potential assay, ROS production, RT-PCR, western-blot analysis, siRNA transfection, and cellular bioimaging ability. Results: The NPCDs inhibited the proliferation of B16F10 melanoma cancer cells after 24 h of treatment and induced apoptosis, as confirmed by the presence of fragmented nuclei, reduced mitochondrial membrane potential, and elevated levels of reactive oxygen species. The NPCDs treatment further elevated the levels of pro-apoptotic factors and down-regulated the level of Bcl2 (B-cell lymphoma 2) that weakened the mitochondrial membrane, and activated proteases such as caspases. Treatment with NPCDs also resulted in dose-dependent cell cycle arrest, as indicated by reduced cyclin-dependent kinase (CDK)-2, -4, and -6 protein levels and an enhanced level of p21. More importantly, the NPCDs induced the activation of autophagy by upregulating the protein expression levels of LC3-II and ATG-5 (autophagy-related-5) and by downregulating p62 level, validated by knockdown of ATG-5. Additionally, owing to their excellent luminescence property, these NPCDs were also applicable in cellular bioimaging, as evidenced by the microscopic fluorescence imaging of B16F10 melanoma cells. Conclusion: Based on these findings, we conclude that our newly synthesized NPCDs induced cell cycle arrest, autophagy, and apoptosis in B16F10 melanoma cells and presented good cellular bioimaging capability.

N,P-Doped Carbon Nanodots for Food-Matrix Decontamination, Anticancer Potential, and Cellular Bio-Imaging Applications.

We report a facile one-step thermal treatment method for the synthesis of biocompatible, fluorescent nitrogen-phosphorus-doped carbon nanodots (NPCDs) as multifunctional agents for the food matrix decontamination, cancer targeting, and cellular bio-imaging. NPCDs exhibit high toxicity towards L. monocytogenes, as illustrated by fluorescent live-dead cell counting, disruption of membrane permeability/potential, changes in the levels of cellular ions, genetic materials, and proteins, as well as intracellular production of reactive oxygen species. The tryptophan and protein peaks released in NPCDs treated cells contributed to indole ring breathing and correlated with induced cell death. NPCDs significantly inhibited bacterial biofilm formation on a solid substrate. NPCDs-coated low-density polyethylene (LDPE) film crosslinked with 1% aminopropyltriethoxy silane (APTES) via silane-hydroxyl linking as a food-grade wrap significantly reduced bacterial counts in a raw chicken food model. Furthermore, NPCDs induced apoptosis in HeLa cervical cancer cells, as confirmed by the distorted cell morphology, fluorescence microscopic analysis, presence of fragmented nuclei and the qPCR results of mRNA expression levels of apoptotic markers. Moreover, NPCDs were also applicable in utilized for the cellular bio-imaging of KM12-C colon cancer cells under confocal microscopy owing to their excellent luminescence properties. Overall, NPCDs represent a promising platform to reduce the environmental health risks associated with hazardous pathogens, anticancer targeting, and their application in cellular bio-imaging as multifunctional targets/nanocarriers.

Synthesis and characterization of magnetic biochar adsorbents for the removal of Cr(VI) and Acid orange 7 dye from aqueous solution.

In this study, different types of magnetic biochar nanocomposites were synthesized using the co-precipitation method. Two biochar materials, namely, sewage sludge biochar and woodchips biochar, were prepared at two different temperatures, viz., 450 and 700 °C. These biochars were further modified with magnetic nanoparticles (Fe3O4). The modified biochar nanocomposites were characterized using field emission-scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET), SQUID analysis, X-ray photoelectron spectroscopy (XPS), and Fourier-transform infrared spectroscopy (FTIR). The potential of prepared adsorbents was examined for the removal of hexavalent chromium (Cr(VI)) and Acid orange 7 (AO7) dye from water as a function of various parameters, namely, contact time, pH of solution, amount of adsorbents, and initial concentrations of adsorbates. Various kinetic and isotherm models were tested to discuss and interpret the adsorption mechanisms. The maximum adsorption capacities of modified biochars were found as 80.96 and 110.27 mg g-1 for Cr(VI) and AO7, respectively. Magnetic biochars showed high pollutant removal efficiency after 5 cycles of adsorption/desorption. The results of this study revealed that the prepared adsorbents can be successfully used for multiple cycles to remove Cr(VI) and AO7 from water. Graphical Abstract.

Sustainable nitrogen-doped functionalized graphene nanosheets for visible-light-induced photocatalytic water splitting.

Nitrogen-doped functionalized graphene nanosheets (N-fGNS) were synthesized by a simple and green method and used for the visible-light-driven water splitting. Under visible light irradiation, N-fGNS produced H2 and O2 (1380 and 689 µM g-1 h-1, respectively) efficiently without co-catalysts. The excellent photocatalytic water splitting performance of N-fGNS is attributed to nitrogen doping and abundant surface defects as active sites.

Synthesis of clay-cellulose biocomposite for the removal of toxic metal ions from aqueous medium.

Clay-cellulose biocomposite (CCB) was synthesized in the present study. Spin and pressure-induced heating was applied to aggregate exfoliated clay tubules and cellulose using polyethylene glycol as an intermediate. The synthesized CCB was modified in the presence of NaOH at high temperature to obtain negative surface charge on the adsorbent. Physico-chemical properties of CCB were evaluated using different characterization techniques including Fourier transform infrared (FT-IR) and X-ray photoelectron (XPS) spectroscopy. The efficiency of the synthesized biocomposite for Pb(II) and Cd(II) removal from water was studied via laboratory scale experiments. The adsorption kinetics of Pb(II) and Cd(II) onto CCB was well described by the pseudo-second-order kinetic model. The maximum Langmuir adsorption capacity of CCB was found to be 389.78 and 115.96 mg g-1 for Pb(II) and Cd(II), respectively. Fixed-bed column studies were conducted for the adsorption system to compare the adsorption performance of CCB in continuous mode.

A Sustainable Graphene Aerogel Capable of the Adsorptive Elimination of Biogenic Amines and Bacteria from Soy Sauce and Highly Efficient Cell Proliferation.

A graphene aerogel (GA) with a three-dimensional (3D) structure, ultra-lightweight nature, and high hydrophobicity was simply fabricated by the one-step pyrolysis of glucose and ammonium chloride. The as-synthesized GA exhibited a 3D interconnected microporous architecture with a high surface area of ∼2860 m2 g-1 and pore volume of 2.24 cm3 g-1. The hydrophobic GA (10 mg 100 mL-1) demonstrated rapid and excellent adsorption performance for the removal of food toxins such as various biogenic amines (histamine, cadaverine, and spermine) and the hazardous bacterium Staphylococcus aureus (a food contaminant and a cause of poor wound healing) from a liquid matrix with a maximum simultaneous adsorption capacity for multiple biogenic amines of >85.19% (histamine), 74.1% (cadaverine), and 70.11% (spermidine) and a 100% reduction in the viable cell count of S. aureus within 80 min of interaction. The outstanding adsorption capacity can be attributed to a highly interconnected porous network in the 3D architecture and a high surface-to-volume ratio. A case study using soy sauce spiked with multiple biogenic amines showed successful removal of toxins with excellent recyclability without any loss in absorption performance. Biocompatibility of the GA in terms of cell viability was observed even at high concentrations (83.46% and 75.28% at 25 and 50 mg mL-1, respectively). Confirmatory biocompatibility testing was conducted via live/dead cell evaluation, and the morphology of normal lung epithelial cells was examined via scanning electron microscopy showed no cellular shrinkage. Moreover, GA showed excellent removal of live colonies of S. aureus from the food matrix and immunoblotting analysis showed elevated protein expression levels of ß-catenin and α-SMA (α-smooth muscle actin). The biocompatible sugar-based GA could simultaneously adsorb multiple biogenic amines and live bacteria and was easy to regenerate via simple separation due to its high floatability, hydrophobicity, surface area, and porosity without any structural and functional loss, making it especially relevant for food safety and biomedical applications.

Biomass-derived Carbon Quantum Dots for Visible-Light-Induced Photocatalysis and Label-Free Detection of Fe(III) and Ascorbic acid.

Visible-light-driven photocatalysts prepared using renewable resources are crucial but challenging to develop for the efficient degradation of organic pollutants, which is required to solve ever-increasing water deterioration issues. In this study, we report a visible-light-responsive photocatalyst for the efficient degradation of methylene blue (MB) as a model pollutant dye. Green-emissive carbon quantum dots (CQDs) were synthesized from pear juice via a facile, scalable, one-pot solvothermal process. The as-synthesized CQDs exhibit superior photocatalytic activity under visible-light irradiation owing to their efficient light absorption, electron transfer, and separation of photogenerated charge carriers, facilitating ~99.5% degradation of MB within 130 min. A possible mechanism for the photocatalysis is proposed on the basis of comprehensive active species trapping experiments. Furthermore, the CQDs were used in a specific sensitive assay for Fe(III) and ascorbic acid (AA), even with interference from other metal ions. The fluorescence emission of CQDs was "turned off" specifically upon binding of Fe(III) and "turned on" with AA. The prepared CQDs represent efficient photocatalysts and fluorescent probes that are not restricted by toxicity, cost, or lack of scalability.

Sustainable Graphene Aerogel as an Ecofriendly Cell Growth Promoter and Highly Efficient Adsorbent for Histamine from Red Wine.

The utilization of a sustainable and lightweight graphene aerogel (GA), synthesized from crude biomass, as a cell growth promoter and an adsorbent for the efficient removal of histamine (HIS), a food toxicant, from the real food matrix has been explored. Due to the self-supported three-dimensional nanoporous honeycomb-like structure of the graphene framework and the high surface area, the synthesized GA achieved an 80.69 ± 0.89% removal of HIS from red wine (spiked with HIS) after just 60 min under both acidic (3.0) and neutral (7.4) pH conditions. Furthermore, simple cleaning with 50% ethanol and deionized water, without any change in weight, allowed them to be reused more than 10 times with a still significant HIS removal ability (more than 71.6 ± 2.57%). In vitro cell culture experiments demonstrated that the synthesized GA had nontoxic effects on the cell viability (up to 80.35%) even at higher concentrations (10 mg mL-1), as determined via the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide and lactate dehydrogenase assays using human lung bronchial epithelial cells. Interestingly, GA promotes the wound-healing ability on the scratched epithelial cell surfaces via enhancing the cell migrations as also validated by the western blot analysis via expression levels of epithelial ß-catenin and E-cadherin proteins. The distinct structural advantage along with the nontoxicity of the green synthesized GA will not only facilitate the economic feasibility of the synthesized GA for its practical real-life applications in liquid toxin and pollutant removal from the food and environment but also broaden its applicability as a promising biomaterial of choice for biomedical applications.

Soluble Graphene Nanosheets for the Sunlight-Induced Photodegradation of the Mixture of Dyes and its Environmental Assessment.

Currently, the air and water pollutions are presenting the most serious global concerns. Despite the well known tremendous efforts, it could be a promising sustainability if the black carbon (BC) soot can be utilized for the practical and sustainable applications. For this, the almost complete aqueous phase photodegradation of the three well-known organic pollutant dyes as crystal violet (CV); rhodamine B (RhB); methylene blue (MB) and their mixture (CV + RhB + MB), by using water-soluble graphene nanosheets (wsGNS) isolated from the BC soot under the influence of natural sunlight is described. The plausible mechanism behind the photocatalytic degradation of dyes and their mixture has been critically analyzed via the trapping of active species and structural analysis of photodegraded products. The impact of diverse interfering ions like Ca2+, Fe3+, SO42-, HPO42-, NO3-, and Cl- on the photodegradation efficiency of wsGNS was also investigated. Importantly, the environmental assessment of the whole process has been evaluated towards the growth of wheat plants using the treated wastewater. The initial studies for the fifteen days confirmed that growth of wheat plants was almost the same in the photodegraded wastewater as being noticed in the control sample, while in case of dyes contaminated water it showed the retarded growth. Using the natural sunlight, the overall sustainability of the presented work holds the potential for the utilization of pollutant soot in real-practical applications related to the wastewater remediation and further the practical uses of treated water.

P2O5 assisted green synthesis of multicolor fluorescent water soluble carbon dots.

A low cost synthesis of multicolor fluorescent carbon dots (C-dots) from edible sugars is described here. Common sugars like dextrose, lactose or maltose in aqueous medium gets dehydrated using phosphorus pentoxide (P2O5). The reaction is facile and completed within few minutes to form insoluble carbon (C-dots) mostly having the graphitic (G-band, Raman) sp2 hybridized carbon atoms (C-atoms). This insoluble carbon on oxidative treatment with nitric acid produced disordered sp3 (D-band retaining G-band, Raman) hybridized C-atoms, originated from the graphitic pool with sp2 hybridized C-atoms. This high density assimilation of self passivated "surfacial defects" become emissive during electronic transitions. Surfacial defects due to high degree of electrophilic carboxylation create the water soluble version of multicolor fluorescent C-dots as "water soluble fluorescent carbon dots" (wsFCDs). wsFCDs being itself self-passivated imposes the tunable multicolor emission throughout the visible spectrum without having any external coating and surface passivation and could be used as multicolor fluorescent probe especially in the emerging field of optical bio-imaging.

Ferromagnetic behaviour of anthropogenic multi-walled carbon nanotubes trapped in spider web indoor.

Black carbon (BC) (as partly burnt black particulate matter) present indoor are deposited on interior surfaces of the indoors (easily visualize over the blades of electric fan/exhausts and over domestic spider webs) are known to be a potential indoor pollution problem. We detect with the help of indoor spider webs the floating BC contains a significant amount of defective multiwalled carbon nanotubes (MWCNTs) possessing room temperature ferromagnetism. Microscopic studies shows a lot of internal and surfacial defects in these indoor-MWCNTs. Electron paramagnetic resonance (EPR) showed the presence of very stable carbon centred radicals in these indoor-MWCNTs. Room temperature ferromagnetism most importantly originated by the presence of a large amount of unpaired spin frustrated carbon centred radicals (trapped in defects, junctions and fractures) which are inadvertently formed during the pyrolysis of carbonaceous materials through routine domestic activities.