Recent advances in nanoremediation: Carving sustainable solution to clean-up polluted agriculture soils.

Agriculture is one of the foremost significant human activities, which symbolizes the key source for food, fuel and fibers. This activity results in a lot of ecological harms particularly with the excessive usage of chemical fertilizers and pesticides. Different agricultural practices have remained industrialized to advance food production, due to the growth in the world population and to meet the food demand through the routine use of more effective fertilizers and pesticides. Soil is intensely embellished by environmental contamination and it can be stated as "universal incline." Soil pollution usually occurs from sewage wastes, accidental discharges or as byproducts of chemical residues of unrestrained production of numerous materials. Soil pollution with hazardous materials alters the physical, chemical, and biological properties, causing undesirable changes in soil fertility and ecosystem. Engineered nanomaterials offer various solutions for remediation of contaminated soils. Engineered nanomaterial-enable technologies are able to prevent the uncontrolled release of harmful materials into the environment along with capabilities to combat soil and groundwater borne pollutants. Currently, nanobiotechnology signifies a hopeful attitude to advance agronomic production and remediate polluted soils. Studies have outlined the way of nanomaterial applications to restore the eminence of the environment and assist the detection of polluted sites, along with potential remedies. This review focuses on the latest developments in agricultural nanobiotechnology and the tools developed to combat soil or land and or terrestrial pollution, as well as the benefits of using these tools to increase soil fertility and reduce potential toxicity.

Phytotoxicological effects of engineered nanoparticles: An emerging nanotoxicology.

Recent innovations in the field of nanoscience and technology and its proficiency as a part of inter-disciplinary science has set an eclectic display in innumerable branches of science, a majority in aliened health science of human and agriculture. Modern agricultural practices have been shifting towards the implementation of nanotechnology-based solutions to combat various emerging problems ranging from safe delivery of nutrients to sustainable approaches for plant protection. In these processes, engineered nanoparticles (ENPs) are widely used as nanocarriers (to deliver nutrients and pesticides) due to their high permeability, efficacy, biocompatibility, and biodegradability properties. Even though the constructive nature of nanoparticles (NPs), nanomaterials (NMs), and other modified or ENPs towards sustainable development in agriculture is referenced, the darker side i.e., eco-toxicological effects is still not covered to a larger extent. The overwhelming usage of these trending NMs has led to continuous persistence in the ecosystem, and their interface with the biotic and abiotic community, degradation lanes and intervention, which might lead to certain beneficial or malefic effects. Metal oxide NPs and polymeric NPs (Alginate, chitosan, and polyethylene glycol) are the most used ENPs, which are posing the nature of beneficial as well as environmentally concerning hazardous materials depending upon their fate and persistence in the ecosystem. The cautious usage of NMs in a scientific way is most essential to harness beneficial aspects of NMs in the field of agriculture whilst minimizing the eco-toxicological effects. The current review is focused on the toxicological effects of various NMs on plant physiology and health. It details interactions of plant intracellular components between applied/persistent NMs, which have brought out drastic changes in seed germination, crop productivity, direct and indirect interaction at the enzymatic as well as nuclear levels. In conclusion, ENPs can pose as genotoxicants that may alter the plant phenotype if not administered appropriately.

Mitigation of organophosphorus insecticides from environment: Residual detoxification by bioweapon catalytic scavengers.

Organophosphorus insecticides (OPIs) have low persistence and are easily biodegradable in nature. The United States and India are the major countries producing OPIs of about 25% and 17% of the world, respectively. OPIs commonly used for agricultural practices occupy a major share in the global market, which leads to the increasing contamination of OPIs residues in various food chains. To overcome this issue, an enzymatic degradation method has been approved by several environmental toxic, and controlling agencies, including United States Environmental Protection Agency (USEPA). Different catalytic enzymes have been isolated and identified from various microbial sources to neutralize the toxic pesticides and/or insecticides. In this review, we have gathered information on OPIs biotransformation and their residual toxicity in the environment. Particularly, it focuses on OPIs degrading enzymes such as chlorpyrifos hydrolase, diisopropylfluorophosphatase, organophosphate acid anhydrolase, organophosphate hydrolases, and phosphotriesterases like lactonasesspecific activity either P-O link group type or P-S link group of pesticides. To summarize, the catalytic degradation of organophosphorus insecticides is not only profitable but also environmentally friendly. Hence, the enzymatic catalyst is an ultimate and super bio-weapon to mitigate or decontaminate various OPIs residues in both terrestrial and aqueous environments.