Polycyclic Aromatic Hydrocarbons in Soil at Different Depths under a Long-Term Experiment Depending on Fertilization.

The aim of this study was to assess the effect of long-term fertilization with manure and mineral fertilizers on the content and distribution of selected polycyclic aromatic hydrocarbons (PAHs)-the content of a sum of 16 polycyclic aromatic hydrocarbons, light and heavy PAHs in two soil layers (0-30 cm and 30-60 cm). The material for the study was composed of soil samples collected from the sixth rotation in a long-term, controlled field experiment, conducted in Balcyny since 1986. The content of 16 polycyclic aromatic hydrocarbons was determined on a gas chromatographer coupled with an FID detector. In order to evaluate the significance of differences between the mean effects on the tested characteristics, a non-parametric Mann-Whitney U test for two independent samples was applied. A higher content of the sum (16) of PAHs was found in the 0-30 cm than in the 30-60 cm soil layer. The research results also demonstrated a higher content of the sum of light PAHs in the 30-60 cm than in the 0-30 cm soil layer. The content of heavy PAHs, in turn, was significantly higher in the upper than in the deeper soil layer. This dependence appeared in both the soil fertilized with manure and soil nourished only with mineral fertilizers.

Phosphorus fractions in soil fertilised with organic waste.

The aim of this study has been to evaluate the effect of sewage sludge and composted sewage sludge and municipal waste on the content of various forms of P in soil. The experiment scheme: C, control; NPK; FYM; DGSS, dried and granulated sewage sludge; CSS, composed sewage sludge; CSSS, composted sewage sludge and straw; CMMW, composted mixed municipal waste; CMGW, composted municipal green waste. The content of bound P was determined in the fractions: F1, easily soluble; F2, exchangeable; F3, organic; F4, carbonate; F5, stable organic-mineral and mineral bonds; and F6, residual. The NPK fertilisation as well as the soil fertilisation with organic substances raised the P-total content and of P bound in the fractions: F3, F4, F5 and F6. The highest amount of phosphorus in the studied soil was in fraction F3 (phosphorus in organic compounds) and the lowest in fraction F1 (phosphorus in the ionic form as H2PO4- and HPO42-). Composted sludge and straw introduced into the soil increased the content of readily soluble P (F1), while the NPK effect was reversed. NPK fertilisation and enhancement of soil organic matter (except CSSS, CMGW) led to a reduction of the P content in F2 fraction. The content of available P determined by the Egner-Riehm method depended on the content of C-organic, P-total and CEC soil. Among the determined phosphorus fractions, the content of available P was most strongly correlated with the content of P bound in the carbonate fraction (F4) and residual fraction (F6) and, less strongly, with the organic phosphorus fraction.

Determination of heavy metals and their availability to plants in soil fertilized with different waste substances.

Field trials were conducted in 2004-2015, in Balcyny, on haplic Luvisol formed out of light boulder clay. The experiment consisted of the following treatments: control (no fertilization), NPK, manure (FYM), dried pelleted sewage sludge (DPSS), composted sewage sludge (CSS), compost made from municipal sewage sludge and straw (SSCS), compost Dano made from unsorted household waste (CUHW), and compost produced from urban green waste (CUGW). Over a period of 12 years, 30 t DM/ha of each manure and composts were used, that is, 10 t DM/ha in each rotation of a crop rotation sequence. Nitrogen fertilization was kept on the same level on all experimental plots. Soil samples from the 0- to 20-cm horizon were collected after the third rotation crop, which was winter wheat harvested in 2015. It has been demonstrated that CUHW raised the soil total Cu content the highest, while the soil content of Zn was elevated the most by DPSS. The content of the remaining heavy metals (Pb, Ni, Cr, Mn, and Fe) increased as well, but to a lesser extent. The soil abundance of phytoavailable forms of copper improved even greater (from 75% when fertilized with CUGW or CSS, up to 124% when treated with CUHW). Soil content of soluble forms of such metals as Zn, Pb, Cr, Mn, and Fe changed less. The content of all analyzed heavy metals in soil (a form approximating the total content) was significantly positively correlated with the content of organic carbon (C-org.). This is the evidence for stronger adsorption of the above elements in soil richer in organic matter. On the other hand, the content of available forms of heavy metals depended more on the soil pH than on its content of C-org.

Heavy Metals in Water Percolating Through Soil Fertilized with Biodegradable Waste Materials.

The influence of manure and composts on the leaching of heavy metals from soil was evaluated in a model lysimeter experiment under controlled conditions. Soil samples were collected from experimental fields, from 0- to 90-cm layers retaining the layout of the soil profile layers, after the second crop rotation cycle with the following plant species: potatoes, spring barley, winter rapeseed, and winter wheat. During the field experiment, 20 t DM/ha of manure, municipal sewage sludge composted with straw (SSCS), composted sewage sludge (SSC), dried granular sewage sludge (DGSS), "Dano" compost made from non-segregated municipal waste (CMMW), and compost made from municipal green waste (CUGW) was applied, i.e., 10 t DM/ha per crop rotation cycle. The concentrations (µg/dm3) of heavy metals in the leachate were as follows: Cd (3.6-11.5) < Mn (4.8-15.4) < Cu (13.4-35.5) < Zn (27.5-48.0) < Cr (36.7-96.5) < Ni (24.4-165.8) < Pb (113.8-187.7). Soil fertilization with organic waste materials did not contaminate the percolating water with manganese or zinc, whereas the concentrations of the other metals increased to the levels characteristic of unsatisfactory water quality and poor water quality classes. The copper and nickel content of percolating water depended on the concentration of those metals introduced into the soil with organic waste materials. The concentrations of Cd in the leachate increased, whereas the concentrations of Cu and Ni decreased with increasing organic C content of organic fertilizers. The widening of the C/N ratio contributed to Mn leaching. The concentrations of Pb, Cr, and Mn in the percolating water were positively correlated with the organic C content of soil.