Broadband electromagnetic wave absorption using pure carbon aerogel by synergistically modulating propagation path and carbonization degree.

Carbon materials were widely used as electromagnetic (EM) wave absorption due to their advantages of light weight, environmental resistance and high electrical conductivity. However, conventional means were typically available by combining carbon and other materials to achieve effective absorption. Herein, a novel strategy using pure carbon aerogel with oriented structure was reported to enhance the EM wave absorption by synergistically modulating the wave propagation path and carbonization degree. The aerogel contained proposed modified carbon nanofibers (MCNF) derived from bacterial cellulose (BC), and core-shell carbon nanofibers @ reduced oxide graphene (CNF@RGO). The oriented structure was induced by the temperature field, which manifests anisotropic EM constitutive parameters (εx ≠ Îµz) at different directions of incident wave. The carbonization degree was adjusted by varying the carbonization temperature. At the carbonization temperature of 700 °C, the maximum reflection loss and effective absorption bandwidth reached -53.94 dB and 7.14 GHz, respectively, enabling the aerogel to outperform its previous counterparts. To clarify the EM wave mode-of-action in conjunction, physical models of the aerogel were established in addition to finite element simulation and theoretical analysis. Notably, the aerogel with a density of 3.6 mg/cm3 featured ultra-light weight, superhydrophobicity, superior compressibility, and thermal insulation. Our work offers an efficient strategy for designing broadband and multifunctional EM wave absorption materials (EWAMs), promising great potentials in complex stealth equipment.

A review on composite strategy of MOF derivatives for improving electromagnetic wave absorption.

To address the electromagnetic wave (EMW) pollution issues caused by the development of electronics and wireless communication technology, it is urgent to develop efficient EMW-absorbing materials. With controllable composition, diverse structure, high porosity, and large specific surface area, metal-organic framework (MOF) derivatives have sparked the infinite passion and creativity of researchers in the electromagnetic field. Against the challenges of poor inherent impedance matching and insufficient attenuation capability of pure MOF derivative, designing and developing MOF derivative-based composites by compounding MOF with other materials, such as graphene, CNTs, MXene, and so on, has been an effective strategy for constructing high-efficiency EMW absorbing materials. This review systematically expounds the research progress of MOF derivative-based composite strategies, and discusses the challenges and opportunities faced by MOF derivatives in the field of EMW absorption. This work can provide some good ideas for researchers to design and prepare high-efficiency MOF-based EMW absorbing materials in applications of next-generation electronics and aerospace.

Ultrathin Cellulose Nanofiber Assisted Ambient-Pressure-Dried, Ultralight, Mechanically Robust, Multifunctional MXene Aerogels.

Ambient-pressure-dried (APD) preparation of transition metal carbide/nitrides (MXene) aerogels is highly desirable yet remains highly challenging. Here, ultrathin, high-strength-to-weight-ratio, renewable cellulose nanofibers (CNFs) are efficiently utilized to assist in the APD preparation of ultralight yet robust, highly conductive, large-area MXene-based aerogels via a facile, energy-efficient, eco-friendly, and scalable freezing-exchanging-drying approach. The strong interactions of large-aspect-ratio CNF and MXene as well as the biomimetic nacre-like microstructure induce high mechanical strength and stability to avoid the structure collapse of aerogels in the APD process. Abundant functional groups of CNFs facilitate the chemical crosslinking of MXene-based aerogels, significantly improving the hydrophobicity, water resistance, and even oxidation stability. The ultrathin, 1D nature of the CNF renders the minimal MXenes' interlayered gaps and numerous heterogeneous interfaces, yielding the excellent conductivity and electromagnetic interference (EMI) shielding performance of aerogels. The synergies of the MXene, CNF, and abundant pores efficiently improve the EMI shielding performance, photothermal conversion, and absorption of viscous crude oil. This work shows great promises of the APD, multifunctional MXene-based aerogels in electromagnetic protection or compatibility, thermal therapy, and oil-water separation applications.

Regulated dielectric loss based on core-sheath carbon-carbon hierarchical nanofibers toward the high-performance microwave absorption.

As a response to stealth technology and electromagnetic pollution, microwave absorbing materials have attracted the attention of many research scholars. However, achieving effective absorption with a low filling level is still a challenge in the harsh environment. Here, an emerging carbon-carbon composite fiber with a core-sheath structure is cleverly tailored for high-performance microwave absorber by tuning the dielectric loss. Reasonable engineering heterogeneous interfaces and conductive paths give rise to a synergistic effect of the impedance matching, conductive loss, polarization loss and multiple scattering. The obtained CR-800 achieves the maximum reflection loss of -51.91 dB, effective absorbing bandwidth of 4.82 GHz, and radar cross section (RCS) reduction value of 41.5 dBm2. Furthermore, the composites own superior environmental adaptation with stable absorbing properties in the harsh environment benefited from great environmental resistance of carbon materials. Given this, the core-sheath carbon-carbon composite fibers are expected to be a candidate for radar stealth technology and electromagnetic pollution.

Facile Synthesis of Cobalt-Doped Porous Composites with Amorphous Carbon/Zn Shell for High-Performance Microwave Absorption.

A facile method for the preparation of microwave absorbers with low density, high microwave absorptivity, and broad band is of paramount importance to the progress in practical application. Herein, commonly-used metal organic frameworks (MOFs) prepared just by mechanical stirring in methanol at room temperature were chosen as sacrificial templates to synthesize porous carbon composites with tunable dielectric and magnetic properties. With the replacement of Co atoms on the surface of zeolitic imidazolate framework-67 (ZIF-67) by Zn atoms, a Co-doped porous carbon composite with a low-dielectric amorphous carbon/Zn shell was constructed after annealing, leading to excellent impedance matching condition. Consequently, the as-obtained composite (Co/C@C-800) shows marvelous microwave absorption properties with an absorption capacity of -43.97 dB and a corresponding effective absorption bandwidth of 4.1 GHz, far exceeding that of the traditional porous carbon and composites directly derived from ZIF-67. The results provide a convenient way to modify MOFs for enhanced microwave absorption materials from the synergy of dielectric and magnetic losses.