RESUMEN
As a typical planar 4-connected ligand that possesses D4h symmetry, the squarate ligand is expected to construct some interesting topologies. Here, we report that the assembly of the squarate ligand with rare-earth ions can produce a series of (4, 8)-connected frameworks with the "smallest" scu type topology. Among these compounds, the Tb based analogue not only possesses a good proton conductivity, but also exhibits luminescence responses toward MnO4- and Cr2O72-, making it a candidate for multifunctional materials.
RESUMEN
It is a challenge to effectively load proton carriers in COFs to improve their proton conductivity. Herein, we report a series of COF-based composites, PANa@UCOF-x (PANa: sodium polyacrylate, x: weight percentage of PANa), which were prepared by coating different proportions of superabsorbent PANa on the COF surface based on an in situ reaction strategy. Since PANa can greatly enhance the enrichment of water molecules in one-dimensional (1D) channels of COFs, these COF-based composites exhibit superprotonic conduction. At 80 °C and 95% relative humidity (RH), the proton conductivity of PANa@UCOF-10, PANa@UCOF-28 and PANa@UCOF-40 reaches 1.6 × 10-2, 5.1 × 10-2, and 1.1 × 10-1 S cm-1, respectively, which is 4-5 orders of magnitude higher than 7.4 × 10-7 S cm-1 of the original UCOF. This work not only develops a new method to improve the water content of the COF channels, but also proves the important role of ordered channels in constructing effective proton conduction pathways.
RESUMEN
This work contributes experimental demonstrations and comprehensive comparisons of various modulation and coding techniques for 200 Gb/s intensity modulation and direct detection links including four-level pulse amplitude modulation (PAM-4), PAM-6, trellis-coded modulation (TCM) over PAM and discrete multi-tone (DMT) transmission. Both C-band Mach-Zehnder modulator and O-band electro-absorption modulated laser transmitters were examined for intra-data center applications based on state-of-the-art commercial components.
RESUMEN
Creating novel and practical materials to separate oil/water mixtures with high efficacy is in urgent demand. Herein, we demonstrate an amphipathic pentiptycene-based copper metal-organic framework (Cu-MOF; UPC-29) to satisfy this purpose. UPC-29 exhibits a efficient separation performance for mixtures of naphtha/water, gasoline/water, and diesel/water. Furthermore, materials under loose-packed and tight-pressed forms exhibit opposite hydrophilic-hydrophobic phenomena. This unique feature of UPC-29 provides a new avenue for the application of MOF materials.
RESUMEN
Coherent optical communication systems are still too expensive for metro and short reach networks in the near future. Coherent detection with an intensity modulator replacing a costly dual-polarization in-phase and quadrature modulator could offer a good trade-off between cost and performance for metro networks. The major performance limit of such systems is the nonlinearity. To the best of our knowledge, this Letter offers the first known investigation on nonlinearity of a high speed intensity modulation and coherent detection system using an integrated laser and electro-absorption modulator. Advanced nonlinearity mitigation digital signal processing (DSP) are proposed including a 2×1 multiple-input single-output complex transversal Volterra feed-forward equalizer (FFE) filter, a first proposed post-FFE noise cancellation filter taking into account both pre- and post-cursor noise correlations based on a simple autocorrelation coefficient calculation, and a maximum likelihood sequence estimator. The receiver DSP needs no carrier and phase recovery that is required by a conventional coherent receiver DSP. Results show that, compared to a simple linear FFE equalization, the proposed nonlinear DSP enables over 8 and 4 dB improvement in optical signal to noise ratio (OSNR) sensitivity at 7% overhead hard-decision feed-forward error correction (FEC) and 20% overhead soft-decision FEC threshold bit error rates (BERs), respectively, for a 56 Gb/s intensity modulation and coherent detection system. To the best of our knowledge, a record 18 dB OSNR sensitivity at a hard-decision FEC threshold BER of 3.8×10-3 is also achieved.
RESUMEN
We experimentally demonstrate the generation and successful transmission of a single-lane 180 Gb/s (90 GBd) duo-binary four-level pulse-amplitude modulation (DB-PAM-4) signal over an 80 km standard single-mode fiber with a net data-rate of 150 Gb/s, enabled by a dual-drive Mach-Zehnder modulator-aided dispersion pre-compensation. A net data rate of 168 Gb/s is also achievable, for ranges up to 40 km. To mitigate bandwidth limitations and error spreading, pre-coded DB-PAM-4 is used; the pre-coding provides a gain of approximately 1 dB. A Volterra filter and a maximum likelihood sequence estimator are used at the receiver side to reduce the linear and nonlinear distortions.
RESUMEN
We experimentally demonstrate the possibility of transmitting 112 Gb/s PAM-4 signals over 30-km standard single-mode fibers with commercial 20-GHz components. The impact on system performance of three different equalization schemes-feed-forward equalizer (FFE), Volterra filter (VF), and maximum likelihood sequence estimator (MLSE)-is investigated and compared. We prove that the |x| and x|x| components of the VF can efficiently reduce the chirp-induced signal skew distortion, and that an MLSE with only four states can be used to remove the error floor. In contrast, the performance of FFE is worse than that of VF with a 4-state MLSE, even when a 64-state MLSE is used.
RESUMEN
Direct detection systems with advanced modulation schemes are of great importance in metropolitan networks, because of their low cost and low power requirements. In particular, PAM-4 has attracted considerable attention, but has significant transmission distance limitations in the C-band. To extend its reach, we used a dual drive Mach-Zehnder modulator to generate a chromatic dispersion (CD) pre-compensated signal with an extra (j-1) multiplication to align the optical carrier and the modulated optical signal; by doing so, we achieved successful 128 Gbit/s transmission over an 80 km SSMF link, the longest reported reach of single lane 100 Gbit/s PAM-4 signals over DCF-free links. Synchronized bandwidth pre-compensation was also used, to reduce the influence of bandwidth-limitations.
RESUMEN
We experimentally demonstrate the generation and transmission of a single-lane 180 Gbit/s (90 GBaud) four-level pulse-amplitude modulation (PAM-4) signal in an intensity-modulation direct-detection system with a 7.5 GHz 3 dB bandwidth. The generated signal is transmitted over a 2 km standard single-mode fiber with, to the best of our knowledge, the highest reported net data rate in the C-band: 150 Gbit/s. A net data rate of 168 Gbit/s is also reachable with 1 km reach. The PAM-4 and duobinary (DB) PAM-4 modulation schemes are compared; the obtained results show that DB-PAM-4 significantly outperforms PAM-4 in the considered strong bandwidth-constrained system. Both a feed-forward equalizer and a maximum-likelihood sequence estimator are investigated for data recovery.
