Towards long-term operation of flow-electrode capacitive deionization (FCDI): Optimization of operating parameters and regeneration of flow-electrode.

This study systematically optimized the key operating parameters and interpreted their effecting mechanisms in a flow-electrode capacitive deionization (FCDI) system. The optimal voltage, activated carbon electrode content, electrolyte concentration, feedwater flowrate, and electrode flowrate for desalinating low salinity feedwater (1.0 g L-1 NaCl) were determined to be 1.8 V, 2.0 wt%, 10.0 g L-1, 80 mL min-1, and 60 mL min-1, respectively. The variations of the above parameters can affect the system conductivity, the thickness and stability of the electric double layers, and/or the degree of concentration polarization, thereby influencing the desalination performance. Moreover, a sensitivity analysis identified the operating voltage as the dominant parameter with the most significant influence on the FCDI system. Subsequently, a long-term operation was carried out under single-pass mode. The results showed that the lab-scale FCDI system was able to constantly maintain the desalination efficiency of 1.0 g L-1 feedwater (NaCl) at 40-60 % for multiple operating cycles. Over 99.8 % of electrode material regeneration and desalination efficiency recovery was able to be obtained during a 60-h operation, demonstrating that the FCDI system showed strong stability and long-term operation potential.

Bi-decadal trend of atmospheric emissions from thermal power plants in Mainland Southeast Asia: Implications on acid deposition and climate change Mitigation.

Steady increase in electricity generation and heavy reliance on coal in Mainland Southeast Asia (M-SEA) create huge pressure on the environment. This study used information collected from individual thermal power plants (TPPs) in M-SEA to calculate emissions of air pollutants and greenhouse gases (GHG) for 2010, 2015 and 2019. The emissions were projected to 2030 following the latest national Power Development Plans. The emission results were analyzed in relation to the power development by country and fuel type, and environmental impacts. The region collective annual TPP emissions in 2019, in Gg/yr, were 27 PM2.5, 77 PM10, 0.7 BC, 4.9 OC, 255 SO2, 451 NOx, 91 CO, 12 NMVOC, 0.4 NH3, 260 CO2, 13 CH4, and 26 N2O. Coal-fired TPPs dominated the emissions of most species while NG-fired contributed the largest amounts of NH3 and CH4. Bi-decadal increase in energy production from TPPs of nearly 3 times is accompanied by 2.7 times increase in emissions. The 2010-2019 period saw average emissions increase by 1.9 times (TPPs' energy production increased 1.6 times), slightly higher than the rate of 1.4 times projected for 2019-2030 (double TPPs' energy production). The current intrusion rate of renewable energy accompanied by phasing-out of old TPPs are still by far insufficient to reverse the emission trend. Aggressive power development in Vietnam with its heavy coal reliance made it the largest emitter in 2019 and the projected for 2030, followed by Thailand. Spatially, higher emissions are seen over locations of large coal-fired TPPs in Vietnam and Thailand. Available rainwater composition monitoring data showed higher deposition amounts of sulfate and nitrate in areas located near or downwind of large TPPs. Significant GHG emissions projected for TPPs in 2030 indicated that TPPs should be the priority for emission reduction to achieve Nationally Determined Contribution targets. Emission database produced by this study can be used in dispersion modeling studies to assess impacts of TPPs on air quality, health, and acid deposition.

Ambient black carbon variations and emission characteristics of typical Chinese vessels in the Yangtze River Delta, China.

Black carbon (BC) has a significant impact on air quality, climate change, and human health. Studies on BC from vessel exhaust have been focused on in recent years. To realize the contribution of BC from vessels to ambient air quality, 28 months of BC variation were observed from February 2019 to May 2022, including 3 fishing moratoriums and 2 normal periods. The results showed that the average daily concentration of BC in the fishing moratorium was significantly lower than that in the normal period. The difference proportion of the BC concentration between 370 and 880 nm was calculated over the whole period. As a result, the mean difference value in the fishing moratorium from February to May was 0.06 ± 0.07, and the normal period was -0.02 ± 0.05. The aethalometer model indicated that BC was greatly affected by fossil fuel combustion in the normal period. The effect of vessel emissions on regional BC concentrations was considerable. In addition, 16 PAHs and 21 elements in PM emitted from 24 vessels of different types were sampled and analyzed in Dianshan Lake and the Taipu River. EC accounted for the highest proportion (23.64%) in the sample of small trawlers compared to the emissions from cargo ships with large tonnages. The component profiles of vessel exhaust showed that Zn, As, phenanthrene (Phe), anthracene (Ant), fluoranthene (Fla), and pyrene (Pyr) were the dominant species, although some of these species were mainly recognized as characteristic factors of coal combustion. To improve the accuracy of identifying the vessel source, the diagnostic ratios of Ant/(Ant + Phe), BaA/(BaA + Chr), Phe/Ant, and BaA/Chr were provided, and they exhibited the obvious characteristics of fuel combustion.

Land use-based characterization and source apportionment of microplastics in urban storm runoffs in a tropical region.

Urban stormwater runoff has been suggested as one important land-based pathway of microplastics (MPs) entering the oceans, in which the abundance and characteristics of MPs may be influenced by urban land use types. However, little information has been reported regarding this, especially in the tropical monsoon region. This study first reports the MPs in urban stormwater runoffs in a tropical monsoon region that were collected from four typical urban land use types, including industrial, highways, commercial, and residential areas. The average MP particle count and mass concentration were measured as 4.7 ± 3.5 particles/L and 3.8 ± 2.9 mg/L, respectively. MP abundances showed clear urban land use gradients following the order of industrial > transportation > commercial > residential area. In terms of the seasonal variation in MP abundances, a slightly increasing particle count in the dry season was noted for the residential site. Source apportionment of MPs in stormwater runoffs was demonstrated based on the land use type, particle morphology, and chemical compositions. With the simple apportionment approach, approximately 85% of the MP sources were able to be identified in the industrial, transportation, and residential sites. However, the commercial site showed high variability in terms of the morphology and polymer type of MPs. Furthermore, significantly positive correlations between MP abundance and runoff turbidity, TSS, COD, and rainfall intensity were identified, while, no significant correlation was found between MP characteristics and selected water quality/meteorological parameters.

Spectroscopic fingerprints profiling the polysaccharide/protein/humic architecture of stratified extracellular polymeric substances (EPS) in activated sludge.

Extracellular polymeric substances (EPS), with a stratified structure including tightly-bound EPS (TB-EPS), loosely-bound EPS (LB-EPS), and soluble EPS (S-EPS) surrounding the microbial cells, are known to vitally affect the physicochemical and biological functions of activated sludge in wastewater treatment. Polysaccharides (PS), proteins (PN), and humic acids (HA) are key components of EPS but their roles in constructing the multi-layer architecture are still unclear. This study explored the EPS characteristics in relation to the components using spectroscopic fingerprinting techniques. Ultraviolet-visible (UV-vis) spectra demonstrated stark difference between TB-EPS and other EPS. Fluorescence excitation-emission matrix (FEEM) and apparent quantum yield revealed further detailed differences. Fluorescence quotient analysis highlighted the dominance of TB-EPS, LB-EPS, and S-EPS in the excitation/emission wavelength (Ex/Em) region of Em = 350-400 nm, Em > 400 nm, and low-Stokes shift band (Em - Ex < 25 nm), respectively. Wavelength-wise prediction of the FEEM intensity was achieved through multiple linear regression against the chemical composition and variance partitioning analysis witnessed binary interactions of PS×HA and PS×PN in S-EPS, PN×HA and PS×PN in LB-EPS, and ternary interaction of PS×PN×HA in TB-EPS as well as the wavelength-specific fluorescence responses of these interactions. Further, X-ray photoelectron spectroscopy, infrared spectra, and circular dichroism spectra corroborated the differences in primary, secondary, and tertiary structures across the EPS layers. Ultrahigh-performance liquid chromatography-mass spectrometry detected molecular fragments confirming the multi-component hybridization among PS, PN, and HA. This study demonstrates a spectroscopic approach to sensitively fingerprint the fine structure of EPS, which has the potential for rapid monitoring of EPS and related sludge properties in wastewater treatment systems.

On adjustable and lossless suppression to disturbances and uncertainties for nonminimum-phase laser pointing system.

This paper focuses on the nonminimum-phase laser pointing system's disturbances and uncertainties rejection problems on moving platforms. Moving platforms cause a variety of noticeable vibrations that substantially impair pointing accuracy. Additionally, the disturbance-observer-based control approaches currently in use sacrifice the desired disturbance suppression effects, stability margins, or tracking characteristics due to the nonminimum-phase laser pointing system. This paper suggests an adjustable disturbance-observer-based control strategy with dual filters to obtain lossless and adjustable disturbance suppression effects without sacrificing stability margins or tracking characteristics. The closed-loop controller and forward plant are presented to reduce the laser pointing system's nonminimum-phase properties. An additional flexible filter is added to deal with the weakened nonminimum-phase system. Both filters are uniformly proposed depending on various disturbances brought on by moving platforms and work together to accomplish lossless desired disturbance suppression effects. The analyses and experiments show that the suggested approach can accomplish the lossless and adjustable disturbance suppression effects in the nonminimum-phase laser pointing system, which cancels out many more disturbances and uncertainties than the current methods.

Spatial changes of nutrients and metallic contaminants in topsoil with multi-geostatistical approaches in a large-size watershed.

Appropriate assessment on concerned soil contaminants spatially is of importance for decision-makers and stakeholders to make efficient mitigation countermeasures. In this study, we applied multiple geostatistical approaches to explore soil nutrient and metallic contaminant distributions in a large river watershed in Thailand, and to compare their performances in predicting spatial distribution patterns of the concerned soil contaminants under suitable application scenarios. The total carbon, nitrogen and phosphorous in surface soils over the whole watershed were measured with their maximum concentrations up to 131.47, 9.24, 5.33 g·kg-1, respectively, while the concentrations of eight metallic elements (Cu, Zn, Pb, Cd, Hg, As, Cr, and Ni) were 933.00, 6862.50, 373.00, 6.22, 1.15, 178.53, 761.11, and 372.44 mg·kg-1, respectively. It was found that the conditional interpolation approaches such as land use stratified inverse distance weighted and land use stratified original kriging provided better boundary details than original interpolations, with substantially reduced root mean square errors (up to 28% for nutrients and 54% for specific metals) and mean relative errors (up to 38% for nutrients and specific metals respectively) in predicting the spatial patterns of soil nutrients and several land use specific metals (Cu, Zn, Cd, and Pb). The global accuracies were equivalent or higher than those of geographically weighted regression. Nonetheless, the prediction accuracy for Cr, Ni, As, and Hg could not be improved using the land use stratified interpolation because their sources and pathways were not significantly correlated with land use types in the watershed, as reflected by the results of analysis of variance with post hoc test (p ≤ 0.05) and principal component analysis.

From online to offline education in the post-pandemic era: Challenges encountered by international students at British universities.

Background: After 2 years of anti-pandemic struggles, universities in the United Kingdom have started to witness a reverse transition, a shift from online to offline education. This includes encouraging students to begin face-to-face programmes and allowing flexibility for remote learners, but later requiring all students to return to campus by a certain date. Objectives: This paper aims to explore the challenges and impacts brought about by this new transition and provide recommendations for universities to enhance student experience for future adversity. Method: This qualitative study conducted semi-structured interviews with 24 international students from a British university to explore their experiences during the transition. The results were analysed using thematic analysis. Results: Our data revealed both internal and external challenges to students during the online-to-offline shift, which lead to a general resistance to said shift. Specifically, policy challenges (e.g., policy conflicts) imposed the most significant impacts on international students, resulting in psychological anxiety, financial losses, and negative learning experiences. The reduction of digital tools and learning materials during the shift also presented challenges to students who developed a reliance on digital resources while learning remotely. Other challenges have also been identified, including academic barriers and social engagement issues. Conclusion: By highlighting these challenges, this paper has practical implications for university policy decisions and provides recommendations for supporting students' transition back to traditional offline learning.

Membrane cleaning and performance insight of osmotic microbial fuel cell.

Osmotic microbial fuel cell (OsMFC) integrating forward osmosis into microbial fuel cell (MFC) favors the merits of organic removal, bioenergy generation, and high-quality water extraction from wastewater. This study demonstrated an 18.7% power density enhancement over a conventional MFC due to the water-flux-facilitated proton advection and net positive charge (NPC)-flux-promoted countercurrent proton exchange. Among the three examined membrane cleaning methods, chemical cleaning using 0.2% NaClO was found to be especially effective in removing organic foulants composed of proteins and polysaccharides, resulting in a water flux recovery of up to 91.6% with minimal impact on average maximum power density and internal resistance. The effects of operating parameters including anode HRT and draw solution concentration were studied. Shortening HRT from 6.0 to 3.0 h increased power density by 78.0% due to a high organic loading rate and a slightly reduced polarization concentration. Increasing draw solution concentration from 0.2 to 1.0 M NaCl enhanced power density by approximately 2.7-fold due to enhanced proton advection. Water-flux-facilitated proton advection played a more important role in determining the electricity generation performance of OsMFC than the NPC-flux-promoted countercurrent proton exchange under varied operating conditions.

Cellular automata based framework for evaluating mitigation strategies of sponge city.

Urban surface water flooding is increasing because of climate change and urbanization, and brings great challenges to urban sustainable development. It is, therefore, most important to develop urban flood management approaches to alleviate the consequences of floods. China is implementing a "sponge city" initiative to tackle urban surface water flooding and improve urban water management. There is, however, limited cost-effectiveness evaluation to support the choice of economically efficient mitigation strategies. To address this gap, this study developed an evaluation framework based on cellular automata and cost-benefit analysis to assess the performance of mitigation strategies in sponge city construction. This approach is demonstrated with a case study of Siergou (Dalian, China), which has a total area of 10.1 km2. The mitigation measures of green roofs, permeable pavements and bio-retention were used to generate mitigation scenarios. A two-dimensional cellular automata-based model was used to simulate urban surface water flooding. The results obtained from the case study indicate that the framework can achieve cost-effective mitigation strategies for sponge city construction, which can support robust decision making. The distribution of mitigation strategies has great impacts on the effectiveness of alleviating urban flood risk. This study provides new insight into the development of cost-effective mitigation strategies for sponge city construction.

Resource recovery toward sustainability through nutrient removal from landfill leachate.

This study investigated the feasibility of integrated ammonium stripping and/or coconut shell waste-based activated carbon (CSWAC) adsorption in treating leachate samples. To valorize unused biomass for water treatment application, the adsorbent originated from coconut shell waste. To enhance its performance for target pollutants, the adsorbent was pretreated with ozone and NaOH. The effects of pH, temperature, and airflow rate on the removal of ammoniacal nitrogen (NH3-N) and refractory pollutants were studied during stripping alone. The removal performances of refractory compounds in this study were compared to those of other treatments previously reported. To contribute new knowledge to the field of study, perspectives on nutrients removal and recovery like phosphorus and nitrogen are presented. It was found that the ammonium stripping and adsorption treatment using the ozonated CSWAC attained an almost complete removal (99%) of NH3-N and 90% of COD with initial NH3-N and COD concentrations of 2500 mg/L and 20,000 mg/L, respectively, at optimized conditions. With the COD of treated effluents higher than 200 mg/L, the combined treatments were not satisfactory enough to remove target refractory compounds. Therefore, further biological processes are required to complete their biodegradation to meet the effluent limit set by environmental legislation. As this work has contributed to resource recovery as the driving force of landfill management, it is important to note the investment and operational expenses, engineering applicability of the technologies, and their environmental concerns and benefits. If properly managed, nutrient recovery from waste streams offers environmental and socio-economic benefits that would improve public health and create jobs for the local community.

Sedimentary metals in developing tropical watersheds in relation to their urbanization intensities.

The spatial distribution of seven metals (Pb, Hg, Cd, Cr, Ni, Cu, and Zn) and As in the surface sediments from three major tributaries of a tropical urbanizing river network (i.e., Chao Phraya River, Thachin River, and Pasak River) was investigated. An obvious metal concentration gradient in response to the intensity of urbanization was found at inter-watershed and intra-watershed scales. Sediment Quality Guidelines (SQGs) exceedances of several metals (Pb, Cr, Ni, Cu, and Zn) and high ecological risk were primarily identified at the down streams of Chao Phraya and Thachin watersheds, where the social-economic center of the country with intensive industries is located. Stepwise multiple linear regression revealed significant correlations between studied metals and catchment land use pattern (with p < 0.0001 except for Ni and Cr). Particularly, urban land use showed remarkable effect on sedimentary Pb, Cd, Cu, and Zn loads with high coefficients over 0.65. The results of cluster analysis and principal component analysis indicated the dominated urban/industrial sources for Pb, Cd, Cu, and Zn, mixed natural and industrial sources for Cr and Ni, and diffuse sources for Hg and As in the watersheds, respectively.

Reforming MSWM in Sukunan (Yogjakarta, Indonesia): A case-study of applying a zero-waste approach based on circular economy paradigm.

Over the past years, Indonesia, the world's fourth most populous country, has confronted environmental problems due to uncontrolled generation of municipal solid waste (MSW). While the integrated solid waste management (ISWM) represents a critical strategy for Indonesia to control its production, it is also recognized that economic approaches also need to be promoted to address the waste problem concertedly. In this case study, empirical approaches are developed to understand how a volume-based waste fee could be incorporated into MSW collection services and how to apply a zero-waste approach in Indonesia by adapting resource recovery initiatives, adapted from Germany's mature experiences in integrating the CE paradigm into the latter's MSWM practices. Currently, Sukunan village (Yogyakarta, Indonesia) promotes waste reduction at sources in the framework of community-based solid waste management (CBSWM) by mobilizing the local community for waste separation (organic and non-organic) and waste recycling. As a result, about 0.2 million Mt of CO2-eq emissions was avoided annually from local landfills. The economic benefits of recycling activities by the village's community also resulted in 30% reduction of the waste generated. This CBSWM scheme not only saves the government budget on waste collection, transport and disposal, but also extends the lifetime of local landfills as the final disposal sites. By integrating the CE paradigm into its MSWM practices through the implementation of economic instruments and adherence to the rule of law in the same way as Germany does, Indonesia could make positive changes to its environmental policy and regulation of MSW. A sound MSWM in Indonesia could play important roles in promoting the effectiveness of urban development with resource recovery approaches to facilitate its transition towards a CE nationwide in the long-term.

Electroconductive moving bed membrane bioreactor (EcMB-MBR) for single-step decentralized wastewater treatment: Performance, mechanisms, and cost.

Membrane bioreactor (MBR) is an advantageous technology for wastewater treatment. However, efficient nutrient removal and membrane fouling mitigation remain major challenges in its applications. In this study, an electroconductive moving bed membrane bioreactor (EcMB-MBR) was proposed for simultaneous removal of organics and nutrients from domestic wastewater. The EcMB-MBR was composed of a submerged MBR, filled with electrodes and free-floating conductive media. Conductive media were introduced to reduce energy consumption in an electrochemical MBR, to improve nitrogen removal, and to mitigate membrane fouling. The results showed that COD, total nitrogen, and total phosphorus removal was up to 97.1 ± 1.4%, 88.8 ± 4.2%, and 99.0 ± 0.9%, respectively, in comparison with those of 93.4 ± 1.5%, 65.2 ± 5.3%, and 20.4 ± 11.3% in a conventional submerged MBR. Meanwhile, a total membrane resistance reduction of 26.7% was obtained in the EcMB-MBR. The optimized operating condition was determined at an intermittent electricity exposure time of 10 min-ON/10 min-OFF, and a direct current density of 15 A/m2. The interactions between electric current and conductive media were explored to understand the working mechanism in this proposed system. The conductive media reduced 21% of the electrical resistivity in the mixed liquor at a selected packing density of 0.20 (v/v). The combination of electrochemical process and conductive media specially enhanced the reduction of nitrate-nitrogen (NO3--N) through hybrid bio-electrochemical denitrification processes. These mechanisms involved with electrochemically assisted autotrophic denitrification by autotrophic denitrifying bacteria. As a result, 5.2% of NO3--N remained in the effluent of EcMB-MBR in comparison with that of 29.5% in the MBR. Membrane fouling was minimized via both mechanical scouring and electrochemical decomposition/precipitation of organic/particulate foulants. Furthermore, a preliminary cost analysis indicated that an additional operating cost of 0.081 USD/m3, accounting for 10 - 30% increment of the operating cost of a conventional MBR, was needed to enhance the nitrogen and phosphorus removal correspondingly in the EcMB-MBR.

Roles of membrane and organic fouling layers on the removal of endocrine disrupting chemicals in microfiltration.

To understand the adsorption behavior of endocrine disrupting chemicals (EDCs) is important for enhancing the treatment performance and preventing potential secondary pollution caused by EDCs desorption in a microfiltration system. The dynamic adsorption of four representative EDCs, namely estriol (E3), 17ß-estradiol (E2), 17α-ethynylestradiol (EE2), and 4-nonylphenol (4-NP) in a microfiltration system was investigated using the Thomas' model. The product of the equilibrium constant and the total adsorption capacity of the membrane, Ka, for E3, E2, EE2, and 4-NP were 4.91, 9.78, 15.6, and 826, respectively, strongly correlating with the compound octanol-water partition coefficient (KOW). Adsorption appeared to be enhanced when organic fouling formed on the surface of membrane, indicating the role of an additional adsorption column for EDCs acted by a fouling layer in microfiltration. Results of a comparison between the Ka values for clean membrane and fouled membrane illustrated that the significant contribution made by fouling layers may be attributed to the foulant layer's hydrophobicity (in the case of calcium humate layer) and thickness (in the case of calcium alginate layer). This study provided a novel perspective to quantitatively analyze the dynamic adsorption behavior of trace pollutants in membrane process.

Binding TiO2 nanoparticles to forward osmosis membranes via MEMO-PMMA-Br monomer chains for enhanced filtration and antifouling performance.

Forward osmosis (FO) has attracted increasing interest in various applications for water and wastewater treatment and reuse. However, drawbacks caused by its lower-than-expected flux performance and fouling issues remain bottlenecks that limit the wider applications of FO technology. In this research, titanium dioxide (TiO2) nanoparticles were grafted onto two commercially available FO membranes, a cellulose triacetate (CTA) membrane and an aquaporin (AqP) membrane, through a specially designed 3-(trimethoxysilyl)propyl methacrylate-polymethyl methacrylate-bromide (MEMO-PMMA-Br) monomer chain, to improve the filtration performance with regard to pure water flux and organic fouling resistance. The success of the surface coating method was verified using FT-IR, SEM-EDX, and AFM. Approximately 30% titanium coverage was obtained for both FO membranes. A reduction of the contact angle on the modified CTA membrane surface indicated enhanced water permeability and antifouling performance. An adverse effect on the surface hydrophilicity of the modified AqP membrane may be attributed to the obstruction of aquaporins from the feed solution due to the coverage of MEMO-PMMA-Br monomers and TiO2 nanoparticles. The pure water flux of both membranes was significantly improved, with average flux increases of 73.4% and 13.6% identified for the modified CTA and AqP membranes, respectively. In addition, the antifouling performance of the AqP membrane was greatly enhanced after surface modification, attributed to the integrated effects of foulant photodegradation (catalyzed by TiO2 nanoparticles at the interface) and the prevention of functional water channels being blocked by organic foulants due to TiO2 coverage.

High loss factor piezoelectric damping composite with three-dimensional reduced graphene oxide as the conductive phase.

In this study, a lead zirconate titanate (PZT)/in situ polymerized polyurethane (PU) composite with three-dimensional (3D) reduced graphene oxide (rGO) as the conductive phase was prepared and the potential of 3D rGO to enhance the damping properties was investigated. The conductivity and damping properties of the composite were systematically investigated. The results show that the conductive threshold of the composite is reached at a very low rGO content of about 0.7 wt% by using the 3D rGO structure. The best damping performance of the piezoelectric damping composite is achieved at the conductive threshold, where the loss factor is 0.22 (almost 41%) higher and the temperature range where tan δ ≥ 0.3 is 13.2 °C (almost 84%) wider than those of the PU matrix. A composite consisting of only PU and rGO sheets without the 3D structure was prepared for comparison. The conductive threshold of this composite is more than 0.9 wt% and the highest tensile strength is 5.63 MPa when the rGO content is 0.6 wt%, indicating that the 3D structure reduces the use of the conductive phase and does not significantly affect the tensile strength of the matrix.

Facile fabrication of polyurethane-based graphene foam/lead zirconate titanate/polydimethylsiloxane composites with good damping performance.

In modern society, much more noise and vibration are produced in traffic and industrial systems, which is harmful to human health, equipment safety and the environment, therefore damping materials are becoming increasingly important. A piezoelectric damping composite could broaden the damping temperature range and enhance the damping loss factor simultaneously by introducing a dissipation route of mechanical to electrical to heat energy. In this paper, a novel piezo-damping polyurethane-based graphene foam (PGF)/PZT/PDMS composite (PGPP) was facilely fabricated using a one-step vacuum-assisted filling method. Using three-dimensional graphene foam as a conductive phase, and due to its three-dimensional network structure, the PGPP composite can reach the percolation threshold with a dramatically reduced amount of RGO sheets. The effects of PZT content and frequency on the damping properties of the PGPP composites were investigated, and the results show that the storage modulus, loss modulus and loss factor of the PGPPs are all greatly enhanced compared to those of the PDMS matrix. Due to their flexibility, the PGPP composites can be used as good surface coating damping materials over a wide temperature range at different frequencies.

Performance analysis of active disturbance rejection tracking control for a class of uncertain LTI systems.

The paper considers the tracking problem for a class of uncertain linear time invariant (LTI) systems with both uncertain parameters and external disturbances. The active disturbance rejection tracking controller is designed and the resulting closed-loop system's characteristics are comprehensively studied. In the time-domain, it is proven that the output of closed-loop system can approach its ideal trajectory in the transient process against different kinds of uncertainties by tuning the bandwidth of extended state observer (ESO). In the frequency-domain, different kinds of parameters' influences on the phase margin and the crossover frequency of the resulting control system are illuminated. Finally, the effectiveness and robustness of the controller are verified through the actuator position control system with uncertain parameters and load disturbances in the simulations.

Seawater-driven forward osmosis for enriching nitrogen and phosphorous in treated municipal wastewater: effect of membrane properties and feed solution chemistry.

Seawater-driven forward osmosis (FO) is considered to be a novel strategy to concentrate nutrients in treated municipal wastewater for further recovery as well as simultaneous discharge of highly purified wastewater into the sea with low cost. As a preliminary test, the performance of FO membranes in concentrating nutrients was investigated by both batch experiments and model simulation approaches. With synthetic seawater as the draw solution, the dissolved organic carbon, phosphate, and ammonia in the effluent from a membrane bioreactor (MBR) treating municipal wastewater were 2.3-fold, 2.3-fold, and 2.1-fold, respectively, concentrated by the FO process with approximately 57% of water reduction. Most of the dissolved components, including trace metals in the MBR effluent, were highly retained (>80%) in the feed side, indicating high water quality of permeate to be discharged. The effect of membrane properties on the nutrient enrichment performance was investigated by comparing three types of FO membranes. Interestingly, a polyamide membrane possessing a high negative charge demonstrated a poor capability of retaining ammonia, which was hypothesized because of an ion exchange-like mechanism across the membrane prompted by the high ionic concentration of the draw solution. A feed solution pH of 7 was demonstrated to be an optimum condition for improving the overall retention of nutrients, especially for ammonia because of the pH-dependent speciation of ammonia/ammonium forms. The modeling results showed that higher than 10-fold concentrations of ammonia and phosphate are achievable by seawater-driven FO with a draw solution to feed solution volume ratio of 2:1. The enriched municipal wastewater contains nitrogen and phosphorous concentrations comparable with typical animal wastewater and anaerobic digestion effluent, which are used for direct nutrient recovery.