Toward Excellent Energy Storage Performance via Well-Aligned and Isolated Interfaces in Multicomponent Polypropylene-Based All-Organic Polymer Dielectric Films.

Polypropylene (PP) serves as an excellent commercialized polymer dielectric film owing to its high breakdown strength, excellent self-healing ability, and flexibility. However, its low dielectric constant causes the large volume of the capacitor. Constructing multicomponent polypropylene-based all-organic polymer dielectric films is a facile strategy for achieving high energy density and efficiency simultaneously. Thereinto, the interfaces between the components become the key factors that determine the energy storage performance of the dielectric films. In this work, we propose to fabricate high-performance polyamide 513 (PA513)/PP all-organic polymer dielectric films via the construction of abundant well-aligned and isolated nanofibrillar interfaces. Laudably, a significant enhancement in the breakdown strength is achieved from 573.1 MV/m of pure PP to 692.3 MV/m with 5 wt % of PA513 nanofibrils. Besides, a maximum discharge energy density of about 4.4 J/cm2 is realized with 20 wt % of PA513 nanofibrils, which is about 1.6-folds higher than pure PP. Simultaneously, the energy efficiency of samples with modulated interfaces maintains higher than 80% up to 600 MV/m, which is much higher than pure PP of about 40.7% at 550 MV/m. This work provides a new strategy to fabricate high-performance multicomponent all-organic polymer dielectric films on an industrial scale.

Trend shifts in satellite-derived vegetation growth in Central Eurasia, 1982-2013.

Central Eurasian vegetation is critical for the regional ecological security and the global carbon cycle. However, climatic impacts on vegetation growth in Central Eurasia are uncertain. The reason for this uncertainty lies in the fact that the response of vegetation to climate change showed nonlinearity, seasonality and differences among plant functional types. Based on remotely sensed vegetation index and in-situ meteorological data for the years 1982-2013, in conjunction with the latest land cover type product, we analyzed how vegetation growth trend varied across different seasons and evaluated vegetation response to climate variables at regional, biome and pixel scales. We found a persistent increase in the growing season NDVI over Central Eurasia during 1982-1994, whereas this greening trend has stalled since the mid-1990s in response to increased water deficit. The stalled trend in the growing season NDVI was largely attributed by summer and autumn NDVI changes. Enhanced spring vegetation growth after 2002 was caused by rapid spring warming. The response of vegetation to climatic factors varied in different seasons. Precipitation was the main climate driver for the growing season and summer vegetation growth. Changes in temperature and precipitation during winter and spring controlled the spring vegetation growth. Autumn vegetation growth was mainly dependent on the vegetation growth in summer. We found diverse responses of different vegetation types to climate drivers in Central Eurasia. Forests were more responsive to temperature than to precipitation. Grassland and desert vegetation responded more strongly to precipitation than to temperature in summer but more strongly to temperature than to precipitation in spring. In addition, the growth of desert vegetation was more dependent on winter precipitation than that of grasslands. This study has important implications for improving the performance of terrestrial ecosystem models to predict future vegetation response to climate change.

Impacts of climate warming on vegetation in Qaidam Area from 1990 to 2003.

The observed warming trend in the Qaidam area, an arid basin surrounded by high mountains, has caused land surface dynamics that are detectable using remotely sensed data. In this paper, we detected land-cover changes in the Qaidam Area between 1990 and 2003 in attempt to depict its spatial variability. The land-cover changes were categorized into two trends: degradation and amelioration, and their spatial patterns were examined. Then we estimated the correlation coefficients between growing-season NDVI and several climatic factors with the consideration of duration and lagging effects. The results show that the inter-annual NDVI variations are positively correlated with May to July precipitations, but not significantly correlated with sunshine duration. We observed no obvious trend in precipitation or sunshine duration from 1990 to 2003. Thus, the authors suggest that their slight fluctuations may not be responsible to the decade-scaled land-cover changes. However, our results indicate a good positive relationship between the NDVI trend and climate warming in the ameliorated areas, but a negative one in the degraded areas. By statistical analyses, we found that degradations mainly occurred at the oasis boundaries and at lower elevations in the non-oasis regions where effective soil moisture might have been reduced by the warming-caused increase in evapotranspiration. At higher elevations where thermal condition acts as a major limiting factor, ameliorations were unequivocally detected, which is attributable to the direct facilitation by temperature increases. We suggest that the impacts of the observed climate warming on vegetation are spatially heterogeneous, depending on the combinations of thermal condition and moisture availability.