FDTD modeling of excitation-balanced, mJ-level pulse amplifiers in Yb-doped double-clad optical fibers.

A finite-difference time-domain (FDTD) simulation of Yb-doped cladding-pumped, mJ-level, excitation-balanced fiber pulse amplifiers (EBFAs) is presented. In EBFAs, two pumps, one above (anti-Stokes pump, or ASP) and one below (Stokes pump, or SP) the signal wavelength, are utilized to reduce the net thermal energy generated due to the quantum defect. From the results of the FDTD simulation, detailed analyses on the fiber length optimization, excited Yb3+ population evolution, pump and signal power evolution, optical-to-optical (o-o) conversion efficiency, wall plug efficiency, as well as thermal energy generation are performed. For example, with an ASP at 990 nm and a SP at 975 nm, only 2.3 µJ of thermal energy is produced when generating a 2 mJ output pulse at 985 nm, whereas a pulse amplifier with only SP pumping rendering the same 2 mJ output gives more than 10 times the thermal energy. In the meantime, the system maintains an o-o efficiency of 8.43% and wall plug efficiency of 6.6%. The results here indicate the feasibility of the power-scaling of excitation-balanced laser systems, and the FDTD model will be beneficial for the design and optimization of such systems. The first half of this paper presents the FDTD model and provides an example calculation outlining the modeling procedure. The remaining half details the impact of varying laser parameters on system performance. These include pumping and input signal energies, repetition rates, and selection of the ASP, SP, and signal wavelengths. The results presented herein can also be extended to excitation balancing in other solid-state laser systems, such as Yb:YAG and Tm:YAG lasers.

Experimental comparison of silica fibers for laser cooling.

Laser cooling in silica has recently been demonstrated, but there is still a lack of understanding on how fiber composition, core size, and OH- contamination influence cooling performance. In this work, six Yb-doped silica fibers were studied to illuminate the influence of these parameters. The best fiber cooled by -70mK with only 170 mW/m of absorbed pump power at 1040 nm, which corresponds to twice as much heat extracted per unit length compared to the first reported laser cooling in silica. This new fiber has an extremely low OH- loss and a higher Al concentration (2.0 wt.% Al), permitting a high Yb concentration (2.52 wt.% Yb) without incurring significant quenching. Strong correlations were found between the absorptive loss responsible for heating and the loss measured at 1380 nm due to absorption by OH-.

Laser cooling in a silica optical fiber at atmospheric pressure.

For the first time, to the best of our knowledge, laser cooling is reported in a silica optical fiber. The fiber has a 21-µm diameter core doped with 2.06 wt.% ${{\rm Yb}^{3 + }}$Yb3+ and co-doped with ${{\rm Al}_2}{{\rm O}_3}$Al2O3 and ${{\rm F}^ - }$F- to increase the critical quenching concentration by a factor of 16 over the largest reported values for the Yb-doped silica. Using a custom slow-light fiber Bragg grating sensor, temperature changes up to $ - {50}\;{\rm mK}$-50mK were measured with 0.33 W/m of absorbed pump power per unit length at 1040 nm. The measured dependencies of the temperature change on the pump power and the pump wavelength are in excellent agreement with predictions from an existing model, and they reflect the fiber's groundbreaking quality for the radiation-balanced fiber lasers.

Efficient and chromaticity-stable flexible white organic light-emitting devices based on organic-inorganic hybrid color-conversion electrodes.

We have developed a novel organic-inorganic hybrid color conversion electrode composed of Ag NWs/poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) via a solution process, which is the first report on a color conversion electrode for applications in flexible optoelectronics. Using the Ag NWs/MEH-PPV composite film as the anode on polyethylene terephthalate substrate and combined with a blue organic light emitting devices (OLEDs) unit employing bis(3,5-difluoro-2-(2-pyridyl)phenyl-(2-carboxypyridyl)iridium(iii)) (Flrpic) in 1,3-bis(carbazol-9-yl)benzene (mCP) as the emitting layer, a highly efficient and chromaticity-stable color-conversion flexible white OLEDs (WOLEDs) is achieved with a maximum current efficiency of 20.5 cd A-1. To the best of our knowledge, this is the highest efficiency reported for color-conversion based flexible WOLEDs. Our work provides an approach to achieving high-performance flexible WOLEDs devices and demonstrates great potential for lighting and display applications.

Measurement and Analysis of Thermal Conductivity of Ti3C2Tx MXene Films.

A new class of 2D materials named "MXene" has recently received significant research interest as they have demonstrated great potential for the applications in batteries, supercapacitors, and electronic devices. However, the research on their thermal properties is still very limited. In this work, Ti3C2Tx films were prepared by the vacuum-assisted filtration of delaminated nano-flake Ti3C2Tx MXenes. The thermal and electrical conductivity of the Ti3C2Tx films were measured by the state-of-the-art T-type method. The results showed that the effective thermal conductivity of the films increased from 1.26 W·m-1·K-1 at 80 K to 2.84 W·m-1·K-1 at 290 K, while the electrical conductivity remained at 12,800 Ω-1·m-1 for the same temperature range. Thermal resistance model was applied to evaluate the inherent thermal conductivity of the Ti3C2Tx flakes, which was estimated to be in the range of tens to hundreds W·m-1·K-1.

Thermal Conductivity Performance of Polypropylene Composites Filled with Polydopamine-Functionalized Hexagonal Boron Nitride.

Mussel-inspired approach was attempted to non-covalently functionalize the surfaces of boron nitride (BN) with self-polymerized dopamine coatings in order to reduce the interfacial thermal barrier and enhance the thermal conductivity of BN-containing composites. Compared to the polypropylene (PP) composites filled with pristine BN at the same filler content, thermal conductivity was much higher for those filled with both functionalized BN (f-BN) and maleic anhydride grafted PP (PP-g-ma) due to the improved filler dispersion and better interfacial filler-matrix compatibility, which facilitated the development of more thermal paths. Theoretical models were also applied to predict the composite thermal conductivity in which the Nielsen model was found to fit well with the experimental results, and the estimated effective aspect ratio of fillers well corresponded to the degree of filler aggregation as observed in the morphological study.