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1.
Chem Commun (Camb) ; 54(84): 11969-11972, 2018 Oct 18.
Artículo en Inglés | MEDLINE | ID: mdl-30289137

RESUMEN

Three kinds of hydrophobic/acidic bifunctional ionic liquids, which contain two different anions, were synthesized and utilized as catalysts for the conversion of cellulosic saccharides into alkyl glucosides, which exhibit a high catalytic conversion for cellobiose and cellulose with a low degree of crystallinity; the catalyst can be easily recovered and reused.

2.
Chem Commun (Camb) ; (44): 4626-8, 2006 Nov 28.
Artículo en Inglés | MEDLINE | ID: mdl-17082864

RESUMEN

Ionic liquids with buffering characteristics, synthesized by the reaction of [RMIM]OH base moieties with phthalic and tartaric acid, respectively, are potential reagents for controlling pH in non-aqueous media; remarkable [Base]/[Acid] molar ratio dependence of the catalytic activities has been observed in the hydrogenation of olefins with [RuCl2(PPh3)3] complex in DMF and [BMIM][BF4].


Asunto(s)
Imidazoles/química , Líquidos Iónicos/química , Tampones (Química) , Concentración de Iones de Hidrógeno , Imidazoles/síntesis química , Líquidos Iónicos/síntesis química , Estructura Molecular , Ácidos Ftálicos/química , Tartratos/química
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