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1.
Materials (Basel) ; 17(5)2024 Mar 06.
Artículo en Inglés | MEDLINE | ID: mdl-38473681

RESUMEN

Hot compression tests were conducted to explore the deformation behavior of an extruded 7075 aluminum alloy bar at elevated temperatures. Specimens with 0°, 45°, and 90° angles along the extrusion direction were prepared. The compression temperatures were 300 and 400 °C, and the strain rates ranged from 0.001 to 0.1 s-1. The corresponding microstructures were characterized via OM and TEM, and the macroscopic texture was tested using XRD. The results indicated that the strength of the 7075 alloy decreases with higher compression temperatures and is in a proportional relationship with respect to the strain rate. During high-temperature compression, it is easier to stimulate atomic diffusion in the matrix, which can improve thermal activation abilities and facilitate dynamic recovery and dynamic recrystallization. In addition, the coarsening of precipitates also contributed to dynamic softening. When compressed at 300 °C, the stress levels of the 0° specimens ranked first, and those for the 45° specimens were the lowest. When compressed at 400 °C, the flow stresses of the specimens along three directions were comparable. The anisotropic mechanical behavior can be explained by the fiber grains and brass {011} <211> texture component. However, higher temperature deformation leads to recrystallization, which can weaken the anisotropy of mechanical properties.

2.
Materials (Basel) ; 16(23)2023 Nov 29.
Artículo en Inglés | MEDLINE | ID: mdl-38068175

RESUMEN

The investigation of thermal deformation behavior plays a significant role in guaranteeing the overall performance of alloy materials. In this manuscript, a series of isothermal compression tests at different temperatures (300, 350, 400, and 450 °C) and strain rates (0.001, 0.01, 0.1, and 1 s-1) were conducted to study the thermal deformation behavior of 7075 aluminum alloy. Subsequently, processing maps at a strain from 0.4 to 1.39 were established according to the stress-strain data obtained from various deformation parameters. The microstructural evolution of the target alloy was observed with an optical microscope and transmission electron microscope. The results reveal the unstable regions are located at (360-450 °C, 0.04-1 s-1) and (300-315 °C, 0.01-0.22 s-1). Precipitation particles, pinned dislocations, and highly dislocated areas can be observed in the microstructure of the alloy in the unstable regions. This is a potential crack and defect formation point. The identified optimum processing parameters are located at (375-450 °C, 0.001-0.03 s-1), with a maximum dissipation efficiency of 0.6.

3.
Materials (Basel) ; 16(21)2023 Nov 02.
Artículo en Inglés | MEDLINE | ID: mdl-37959616

RESUMEN

The tensile properties of rolled 6082-T6 aluminum alloy were tested at a high temperature, and the influences of tensile temperature on its flow stress and anisotropy were studied. The microstructure evolution was characterized using optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD). It was concluded that the tensile strength of the studied alloy decreases with increasing temperature. In higher-temperature deformation, the dislocation density decreases alongside the coarsening of precipitates, leading to a decrease in deformation resistance, and increase in the number of dimples and deepening of their sizes, exhibiting good plasticity. The alloy displays anisotropic mechanical properties at 200 °C due to the elongated grains and the orientation of the α-phase. The anisotropy becomes weaker with increasing temperature. There is no evident anisotropy at 400 °C, as the slip systems are activated more easily and the grains begin to recrystallize.

4.
Chemosphere ; 303(Pt 1): 134943, 2022 Sep.
Artículo en Inglés | MEDLINE | ID: mdl-35569635

RESUMEN

The chemical absorption-bioelectrochemical reduction (CABER) integrated system provides an alternative of good potential for NO removal. The efficient utilization of cathode electrons directly determines the system performance and operating cost. Herein, we synthesize a polypyrrole/carbon nanotubes (PPy/CNTs) composite to engineer a micro-and nanoscale interface with low resistance and high biocompatibility between the cathode and biofilms in the CABER system. The resulting PPy/CNTs biocathodes exhibit 36.4% increase in biomass density, 40.7%-302.6% increase in Faraday efficiency along Fe(III)EDTA reduction, and 204% increase in Fe(II)EDTA-NO reduction rate. The enrichment of functional microorganisms is validated to be a key strengthening factor, as the proportion of which increased from 57.9% to 84.6%. Moreover, for efficient electron transfer and utilization, a low-resistance electron transfer route, "electrode substrate → PPy (→ CNTs) → microbial cells → Fe(III)EDTA or Fe(II)EDTA-NO", is realized in the multiscale conductive networks constructed of PPy/CNTs composite and microbial nanowires.


Asunto(s)
Nanotubos de Carbono , Ácido Edético , Electrones , Nanotubos de Carbono/química , Polímeros/química , Pirroles/química
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