RESUMEN
There is increasing attention on developing efficient processes including circular economy principles, and obtaining fuels from wastewater treatment feedstocks is among the most promising. As a wastewater treatment byproduct, sewage sludge is a source of lipids that can be converted to biodiesel in a transesterification process. Economic and environmental analysis have been applied to a 60 m3/h sewage sludge plant, exploring 32 process alternatives. Using solvent extraction from wet sewage sludge, the high cost associated with the drying step is skipped. The wet alternatives with low amounts of solvent and acid usage depicted higher performance compared to the dry ones. Incorporating additional extraction stages increases both the financial gains and environmental impacts. As a result, a multicriteria analysis is implemented to ascertain the optimum process based on different priorities. The case with 0.5:1 (v/v) of hexane to biomass ratio, 3-stage extractor, 60 min residence time and pH 4 was the optimum alternative in most criteria.
Asunto(s)
Biocombustibles , Aguas del Alcantarillado , Biocombustibles/análisis , Esterificación , SolventesRESUMEN
This paper reports a voltammetric sensor based on copper oxide nanoparticles on nitrogen-doped reduced graphene oxide nanocomposite (N-rGO/CuO)-ionic liquid modified carbon paste electrode (N-rGO/CuO-ILCPE) for determining the hydroquinone (HQ). The N-rGO/CuO was prepared by a facile protocol, followed by characterization via fourier transform-infrared (FT-IR) patterns, field emission-scanning electron microscopy (FE-SEM), energy dispersive X-ray (EDX), and X-ray diffraction (XRD) analysis. The electrochemical behaviour was linearly symmetrical to various hydroquinone levels (1.0-600.0 µM) with a narrow limit of detection (LOD = 0.25 µM). The diffusion coefficient was also estimated to be 4.1 × 10-6 cm2/s. The N-rGO/CuO-ILCPE was impressively applicable in determination of hydroquinone in the real specimens.