Measuring and evaluating colorimetric properties of samples from loess-paleosol sequences.

Colorimetric measurements are valuable in studying paleoenvironmental changes in sediment archives such as loess-paleosol sequences. These measurements allow for the identification of climate-sensitive minerals such as hematite, goethite, and secondary carbonates, as well as the observation of stratigraphic changes influenced by paleoclimate variations. Herein, a detailed workflow protocol emphasizing mineral abundance extraction by determining true band amplitudes is presented. Moreover, we present a protocol for colorimetric measurements that eliminates container bias, allowing the analysis and re-analysis of stored sediment quickly and inexpensively. Finally, we introduce a new R-package ('LESLIE') for graphical data display and enhancement. The protocol and its validation are demonstrated on the Suhia Kladenetz loess-paleosol sequence of northern Bulgaria.•A detailed workflow protocol eliminating container bias in colorimetric measurements and extracting mineral abundances is presented.•The protocol is independently validated with aid of Attenuated Total Reflectance Fourier Transform mid-infrared (ATR-FTIR) spectroscopic experiments.•Stratigraphic color enhancement using the R-package 'LESLIE' is facilitated by a user-friendly R-shiny application.

Insolation-paced sea level and sediment flux during the early Pleistocene in Southeast Asia.

Global marine archives from the early Pleistocene indicate that glacial-interglacial cycles, and their corresponding sea-level cycles, have predominantly a periodicity of ~ 41 kyrs driven by Earth's obliquity. Here, we present a clastic shallow-marine record from the early Pleistocene in Southeast Asia (Cholan Formation, Taiwan). The studied strata comprise stacked cyclic successions deposited in offshore to nearshore environments in the paleo-Taiwan Strait. The stratigraphy was compared to both a δ18O isotope record of benthic foraminifera and orbital parameters driving insolation at the time of deposition. Analyses indicate a strong correlation between depositional cycles and Northern Hemisphere summer insolation, which is precession-dominated with an obliquity component. Our results represent geological evidence of precession-dominated sea-level fluctuations during the early Pleistocene, independent of a global ice-volume proxy. Preservation of this signal is possible due to the high-accommodation creation and high-sedimentation rate in the basin enhancing the completeness of the stratigraphic record.

Organic carbon burial is paced by a ~173-ka obliquity cycle in the middle to high latitudes.

Earth's climate system is complex and inherently nonlinear, which can induce some extraneous cycles in paleoclimatic proxies at orbital time scales. The paleoenvironmental consequences of these extraneous cycles are debated owing to their complex origin. Here, we compile high-resolution datasets of total organic carbon (TOC) and stable carbon isotope (δ13Corg) datasets to investigate organic carbon burial processes in middle to high latitudes. Our results document a robust cyclicity of ~173 thousand years (ka) in both TOC and δ13Corg The ~173-ka obliquity-related forcing signal was amplified by internal climate feedbacks of the carbon cycle under different geographic and climate conditions, which control a series of sensitive climatic processes. In addition, our new and compiled records from multiple proxies confirm the presence of the obliquity amplitude modulation (AM) cycle during the Mesozoic and Cenozoic and indicate the usefulness of the ~173-ka cycle as geochronometer and for paleoclimatic interpretation.

A tale of shifting relations: East Asian summer and winter monsoon variability during the Holocene.

Understanding the dynamics between the East Asian summer (EASM) and winter monsoon (EAWM) is needed to predict their variability under future global warming scenarios. Here, we investigate the relationship between EASM and EAWM as well as the mechanisms driving their variability during the last 10,000 years by stacking marine and terrestrial (non-speleothem) proxy records from the East Asian realm. This provides a regional and proxy independent signal for both monsoonal systems. The respective signal was subsequently analysed using a linear regression model. We find that the phase relationship between EASM and EAWM is not time-constant and significantly depends on orbital configuration changes. In addition, changes in the Atlantic Meridional Overturning circulation, Arctic sea-ice coverage, El Niño-Southern Oscillation and Sun Spot numbers contributed to millennial scale changes in the EASM and EAWM during the Holocene. We also argue that the bulk signal of monsoonal activity captured by the stacked non-speleothem proxy records supports the previously argued bias of speleothem climatic archives to moisture source changes and/or seasonality.

Smoothed millennial-scale palaeoclimatic reference data as unconventional comparison targets: Application to European loess records.

Millennial-scale palaeoclimate variability has been documented in various terrestrial and marine palaeoclimate proxy records throughout the Northern Hemisphere for the last glacial cycle. Its clear expression and rapid shifts between different states of climate (Greenland Interstadials and Stadials) represents a correlation tool beyond the resolution of e.g. luminescence dating, especially relevant for terrestrial deposits. Usually, comparison of terrestrial proxy datasets and the Greenland ice cores indicates a complex expression of millennial-scale climate variability as recorded in terrestrial geoarchives including loess. Loess is the most widespread terrestrial geoarchive of the Quaternary and especially widespread over Eurasia. However, loess often records a smoothed representation of millennial-scale variability without all fidelity when compared to the Greenland data, this being a relevant limiting feature in integrating loess with other palaeoclimate records. To better understand the loess proxy-response to millennial-scale climate variability, we simulate a proxy signal smoothing by natural processes through application of low-pass filters of δ18O data from Greenland, a high-resolution palaeoclimate reference record, alongside speleothem isotope records from the Black Sea-Mediterranean region. We show that low-pass filters represent rather simple models for better constraining the expression of millennial-scale climate variability in low sedimentation environments, and in sediments where proxy-response signals are most likely affected by natural smoothing (by e.g. bioturbation). Interestingly, smoothed datasets from Greenland and the Black Sea-Mediterranean region are most similar in the last ~15 ka and between ~50-30 ka. Between ~30-15 ka, roughly corresponding to the Last Glacial Maximum and the deglaciation, the records show dissimilarities, challenging the construction of robust correlative time-scales in this age range. From our analysis it becomes apparent that patterns of palaeoclimate signals in loess-palaeosol sequences often might be better explained by smoothed Greenland reference data than the original high-resolution Greenland dataset, or other reference data. This opens the possibility to better assess the temporal resolution and palaeoclimate potential of loess-palaeosol sequences in recording supra-regional climate patterns, as well as to securely integrate loess with other chronologically better-resolved palaeoclimate records.

Shift of large-scale atmospheric systems over Europe during late MIS 3 and implications for Modern Human dispersal.

Understanding the past dynamics of large-scale atmospheric systems is crucial for our knowledge of the palaeoclimate conditions in Europe. Southeastern Europe currently lies at the border between Atlantic, Mediterranean, and continental climate zones. Past changes in the relative influence of associated atmospheric systems must have been recorded in the region's palaeoarchives. By comparing high-resolution grain-size, environmental magnetic and geochemical data from two loess-palaeosol sequences in the Lower Danube Basin with other Eurasian palaeorecords, we reconstructed past climatic patterns over Southeastern Europe and the related interaction of the prevailing large-scale circulation modes over Europe, especially during late Marine Isotope Stage 3 (40,000-27,000 years ago). We demonstrate that during this time interval, the intensification of the Siberian High had a crucial influence on European climate causing the more continental conditions over major parts of Europe, and a southwards shift of the Westerlies. Such a climatic and environmental change, combined with the Campanian Ignimbrite/Y-5 volcanic eruption, may have driven the Anatomically Modern Human dispersal towards Central and Western Europe, pointing to a corridor over the Eastern European Plain as an important pathway in their dispersal.

Tracing the influence of Mediterranean climate on Southeastern Europe during the past 350,000 years.

Loess-palaeosol sequences are valuable archives of past environmental changes. Although regional palaeoclimatic trends and conditions in Southeastern Europe have been inferred from loess sequences, large scale forcing mechanisms responsible for their formation have yet to be determined. Southeastern Europe is a climatically sensitive region, existing under the strong influence of both Mediterranean and continental climates. Establishment of the spatial and temporal evolution and interaction of these climatic areas is essential to understand the mechanisms of loess formation. Here we present high-resolution grain-size, environmental magnetic, spectrophotometric and geochemical data from the Stalac section in the Central Balkans (Serbia) for the past ~350,000 years. The goal of this study is to determine the influence of the Mediterranean climate during this period. Data show that the Central Balkans were under different atmospheric circulation regimes, especially during Marine Isotope Stages 9 and 7, while continental climate prevailed further north. We observe a general weakening of the Mediterranean climate influence with time. Our data suggest that Marine Isotope Stage 5 was the first interglacial in the Central Balkans that had continental climate characteristics. This prominent shift in climatic conditions resulted in unexpectedly warm and humid conditions during the last glacial.