Preparation of nanochitin using deep eutectic solvents.

Chitin is an abundant and renewable non-wood biopolymer. Nanochitin is formed by the assembly of chitin molecules, which has the advantages of large tensile strength, high specific surface area, and biodegradability, so it has been widely used. However, the traditional methods of preparing nanochitin have many drawbacks. As the new generation of green solvents, deep eutectic solvents (DESs) have been successfully applied in the fields of chitin dissolution, extraction, and nanochitin preparation. In this review, the relevant knowledge of chitin, nanochitin, and DESs was first introduced. Then, the application status of DESs in the fields of chitin was summarized, with a focus on the preparation of nanochitin using DESs. In conclusion, this review provided a comprehensive analysis of the published literature and proposed insights and development trends in the field of preparation of nanochitin using DESs, aiming to provide guidance and assistance for future researchers.

Nanomicellar Electrolyte To Control Release Ions and Reconstruct Hydrogen Bonding Network for Ultrastable High-Energy-Density Zn-Mn Battery.

Zn-Mn batteries with two-electron conversion reactions simultaneously on the cathode and anode harvest a high voltage plateau and high energy density. However, the zinc anode faces dendrite growth and parasitic side reactions while the Mn2+/MnO2 reaction on the cathode involves oxygen evolution and possesses poor reversibility. Herein, a novel nanomicellar electrolyte using methylurea (Mu) has been developed that can encapsulate ions in the nanodomain structure to guide the homogeneous deposition of Zn2+/Mn2+ in the form of controlled release under an external electric field. Consecutive hydrogen bonding network is broken and a favorable local hydrogen bonding system is established, thus inhibiting the water-splitting-derived side reactions. Concomitantly, the solid-electrolyte interface protective layer is in situ generated on the Zn anode, further circumventing the corrosion issue resulting from the penetration of water molecules. The reversibility of the Mn2+/MnO2 conversion reaction is also significantly enhanced by regulating interfacial wettability and improving nucleation kinetics. Accordingly, the modified electrolyte endows the symmetric Zn∥Zn cell with extended cyclic stability of 800 h with suppressed dendrites growth at an areal capacity of 1 mAh cm-2. The assembled Zn-Mn electrolytic battery also demonstrates an exceptional capacity retention of nearly 100% after 800 cycles and a superior energy density of 800 Wh kg-1 at an areal capacity of 0.5 mAh cm-2.