RESUMEN
Regulation of the exciton generation, diffusion, and carrier transport, as well as optimization of the non-radiative energy loss could further overcome the power conversion efficiency limitation of organic solar cells. However, the relationship between exciton properties and non-radiative energy loss has seldom been investigated. Herein, taking D18-series devices as the research model, the exciton diffusion length (LD) and hole transfer dynamics can be remarkably improved by the variation of electron-withdrawing halogen and the non-radiative energy loss simultaneously can be suppressed. By combining the analysis results of hole transfer, exciton diffusion, charge separation, and recombination, this work demonstrates that the photo-induced exciton in the chlorinated polymer donor can diffuse to a longer distance within the effective exciton lifetime, suppress the exciton recombination, and enhance device performance. The results define the relationship between the exciton behaviors and non-radiative energy loss and further reveal the significance of controlling the bulk heterojunction with superior photo-physical properties.
RESUMEN
The energy difference between a singlet exciton and twice of a triplet exciton, ΔESF, provides the thermodynamic driving force for singlet exciton fission (SF). This work reports a systematic investigation on the effect of ΔESF on SF efficiency of five heteroacenes in their solutions. The low-temperature, near-infrared phosphorescence spectra gave the energy levels of the triplet excitons, allowing us to identify the values of ΔESF, which are -0.58, -0.34, -0.31, -0.32, and -0.34 eV for the thiophene, benzene, pyridine, and two tetrafluorobenzene terminated molecules, respectively. Corresponding SF efficiencies of the five heteroacenes in 0.02 M solutions were determined via femtosecond transient absorption spectroscopy to be 117%, 124%, 140%, 132%, and 135%, respectively. This result reveals that higher ΔESF is not, as commonly expected, always beneficial for higher SF efficiency in solution phase. On the contrary, excessive exoergicity results in reduction of SF efficiency in the heteroacenes due to the promotion of other competitive exciton relaxation pathways. Therefore, it is important to optimize thermodynamic driving force when designing organic materials for high SF efficiency.
RESUMEN
Two molecules containing a central diketopyrrolopyrrole and two oligothiophene units have been designed and synthesized. Comparisons between the molecules containing terminal F (FDPP) and Cl (CDPP) atoms allowed us to evaluate the effects of halogenation on the photovoltaic properties of the small molecule organic solar cells (OSCs). The OSCs devices employing FDPP:PC71BM films showed power conversion efficiencies up to 4.32%, suggesting that fluorination is an efficient method for constructing small molecules for OSCs.
