Oscillating paramagnetic Meissner effect and Berezinskii-Kosterlitz-Thouless transition in underdoped Bi2Sr2CaCu2O8+δ.

Superconducting phase transitions in two dimensions lie beyond the description of the Ginzburg-Landau symmetry-breaking paradigm for three-dimensional superconductors. They are Berezinskii-Kosterlitz-Thouless (BKT) transitions of paired-electron condensate driven by the unbinding of topological excitations, i.e. vortices. The recently discovered monolayers of layered high-transition-temperature ([Formula: see text]) cuprate superconductor Bi2Sr2CaCu2O8+δ (Bi2212) meant that this 2D superconductor promised to be ideal for the study of unconventional superconductivity. But inhomogeneity posed challenges for distinguishing BKT physics from charge correlations in this material. Here, we utilize the phase sensitivity of scanning superconducting quantum interference device microscopy susceptometry to image the local magnetic response of underdoped Bi2212 from the monolayer to the bulk throughout its phase transition. The monolayer segregates into domains with independent phases at elevated temperatures below [Formula: see text]. Within a single domain, we find that the susceptibility oscillates with flux between diamagnetism and paramagnetism in a Fraunhofer-like pattern up to [Formula: see text]. The finite modulation period, as well as the broadening of the peaks when approaching [Formula: see text] from below, suggests well-defined vortices that are increasingly screened by the dissociation of vortex-antivortex plasma through a BKT transition. In the multilayers, the susceptibility oscillation differs in a small temperature regime below [Formula: see text], consistent with a dimensional crossover led by interlayer coupling. Serving as strong evidence for BKT transition in the bulk, we observe a sharp jump in phase stiffness and paramagnetism at small fields just below [Formula: see text]. These results unify the superconducting phase transitions from the monolayer to the bulk underdoped Bi2212, and can be collectively referred to as the BKT transition with interlayer coupling.

Seeded growth of single-crystal black phosphorus nanoribbons.

Two-dimensional materials have emerged as an important research frontier for overcoming the challenges in nanoelectronics and for exploring new physics. Among them, black phosphorus, with a combination of a tunable bandgap and high mobility, is one of the most promising systems. In particular, black phosphorus nanoribbons show excellent electrostatic gate control, which can mitigate short-channel effects in nanoscale transistors. Controlled synthesis of black phosphorus nanoribbons, however, has remained an outstanding problem. Here we report large-area growth of black phosphorus nanoribbons directly on insulating substrates. We seed the chemical vapour transport growth with black phosphorus nanoparticles and obtain uniform, single-crystal nanoribbons oriented exclusively along the [100] crystal direction. With comprehensive structural calculations, we discover that self-passivation at the zigzag edges holds the key to the preferential one-dimensional growth. Field-effect transistors based on individual nanoribbons exhibit on/off ratios up to ~104, confirming the good semiconducting behaviour of the nanoribbons. These results demonstrate the potential of black phosphorus nanoribbons for nanoelectronic devices and also provide a platform for investigating the exotic physics in black phosphorus.

Hyperbranched Dynamic Crosslinking Networks Enable Degradable, Reconfigurable, and Multifunctional Epoxy Vitrimer.

Degradation and reprocessing of thermoset polymers have long been intractable challenges to meet a sustainable future. Star strategies via dynamic cross-linking hydrogen bonds and/or covalent bonds can afford reprocessable thermosets, but often at the cost of properties or even their functions. Herein, a simple strategy coined as hyperbranched dynamic crosslinking networks (HDCNs) toward in-practice engineering a petroleum-based epoxy thermoset into degradable, reconfigurable, and multifunctional vitrimer is provided. The special characteristics of HDCNs involve spatially topological crosslinks for solvent adaption and multi-dynamic linkages for reversible behaviors. The resulting vitrimer displays mild room-temperature degradation to dimethylacetamide and can realize the cycling of carbon fiber and epoxy powder from composite. Besides, they have supra toughness and high flexural modulus, high transparency as well as fire-retardancy surpassing their original thermoset. Notably, it is noted in a chance-following that ethanol molecule can induce the reconstruction of vitrimer network by ester-exchange, converting a stiff vitrimer into elastomeric feature, and such material records an ultrahigh modulus (5.45 GPa) at -150 °C for their ultralow-temperature condition uses. This is shaping up to be a potentially sustainable advanced material to address the post-consumer thermoset waste, and also provide a newly crosslinked mode for the designs of high-performance polymer.

Identification of gastric cancer types based on hyperspectral imaging technology.

Gastric cancer is becoming the second biggest cause of death from cancer. Treatment and prognosis of different types of gastric cancer vary greatly. However, the routine pathological examination is limited to the tissue level and is easily affected by subjective factors. In our study, we examined gastric mucosal samples from 50 normal tissue and 90 cancer tissues. Hyperspectral imaging technology was used to obtain spectral information. A two-classification model for normal tissue and cancer tissue identification and a four-classification model for cancer type identification are constructed based on the improved deep residual network (IDRN). The accuracy of the two-classification model and four-classification model are 0.947 and 0.965. Hyperspectral imaging technology was used to extract molecular information to realize real-time diagnosis and accurate typing. The results show that hyperspectral imaging technique has good effect on diagnosis and type differentiation of gastric cancer, which is expected to be used in auxiliary diagnosis and treatment.

Detoxication and recycling of chromium slag and C-bearing dust via composite agglomeration process (CAP)-blast furnace method.

The utilization of virulent chromium slag has always been a worldwide problem, and lots of C-bearing dust produced in steel industry has not been utilized efficiently. Sintering is a potential method to treat these two kinds of solid wastes, but it is limited by small treatment capacity, incomplete detoxification of Cr(Ⅵ) when they were directly added into sintering process. In this study, an innovative technology of co-processing chromium slag and C-bearing dust via composite agglomeration process (CAP)-blast furnace method was put forward and systematically investigated. In the CAP, the chromium slag and C-bearing dust were first made into composite pellets and added into the matrix feed for co-sintering. The results showed that, 20% chromium slag and 5% C-bearing dust could be co-disposed by the CAP without destroying the quality of the sinters. Cr(VI) was completely reduced to Cr(III) or metal Cr. 12.83% Cr existed as metal Cr, and the rest of Cr existed in spinel as (Mg, Fe)(Cr, Al)2O4 or in silico-ferrite of calcium and alumina as Cr(Ⅲ). After blast furnace smelting, 90.22% Cr in sinters entered stainless mother liquor to be recycled.

High-efficiency all fluorescence white OLEDs with high color rendering index by manipulating excitons in co-host recombination layers.

All fluorescence white organic light-emitting diodes (WOLEDs) based on thermally activated delayed fluorescence (TADF) emitters are an attractive route to realize highly efficient and high color quality white light sources. However, harvesting triplet excitons in these devices remains a formidable challenge, particularly for WOLEDs involving conventional fluorescent emitters. Herein, we report a universal design strategy based on a co-host system and a cascaded exciton transfer configuration. The co-host system furnishes a broad and charge-balanced exciton generation zone, which simultaneously endows the devices with low efficiency roll-off and good color stability. A yellow TADF layer is put forward as an intermediate sensitizer layer between the blue TADF light-emitting layer (EML) and the red fluorescence EML, which not only constructs an efficient cascaded Förster energy transfer route but also blocks the triplet exciton loss channel through Dexter energy transfer. With the proposed design strategy, three-color all fluorescence WOLEDs reach a maximum external quantum efficiency (EQE) of 22.4% with a remarkable color rendering index (CRI) of 92 and CIE coordinates of (0.37, 0.40). Detailed optical simulation confirms the high exciton utilization efficiency. Finally, by introducing an efficient blue emitter 5Cz-TRZ, a maximum EQE of 30.1% is achieved with CIE coordinates of (0.42, 0.42) and a CRI of 84 at 1000 cd m-2. These outstanding results demonstrate the great potential of all fluorescence WOLEDs in solid-state lighting and display panels.

A novel high activity MnXFe3-XO4 spinel catalyst for selective catalytic reduction of NO using NH3 prepared by a short process from natural minerals for low-temperature sintering flue gas: Effect of X value on catalytic mechanism.

The process of smelting and purifying the catalyst precursor salt from minerals is extremely complex, which directly leads to high catalyst costs and serious secondary pollution. In order to achieve energy saving and emission reduction in the catalyst preparation process, in-situ synthesis of catalyst materials from natural minerals is a new research direction. In this study, we firstly explored the optimal X value of MnXFe3-XO4 for the NH3 selective catalytic reduction of NO (NH3-SCR) reaction, i.e., the Mn, Fe ratio, and then prepared a novel highly active mineral-based pure phase MnXFe3-XO4 spinel NH3-SCR catalyst by natural ferromanganese ore fines with iron-red fines (Fe2O3) allotment through in situ solid-phase synthesis and magnetic separation methods according to this ratio. The results show that the X value of 1.5 (Mn1.5Fe1.5O4) is the best for NH3-SCR reaction. Mn1.5Fe1.5O4 nano-particles (201 nm) has nearly 100 % NO conversion (with 5 % H2O(g)) at 125-300 °C. The combination of characterizations and density functional theory (DFT) calculation shows that the catalytic process of Eley-Rideal (E-R) dehydrogenation is enhanced at both the active site Mn site and Fe site, which is a key factor in the acceleration of the NH3-SCR reaction with increasing X value at the MnXFe3-XO4 surface.

Magnetic Field-Stabilized Wigner Crystal States in a Graphene Moiré Superlattice.

ABC-stacked trilayer graphene on boron nitride (ABC-TLG/hBN) moiré superlattices provides a tunable platform for exploring Wigner crystal states in which the electron correlation can be controlled by electric and magnetic fields. Here we report the observation of magnetic field-stabilized Wigner crystal states in a ABC-TLG/hBN. We show that correlated insulating states emerge at multiple fractional and integer fillings corresponding to ν = 1/3, 2/3, 1, 4/3, 5/3, and 2 electrons per moiré lattice site under a magnetic field. These correlated insulating states can be attributed to generalized Mott states for the integer fillings and generalized Wigner crystal states for the fractional fillings. The generalized Wigner crystal states are stabilized by a vertical magnetic field and are strongest at one magnetic flux quantum per three moiré superlattices. The ν = 2 insulating state persists up to 30 T, which can be described by a Mott-Hofstadter transition at a high magnetic field.

Optical engineering of infrared PbS CQD photovoltaic cells for wireless optical power transfer systems.

Infrared photovoltaic cells (IRPCs) have attracted considerable attention for potential applications in wireless optical power transfer (WOPT) systems. As an efficient fiber-integrated WOPT system typically uses a 1550 nm laser beam, it is essential to tune the peak conversion efficiency of IRPCs to this wavelength. However, IRPCs based on lead sulfide (PbS) colloidal quantum dots (CQDs) with an excitonic peak of 1550 nm exhibit low short circuit current (Jsc) due to insufficient absorption under monochromatic light illumination. Here, we propose comprehensive optical engineering to optimize the device structure of IRPCs based on PbS CQDs, for 1550 nm WOPT systems. The absorption by the device is enhanced by improving the transmittance of tin-doped indium oxide (ITO) in the infrared region and by utilizing the optical resonance effect in the device. Therefore, the optimized device exhibited a high short circuit current density of 37.65 mA/cm2 under 1 sun (AM 1.5G) solar illumination and 11.91 mA/cm2 under 1550 nm illumination 17.3 mW/cm2. Furthermore, the champion device achieved a record high power conversion efficiency (PCE) of 7.17% under 1 sun illumination and 10.29% under 1550 nm illumination. The PbS CQDs IRPCs under 1550 nm illumination can even light up a liquid crystal display (LCD), demonstrating application prospects in the future.

The outcome of sutured wounds compared with tissue adhesive for paediatric wound closure: A meta-analysis.

A meta-analysis investigation was executed to measure the outcome of sutured wounds (SWs) compared with tissue adhesive (TA) for paediatric wound closure (PWC). A comprehensive literature inspection till February 2023 was applied and 2018 interrelated investigations were reviewed. The 18 chosen investigations enclosed 1697 children with PWC in the chosen investigations' starting point, 977 of them were utilising SWs, and 906 were utilising TA. Odds ratio (OR) in addition to 95% confidence intervals (CIs) were used to compute the value of the effect of SWs compared with TA for PWC by the dichotomous approaches and a fixed or random model. SWs had significantly higher wound cosmetic (WC) scores (mean deviation [MD], 1.70; 95% CI, 0.57-2.84, P = .003), lower wound dehiscence (WD) (OR 0.60; 95% CI, 0.06-0.43, P < .001), and lower cost (MD, -10.22; 95% CI, -10.94 to -9.50, P < .001) compared with those with TA in PWC. No significant difference was found between children utilising SWs and TA in wound infection (WI) (OR, 0.45; 95% CI, 0.15-1.30, P = .14) with no heterogeneity (I2 = 0%) in PWC. SWs had significantly higher WC scores, lower WD, and lower cost, yet, no significant difference was found in WI compared with those with TA in PWC. However, care must be exercised when dealing with its values because of the low sample size of some of the nominated investigations and the low number of selected investigations for the meta-analysis.

Single-Layered MoS2 Fabricated by Charge-Driven Interlayer Expansion for Superior Lithium/Sodium/Potassium-Ion-Battery Anodes.

Single-layered MoS2 is a promising anode material for lithium-ion batteries (LIBs), sodium-ion batteries (SIBs), and potassium-ion batteries (PIBs) due to its high capacity and isotropic ion transport paths. However, the low intrinsic conductivity and easy-agglomerated feature hamper its applications. Here, a charge-driven interlayer expansion strategy that Co2+ replaces Mo4+ in the doping form to endow MoS2 layers with negative charges, thus inducing electrostatic repulsion, together with the insertion of gaseous groups, to drive interlayer expansion which once breaks the confinement of interlayer van der Waals force, single-layered MoS2 is obtained and uniformly dispersed into carbon matrix arising from the transformation of carbonaceous gaseous groups under high vapor pressure, is proposed. Co atom doping helps enhance the intrinsic conductivity of single-layered MoS2 . Carbon matrix effectively prevents agglomeration of single-layered MoS2 . The doped Co atoms can be fully transformed into ultrasmall Co nanoparticles during conversion reaction, which enables strong spin-polarized surface capacitance and thus significantly boosts ion transport and storage. Consequently, the prepared material delivers superb Li/Na/K-ion storage performances, which are best in the reported MoS2 -based anodes. The proposed charge-driven interlayer expansion strategy provides a novel perspective for preparing single-layered MoS2, which shows huge potential for energy storage.

Mn-Doped Spinel for Removing Cr(VI) from Aqueous Solutions: Adsorption Characteristics and Mechanisms.

In this study, the manganese (Mn) was doped in the MnFe2O4 crystal by the solid-phase synthesis method. Under the optimum conditions (pH = 3), the max removal rate and adsorption quantity of Cr(VI) on MnFe2O4 adsorbent obtain under pH = 3 were 92.54% and 5.813 mg/g, respectively. The DFT calculation results indicated that the adsorption energy (Eads) between HCrO4- and MnFe2O4 is -215.2 KJ/mol. The Cr(VI) is mainly adsorbed on the Mn atoms via chemical bonds in the form of HCrO4-. The adsorption of Mn on the MnFe2O4 surface belonged to chemisorption and conformed to the Pseudo-second-order equation. The mechanism investigation indicated that the Mn in MnFe2O4 has an excellent enhancement effect on the Cr(VI) removal process. The roles of Mn in the Cr(VI) removal process included two parts, providing adsorbing sites and being reductant. Firstly, the Cr(VI) is adsorbed onto the MnFe2O4 via chemisorption. The Mn in MnFe2O4 can form ionic bonds with the O atoms of HCrO4-/CrO42-, thus providing the firm adsorbing sites for the Cr(VI). Subsequently, the dissolved Mn(II) can reduce Cr(VI) to Cr(III). The disproportionation of oxidized Mn(III) produced Mn(II), causing Mn(II) to continue to participate in the Cr(VI) reduction. Finally, the reduced Cr(III) is deposited on the MnFe2O4 surface in the form of Cr(OH)3 colloids, which can be separated by magnetic separation.

An ultra-high vacuum system for fabricating clean two-dimensional material devices.

High mobility electron gases confined at material interfaces have been a venue for major discoveries in condensed matter physics. Ultra-high vacuum (UHV) technologies played a key role in creating such high-quality interfaces. The advent of two-dimensional (2D) materials brought new opportunities to explore exotic physics in flat lands. UHV technologies may once again revolutionize research in low dimensions by facilitating the construction of ultra-clean interfaces with a wide variety of 2D materials. Here, we describe the design and operation of a UHV 2D material device fabrication system, in which the entire fabrication process is performed under pressure lower than 5 × 10-10 mbar. Specifically, the UHV system enables the exfoliation of atomically clean 2D materials. Subsequent in situ assembly of van der Waals heterostructures produces high-quality interfaces that are free of contamination. We demonstrate functionalities of this system through exemplary fabrication of various 2D materials and their heterostructures.

Enhanced energy recovery from landfill leachate by linking light and dark bio-reactions: Underlying synergistic effects of dual microalgal interaction.

Bioconversion of nutrients and energy from landfill leachate (LL) to biohydrogen and volatile fatty acids (VFAs) using dark fermentation (DF) is a promising technique for developing a sustainable ecosystem. However, poor performance of DF caused by vulnerable fermentative bacteria vitality and strong LL toxicity significantly hinder its commercialization. Herein, an integrated technique linking microalgae photosynthesis and DF was proposed, in which mixed microalgae were applied to robustly reclaim nutrients and chemical oxygen demand (COD) from LL. Then, microalgae biomass was fermented into biohydrogen and VFAs using the DF process. Underlying synergistic mechanisms of the interaction of Scenedesmus obliquus and Chlorella vulgaris resulting from the functioning of extracellular polymeric substances (EPS) were discussed in detail. For better absorption of nutrients from LL, the mixed microalgae secreted obviously more EPS than pure microalgae, which played vital roles in the assimilation of cellular nutrients by forming more negative zeta potential and secreting more tyrosine-/tryptophan-family proteins in EPS. Besides, mixed microalgae produced more intracellular proteins and carbohydrates than the pure microalgae, thereby providing more feedstock for DF and achieving higher energy yield of 10.80 kJ/L than 6.64 kJ/L that was obtained when pure microalgae were used. Moreover, the energy conversion efficiency of 7.75% was higher for mixed microalgae than 4.77% that was obtained for pure microalgae. This work may inspire efficient disposal of LL and production of bioenergy, together with filling the knowledge gaps of synergistic mechanisms of dual microalgal interactions.

Cadmium tolerance and accumulation from the perspective of metal ion absorption and root exudates in broomcorn millet.

Cadmium (Cd) is a persistent heavy metal that poses environmental and public health concerns. This study aimed to identify the potential biomarkers responsible for Cd tolerance and accumulation by investigating the response of the content of essential metal elements, transporter gene expression, and root exudates to Cd stress in broomcorn millet (Panicum miliaceum). A hydroponics experiment was conducted using two broomcorn millet cultivars with distinct Cd tolerance levels and accumulation phenotypes (Cd-tolerant and Cd-sensitive cultivars). Cd stress inhibited lateral root growth, especially in the Cd-sensitive cultivar. Furthermore, Cd accumulation was significantly greater in the Cd-tolerant cultivar than in the Cd-sensitive cultivar. Cd stress significantly inhibited the absorption of essential metal elements and significantly increased the calcium concentration. Differentially expressed genes involved in metal ion transport were identified via transcriptome analysis. Cd stress altered the composition of root exudates, thus increasing lipid species and decreasing alkaloid, lignan, sugar, and alcohol species. Moreover, Cd stress significantly reduced most alkaloid, organic acid, and phenolic acid exudates in the Cd-tolerant cultivar, while it increased most lipid and phenolic acid exudates in the Cd-sensitive cultivar. Some significantly changed root exudates (ferulic acid, O-coumaric acid, and spermine) are involved in the phenylalanine biosynthesis, and arginine and proline metabolic pathways, thus, may be potential biomarkers of Cd stress response. Overall, metal ion absorption and root exudates are critical for Cd tolerance and accumulation in broomcorn millet. These findings provide valuable insights into improving Cd phytoremediation by applying mineral elements or metabolites.

One-step separation of tin from e-waste by a chemical vapor transport process (CVT): Preparation of nano-SnO2.

E-waste is a valuable resource for the recovery of secondary metals. However, traditional methods only focused on the extraction of Cu and noble metals (Au, Ag, etc.), and significant tin (Sn) loss occurred during the smelting or the leached. In this paper, a novel chemical vapor transport (CVT) process was proposed to separate and recycle Sn from e-waste to prepare nano-SnO2. The effect of roasting parameters on Sn volatilization and characterization of nano-SnO2 were investigated using thermodynamic analysis, XRD, SEM, TEM, etc. The results indicated that Sn volatilization of 92.8 % was obtained under optimal roasting parameters under CO-CO2-N2 atmosphere. In addition, nano-SnO2 with a crystallinity of 99.9 %, an average grain size of 24.8 nm and a specific surface area of 97.9 m2/g was synthesized successfully.

Morphophysiological, proteomic and metabolomic analyses reveal cadmium tolerance mechanism in common wheat (Triticum aestivum L.).

Soil cadmium (Cd) contamination can reduce wheat yield and quality, thus threatening food security and human health. Herein, morphological physiology, Cd accumulation and distribution, proteomic and metabolomic analyses were performed (using wheat cultivars 'Luomai23' (LM, Cd-sensitive) and 'Zhongyu10' (ZY, Cd-tolerant) at the seedling stage with sand culture) to reveal Cd tolerance mechanism. Cd inhibited wheat growth, caused oxidative stress, hindered carbon and nitrogen metabolism, and altered the quantity and composition of root exudates. The root Cd concentration was lower in ZY than in LM by about 35% under 15 µM Cd treatments. ZY reduced Cd uptake through root exudation of amino acids and alkaloids. ZY also reduced Cd accumulation through specific up-regulation (twice) of major facilitator superfamily (MFS) proteins. Furthermore, ZY enhanced Cd cell wall fixation and vacuolar compartmentalization by increasing pectin contents, hemicellulose1 contents, and adenosine triphosphate binding cassette subfamily C member 1 (ABCC1) transporter expression, thus reducing the Cd organelle fraction of ZY by about 12% and 44% in root and shoot, respectively, compared with LM. Additionally, ZY had enhanced resilience to Cd due to increased antioxidant capacity, plasma membrane stability, nitrogen metabolism, and endoplasmic reticulum homeostasis, indicating that the increased Cd tolerance could be because of multi-level coordination. These findings provide a reference for exploring the molecular mechanism of Cd tolerance and accumulation, providing a basis for safe utilization of Cd-contaminated soil by breeding Cd-tolerant and low Cd-accumulating wheat varieties.

Formation and Inhibition Mechanism of Na8SnSi6O18 during the Soda Roasting Process for Preparing Na2SnO3.

To produce Na2SnO3, which is widely used in the ceramics and electroplating industries, a novel process for the preparation of sodium stannate from cassiterite concentrates was developed successfully by the authors' group. It was found that sodium stannosilicate (Na8SnSi6O18) was easily formed due to the main gangue of quartz in cassiterite concentrates, which was almost insoluble and decreased the quality of Na2SnO3. The formation and transitions of Na8SnSi6O18 in the SnO2-SiO2-Na2CO3 system roasted under a CO-CO2 atmosphere were determined. The results indicated that the formation of Na8SnSi6O18 could be divided into two steps: SnO2 reacted with Na2CO3 to form Na2SnO3, and then Na2SnO3 was rapidly combined with SiO2 and Na2CO3 to form low melting point Na8SnSi6O18. In addition, Na8SnSi6O18 can be decomposed into Na2SiO3 and Na2SnO3 by using excess Na2CO3.

Carbon sequestration characteristics of two plantation forest ecosystems with different lithologies of karst.

In karst regions, the majority of studies have focused on ecosystem carbon sequestration in the same lithology, but no studies in different lithologies. In this study, actual measurements were used to reveal carbon sequestration characteristics of two plantation forest ecosystems (Bodinieri cinnamon and Cupressus funebris) with different lithologies of karst. The results showed that the tree layer showed the highest vegetation biomass, carbon content, carbon density, and ratio of aboveground biomass to belowground biomass. The carbon density of B. cinnamon plantation and C. funebris plantation was high in dolomite and in limestone respectively. The soil quality and carbon density of bare ground and plantation varied across different lithologies. The carbon density of various ecosystem components was in the order of vegetation>soil>litterfall. The carbon density and net carbon density of plantation varied across different lithologies. In B. cinnamon plantation, the carbon sequestration rate of vegetation and ecosystem was high in dolomite, moderate in limestone, and low in dolomitic sandstone. In Cupressus funebris plantation, the carbon sequestration rate was in the order of limestone>dolomite>dolomitic sandstone. These findings revealed that lithology is an important factor affecting ecosystem carbon pools, and plantation ecosystems have low biomass and low carbon density in karst areas.

Improving the Properties of Magnetite Green Pellets with a Novel Organic Composite Binder.

A novel composite binder (humic acid modified bentonite, HAMB) and two other binders (bentonite and Modified humic acid, MHA) were used to explore the effects of binders on the properties of magnetite green pellets in this study. The results of green pellet properties and drying tests show that the low doses of a humic substance-based binder can achieve the same effect as high doses of bentonite binder. A humic substance-based binder could be a promising organic binder to replace bentonite. Meanwhile, the influence mechanism of adding different binders on the strength of green pellet was discussed, and the relationship between moisture content in the pellet and the compression strength of three binders was determined. A TG-DSC analysis found that the novel composite binder (HAMB) was not a simple mix of humic acid and bentonite, in which a humic substance could change the structure of bentonite and reduce the thermal stability of bentonite, causing the HAMB composite binder to have a high decomposition temperature.