RESUMEN
The addition of single-wall carbon nanotubes (SWCNT) to lead-acid battery electrodes is the most efficient suppresser of uncontrolled sulfation processes. Due to the cost of SWCNT, we studied the optimization loading of SWCNT in lead-acid battery electrodes. We optimized the SWCNT loading concentrations in both the positive and negative plates, separately. Loadings of 0.01% and 0.001% in the positive and negative active masses were studied, respectively. Two volts of lead-acid laboratory cells with sulfuric acid, containing silica gel-type electrolytes, were cycled in a 25% and 50% depth-of-discharge (DOD) cycling with a charging rate of C and 2C, respectively, and discharge rates of C/2 and C, respectively. All tests successfully demonstrated an excellent service life up to about 1700 and 1400 cycles for 25% and 50% DOD operations, respectively, at a low loading level of SWCNT. This performance was compared with CNT-free cells and cells with a multiwall carbon nanotube (MWCNT) additive. The outstanding performance of the lead-acid cells with the SWCNT additive is due to the oxidative stability of the positive plates during charging and the efficient reduction in sulfation in both plates while forming conducting active-material matrices.
RESUMEN
We demonstrate herein that Mn3+ and not Mn2+, as commonly accepted, is the dominant dissolved manganese cation in LiPF6-based electrolyte solutions of Li-ion batteries with lithium manganate spinel positive and graphite negative electrodes chemistry. The Mn3+ fractions in solution, derived from a combined analysis of electron paramagnetic resonance and inductively coupled plasma spectroscopy data, are â¼80% for either fully discharged (3.0 V hold) or fully charged (4.2 V hold) cells, and â¼60% for galvanostatically cycled cells. These findings agree with the average oxidation state of dissolved Mn ions determined from X-ray absorption near-edge spectroscopy data, as verified through a speciation diagram analysis. We also show that the fractions of Mn3+ in the aprotic nonaqueous electrolyte solution are constant over the duration of our experiments and that disproportionation of Mn3+ occurs at a very slow rate.
RESUMEN
Manganese dissolution from positive electrodes significantly reduces the durability of lithium-ion batteries. Knowledge of dissolution rates and oxidation states of manganese ions is essential for designing effective mitigation measures for this problem. We show that electron paramagnetic resonance (EPR) combined with atomic absorption spectroscopy (AAS) or inductively coupled plasma (ICP) can determine both manganese dissolution rates and relative Mn(3+) amounts, by comparing the correlation between EPR and AAS/ICP data for Mn(2+) standards with that for samples containing manganese cations dissolved from active materials (LiMn2O4 (LMO) and LiNi(0.5)Mn(1.5)O4 (LNMO)) into the same electrolyte solution. We show that Mn(3+), and not Mn(2+), is the dominant species dissolved from LMO, while Mn(2+) is predominant for LNMO. Although the dissolution rate of LMO varies significantly for the two investigated materials, due to particle morphology and the presence of Cr in one of them, the Mn speciation appears independent of such details. Thus, the relative abundance of dissolved manganese ions in various oxidation states depends mainly on the overall chemical identity of the active material (LMO vs LNMO). We demonstrate the relevance of our methodology for practical batteries with data for graphite-LMO cells after high-temperature cycling or stand at 4.2 V.
RESUMEN
Field observations of air and surface temperatures, relative humidity, solar radiation and wind were performed in the daytime hours of the warm season around a pond of 4 ha, located in Begin Park, in the city of Tel Aviv, Israel. Observations were carried out at screened meteorological stations on four randomly selected days, all associated with moderate heat stress. Two of them, one representing a warm and dry day, and other, representing a sultry day, are analyzed in detail. At the downwind side of the pond, lower temperatures, a higher relative humidity and a lower heat stress index were observed consistently when compared with stations located upwind of the pond. This effect is regarded here as the "lake effect". The fact that no significant change was noted in the water vapor pressure during most of the daytime hours indicates that the lake effect was related mainly to cooling rather than to moisture transport from the pond. A positive relationship was found between the lake effect and wind speed in both types of weather. The maximum effect of the wind's speed on the lake effect was observed at midday, at which time the temperature drop reached 1.6 degrees C, while the relative humidity rose by 6%. As a result, the heat stress index dropped by 0.8-1.1 degrees C. It is suggested that the temperature drop induced by the pond during the warmest hours of the day was mainly the result of a truncation of the sensible heat flux from the underlying surface when the air, which had previously passed over hot surfaces, swept over the relatively cool water. During the late afternoon and evening hours, when the water became warmer than the surrounding surfaces, latent heat cooling resulting from evaporation became the dominant source of the lake effect, and the lake effect resulted in increasing heat stress. It is concluded that even small bodies of water have a relieving effect on humans in the daytime hours, within the range of 40 m, under both dry and humid hot weather conditions.
