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Ultrasound sensors play an important role in biomedical imaging, industrial nondestructive inspection, etc. Traditional ultrasound sensors that use piezoelectric transducers face limitations in sensitivity and spatial resolution when miniaturized, with typical sizes at the millimeter to centimeter scale. To overcome these challenges, optical ultrasound sensors have emerged as a promising alternative, offering both high sensitivity and spatial resolution. In particular, ultrasound sensors utilizing high-quality factor (Q) optical microcavities have achieved unprecedented performance in terms of sensitivity and bandwidth, while also enabling mass production on silicon chips. In this review, we focus on recent advances in ultrasound sensing applications using three types of optical microcavities: Fabry-Perot cavities, π-phase-shifted Bragg gratings, and whispering gallery mode microcavities. We provide an overview of the ultrasound sensing mechanisms employed by these microcavities and discuss the key parameters for optimizing ultrasound sensors. Furthermore, we survey recent advances in ultrasound sensing using these microcavity-based approaches, highlighting their applications in diverse detection scenarios, such as photoacoustic imaging, ranging, and particle detection. The goal of this review is to provide a comprehensive understanding of the latest advances in ultrasound sensing with optical microcavities and their potential for future development in high-performance ultrasound imaging and sensing technologies.
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Enhancing the flame retardancy of epoxy (EP) resins typically entailed a trade-off with other physical properties. Herein, hyperbranched poly(amidoamine) (HPAA) and phytic acid (PA) were used to functionalize graphene oxide (GO) via electrostatic self-assembly in water to prepare a phosphorus-nitrogen functionalized graphene oxide nanosheet (PN-GOs), which could be utilized as high efficient flame-retardant additive of epoxy resin without sacrificing other properties. The PN-GOs demonstrated improved dispersion and compatibility within the EP matrix, which resulted in significant concurrent enhancements in both the mechanical performance and flame-retardant properties of the PN-GOs/EP nanocomposites over virgin EP. Notably, the incorporation of just 1.0 wt% PN-GOs yielded a 20.4, 6.4 and 42.7 % increases in flexural strength, flexural modulus and impact strength for the PN-GOs/EP nanocomposites, respectively. Furthermore, simultaneous reductions were achieved in the peak heat release rate (pHRR) by 60.0 %, total smoke production (TSP) by 43.0 %, peak CO production rate (pCOP) by 57.9 %, and peak CO2 production rate (pCO2P) by 63.9 %. This study presented a facile method for the design of GO-based nano flame retardants, expanding their application potential in polymer-matrix composites.
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Aqueous zinc-ion batteries (ZIBs) are regarded as a type of promising energy-storage device because of their high safety and low cost, and polyaniline (PANI) is normally employed as a cathode material for ZIBs owing to its unique electrochemical properties and high environmental stability. However, a low specific capacity and a short cycle life limit the development and applications of PANI-based electrodes. Herein, we have developed a novel type of highly stable PANI-based cathode material enabled by phosphene (PR) for aqueous Zn-PANI batteries through in situ chemical oxidative polymerization. The introduction of PR nanoflakes not only inhibits the degradation of PANI and generates more active sites for Zn2+ storage but also enables a synergistic effect of the Zn2+ insertion/extraction and P-Zn alloying reaction. This promotes a high reversible specific capacity of 240.2 mAh g-1 at 0.2 A g-1 and excellent rate performance for the PR/PANI nanocomposite cathode material. Compared to the pristine PANI cathode material, the PR/PANI nanocomposite cathode material is more suitable for the Zn-PANI battery, thanks to its higher specific capacity and better cycle stability. This study provides an innovative approach for developing the next generation of reliable PR-based electrode materials for aqueous energy-storage devices.
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Studying the relationship between biodiversity and ecosystem multifunctionality (the ability of ecosystems to provide multiple ecosystem functions) (BEMF) is a current hotspot in ecology research. Previous studies on BEMF emphasized the role of plant and microbial diversity but rarely mention stand spatial structure. To investigate the effect of stand spatial structure on BEMF, this study established 30 forest dynamic plots in three natural restoration stages (shrubbery, secondary growth forest, and old-growth forest) in Maolan National Nature Reserve, Guizhou province, China. A positive response in soil multifunctionality (SMF), plant species diversity, stand spatial structure, and fungal ß diversity (p < 0.05) followed natural restoration. However, bacterial ß diversity showed a negative response (p < 0.05), while microbial α diversity remained unchanged (p > 0.05). These results based on a structural equation model showed that plant species diversity had no direct or indirect effect on SMF, soil microbial diversity was the only direct driver of SMF, and stand spatial structure indirectly affected SMF through soil microbial diversity. The random forest model showed that soil microbial ß diversity and the Shannon-Wiener index of the diameter at breast height for woody plant species were the optimal variables to characterize SMF and soil microbial diversity, respectively. These results suggested that natural restoration promoted SMF, and microbial diversity had a direct positive effect on SMF. In the meantime, stand spatial structure had a significant indirect effect on SMF, while plant species diversity did not. Future work on degraded karst forest restoration should direct more attention to the role of the stand spatial structure and emphasize the importance of biodiversity.
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Biodiversidad , Bosques , Microbiología del Suelo , Suelo , China , Suelo/química , Microbiota , Ecosistema , Hongos , Monitoreo del Ambiente , Conservación de los Recursos NaturalesRESUMEN
Several Pulsar Timing Array (PTA) Collaborations have recently provided strong evidence for a nHz Stochastic Gravitational-Wave Background (SGWB). Here we investigate the implications of a first-order phase transition occurring within the early Universe's dark quantum chromodynamics epoch, specifically within the framework of the mirror twin Higgs dark sector model. Our analysis indicates a distinguishable SGWB signal originating from this phase transition, which can explain the measurements obtained by PTAs. Remarkably, a significant portion of the parameter space for the SGWB signal also effectively resolves the existing tensions in both the H0 and S8 measurements in Cosmology. This intriguing correlation suggests a possible common origin of these three phenomena for 0.2<ΔNeff<0.5, where the mirror dark matter component constitutes less than 30% of the total dark matter abundance. Next-generation CMB experiments such as CMB-S4 can test this parameter region.
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Microwave absorbers with high efficiency and mechanical robustness are urgently desired to cope with more complex and harsh application scenarios. However, manipulating the trade-off between microwave absorption performance and mechanical properties is seldom realized in microwave absorbers. Here, a chemistry-tailored charge dynamic engineering strategy is proposed for sparking hetero-interfacial polarization and thus coordinating microwave attenuation ability with the interfacial bonding, endowing polymer-based composites with microwave absorption efficiency and mechanical toughness. The absorber designed by this new conceptual approach exhibits remarkable Ku-band microwave absorption efficiency (-55.3 dB at a thickness of 1.5 mm) and satisfactory effective absorption bandwidth (5.0 GHz) as well as desirable interfacial shear strength (97.5 MPa). The calculated differential charge density depicts the uneven distribution of space charge and the intense hetero-interfacial polarization, clarifying the structure-performance relationship from a theoretical perspective. This work breaks through traditional single performance-oriented design methods and ushers a new direction for next-generation microwave absorbers.
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The automated fiber placement (AFP) process faces a crucial challenge: the emergence of out-of-plane buckling in thermoplastic prepreg tows during steering, significantly impeding the quality of composite layup. In response, this study introduces a novel approach: the development of equations for wrinkle-free fiber placement within composite pressure vessels. The investigation encompasses a detailed analysis of prepreg trajectories in relation to shell geometry, accompanied by an in-depth understanding of the underlying causes of wrinkling on dome surfaces. Moreover, a comprehensive model for shell coverage, grounded in placement parameters, is meticulously established. To validate the approach, a simulation tool is devised to calculate press roller motions, ensuring the uniform fiber dispersion on the mandrel and achieving flawless coverage of the shell without wrinkles. This innovative strategy not only optimizes the AFP process for composite layup but also remarkably enhances the overall quality of composite shells. As such, this research carries significant implications for the advancement of composite manufacturing techniques and the concurrent improvement in material performance.
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Enhancing gasoline detergency is pivotal for enhancing fuel efficiency and mitigating exhaust emissions in gasoline vehicles. This study investigated gasoline vehicle emission characteristics with different gasoline detergency, explored synergistic emission reduction potentials, and developed versatile emission prediction models. The results indicate that improved fuel detergency leads to a reduction of 5.1% in fuel consumption, along with decreases of 3.2% in total CO2, 55.4% in CO, and 15.4% in HC emissions. However, during low-speed driving, CO2 and CO emissions reductions are limited, and HC emissions worsen. A synergistic emission reduction was observed, particularly with CO exhibiting a pronounced reduction compared to HC. The developed deep-learning-based vehicle emission model for different gasoline detergency (DPVEM-DGD) enables accurate emission predictions under various fuel detergency conditions. The Pearson correlation coefficients (Pearson's r) between predicted and measured values of CO2, CO, and HC emissions before and after adding detergency agents are 0.913 and 0.934, 0.895 and 0.915, and 0.931 and 0.969, respectively. The predictive performance improves due to reduced peak emissions resulting from improved fuel detergency. Elevated gasoline detergency not only reduces exhaust emissions but also facilitates more refined emission management to a certain extent.
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Technology for recycling retired lithium batteries has become increasingly environment-friendly and efficient. In traditional recovery methods, pyrometallurgy or hydrometallurgy is often used as an auxiliary treatment method, which results in secondary pollution and increases the cost of harmless treatment. In this article, a new method for combined mechanical recycling of waste lithium iron phosphate (LFP) batteries is proposed to realize the classification and recycling of materials. Appearance inspections and performance tests were conducted on 1000 retired LFP batteries. After discharging and disassembling the defective batteries, the physical structure of the cathode binder was destroyed under ball-milling cycle stress, and the electrode material and metal foil were separated using ultrasonic cleaning technology. After treating the anode sheet with 100 W of ultrasonic power for 2 minutes, the anode material was completely stripped from the copper foil, and no cross-contamination between the copper foil and graphite was observed. After the cathode plate was ball-milled for 60 seconds with an abrasive particle size of 20 mm and then ultrasonically treated for 20 minutes with a power of 300 W, the stripping rate of the cathode material reached 99.0%, and the purities of the aluminium foil and LFP reached 100% and 98.1%, respectively.
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Cobre , Litio , Suministros de Energía Eléctrica , Reciclaje/métodos , Electrodos , Hierro , FosfatosRESUMEN
Red phosphorus (RP) is considered to be the most promising anode material for lithium-Ion batteries (LIBs) due to its high theoretical specific capacity and suitable voltage platform. However, its poor electrical conductivity (10-12 S/m) and the large volume changes that accompany the cycling process severely limit its practical application. Herein, we have prepared fibrous red phosphorus (FP) that possesses better electrical conductivity (10-4 S/m) and a special structure by chemical vapor transport (CVT) to improve electrochemical performance as an anode material for LIBs. Compounding it with graphite (C) by a simple ball milling method, the composite material (FP-C) shows a high reversible specific capacity of 1621 mAh/g, excellent high-rate performance and long cycle life with a capacity of 742.4 mAh/g after 700 cycles at a high current density of 2 A/g, and coulombic efficiencies reaching almost 100% for each cycle.
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To reduce the heavy dependence on petroleum, bioethanol has been increasingly employed as an alternative and sustainable transportation fuel. However, the characteristics of black carbon (BC) emissions from E10 petrol vehicles (i.e., ethanol-gasoline containing 10% ethanol) are still unclear, especially under real driving conditions. Here, a tunnel test was conducted during a cold winter. This tunnel was characterized by heavy traffic comprising more than 98% E10-fueled gasoline vehicles (GVs). Real-time BC concentrations, traffic parameters and meteorological conditions were recorded during the sampling campaign. The average BC concentration inside the tunnel (10.94 ± 5.02 µg m-3) was almost twice the background concentration. Based on aethalometer AE33 in situ measurements and the minimum R-squared (MRS) method, real-time aerosol light absorption was apportioned. The light absorption proportions of BC, primary brown carbon (BrC1) and secondary brown carbon (BrC2) were 79.86%, 2.78% and 17.36%, respectively, at 370 nm. The BC emission factor (EFBC) of the E10-fueled vehicles was 1.09 ± 0.49 mg km-1·veh-1 and 15.24 ± 6.85 mg·(kg fuel)-1, lower than those of traditional gasoline fueled vehicles in previous studies. This study can support the compilation of vehicular BC emission inventories, provide recommendations for biofuel policies and contribute to comprehensively understanding the climatic impact of E10 petrol.
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Contaminantes Atmosféricos , Gasolina , Gasolina/análisis , Contaminantes Atmosféricos/análisis , Emisiones de Vehículos/análisis , Aerosoles/análisis , Hollín/análisis , Carbono/análisis , Etanol/análisis , Monitoreo del Ambiente/métodosRESUMEN
Background: Neoadjuvant anti-programmed death receptor-1 (PD-1) blockade has been explored in the treatment of locally advanced esophageal squamous cell carcinoma (ESCC). We conducted this study to assess the efficacy and safety of neoadjuvant camrelizumab plus chemotherapy in locally advanced ESCC. Methods: We retrospectively enrolled ESCC patients who received surgery within 3 months of treatment with camrelizumab plus chemotherapy from June 2019 to January 2021. Results: A total of 34 eligible patients were enrolled. The neoadjuvant treatment was well tolerated with no serious treatment-related adverse events. Thirty-two (94.1%) patients achieved a R0 resection, and 14 patients (41.2%) developed postoperative complications. The objective response rate (ORR) was 61.8% and the disease control rate (DCR) was 100.0%. The major pathological response (MPR), pathological complete response (pCR), and clinical to pathological downstaging rate were 50.0%, 35.3%, and 79.4%, respectively. With a median follow-up of 14.8 months, 30 (88.2%) patients who underwent surgical resection remain alive. The disease-free survival (DFS) and overall survival (OS) at 12 months were 86.4% and 92.8%, respectively. Conclusion: Neoadjuvant camrelizumab plus chemotherapy is safe and efficacious in treating patients with locally advanced ESCC.
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Ionic electroactive polymer-based actuators have attracted much attention due to their low potential stimuli. In this work, MXene-Nafion composite actuators were fabricated, and the actuation performances were tested. The morphology of the as-made MXene-Nafion composite showed that the composite membrane was homogeneous, with an MXene doping level up to 5 wt%. In addition, the results of blocked force, response speed, and durability demonstrated that the actuation behavior of the composite-based actuator was enhanced due to the efficient dispersion of the two-dimensional nanofiller MXene. In addition, the blocking force of the composite actuator with a doping level of 0.5 wt% was about 6 times that of the pure Nafion without back-relaxation and durability degradation during the testing period.
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To explore the emission characteristics of volatile organic compounds (VOCs) from vehicular exhaust sources and evaporative sources with ethanol gasoline (E10) as the main fuel, VOCs sampling campaigns were carried out in the north third ring tunnel of Zhengzhou city for two consecutive weeks in December 2019. In addition, the characteristics of traffic flow and environmental information were also monitored in the tunnel. Firstly, 106 VOCs were quantified using gas chromatography/mass spectrometry (GC/MS), and then source apportionment of VOCs in the tunnel was carried out using a positive matrix factorization (PMF5.0)-chemical mass balance (CMB8.2) composite model. Finally, the ozone formation potential (OFP) and secondary organic aerosol formation potential (SOAFP) of vehicle exhaust sources and evaporative sources were analyzed using the maximum incremental reactivity (MIR) and fractional aerosol coefficient (FAC). The results showed that ρ(VOCs) in the tunnel was (2794.5±147.4) µg·m-3 during the experiment, among which halogenated hydrocarbons[(32.4±2.0)%] accounted for the highest proportion, followed by aromatic hydrocarbons[(27.5±0.6)%] and alkanes[(23.3±0.8)%]. Source apportionment of vehicular VOCs showed that exhaust emissions (62.5%)>evaporative emissions (37.5%), whereas the contribution of OFP was that exhaust emissions (71.9%)>evaporative emissions (28.1%), and the contribution of SOAFP was that exhaust emissions (75.8%)>evaporative emissions (24.2%). The dominant components of OFP in evaporative sources were m,p-diethylbenzene, isoprene, and trans-2-pentene, whereas m,p-diethylbenzene, m,p-xylene, and 1,2,3-trimethylbenzene were the dominant components of SOAFP. The major components of OFP in exhaust sources were m,p-xylene, 1,2,4-trimethylbenzene, and 1,3,5-trimethylbenzene, whereas m,p-xylene, m,p-diethylbenzene, and 1,3,5-trimethylbenzene were the dominant components of SOAFP. In regions where ethanol gasoline is used, special attention should be paid not only to the exhaust emissions control but also to strengthening the emissions reduction of VOCs from vehicle evaporative sources, especially the high active components such as aromatic hydrocarbons and alkenes.
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Contaminantes Atmosféricos , Ozono , Compuestos Orgánicos Volátiles , Aerosoles/análisis , Contaminantes Atmosféricos/análisis , China , Monitoreo del Ambiente/métodos , Etanol , Gasolina/análisis , Ozono/análisis , Emisiones de Vehículos/análisis , Compuestos Orgánicos Volátiles/análisisRESUMEN
MiR-19b-3p has been reported in several types of human cancer. Nevertheless, the expression profile and biological functions of miR-19b-3p remain unclear in non-small cell lung cancer (NSCLC). The expression level of miR-19b-3p was evaluated in NSCLC tissues and cell lines using qRT-PCR. Survival analysis was performed using Kaplan-Meier curves, while the prognostic significance of miR-19b-3p was analyzed using Cox regression analysis in 80 NSCLC patients. The effects of miR-19b-3p on cell proliferation and invasion capacities were analyzed using CCK-8, crystal violet, and transwell assays. Target genes of miR-19b-3p were assessed using luciferase reporter assay, qRT-PCR, Western blot and rescue experiments. MiR-19b-3p was found to be upregulated in human NSCLC tissues and cell lines. The expression of miR-19b-3p was observed to be closely associated with TNM stage and metastasis. High expression of miR-19b-3p was found to be capable of predicting poor clinical prognosis in NSCLC patients. Whilst overexpression of miR-19b-3p was demonstrated to promote the proliferation and invasion of NSCLC cells, knockdown of miR-19b-3p showed an opposite inhibitory effect. Bioinformatics analysis and luciferase reporter assays confirmed that HOXA9 is a direct target of miR-19b-3p. Functional assays demonstrated that NSCLC cell proliferation and invasion were promoted by miR-19b-3p via negative regulation of HOXA9. Finally, overexpression of HOXA9 was shown to partially reverse the tumor promoting effect of miR-19b-3p. This study indicates that miR-19b-3p is a crucial prognostic biomarker of NSCLC, and that targeting of the miR-19b-3p/HOXA9 axis may be a promising strategy in NSCLC therapy.
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Carcinoma de Pulmón de Células no Pequeñas , Neoplasias Pulmonares , MicroARNs , Biomarcadores , Carcinoma de Pulmón de Células no Pequeñas/patología , Línea Celular Tumoral , Movimiento Celular , Proliferación Celular/genética , Regulación Neoplásica de la Expresión Génica , Violeta de Genciana , Humanos , Neoplasias Pulmonares/metabolismo , MicroARNs/metabolismo , Pronóstico , Sincalida/genética , Sincalida/metabolismoRESUMEN
Characterized by a high frequency of use, harsh working environments, poor maintenance, and low levels of emission controls, rural vehicles (RVs) are becoming an important source of air pollution. Our study used a portable emission measurement system (PEMS) to test the real-world emissions of 35 RVs on provincial, rural, and farm roads. The results show that high emission rates of carbon monoxide (CO) and hydrocarbons (HC) mainly occurred when accelerating at low speeds. However, high levels of nitrogen oxides (NOx) were emitted during high-speed acceleration. The particulate number (PN) of emissions was higher when the RVs were accelerating. According to the overall test results, the vehicle specific power (VSP) on the provincial road mostly ranged within (0, 3], accounting for 68.80% of the total. The VSP on rural and farm roads was concentrated within (0, 2] kW·ton-1, accounting for 67.09% and 76.64% of the total, respectively. We defined 14 bins based on the distribution of the VSP values and calculated the average emission rate of each bin. By comparing the average emission rate among the bins, we found that within Bins 1-7 (VSP < 0 kW·ton-1), CO, HC, and NOx emissions slowly increased as the VSP increased. In Bins 8-13 (VSP ≥ 0 kW·ton-1), the average emission rates of four pollutants increased as the VSP increased. However, all pollutants decreased in Bin 14 (VSP ≥ 6 kW·ton-1). We built a microscopic emission model according to the VSP distribution characteristics of RVs on different road types. We compared the measured and simulated emission factors and found that our emission model can greatly simulate the HC, NOx and PN emission factors of RVs.
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Contaminantes Atmosféricos , Contaminación del Aire , Contaminantes Atmosféricos/análisis , Monóxido de Carbono/análisis , Monitoreo del Ambiente , Vehículos a Motor , Óxidos de Nitrógeno/análisis , Emisiones de Vehículos/análisisRESUMEN
The Chinese government has developed an ambitious project to promote the application of ethanol gasoline (E10) on a national scale since 2017. Given the difference in fuel properties between E10 and traditional gasoline, it is necessary to evaluate the volatile organic compound (VOC) emissions from E10-fuelled vehicles. In this study, a two-week sampling campaign was conducted in an urban tunnel, in which E10-fuelled vehicles were dominant, to evaluate the characteristics of VOC emissions from the mixed fleet. In total, 105 VOC species were identified, and the ozone formation potential (OFP) and secondary organic aerosol formation potential (SOAFP) were estimated. The results showed that for vehicular VOC concentrations in the tunnel, alkanes, oxygenated VOCs (OVOCs) and alkenes were the most abundant VOC groups, with the average proportion being more than 80% of the total VOCs. The fleet-average VOC emission factor (EF) was 14.8 mg/km/veh, which was much lower than that from traditional gasoline-fuelled vehicle fleets, and alkanes, OVOCs, alkenes and aromatics were the major VOC groups. Because of the large number of E10-fuelled vehicles in the mixed fleet, a high proportion of OVOCs among the vehicular VOC emissions was observed. Ethane, acrolein, ethanol, ethylene and toluene were the top five VOC species with the largest EF in VOC emissions from the fleet. Alkenes were the main contributors with an average contribution of 43.9% of the total OFP, whereas aromatics dominated the total SOAFP by 95.8% on average. These results may provide a reference for the extensive application of ethanol gasoline and the development of vehicular emission models.
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Contaminantes Atmosféricos , Ozono , Compuestos Orgánicos Volátiles , Aerosoles/análisis , Contaminantes Atmosféricos/análisis , China , Monitoreo del Ambiente , Ozono/análisis , Emisiones de Vehículos/análisis , Compuestos Orgánicos Volátiles/análisisRESUMEN
To better understand the real-world emissions of rural vehicles (RVs) in China, 8 China II RVs and 18 China III RVs were tested on a provincial road, rural road and farm road using a portable emissions measurement system. The results are illustrated in contour maps of the speed, acceleration and emission rates and show that CO, HC, NOx and PM emissions differ for the three road types; however, the peak emission points all occur on the provincial road. The average CO, HC, NOx and PM emission factors based on distance for the China II RVs are 9.21, 4.05, 1.68 and 2.58 times higher, respectively, than those of the China III RVs. However, the average NOx emission factors of the China II and III RVs are 2.21 and 1.65 times higher than the corresponding recommended values of national emission inventory guideline, resulting in underestimation of overall RVs' emissions. Distance-based emission factors of four pollutants ranked from high to low are farm road > rural road > provincial road. In contrast to the average emission factors of the China II RVs on the three road types, those of the China III RVs are significantly less in terms of distance and fuel consumption. The results of other researchers differ from those in this study: the CO emission factor of the China II RVs is 2.12 times higher than that of the China II light-duty diesel vehicles (LDDVs). The PM emission factor of the China III RVs is 2.67 times higher than that of the China III LDDVs. The NOx emission factors of the China II and III RVs are similar to those of the corresponding China II and III LDDVs. Our research increases the understanding of real-world emissions of RVs and can act as great references for policy makers developing RV emission baselines.
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Lithium iron phosphate (LFP) batteries contain metals, toxic electrolytes, organic chemicals and plastics that can lead to serious safety and environmental problems when they are improperly disposed of. The published literature on recovering spent LFP batteries mainly focuses on policy-making and conceptual design. The production line of recovering spent LFP batteries and its detailed operation are rarely reported. A set of automatic line without negative impact to the environment for recycling spent LFP batteries at industrial scale was investigated in this study. It includes crushing, pneumatic separation, sieving, and poison gas treatment processes. The optimum retaining time of materials in the crusher is 3 minutes. The release rate is the highest when the load of the impact crusher is 800 g. An air current separator (ACS) was designed to separate LFP from aluminium (Al) foil and LFP powder mixture. Movement behaviour of LFP powder and Al foil in the ACS were analysed, and the optimized operation parameter (35.46 m/s) of air current speed was obtained through theoretical analysis and experiments. The weight contents of an Al foil powder collector from vibrating screen-3 and LFP powder collector from bag-type dust collector are approximately 38.7% and 52.4%, respectively. The economic cost of full manual dismantling is higher than the recovery production line. This recycling system provides a feasible method for recycling spent LFP batteries.
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Aluminio , Litio , Suministros de Energía Eléctrica , Electrodos , Hierro , Fosfatos , ReciclajeRESUMEN
Spent lithium iron phosphate (LFP) batteries contain abundant strategic lithium resources and are thus considered attractive secondary lithium sources. However, these batteries may contaminate the environment because they contain hazardous materials. In this work, a novel process involving low-temperature heat treatment is used as an alternative pretreatment method for recycling spent LFP batteries. When the temperature reaches 300°C, the dissociation effect of the anode material gradually improves with heat treatment time. At the heat treatment time of 120 minutes, an electrode material can be dissociated. The extension of heat treatment time has a minimal effect on quality loss. The physicochemical changes in thermally treated solid cathode and anode materials are examined through scanning electron microscopy with energy-dispersive X-ray spectroscopy. The heat treatment results in the complete separation of the materials from aluminium foil without contamination. The change in heat treatment temperature has a small effect on the quality of LFP material shedding. When the heat treatment temperature reaches 300°C and the time reaches 120 minutes, heat treatment time increases, and the yield of each particle size is stable and basically unchanged. The method can be scaled up and may reduce environmental pollution due to waste LFP batteries.