Integration of life cycle assessment and system dynamics modeling for environmental scenario analysis: A systematic review.

System dynamics (SD) is widely recognized as a tool for simulating spatial and temporal dynamics in life cycle assessment (LCA) studies of the product system. However, there is no agreement on how SD and LCA could be applied effectively together in a consistent way. To address this gap, this research conducted a systematic literature review, analyzing 54 scientific articles published worldwide between 2010 and 2023, to explore the joint application of LCA with SD. The study aimed to answer three research questions: (1) What can be considered an integration of LCA and SD? (2) How can SD and LCA be effectively integrated? and (3)What are the advantages and constraints of this integration? The results highlighted the popularity of LCA and SD as impact assessment tools for sustainable design, each with its own strengths and limitations. Two primary integration types were identified when LCA was jointly applied with SD: (1) inclusion of the life cycle inventory and characterization factors in an SD model, and (2) inclusion of SD model results in an LCA. In the second type of integration, SD models the components of the technical system, and its outcomes served as input for scenario analysis, providing temporal and potentially spatial inventory data for the LCA model. The integrated approach offers a comprehensive understanding of product sustainability, aids decision-making, and enhances stakeholder engagement. The study also identifies knowledge gaps in the joint application of SD and LCA for environmental scenario analysis, suggesting the incorporation of optimization tools and strategy guidance for policy makers.

A life cycle assessment approach for nitrogen footprint quantification: the reactive nitrogen indicator.

Among the environmental issues that have recently catalyzed the attention of the scientific world, we must undoubtedly include the perturbation in the biogeochemical flows of nitrogen and phosphorus, which have been identified as one of the major risks on a global scale, also considering its social implications, since the use of macronutrients is essential to guarantee the food needs of the world population. In this context, there is a growing interest in the evaluation of the environmental impact related to this issue, particularly with regard to the effects of changes in the nitrogen cycle and the methods for quantifying them. In the latter field, several researches have recently been developed focusing on the indicator known as the nitrogen footprint, associated with the environmental releases of reactive nitrogen. This study proposes an innovative method to quantify the reactive nitrogen emissions of a product system through the reactive nitrogen indicator; the method is designed using as a reference the requirements of the international standards ISO 14040 and ISO 14044, in order to be aligned with the operating procedures of the life cycle assessment technique, thus differing from the previous approaches to calculate the nitrogen footprint. As part of the study, the proposed method is applied to calculate the reactive nitrogen emissions of a set of agricultural and livestock supply chain products, using secondary inventory data from an internationally recognized database. A validation of the method was also carried out by comparing references in the literature regarding the nitrogen footprint accounting for the same products, generally obtaining a good level of agreement. The proposed method, due to its reproducibility, ease of application and completeness, can therefore be usefully applied to any product system for the calculation of reactive nitrogen emissions, thanks to an innovative approach that meets the requirements of life cycle assessment.

Combination of product environmental footprint method and eco-design process according to ISO 14006: The case of an Italian vinery.

To support the sustainable development of the primary sector, in line with green new deals emerging worldwide, eco-design of new agri-food products is a priority. The wine industry, due to its growing market, has matured the need to develop an approach for understanding the environmental impacts of its products and to develop strategies to reduce such impacts in a life cycle perspective. This study has a two-fold aim: presenting the development of a methodological proposal for the use of PEF and PEF-CR in the eco-design of wine products; testing its applicability in a case study in the wine sector. The methodological proposal considered the combination of ISO 14006 and PEF methods into a procedure consisting of 8 steps. The proposal was successfully applied in the case of an Italian vinery committed to develop a new red wine product with improved performance if compared to its standard red wine production. The study occurred between 2018 and 2020, collecting primary data related to vineyards and vinery operations. Results proved that PEF method and PEF-CR can be effectively used in the eco-design of new wine products with reduced environmental impacts. Moreover, the study confirmed that PEF method can be used within the framework of ISO 14006. The study on standard red wine production confirmed that the fuel and pesticide consumption in the vineyard operation are environmental hotspots. To reduce these impacts, a new selection of Merlot Khorus grapes was made by the Italian vinery. Results of the eco-designed proved that the new product scored a reduction in the potential environmental impacts.

Theoretical analysis of fluorine addition to single-walled carbon nanotubes: functionalization routes and addition patterns.

We present a theoretical investigation on the chemical addition patterns governing the fluorination of single wall carbon nanotubes. Monte Carlo calculations based on a Hückel model suggest that fluorination is stabilized in a bandlike pattern due to electronic confinement effects on the tube bond network topology. Ab initio analysis of the fluorination of small nanotubes show that fluorine addition along the nanotube axis direction is favored by a mechanism of carbon framework distortion. The experimentally observed formation of fluorine bands may be thus explained in terms of multiple axial C(2)F rows expanding by contiguous axial addition.