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Environ Sci Pollut Res Int ; 20(7): 5028-35, 2013 Jul.
Artículo en Inglés | MEDLINE | ID: mdl-23334547

RESUMEN

The modification of MCM-41 was performed with 3-aminopropropyltrimethoxysilane. The structural order and textural properties of the synthesized materials were studied by X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetry/differential thermogravimetry, nitrogen adsorption, and desorption analysis. The adsorption capacity of NH2-MCM-41 was studied with Remazol Red dye. The following parameters were studied in the adsorption process: pH, temperature, adsorbent dosage, and initial concentration. The desorption process was studied in different concentrations of NaOH solutions. The Freundlich isotherm model was found to be fit with the equilibrium isotherm data. Kinetics of adsorption follows the modified Avrami rate equation. The maximum adsorption capacity was estimated to be 45.9 mg g(-1), with removal of the dye of 99.1%. The NH2-MCM-41 material exhibited high desorption capacity with 98.1%.


Asunto(s)
Colorantes/aislamiento & purificación , Dióxido de Silicio/análisis , Dióxido de Silicio/química , Adsorción , Concentración de Iones de Hidrógeno , Cinética , Nitrógeno/análisis , Nitrógeno/química , Propilaminas/química , Silanos/química , Espectroscopía Infrarroja por Transformada de Fourier , Temperatura , Termogravimetría , Difracción de Rayos X
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