RESUMEN
Bio-energy systems with carbon capture and storage (BECCS) will be essential if countries are to meet the gas emission reduction targets established in the 2015 Paris Agreement. This study seeks to carry out a thermodynamic optimization and analysis of a BECCS technology for a typical Brazilian cogeneration plant. To maximize generated net electrical energy (MWe) and carbon dioxide CO2 capture (Mt/year), this study evaluated six cogeneration systems integrated with a chemical absorption process using MEA. A key performance indicator (gCO2/kWh) was also evaluated. The set of optimal solutions shows that the single regenerator configuration (REG1) resulted in more CO2 capture (51.9% of all CO2 emissions generated by the plant), penalized by 14.9% in the electrical plant's efficiency. On the other hand, the reheated configuration with three regenerators (Reheat3) was less power-penalized (7.41%) but had a lower CO2 capture rate (36.3%). Results showed that if the CO2 capture rates would be higher than 51.9%, the cogeneration system would reach a higher specific emission (gCO2/kWh) than the cogeneration base plant without a carbon capture system, which implies that low capture rates (<51%) in the CCS system guarantee an overall net reduction in greenhouse gas emissions in sugarcane plants for power and ethanol production.
RESUMEN
Typical large-scale sewage-water treatments consume energy, occupy space and are unprofitable. This work evaluates a conceivable two-staged sewage-water treatment at 40,000 m3/d of sewage-water with sewage-sludge (totaling 10kgCOD/m3) that becomes a profitable bioenergy producer exporting reusable water and electricity, while promoting carbon capture. The first stage comprises microbial anaerobic digesters reducing the chemical oxygen demand (COD) by 95% and producing 60%mol methane biogas. The effluent waters enter the subsequent aerobic stage comprising microbial air-fed digesters that extend COD reduction to 99.7%. To simulate the process, up-to-date anaerobic/aerobic digester models were implemented. A biogas-combined-cycle power plant with/without post-combustion carbon capture is designed to match the biogas production, supplying electricity to the process and to the grid. Results comprehend electricity exportation of 13.21 MW (7.92 kWh/tReusable-Water) with -9.957tCO2/h of negative carbon emission (-0.6 kgCO2-Emitted/kgCOD-Removed). The biogas-combined-cycle without carbon capture achieves 21.08 MW of power exportation, while a 37.3% energy penalty arises if carbon capture is implemented. Configurations with/without carbon capture reach feasibility at 125 USD/MWh of electricity price, with respective net present values of 6.86 and 85.07 MMUSD and respective payback-times of 39 and 12 years. These results demonstrate that large-scale sewage-water treatment coupled to biogas-fired combined-cycles and carbon capture can achieve economically feasible bioenergy production with negative carbon emissions.