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1.
Electrophoresis ; 2024 Jun 04.
Artículo en Inglés | MEDLINE | ID: mdl-38837441

RESUMEN

The integration of microfluidics with electric field control, commonly referred to as electrofluidics, has led to new opportunities for biomedical analysis. The requirement for closed microcapillary channels in microfluidics, typically formed via complex microlithographic fabrication approaches, limits the direct accessibility to the separation processes during conventional electrofluidic devices. Textile structures provide an alternative and low-cost approach to overcome these limitations via providing open and surface-accessible capillary channels. Herein, we investigate the potential of different 3D textile structures for electrofluidics. In this study, 12 polyester yarns were braided around nylon monofilament cores of different diameters to produce functional 3D core-shell textile structures. Capillary electrophoresis performances of these 3D core-shell textile structures both before and after removing the nylon core were evaluated in terms of mobility and bandwidth of a fluorescence marker compound. It was shown that the fibre arrangement and density govern the inherent capillary formation within these textile structures which also impacts upon the solute analyte mobility and separation bandwidth during electrophoretic studies. Core-shell textile structures with a 0.47 mm nylon core exhibited the highest fluorescein mobility and presented a narrower separation bandwidth. This optimal textile structure was readily converted to different geometries via a simple heat-setting of the central nylon core. This approach can be used to fabricate an array of miniaturized devices that possess many of the basic functionalities required in electrofluidics while maintaining open surface access that is otherwise impractical in classical approaches.

2.
3D Print Addit Manuf ; 11(2): e586-e606, 2024 Apr 01.
Artículo en Inglés | MEDLINE | ID: mdl-38689919

RESUMEN

The article reviews the literature focused on investigating the adhesion strength between the 3D-printed polymers and the textile substrates, and its dependence on different factors related to materials, printing parameters, and fabrics type and structure. 3D printing (3DP) onto textiles is a domain in expansion as it allows developing products with new functionalities by gathering the advantages of design freedom, tailor-fit, comfort, variety, and mass customization provided by both the textiles and the additive manufacturing technology. In this context, it becomes important to document and understand how the adherence of different 3D-printed molten polymer to diverse textiles substrates can be improved for obtaining products more resistant to specific conditions, such as washing, wear, or ironing. Following a systematic search of electronic databases, 28 articles were selected for the full-text read and data extraction. The summarized information was grouped per 3DP material and analyzed factors, and then discussed in terms of variables influencing the adherence, including pretreatments and post-treatments applied to fabrics or 3D-printed onto fabrics specimens and objects. A case study of a customized polylactic acid-cotton-elastane wrist-hand orthosis is also presented to exemplify the modality in which the information synthetized in this review can be used in the development process of a new product.

3.
Colloids Surf B Biointerfaces ; 240: 113970, 2024 May 23.
Artículo en Inglés | MEDLINE | ID: mdl-38788474

RESUMEN

Extracts of traditional Chinese herbs (TCH) contain a variety of anti-allergic, anti-inflammatory and other bioactive factors. However, the defect of easy degradation or loss of active ingredients limits its application in traditional Chinese medicines (TCM) loaded textiles. In this work, TCH extracts containing different active ingredients were innovatively proposed as the core material of microcapsules. The feasibility of microencapsulation of multi-component TCH extracts in the essential oil state was initially demonstrated. Polyacrylate was also used as a binder to load the microcapsules onto the fabric to improve the durability and wash resistance of the treated fabric. Modeling the oil release of microcapsules for controlled release under different conditions may provide new possible uses for the materials. Results show that the constructed microcapsule has a smooth surface without depression and can be continuously released for over 30 days. The release behavior of microcapsules follows different release mechanisms and can be modulated by temperature and water molecules. The incorporation of microcapsules and polyacrylate does not significantly change the fabric's air permeability, water vapor transmission and hydrophilicity. The washing durability and friction properties of the microcapsule-based fabric are greatly improved, and it can withstand 30 washing tests and 200 friction tests. Moreover, the results of methyl thiazolyl tetrazolium (MTT) release assay using human dermal papilla cells (HDP) as an in vitro template confirm that the microcapsule has no toxic effects on human cells. Therefore, the successful microencapsulation of multi-component TCH extracts indicates their potential application in the field of TCM-loaded textiles.

4.
Biomimetics (Basel) ; 9(5)2024 Apr 25.
Artículo en Inglés | MEDLINE | ID: mdl-38786471

RESUMEN

In addition to water repellency, superhydrophobic leaves of plants such as Salvinia molesta adsorb oil and separate it from water surfaces. This phenomenon has been the inspiration for a new method of oil-water separation, the bionic oil adsorber (BOA). In this paper, we show how the biological effect can be abstracted and transferred to technical textiles, in this case knitted spacer textiles hydrophobized with a layered silicate, oriented at the biology push approach. Subsequently, the transport of the oil within the bio-inspired textile is analyzed by a three-dimensional fluid simulation. This fluid simulation shows that the textile can be optimized by reducing the pile yarn length, increasing the pile yarn spacing, and increasing the pile yarn diameter. For the first time, it has been possible with this simulation to optimize the bio-inspired textile with regard to oil transport with little effort and thus enable the successful implementation of a self-driven and sustainable oil removal method.

5.
ACS Sens ; 9(5): 2575-2584, 2024 May 24.
Artículo en Inglés | MEDLINE | ID: mdl-38695880

RESUMEN

Although electronic textiles that can detect external stimuli show great promise for fire rescue, existing firefighting clothing is still scarce for simultaneously integrating reliable early fire warning and real-time motion sensing, hardly providing intelligent personal protection under complex high-temperature conditions. Herein, we introduce an "all-in-one" hierarchically sandwiched fabric (HSF) sensor with a simultaneous temperature and pressure stimulus response for developing intelligent personal protection. A cross-arranged structure design has been proposed to tackle the serious mutual interference challenge during multimode sensing using two separate sets of core-sheath composite yarns and arrayed graphene-coated aerogels. The functional design of the HSF sensor not only possesses wide-range temperature sensing from 25 to 400 °C without pressure disturbance but also enables highly sensitive pressure response with good thermal adaptability (up to 400 °C) and wide pressure detection range (up to 120 kPa). As a proof of concept, we integrate large-scalable HSF sensors onto conventional firefighting clothing for passive/active fire warning and also detecting spatial pressure and temperature distribution when a firefighter is exposed to high-temperature flames, which may provide a useful design strategy for the application of intelligent firefighting protective clothing.


Asunto(s)
Presión , Temperatura , Textiles , Textiles/análisis , Humanos , Incendios , Bomberos , Ropa de Protección , Grafito/química , Dispositivos Electrónicos Vestibles
6.
Nanomicro Lett ; 16(1): 199, 2024 May 21.
Artículo en Inglés | MEDLINE | ID: mdl-38771428

RESUMEN

Skin-attachable electronics have garnered considerable research attention in health monitoring and artificial intelligence domains, whereas susceptibility to electromagnetic interference (EMI), heat accumulation issues, and ultraviolet (UV)-induced aging problems pose significant constraints on their potential applications. Here, an ultra-elastic, highly breathable, and thermal-comfortable epidermal sensor with exceptional UV-EMI shielding performance and remarkable thermal conductivity is developed for high-fidelity monitoring of multiple human electrophysiological signals. Via filling the elastomeric microfibers with thermally conductive boron nitride nanoparticles and bridging the insulating fiber interfaces by plating Ag nanoparticles (NPs), an interwoven thermal conducting fiber network (0.72 W m-1 K-1) is constructed benefiting from the seamless thermal interfaces, facilitating unimpeded heat dissipation for comfort skin wearing. More excitingly, the elastomeric fiber substrates simultaneously achieve outstanding UV protection (UPF = 143.1) and EMI shielding (SET > 65, X-band) capabilities owing to the high electrical conductivity and surface plasmon resonance of Ag NPs. Furthermore, an electronic textile prepared by printing liquid metal on the UV-EMI shielding and thermally conductive nonwoven textile is finally utilized as an advanced epidermal sensor, which succeeds in monitoring different electrophysiological signals under vigorous electromagnetic interference. This research paves the way for developing protective and environmentally adaptive epidermal electronics for next-generation health regulation.

7.
Int J Mol Sci ; 25(10)2024 May 14.
Artículo en Inglés | MEDLINE | ID: mdl-38791366

RESUMEN

The rise in the antibiotic resistance of bacteria has increased scientific interest in the study of materials with unique mechanisms of antimicrobial action. This paper presents the results of studies on the antimicrobial activity of carbon materials and textiles decorated with them. A comparative analysis of the bactericidal and fungicidal activities of graphene oxide, electrochemically exfoliated multigraphene, carbon dots, and their combinations was performed. Microbiological studies on reference strains of E. coli, S. aureus, and C. albicans showed that graphene oxide inhibited growth with up to 98% efficiency. Electrochemically exfoliated multigraphene was less effective (up to 40%). This study found no significant antimicrobial activity of carbon dots and the combination of carbon dots with graphene oxide significantly weakened their effectiveness. However, the combination of electrochemically exfoliated multigraphene and carbon dots exhibits a synergistic effect (up to 76%). A study on the antimicrobial activity of decorated cotton textiles demonstrated the effectiveness of antimicrobial textiles with graphene oxide, electrochemically exfoliated multigraphene, and a combination of carbon dots with electrochemically exfoliated multigraphene.


Asunto(s)
Antiinfecciosos , Fibra de Algodón , Grafito , Grafito/química , Grafito/farmacología , Antiinfecciosos/farmacología , Antiinfecciosos/química , Escherichia coli/efectos de los fármacos , Escherichia coli/crecimiento & desarrollo , Candida albicans/efectos de los fármacos , Candida albicans/crecimiento & desarrollo , Carbono/química , Staphylococcus aureus/efectos de los fármacos , Pruebas de Sensibilidad Microbiana , Textiles , Puntos Cuánticos/química
8.
Int J Biol Macromol ; : 132673, 2024 May 27.
Artículo en Inglés | MEDLINE | ID: mdl-38821804

RESUMEN

Smart textiles with flame retardant and fire-warning functions have received more and more attention. However, improving the fire-warning response sensitivity and long-term responsiveness of the smart textiles is a top priority. In this research, flame retardant and fire-warning cotton fabrics were prepared by layer-by-layer assembly composite coating consisting of bio-based flame retardants composed of chitosan (CS) and phytic acid (PA) and carbon-based nanomaterials composed of carbon nanotubes (CNTs) and graphene oxide (GO). The PA-GO/CS-CNTs coated cotton fabric showed excellent flame retardancy with a limiting oxygen index (LOI) value of 31 %, and the coated fabrics could self-extinguish rapidly when the flame was removed. The fire hazard of the coated fabric was significantly reduced by reducing the 45.77 % of peak heat release rate, 29.69 % of total heat release and 81.9 % of total smoke production. The PA-GO/CS-CNTs coated cotton fabric showed ultra-fast fire warning response with the response time of 1.0 s. And the fire-warning response time of the coated cotton fabric could last longer than 600 s revealing it possessed the continuous fire warning response property. This research provides a new strategy to prepare the smart fireproof textiles with flame retardant and fire-warning functions to broaden its application in early fire-warning.

9.
J Colloid Interface Sci ; 670: 337-347, 2024 Sep 15.
Artículo en Inglés | MEDLINE | ID: mdl-38763029

RESUMEN

Electroactive coatings for smart wearable textiles based on a furan bio-epoxy monomer (BOMF) crosslinked with isophorone diamine (IPD) and additivated with carbon nanotubes (CNTs) are reported herein. The effect of BOMF/IPD molar ratio on the curing reaction, as well as on the properties of the crosslinked resins was first assessed, and it was found that 1.5:1 BOMF/IPD molar ratio provided higher heat of reaction, glass transition temperature, and mechanical performance. The resin was then modified with CNT to prepare electrically conductive nanocomposite films, which exhibited conductivity values increased by eight orders of magnitude upon addition of 5 phr of CNTs. The epoxy/CNT nanocomposites were finally applied as coatings onto a cotton fabric to develop electrically conductive, hydrophobic and breathable textiles. Notably, the integration of CNTs imparted efficient and reversible electrothermal behavior to the cotton fabric, showcasing its potential application in smart and comfortable wearable electronic devices.

10.
ACS Nano ; 18(21): 13808-13817, 2024 May 28.
Artículo en Inglés | MEDLINE | ID: mdl-38747521

RESUMEN

Heating requirements for residential and commercial dwellings result in significant energy consumption and deleterious environmental effects. Personal radiative thermal management textiles regulate the wearer's body temperature by controlling the material's intrinsic optical properties. Passive heating textiles suppress radiative heat losses and therefore significantly reduce the energy consumption required for building heating systems. Guided by an optical theoretical approach, a transparent radiation shield (TRS) is designed based on silver nanowires (AgNWs) that can suppress human body heat with simultaneous visible light transmittance anticipated for practical fabrics. We experimentally demonstrated a TRS with large infrared light reflectance (low emissivity of 35%) and a visible (VIS) transparency value of 75% (400-800 nm). The results are well corroborated by the Mie scattering theory and the wire-mesh equivalent sheet impedance model, which provide fundamental mechanism understanding and guidance toward higher performance. The TRS is fabricated by a simple, solution-processing method with thermoplastic elastomer protective layers, granting notable stretching capabilities, mechanical robustness, and conformability to any body shape or object. The rigorous theoretical strategy enables the scalable synthesis of low-emissivity and visibly transparent textiles for personal thermal comfort.

11.
Int J Biol Macromol ; 270(Pt 2): 132462, 2024 Jun.
Artículo en Inglés | MEDLINE | ID: mdl-38772470

RESUMEN

Rapid development of society and the improvement of people's living standards have stimulated people's keen interest in fashion clothing. This trend has led to the acceleration of new product innovation and the shortening of the lifespan for cotton fabrics, which has resulting in the accumulation of waste cotton textiles. Although cotton fibers can be degraded naturally, direct disposal not only causes a serious resource waste, but also brings serious environmental problems. Hence, it is significant to explore a cleaner and greener waste textile treatment method in the context of green and sustainable development. To realize the high-value utilization of cellulose II aerogel derived from waste cotton products, great efforts have been made and considerable progress has been achieved in the past few decades. However, few reviews systematically summarize the research progress and future challenges of preparing high-value-added regenerated cellulose aerogels via dissolving cotton and other cellulose wastes. Therefore, this article reviews the regenerated cellulose aerogels obtained through solvent methods, summarizes their structure, preparation strategies and application, aimed to promote the development of the waste textile industry and contributed to the realization of carbon neutrality.


Asunto(s)
Celulosa , Fibra de Algodón , Geles , Textiles , Celulosa/química , Fibra de Algodón/análisis , Geles/química
12.
Sci Rep ; 14(1): 8045, 2024 04 05.
Artículo en Inglés | MEDLINE | ID: mdl-38580674

RESUMEN

Silver and titanium-silver nanoparticles have unique properties that make the textile industry progress through the high quality of textiles. Preparation of AgNPs and TiO2-Ag core-shell nanoparticles in different concentrations (0.01% and 0.1% OWF) and applying it to cotton fabrics (Giza 88 and Giza 94) by using succinic acid 5%/SHP as a cross-linking agent. Ultra-violet visible spectroscopy (UV-Vis), X-ray diffraction (XRD), dynamic light scattering (DLS), zeta potential, transmission electron microscopy (TEM), scanning electron microscopy/energy-dispersive X-ray (SEM-EDX) are tools for AgNPs and TiO2-AgNPs characterization and the treated cotton. The resulting AgNPs and TiO2-AgNPs were added to cotton fabrics at different concentrations. The antimicrobial activities, UV protection, self-cleaning, and the treated fabrics' mechanical characteristics were investigated. Silver nanoparticles and titanium dioxide-silver nanoparticles core-shell were prepared to be used in the treatment of cotton fabrics to improve their UV protection properties, self-cleaning, elongation and strength, as well as the antimicrobial activities to use the produced textiles for medical and laboratory uses and to increase protection for medical workers taking into account the spread of infection. The results demonstrated that a suitable distribution of prepared AgNPs supported the spherical form. Additionally, AgNPs and TiO2-AgNPs have both achieved stability, with values of (- 20.8 mV and - 30 mV, respectively). The synthesized nanoparticles spread and penetrated textiles' surfaces with efficiency. The findings demonstrated the superior UV protection value (UPF 50+) and self-cleaning capabilities of AgNPs and TiO2-AgNPs. In the treatment with 0.01% AgNPs and TiO2-AgNPs, the tensile strength dropped, but the mechanical characteristics were enhanced by raising the concentration to 0.1%. The results of this investigation demonstrated that the cotton fabric treated with TiO2-AgNPs exhibited superior general characteristics when compared to the sample treated only with AgNPs.


Asunto(s)
Antiinfecciosos , Nanopartículas del Metal , Humanos , Plata/química , Fibra de Algodón , Ácido Succínico , Nanopartículas del Metal/química , Textiles , Antibacterianos/farmacología , Antibacterianos/química
13.
ACS Sens ; 9(4): 1809-1819, 2024 Apr 26.
Artículo en Inglés | MEDLINE | ID: mdl-38587867

RESUMEN

While most of the research in graphene-based materials seeks high electroactive surface area and ion intercalation, here, we show an alternative electrochemical behavior that leverages graphene's potential in biosensing. We report a novel approach to fabricate graphene/polymer nanocomposites with near-record conductivity levels of 45 Ω sq-1 and enhanced biocompatibility. This is realized by laser processing of graphene oxide in a sandwich structure with a thin (100 µm) polyethylene terephthalate film on a textile substrate. Such hybrid materials exhibit high conductivity, low polarization, and stability. In addition, the nanocomposites are highly biocompatible, as evidenced by their low cytotoxicity and good skin adhesion. These results demonstrate the potential of graphene/polymer nanocomposites for smart clothing applications.


Asunto(s)
Grafito , Rayos Láser , Textiles , Grafito/química , Humanos , Técnicas Electroquímicas/métodos , Nanocompuestos/química , Conductividad Eléctrica , Tereftalatos Polietilenos/química , Animales , Materiales Biocompatibles/química , Técnicas Biosensibles/métodos
14.
ACS Appl Mater Interfaces ; 16(15): 19605-19614, 2024 Apr 17.
Artículo en Inglés | MEDLINE | ID: mdl-38568178

RESUMEN

Wearable sweat sensors have received considerable attention due to their great potential for noninvasive continuous monitoring of an individual's health status applications. However, the low secretion rate and fast evaporation of sweat pose challenges in collecting sweat from sedentary individuals for noninvasive analysis of body physiology. Here, we demonstrate wearable textiles for continuous monitoring of sweat at rest using the combination of a heating element and a microfluidic channel to increase localized skin sweat secretion rates and combat sweat evaporation, enabling accurate and stable monitoring of trace amounts of sweat. The Janus sensing yarns with a glucose sensing sensitivity of 36.57 mA cm-2 mM-1 are embroidered into the superhydrophobic heated textile to collect sweat directionally, resulting in improved sweat collection efficiency of up to 96 and 75% retention. The device also maintains a highly durable sensing performance, even in dynamic deformation, recycling, and washing. The microfluidic sensing textile can be further designed into a wireless sensing system that enables sedentary-compatible sweat analysis for the continuous, real-time monitoring of body glucose levels at rest.


Asunto(s)
Técnicas Biosensibles , Dispositivos Electrónicos Vestibles , Humanos , Sudor/química , Microfluídica , Glucosa/análisis , Monitoreo Fisiológico , Textiles , Técnicas Biosensibles/métodos
15.
Work ; 2024 Apr 04.
Artículo en Inglés | MEDLINE | ID: mdl-38640184

RESUMEN

BACKGROUND: Textile-sizing mill workers are exposed to various hazards in the sizing units during their working hours and are at risk of acquiring lung impairments due to the usage of sizing chemicals in the sizing process. OBJECTIVE: The main aim of this study is to assess the influence of cotton dust and sizing agents on lung function and breathing difficulties among Indian textile sizing mill workers. METHODS: This cross-sectional study was carried out at a textile-sizing mill from August 2022 to September 2022. A modified questionnaire based American Thoracic Society's standard was used to assess respiratory symptoms among sizing mill workers and the pulmonary function test was conducted Spirometry. The chi-square test was used to find the difference between respiratory symptoms and the t-test was used to find the difference between spirometric parameters. RESULTS: Textile sizing mill workers showed significant (P <  0.0001) decline in peak expiratory flow rate, forced vital capacity (FVC), ratio of FEV1 and forced vital capacity, and forced expiratory volume in 1 s (FEV1). There was an association between symptoms and duration of exposure to pulmonary abnormality. Sizing mill workers showed a significant decline in lung functions and an increase in pulmonary symptoms. As the service duration of exposure in terms of years increased, respiratory symptoms increased and spirometric abnormality also increased. CONCLUSION: This study confirms that sizing agents such as polyvinyl alcohol (PVA), emulsifier, wax, carboxymethyl cellulose (CMC), and starch used in sizing mills are also responsible for respiratory illness and lung impairment among textile workers.

16.
ACS Appl Mater Interfaces ; 16(17): 22113-22121, 2024 May 01.
Artículo en Inglés | MEDLINE | ID: mdl-38636102

RESUMEN

New technologies to integrate electronics and sensors on or into objects can support the growth of embedded electronics. The method proposed in this paper has the huge advantage of being substrate-free and applicable to a wide range of target materials such as fiber-based composites, widely used in manufacturing, and for which monitoring applications such as fatigue, cracks, and deformation detection are crucial. Here, sensors are first fabricated on a donor substrate using standard microelectronic processes and then transferred to the host material by direct transfer printing. Results show the viability of composites instrumented by strain gauges. Indeed, dynamic and static measurements highlight that the deformations can be detected with high sensitivity both on the surface and at various points in the depth of the composite material. Thanks to this technology, for the first time, a substrate-free piezoresistive n-doped silicon strain sensor is transferred into a composite material and characterized as a function of strain applied on it. It is shown that the transfer process does not alter the electrical behavior of the sensors that are five times more sensitive than extensively used metallic ones. An application designed for monitoring the deformation of a rudder foil with a classic NACA profile in real time is presented.

17.
Int J Biol Macromol ; 267(Pt 1): 131512, 2024 May.
Artículo en Inglés | MEDLINE | ID: mdl-38608972

RESUMEN

Two-dimensional (2D) transition metal carbides (Ti3C2Tx MXene) have gained significant attention for their potential in constructing diverse functional materials, However, MXene is easily oxidized and weakly bound to the cellulose matrix, which pose challenges in developing MXene-decorated non-woven fabric with strong bonding and stable thermal management properties. Herein, we successfully prepared deep eutectic supramolecular polymer (DESP) functionalized MXene to address these issues. MXene can be wrapped with DESP to be insulated from water and protected from being oxidized. Subsequently, we achieved an efficient in-situ deposition of DESP-functionalized MXene onto fibers through a combination of dip coating and photopolymerization technique. The resulting nonwoven fabric (CNs-DESP@M) exhibited excellent photothermal conversion properties along with rapid thermal response and functional stability. Interestingly, the interface bonding between MXene and the fiber surface was significantly enhanced due to the abundant pyrogallol groups in DESP, resulting in the composite textile exhibiting commendable mechanical properties (2.68 MPa). Moreover, the as-prepared textile demonstrates outstanding bactericidal efficacy against both Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). The multifunctional textile, created through a facile and efficient approach, demonstrates remarkable potential for applications in smart textiles, catering to the diverse needs of individuals in the future.


Asunto(s)
Antibacterianos , Celulosa , Escherichia coli , Polímeros , Staphylococcus aureus , Textiles , Celulosa/química , Celulosa/farmacología , Escherichia coli/efectos de los fármacos , Staphylococcus aureus/efectos de los fármacos , Antibacterianos/farmacología , Antibacterianos/química , Polímeros/química , Fenómenos Mecánicos , Temperatura , Viabilidad Microbiana/efectos de los fármacos
18.
ACS Appl Mater Interfaces ; 16(19): 25221-25235, 2024 May 15.
Artículo en Inglés | MEDLINE | ID: mdl-38688012

RESUMEN

This study aims at understanding the effect of the photoreduction process during the synthesis of gold (Au)-doped TiO2 colloids on the conferred functionalities on cotton fabrics. TiO2/Au and TiO2/Au/SiO2 colloids were synthesized through the sol-gel method with and without undergoing the photoreduction step based on different molar ratios of Au:Ti (0.001 and 0.01) and TiO2/SiO2 (1:1 and 1:2.3). The colloids were applied to cotton fabrics, and the obtained photocatalytic self-cleaning, wet photocatalytic activity, UV protection, and antibacterial activity against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) bacteria were investigated. The obtained results demonstrated that the photoreduction of Au weakened the self-cleaning effect and reduced the photocatalytic activity of coated fabrics. Also, an excess amount of Au deteriorated the photocatalytic activity under both UV and visible light. The most efficient self-cleaning effect was obtained on fabrics coated with a ternary TiO2/Au/SiO2 colloid containing ionic Au, where it decomposed coffee and red-wine stains after 3 h of illumination. Adding silica (SiO2) made the fabrics superhydrophilic and led to greater methylene blue (MB) dye adsorption, a faster dye degradation pace, and more efficient stain removal. Moreover, the photoreduction process affected the size of Au nanoparticles (NPs), weakened the antibacterial activity of fabrics against both types of tested bacteria, and modestly increased the UV protection. In general, the photoactivity of Au-doped colloids was influenced by the synthesis method, the ionic and metallic states of the Au dopant, the concentration of the Au dopant, and the presence and concentration of silica.


Asunto(s)
Antibacterianos , Coloides , Fibra de Algodón , Escherichia coli , Oro , Staphylococcus aureus , Titanio , Titanio/química , Titanio/farmacología , Antibacterianos/farmacología , Antibacterianos/química , Oro/química , Oro/farmacología , Staphylococcus aureus/efectos de los fármacos , Escherichia coli/efectos de los fármacos , Coloides/química , Dióxido de Silicio/química , Dióxido de Silicio/farmacología , Catálisis , Rayos Ultravioleta , Oxidación-Reducción
19.
Sci Total Environ ; 931: 172752, 2024 Jun 25.
Artículo en Inglés | MEDLINE | ID: mdl-38677427

RESUMEN

The objective of this work is to develop a closed-loop recycling method specifically tailored for acrylic fibers. Recycling waste acrylic is essential, given the vast volumes of acrylic-containing textiles produced yearly and the strong capability of acrylics to generate toxic microplastics. However, none of the available closed-loop recycling, mechanical recycling, chemical recycling, and direct extrusion technologies work for acrylics. Acrylic fibers are always blended with other textile fibers, making fiber separation via mechanical recycling almost impossible. Polyacrylonitrile, an addition-polymerized thermoplastic material, cannot be depolymerized into its original monomer. Direct extrusion of waste acrylics faces issues of uncontrollable colors on fibers and pollution of spinning lines due to the influence of existing colorants. In our method, acrylic fibers were extracted from waste textiles using a novel approach involving maximized acrylic swelling and dissolution with dimethyl sulfoxide and butanediol. Cationic dyes were effectively removed through cost-effective recycling technology. This work demonstrates that cationic dyes seriously affect the acrylic dissolution, color consistency, and dyeability of regenerated fibers via direct wet extrusion. Such negative impacts of dyes have been eliminated by our cost-effective and closed-loop acrylic recycling technology, which enables the efficient separation of non-acrylic fibers and dyes from acrylic fibers. Our recycling system achieved zero discharges through recycling solvents, dyes, and acrylics. The regenerated acrylic fibers exhibited mechanical properties and dyeability comparable to virgin acrylic fibers. The material and energy costs to produce pure acrylic from waste textiles were only 40 % of those from fossils. This study successfully introduces a closed-loop recycling method for acrylic fibers from waste textiles, addressing key challenges in acrylic fiber recycling. Further research and implementation of this technology are recommended to advance its commercial viability and widespread adoption.

20.
Int J Biol Macromol ; 268(Pt 1): 131605, 2024 May.
Artículo en Inglés | MEDLINE | ID: mdl-38641284

RESUMEN

In the ever-evolving landscape of tissue engineering, medicated biotextiles have emerged as a game-changer. These remarkable textiles have garnered significant attention for their ability to craft tissue scaffolds that closely mimic the properties of natural tissues. This comprehensive review delves into the realm of medicated protein and polysaccharide-based biotextiles, exploring a diverse array of fabric materials. We unravel the intricate web of fabrication methods, ranging from weft/warp knitting to plain/stain weaving and braiding, each lending its unique touch to the world of biotextiles creation. Fibre production techniques, such as melt spinning, wet/gel spinning, and multicomponent spinning, are demystified to shed light on the magic behind these ground-breaking textiles. The biotextiles thus crafted exhibit exceptional physical and chemical properties that hold immense promise in the field of tissue engineering (TE). Our review underscores the myriad applications of drug-eluting protein and polysaccharide-based textiles, including TE, tissue repair, regeneration, and wound healing. Additionally, we delve into commercially available products that harness the potential of medicated biotextiles, paving the way for a brighter future in healthcare and regenerative medicine. Step into the world of innovation with medicated biotextiles-where science meets the art of healing.


Asunto(s)
Polisacáridos , Proteínas , Textiles , Ingeniería de Tejidos , Ingeniería de Tejidos/métodos , Polisacáridos/química , Humanos , Proteínas/química , Andamios del Tejido/química , Animales , Medicina Regenerativa/métodos , Materiales Biocompatibles/química , Cicatrización de Heridas/efectos de los fármacos
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