Removal Performance of KOH-Modified Biochar from Tropical Biomass on Tetracycline and Cr(VI).

Biochar can be used to address the excessive use of tetracycline and micronutrient chromium (Cr) in wastewater that potentially threatens human health. However, there is little information about how the biochar, made from different tropical biomass, facilitates tetracycline and hexavalent chromium (Cr(VI)) removal from aqueous solution. In this study, biochar was prepared from cassava stalk, rubber wood and sugarcane bagasse, then further modified with KOH to remove tetracycline and Cr(VI). Results showed that pore characteristics and redox capacity of biochar were improved after modification. KOH-modified rubber wood biochar had the highest removal of tetracycline and Cr(VI), 1.85 times and 6 times higher than unmodified biochar. Tetracycline and Cr(VI) can be removed by electrostatic adsorption, reduction reaction, π-π stacking interaction, hydrogen bonding, pore filling effect and surface complexation. These observations will improve the understanding of the simultaneous removal of tetracycline and anionic heavy metals from wastewater.

Electroactive microorganism-assisted remediation of groundwater contamination: Advances and challenges.

Groundwater contamination has become increasingly prominent, therefore, the development of efficient remediation technology is crucial for improving groundwater quality. Bioremediation is cost-effective and environmentally friendly, while coexisting pollutant stress can affect microbial processes, and the heterogeneous character of groundwater medium can induce bioavailability limitations and electron donor/acceptor imbalances. Electroactive microorganisms (EAMs) are advantageous in contaminated groundwater because of their unique bidirectional electron transfer mechanism, which allows them to use solid electrodes as electron donors/acceptors. However, the relatively low-conductivity groundwater environment is unfavorable for electron transfer, which becomes a bottleneck problem that limits the remediation efficiency of EAMs. Therefore, this study reviews the recent advances and challenges of EAMs applied in the groundwater environment with complex coexisting ions, heterogeneity, and low conductivity and proposes corresponding future directions.

Competitive Degradation of Steroid Estrogens by Potassium Permanganate Combined with Ultrasound.

The occurrence of natural estrogens including estrone (E1), 17ß-estradiol (E2), and synthetic 17α-ethinylestradiol (EE2), which can be excreted by both humans and animals, and can enter the aqueous environment along with the discharge of domestic sewage, is a major concern since this may represent a serious health risk to humans even at extremely trace levels (ng·L(-1)). Simultaneous degradation of three coexisting steroid estrogens (SEs) in aqueous solutions by coupled ultrasound and KMnO4 systems (KMnO4/ultrasound) were investigated to find out whether there is a competitive degradation of multiple contaminants or not. Results indicate that the degradation ratios of target SEs were all more than 50% after 120 min reaction contact, greatly enhanced when compared with the single KMnO4 (2 mg·L(-1)) oxidation of E2 (37.0%), EE2 (34.4%), and E1 (34.0%), and the single sonochemical oxidation of E2 (37.1%), EE2 (31.1%), and E1 (29.7%). In the adopted processes, the degradations of SEs fit the first-order kinetic reaction, with different reaction rates. Kinetic parameters revealed there was little difference between coexisting SEs, which means there was almost no competitive degradation. The removal efficiency and degradation rate of SEs in natural water was higher than those in pure water, which suggested that the coupled KMnO4/ultrasound technology had prospective applications in the removal of complex contaminants in actual drinking water treatment.