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1.
Nano Lett ; 2024 Sep 04.
Artículo en Inglés | MEDLINE | ID: mdl-39230046

RESUMEN

Rewarming cryopreserved samples requires fast heating to avoid devitrification, a challenge previously attempted by magnetic nanoparticle-mediated hyperthermia. Here, we introduce Fe3O4@SiO2 nanorods as the heating elements to manipulate the heating profile to ensure safe rewarming and address the issue of uneven heating due to inhomogeneous particle distribution. The magnetic anisotropy of the nanorods allows their prealignment in the cryoprotective agent (CPA) during cooling and promotes subsequent rapid rewarming in an alternating magnetic field with the same orientation to prevent devitrification. More importantly, applying an orthogonal static magnetic field at a later stage could decelerate heating, effectively mitigating local overheating and reducing CPA toxicity. Furthermore, this orientational configuration offers more substantial heating deceleration in areas of initially higher heating rates, therefore reducing temperature variations across the sample. The efficacy of this method in regulating heating rate and improving rewarming uniformity has been validated using both gel and porcine artery models.

2.
Small ; : e2404729, 2024 Aug 08.
Artículo en Inglés | MEDLINE | ID: mdl-39113671

RESUMEN

Development of high-performance, low-cost catalysts for electrochemical water splitting is key to sustainable hydrogen production. Herein, ultrafast synthesis of carbon-supported ruthenium-copper (RuCu/C) nanocomposites is reported by magnetic induction heating, where the rapid Joule's heating of RuCl3 and CuCl2 at 200 A for 10 s produces Ru-Cl residues-decorated Ru nanocrystals dispersed on a CuClx scaffold, featuring effective Ru to Cu charge transfer. Among the series, the RuCu/C-3 sample exhibits the best activity in 1 m KOH toward both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), with an overpotential of only -23 and +270 mV to reach 10 mA cm-2, respectively. When RuCu/C-3 is used as bifunctional catalysts for electrochemical water splitting, a low cell voltage of 1.53 V is needed to produce 10 mA cm-2, markedly better than that with a mixture of commercial Pt/C+RuO2 (1.59 V). In situ X-ray absorption spectroscopy measurements show that the bifunctional activity is due to reduction of the Ru-Cl residues at low electrode potentials that enriches metallic Ru and oxidation at high electrode potentials that facilitates the formation of amorphous RuOx. These findings highlight the unique potential of MIH in the ultrafast synthesis of high-performance catalysts for electrochemical water splitting.

3.
Heliyon ; 10(12): e33073, 2024 Jun 30.
Artículo en Inglés | MEDLINE | ID: mdl-39021994

RESUMEN

At present, in the process of weld induction heat treatment, the common method is to carry out centralized induction heating in the weld area, which will lead to large radial temperature difference of the weld, poor controllability of temperature distribution and easy to cause the defects of residual stress concentration in the weld area. To solve the above problems, this paper adopts the two-sided method to conduct induction heating on both sides of the weld, and at the same time, the auxiliary pulse current is passed into the weld to improve the quality of the weld. ANSYS finite element software is used to establish a multi-field coupling prediction model of electric-magnetic-thermal structure, and explore the distribution law of the auxiliary pulse current and the temperature field of the weld. Finally, an experimental study of pulsed current assisted two-sided induction heating is carried out. Temperature test and metallographic test were carried out respectively to verify the effectiveness of pulsed current assisted induction heating technology.

4.
Materials (Basel) ; 17(14)2024 Jul 20.
Artículo en Inglés | MEDLINE | ID: mdl-39063881

RESUMEN

In this paper, a Cr coating was prepared by induction heating and pack-cementation chromizing on AISI 304 austenitic stainless steel. Then, the cold-rolling deformation and annealing treatment were introduced to refine the coarse matrix grains caused by pack-chromizing and improve the overall performance of 304 austenitic stainless steel. The phase composition, element distribution, and microstructure of the coating were carefully characterized. The microhardness, wear resistance, and corrosion resistance of the coating were tested. The results show that the Cr coating with a thickness of 100 µm is mainly composed of a (Cr,Fe)23C6, (Cr,Fe)7C3, and α-Fe-Cr solid solution. After the cold-rolling deformation and subsequent annealing treatment, the grains are significantly refined and the Cr coating is divided into two layers, consisting of carbon-chromium compounds such as Cr23C6, Cr7C3, Cr2C, and Cr3C2 in the surface layer and a Fe-Cr solid solution in the subsurface layer. The cold-rolling deformation and annealing treatment significantly improved the microhardness and wear resistance of the coated sample, and the corrosion resistance was also better than that of the uncoated sample.

5.
Foods ; 13(13)2024 Jun 26.
Artículo en Inglés | MEDLINE | ID: mdl-38998532

RESUMEN

This study investigates the application of microwave combined induction heating (MCIH) to steam ready-to-eat pork with rice powder, emphasizing the advantages of rapid and uniform heating. The experimental setup included a mixture of 180 g pork strips, 30 g rice powder, and 10 g water in a CPET tray using MCIH with 1080 W microwave (MW) and 130 °C induction heating (IH) for 150 s. The results showed a quick temperature increase rate of 0.56 °C/s that achieved pasteurization against a variety of pathogenic bacteria, such as Listeria monocytogenes, but not Clostridium botulinum, by lethality calculation. Compared to typical electric cooker steaming, MCIH significantly shortened cooking time (8.6 times faster). To address rice starch gelatinization, two-stage heating techniques to steam pork with rice powder were MCIH: 150 s, and then IH: 60 s (MW1), and MCIH: 180 s, and then IH: 30 s (MW2), with no significant differences seen in color or the nine-point taste scale between treatment groups. MCIH groups had smaller shear forces than control. After MCIH cooking, no microbial counts were detected in the MW1 and MW2 groups initially, and the pork with rice powder had a shelf life of 14 days at 4 °C based on aerobic plate count assay.

6.
Materials (Basel) ; 17(11)2024 Jun 05.
Artículo en Inglés | MEDLINE | ID: mdl-38894017

RESUMEN

Addressing the issue of low bonding strength in Ti/Mg laminated composites due to interfacial oxidation, this study employs a differential temperature rolling method using longitudinal induction heating to fabricate Ti/Mg composite plates. The entire process is conducted under an argon gas protective atmosphere, which prevents interfacial oxidation while achieving uniform deformation. The effects of reduction on the mechanical properties and microstructure of the composite plates are thoroughly investigated. Results indicate that as the reduction increases, the bonding strength gradually increases, mainly attributed to the increased mechanical interlocking area and a broader element diffusion layer. This corresponds to a transition from a brittle to a ductile fracture at the microscopic tensile-shear fracture surface. When the reduction reaches 47.5%, the Ti/Mg interfacial strength reaches 63 MPa, which is approximately a 20% improvement compared to the bonded strength with previous oxidation at the interface. Notably, at a low reduction of 17.5%, the bonding strength is significantly enhanced by about one time. Additionally, it was found that a strong bonded interface at a high reduction is beneficial in hindering the propagation of interfacial cracks during tensile testing, enhancing the ability of the Ti/Mg composite plates to resist interfacial delamination.

7.
Materials (Basel) ; 17(12)2024 Jun 19.
Artículo en Inglés | MEDLINE | ID: mdl-38930380

RESUMEN

In order to optimize the application effect of induction heating (IH) tundishes, a four-channel IH tundish is taken as the research object. Based on numerical simulation methods, the influence of different relative placement angles of induction heaters and channels on the electromagnetic field, flow field and temperature field of the tundish is investigated. We focus on comparing the magnetic flux density (B) and electromagnetic force (EMF) distribution of the channel. The results show that regardless of the relative placement angle between the heater and the channel, the distribution of B in the central circular cross-section of the channel is eccentric. When the heater rotates around channel 1 towards the bottom of the tundish, the distribution of B in the central circular cross-section of the channel changes from a horizontal eccentricity to a vertical one. Through the analysis of the B contour in the longitudinal section of the channel, the difference in effective magnetic flux density area (ΔAB) between the upper and lower parts of the channel can be obtained, thereby quantitatively analyzing the distribution of B in this section. The distribution pattern of ΔAB is consistent with the distribution pattern of the electromagnetic force in the vertical direction (FZ) of the channel centerline. The ΔAB and FZ of channel 1 gradually increase as the heater rotates downwards, while those of channel 2 reach their maximum value at a rotation angle of 60°. Compared to the conventional placement, when the heater rotation angle is 60°, the outlet flow velocities at channel 1 and channel 2 decrease by 15% and 12%, respectively. However, the outlet temperature at channel 2 increases by 1.96 K, and the molten steel flow at the outlet of channel 1 and channel 2 no longer exhibits significant downward flow. This shows that when the heater rotation angle is 60°, it has a dual advantage. On the one hand, it is helpful to reduce the erosion of the molten steel on the channel and the bottom of the discharging chamber, and on the other hand, it can more effectively exert the heating effect of the induction heater on the molten steel in the channel. This presents a new approach to enhance the application effectiveness of IH tundish.

8.
Adv Mater ; 36(30): e2404689, 2024 Jul.
Artículo en Inglés | MEDLINE | ID: mdl-38748686

RESUMEN

Revitalizing metal anodes for rechargeable batteries confronts challenges such as dendrite formation, limited cyclicity, and suboptimal energy density. Despite various efforts, a practical fabrication method for dendrite-free metal anodes remains unavailable. Herein, focusing on Li as exemplar, a general strategy is reported to enhance reversibility of the metal anodes by forming alloyed metals, which is achieved by induction heating of 3D substrate, lithiophilic metals, and Li within tens of seconds. It is demonstrated that preferred alloying interactions between substrates and lithiophilic metals created a lithiophilic metal-rich region adjacent to the substrate, serving as ultrastable lithiophilic host to guide dendrite-free deposition, particularly during prolonged high-capacity cycling. Simultaneously, an alloying between lithiophilic metals and Li creates a Li-rich region adjacent to electrolyte that reduces nucleation overpotential and constitutes favorable electrolyte-Li interface. The resultant composite Li anodes paired with high areal loading LiNi0.8Co0.1Mn0.1O2 cathodes achieve superior cycling stability and remarkable energy density above 1200 Wh L-1 (excluding packaging). Furthermore, this approach shows broader applicability to other metal anodes plagued by dendrite-related challenges, such as Na and Zn. Overall, this work paves the way for development of commercially viable metal-based batteries that offer a combination of safety, high energy density, and durability.

9.
Materials (Basel) ; 17(10)2024 May 07.
Artículo en Inglés | MEDLINE | ID: mdl-38793242

RESUMEN

The inductive heating of a CMC susceptor for industrial applications can generate very high process temperatures. Thus, the behavior of a silicon carbide-based matrix with carbon-fiber-reinforced carbon (C/C-SiC) as a susceptor is investigated. Specifically, the influence of fiber length and the distribution of carbon fibers in the composite were investigated to find out the best parameters for the most efficient heating. For a multi-factorial set of requirements with a combination of filling levels and fiber lengths, a theoretical correlation of the material structure can be used as part of a digital model. Multi-physical simulation was performed to study the behavior of an alternating magnetic field generated by an inducing coil. The simulation results were verified by practical tests. It is shown that the inductive heating of a C/C-SiC susceptor can reach very high temperatures in a particularly fast and efficient way without oxidizing if it is ensured that a silicon carbide-based matrix completely encloses the fibers.

10.
Bioresour Technol ; 402: 130844, 2024 Jun.
Artículo en Inglés | MEDLINE | ID: mdl-38754560

RESUMEN

In this study, a novel magnetic Ni-Fe2O3-C catalyst combined with electromagnetic induction heating in biomass steam gasification was proposed to enhance H2 production. Better catalytic performance for H2 production was observed with the Ni-Fe2O3-C catalyst under induction heating, resulting in an increase in H2 yield from 735.1 to 2271.2 mL/g-biomass (a 209.1 % enhancement). SEM, TGA and XRD analysis demonstrated a significant decrease in coking deposition, caking, and particle agglomeration of the Ni-Fe2O3-C catalyst under induction heating, while maintaining more active sites. Importantly, the benefits of induction heating were also applicable to different magnetic catalysts like Ni-Al2O3-C, Ni-ZrO2-C, and Ni-MgO-C. Experimental results revealed a logarithmic correlation between the increase in H2 yields due to induction heating and the magnetic saturation (Ms) of the catalysts. The Ni-Fe2O3-C catalyst, with a high Ms of 50.9 emu/g, showed the highest catalytic activity for H2 production under induction heating in this study.


Asunto(s)
Biomasa , Compuestos Férricos , Hidrógeno , Níquel , Vapor , Catálisis , Hidrógeno/química , Níquel/química , Compuestos Férricos/química , Calor , Calefacción , Difracción de Rayos X , Fenómenos Electromagnéticos
11.
Materials (Basel) ; 17(9)2024 Apr 26.
Artículo en Inglés | MEDLINE | ID: mdl-38730847

RESUMEN

Induction healing technology can effectively repair microcracks in asphalt mixtures and is a promising maintenance technology for asphalt pavements. However, it requires the addition of steel wool fibers to asphalt mixtures and cannot be directly used to repair existing pavements. In order to improve the practicality of the induction healing technology, this article designs a wearing course asphalt mixture with induction healing function that is going to be paved above the existing road surface. The AC-10 asphalt wearing course for induction heating was prepared by adding steel fiber (SF). Analysis of the overall temperature of the surface revealed the unevenness of the temperature distribution, and the healing properties were investigated through protective heating that controlled the maximum temperature of the upper surface. The results show that the addition of SF can improve the high-temperature stability, low-temperature and intermediate-temperature crack resistance, and moisture stability of asphalt wearing courses; however, it has adverse effects on volumetric performance and skid resistance. The heating temperature increases with the increase in SF content, but higher maximum temperature heating rate causes worse heating uniformity and lower healing effect. The maximum heating rate of the sample with 10% SF reaches 3.92 °C/s, while its heating rate at minimum temperature is similar to that of the sample with 6% SF, which is only 0.7 °C/s, indicating the worst heating uniformity. The best healing effect occurs when the maximum temperature of the upper surface reaches 160 °C. The recommended optimal SF content is 6% of the asphalt volume. The asphalt mixture with 6% SF has an appropriate volume performance, moisture stability, and skid resistance; additionally, it has the best high-temperature stability, as well as low-temperature and intermediate-temperature crack resistance. Meanwhile, it also has uniform temperature distribution and efficient healing efficiency.

12.
J Pept Sci ; 30(9): e3605, 2024 Sep.
Artículo en Inglés | MEDLINE | ID: mdl-38660732

RESUMEN

On December 12th, 2023, the European Commission took regulatory action to amend Annex XVII of REACH, imposing restrictions on the use of N,N-dimethylformamide (DMF) within the EU market owing to its high toxicity. Historically, DMF has been widely considered the gold standard for solid-phase peptide synthesis (SPPS). Being urgent to propose alternative solvents, we tested the suitability of non-hazardous neat and mixed solvents. Notably, binary solvent mixtures containing dimethyl sulfoxide as one of the solvent partners demonstrated high efficacy in solubilizing reagents while maintaining the desired swelling characteristics of common resins. A series of binary solvent mixtures were tested in automated SPPS, both at room temperature and high temperature, employing the PurePep® Chorus synthesizer, which enabled controlled induction heating between 25 and 90°C with oscillation mixing. The performances were assessed in challenging peptide sequences, i.e., ACP (65-74), and in longer and aggregating sequences like SARS-CoV-2 RBM (436-507) and ß-amyloid (1-42). Furthermore, as part of the proposed sustainable approach to minimize the utilization of hazardous solvents, we coupled the novel PurePep EasyClean catch-and-release purification technology. This work, addressing regulatory compliance, emphasizes the crucial role of green chemistry in advancing safer and more environmentally friendly practices in SPPS.


Asunto(s)
Péptidos , Técnicas de Síntesis en Fase Sólida , Solventes , Solventes/química , Péptidos/química , Péptidos/síntesis química , Técnicas de Síntesis en Fase Sólida/métodos , Péptidos beta-Amiloides/química , Tecnología Química Verde , Dimetilformamida/química , Dimetilsulfóxido/química , Fragmentos de Péptidos/química , Fragmentos de Péptidos/síntesis química , SARS-CoV-2 , Calefacción , Automatización , Calor
13.
J Environ Manage ; 356: 120644, 2024 Apr.
Artículo en Inglés | MEDLINE | ID: mdl-38522274

RESUMEN

Plastics are a wide range of synthetic or semi-synthetic materials, mainly consisting of polymers. The use of plastics has increased to over 300 million metric tonnes in recent years, and by 2050, it is expected to grow to 800 million. Presently, a mere 10% of plastic waste is recycled, with approximately 75% ended up in landfills. Inappropriate disposal of plastic waste into the environment poses a threat to human lives and marine species. Therefore, this review article highlights potential routes for converting plastic/microplastic waste into valuable resources to promote a greener and more sustainable environment. The literature review revealed that plastics/microplastics (P/MP) could be recycled or upcycled into various products or materials via several innovative processes. For example, P/MP are recycled and utilized as anodes in lithium-ion (Li-ion) and sodium-ion (Na-ion) batteries. The anode in Na-ion batteries comprising PP carbon powder exhibits a high reversible capacity of ∼340 mAh/g at 0.01 A/g current state. In contrast, integrating Fe3O4 and PE into a Li-ion battery yielded an excellent capacity of 1123 mAh/g at 0.5 A/g current state. Additionally, recycled Nylon displayed high physical and mechanical properties necessary for excellent application as 3D printing material. Induction heating is considered a revolutionary pyrolysis technique with improved yield, efficiency, and lower energy utilization. Overall, P/MPs are highlighted as abundant resources for the sustainable production of valuable products and materials such as batteries, nanomaterials, graphene, and membranes for future applications.


Asunto(s)
Microplásticos , Plásticos , Humanos , Reciclaje , Instalaciones de Eliminación de Residuos
14.
Heliyon ; 10(4): e25504, 2024 Feb 29.
Artículo en Inglés | MEDLINE | ID: mdl-38384505

RESUMEN

Over the past few decades, the demand for high-quality food has increased steadily. Therefore, it is essential to develop innovative technologies that effectively reduce microbial load while minimizing any negative effect on the quality of spices. The objective of this study was to determine the efficacy of a self-designed non-contact induction heating system using contaminated cumin seeds. The non-contact induction heating decontamination process was performed at different temperatures of 115, 135 and 155°C and durations (45, 60 and 75 s) through continuous process (screw conveyor) in Pyrex cylinder chamber. Various parameters including microbial load, color characteristics, essential oil content, surface morphology, sample temperature, and energy consumption were analyzed as dependent variables in the study. The results showed that the treatment combination (155°C - 60 s) reduced the aerobic plate count from 6.21 to 2.97 CFU/g. Mold, yeast and coliforms in the treatment combination (155°C-45 s) were also reduced by 3.26 and 3.6 CFU/g, respectively. The total color difference of the samples increased due to the degradation and alteration of pigments at high temperatures. However, no statistically significant disparity in essential oil content was observed between the treatment groups and the control group. The quantities of essential oil components in the cumin seeds were determined to align with the ISO standard, with the primary constituents identified as follows: Terpinen-7-al γ (38.98%), Cumin aldehyde (20.75%), γ-Terpinene (18.81%), ß-Pinene (13.66%), and p-Cymene (6.2%). In summary, non-contact induction heating system shows promise as an effective technology for surface decontamination of spices. The acquired findings contribute to a deeper understanding of the impact of the induction heating process on both the microbial contamination levels and the quality attributes of cumin seeds. This scientific knowledge serves as a foundational framework for the prospective adoption and integration of this technology on a larger industrial scale.

15.
Environ Sci Technol ; 58(2): 1410-1419, 2024 Jan 16.
Artículo en Inglés | MEDLINE | ID: mdl-38158605

RESUMEN

Catalytic oxidation has been considered an effective technique for volatile organic compound degradation. Development of metal foam-based monolithic catalysts coupling electromagnetic induction heating (EMIH) with efficiency and low energy is critical yet challenging in industrial applications. Herein, a Mn18.2-NF monolithic catalyst prepared by electrodeposition exhibited superior toluene catalytic activity under EMIH conditions, and the temperature of 90% toluene conversion decreased by 89 °C compared to that in resistance furnace heating. Relevant characterizations proved that the skin effect induced by EMIH encouraged activation of gaseous oxygen, leading to superior low-temperature redox properties of Mn18.2-NF under the EMIH condition. In situ Fourier transform infrared spectroscopy results showed that skin effect-induced activation of oxidizing species further accelerated the conversion of intermediates. As a result, the Mn18.2-NF monolithic catalyst under EMIH demonstrated remarkable performance for the toluene oxidation, surpassing the conventional nonprecious metal catalyst and other reported monolithic catalysts.


Asunto(s)
Óxidos , Tolueno , Tolueno/química , Óxidos/química , Oxidación-Reducción , Temperatura , Catálisis
16.
Materials (Basel) ; 16(24)2023 Dec 08.
Artículo en Inglés | MEDLINE | ID: mdl-38138698

RESUMEN

Impurity elimination in tundishes is an essential metallurgical function in continuous casting. If inclusions in a tundish cannot be effectively removed, their presence will have a serious impact on the quality of the bloom. As a result, this research investigates the locations of inclusion particles in a six-strand induction-heating tundish in depth, combining the flow, temperature, and inclusion trajectories of molten steel under electromagnetic fields. The results show that a pinch effect occurred in the induction-heating tundish, and a rotating magnetic field formed in the channel, with a maximum value of 0.158 T. The electromagnetic force was directed toward the center of the axis, and its numerical distribution corresponds to the magnetic flux density distribution, with a maximum value of 2.11 × 105 N/m3. The inclusion particles' movement speed accelerated as the molten steel's temperature rose, and their distribution in the channel was identical to the rotating flow field distribution. When the steel's temperature rose from 1750 K to 1850 K, the removal percentage of inclusion particles in the discharge chamber rose by 9.20%, the removal rate at the outlet decreased from 8.00% to 3.00%, and the adhesion percentage of inclusion particles in the channel decreased from 48.40% to 44.40%.

17.
Materials (Basel) ; 16(21)2023 Oct 31.
Artículo en Inglés | MEDLINE | ID: mdl-37959590

RESUMEN

This paper describes the use of cold and hot composite forming technology to produce pointed curtain wall profiles. An electromagnetic-temperature coupling model was constructed using ANSYS to study the temperature and electromagnetic field distribution during the forming process. Numerical simulation was used to optimize the process parameters to obtain the optimum heating parameters with a current of 4000 A, a frequency of 35 kHz, and a duration of 2 s. The accuracy of the model was also verified through experiments. The simulation results show that the use of a conductive magnet can improve the induction heating efficiency, increasing the heating frequency and the temperature peak; however, it also increases the temperature difference. Sharp-corner curtain wall profiles were successfully produced using the optimized process parameters. The temperature of the heating zone was measured using an infrared thermal imager, and the relative errors between the maximum heating temperature obtained from the simulation and the actual measured values were 5.37% and 5.02%, respectively, indicating that the finite element model performs well in terms of prediction.

18.
Int J Hyperthermia ; 40(1): 2280448, 2023.
Artículo en Inglés | MEDLINE | ID: mdl-37987751

RESUMEN

AIM: The use of magnetic carbon nanotubes for multi-modal cancer treatment, incorporating both hyperthermia and drug delivery functions, has drawn substantial interest. Yet, the present method of regulating hyperthermia temperature involves manually adjusting the magnetic field intensity, adding to the complexity and difficulty of clinical applications. This study seeks to design novel magnetic carbon nanotubes capable of self-temperature regulation, and investigate their drug loading and release characteristics. METHODS: Using the co-precipitation method, we synthesized magnetic carbon nanotubes with a Curie temperature of 43 °C. A comprehensive investigation was conducted to analyze their morphology, crystal structure, and magnetic characteristics. To enhance their functionality, chitosan and sodium alginate modifications were introduced, enabling the loading of the antitumor drug doxorubicin hydrochloride (DOX) into these magnetic carbon nanotubes. Subsequently, the loading and release properties of DOX were investigated within the modified magnetic nanotubes. RESULTS: Under alternating magnetic field, magnetic carbon nanotubes exhibit self-regulating properties by undergoing a magnetic phase transition, maintaining temperatures around 43 °C as required for hyperthermia. On the other hand, during magnetic induction heating, the release percentage of DOX reached 23.5% within 2 h and 71.7% within 70 h at tumor pH conditions, indicating their potential for sustained drug release. CONCLUSIONS: The prepared magnetic carbon nanotubes can effectively regulate the temperature during hyperthermia treatment while ensuring controlled drug release, which presents a promising method for preparing nanomaterials that synergistically enhance magnetic hyperthermia and chemotherapy drugs.


Asunto(s)
Nanotubos de Carbono , Humanos , Liberación de Fármacos , Calefacción , Fiebre , Hipertermia , Campos Magnéticos
19.
Water Res ; 246: 120745, 2023 Nov 01.
Artículo en Inglés | MEDLINE | ID: mdl-37866245

RESUMEN

Iron shavings (IS) are low-cost industrial byproducts that show great potential in removing phosphorus (P) from contaminated water. This work investigates the effectiveness of IS for P (PO4-P) removal and emphasizes its pretreatment and longevity. A 4-d pretreatment of IS with 2.5 % NaCl resulted in a significant increase in P adsorption capacity, from approximately 1.0 to 2.5 mg/g. In column tests, the P removal efficiency remained above 60 % over 60 d, with a capacity of 4.1 mg P/g. Longevity tests involved seven adsorption-regeneration cycles, with an effective IS regeneration by 1 N NaOH and neutralization by HCl solution (pH=2), and the P adsorption capacity only slightly decreased from 2.14 to 1.75 mg P/g. To significantly improve the IS regeneration operation, we employed induction heating and compared an intermittent 10-s induction heating with an isothermal hot NaOH (85 ℃) treatment in 10-min desorption tests (95.3 % versus 56.6 % regeneration). We further found that IH completely regenerated IS in 5 min with 100 s of IH application, but 30 min were needed for hot NaOH (85 ℃) treatment. SEM/EDX, XRD, and XPS tests were conducted to track the changes in the morphology, crystallinity, and surface oxidation products of IS in the cycle tests. Notably, IS surface changed from coarse to smooth with fewer reactive sites and a higher conversion of amorphous Fe oxides to more crystalline Fe3O4, resulting in lower reactivity and fewer exposed Fe0 sites over multiple cycles. All of these mechanisms contributed to the deterioration in P removal capacity. Overall, this study provides a solid foundation for applying low-cost IS in effectively removing P from agricultural runoff.


Asunto(s)
Contaminantes Químicos del Agua , Purificación del Agua , Adsorción , Concentración de Iones de Hidrógeno , Hierro/química , Fosfatos/química , Hidróxido de Sodio , Contaminantes Químicos del Agua/química , Purificación del Agua/métodos
20.
Polymers (Basel) ; 15(18)2023 Sep 13.
Artículo en Inglés | MEDLINE | ID: mdl-37765599

RESUMEN

In aerospace applications, composite grids have been widely utilized to enhance the strength of large thin-shell components. Recently, a growing focus has been on the research of 3D printing continuous fiber-reinforced thermoplastic composites. The 3D printing method offers various advantages over traditional molding processes, including a simpler process, higher material utilization, and lower manufacturing costs. However, the use of 3D printing for manufacturing continuous fiber-reinforced composite structures presents challenges, such as a high occurrence of defects within the structure and insufficient mechanical properties. These limitations hinder its widespread application. To address these issues, this study proposes a method for treating 3D-printed composite grid structures using induction heating. Initially, the induction heating mechanism of 3D-printed composite grids was analyzed by studying the impedance at the junction, including direct contact resistance and dielectric hysteresis loss. Subsequently, the impact of induction heating treatment on internal defects was explored by observing micro morphologies. The results show that the combination of induction heating and vacuum pressure effectively reduces porosities within the 3D-printed carbon fiber composite grids. Additionally, 3D-printed composite grid-stiffened PLA structures were fabricated with induction heating, and the bending and impact tests were conducted to evaluate their mechanical properties. The results indicate that using a grid-unit size of 4 mm leads to significant increases in bending strength and modulus of the grid-stiffened structure, with improvements of 137.6% and 217.8%, respectively, compared to the neat PLA panel. This demonstrates the exceptional mechanical enhancement efficiency of the 3D-printed lightweight composite grids.

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