RESUMEN
Moisture actuators can accomplish humidity-triggered energy-conversion process, through material screening and structural design. Inspired by natural caterpillars and the hydrophilic properties of graphene oxide (GO), this work proposes a geometrical design of period-gradient structures in GO films for fabricating moisture actuators. These novel period-gradient-structured GO films exhibit excellent dynamic performance that they could deform at 1000° with a small radius in several seconds at a high relative humidity (RH ≈ 80%). The properties of fast actuating speed and high response to deformation are achieved through the structural designing of the sole GO film by a one-step formation process. A mechanics-based theoretical model combined with the finite element simulation is presented to demonstrate the actuating mechanism in geometry, moisture, and mechanics, which lays the foundation for potential applications of GO films in remote control, environmental monitoring, and man-machine interactions.
RESUMEN
The strong interaction between graphene oxides (GO) and water molecules has trigged enormous research interest in developing GO-based separation films, sensors, and actuators. However, sophisticated control over the ultrafast water transmission among the GO sheets and the consequent deformation of the entire GO film is still challenging. Inspired from the natural "quantum-tunneling-fluidics-effect," here quantum-confined-superfluidics-enabled moisture actuation of GO paper by introducing periodic gratings unilaterally is reported. The folded GO nanosheets that act as quantum-confined-superfluidics channels can significantly promote water adsorption, enabling controllable and sensitive moisture actuation. Water-adsorption-induced expansion along and against the normal direction of a GO paper is investigated both theoretically and experimentally. Featuring state-of-the-art of ultrafast response (1.24 cm-1 s-1 ), large deformation degree, and complex and predictable deformation, the smart GO papers are used for biomimetic mini-robots including a creeping centipede and a smart leaf that can catch a living ladybug. The reported method is simple and universal for 2D materials, revealing great potential for developing graphene-based smart robots.
RESUMEN
A new type of moisture-driven rotational motor is developed using a helical arrangement of graphene sheets along a graphene oxide fiber, which not only presents remarkable performance as a reversible rotary motor with a rotary speed of up to about 5200 revolutions per minute under humidity alternation, but also allows the construction of humidity switches and promising moisture-triggered electric generators.