When solid recovered fuel (SRF) production and consumption maximize environmental benefits? A life cycle assessment.

Solid recovered fuel (SRF) from non-recyclable waste obtained from source separation and mechanical treatments can replace carbon coke in cement plants, contributing to the carbon neutrality. A life cycle assessment (LCA) of the SRF production from non-recyclable and selected waste was conducted in an Italian mechanical treatment plant to estimate the potential environmental impacts per ton of SRF produced. The analysis would contribute to evaluate the benefits that can be obtained due to coke substitution in best- and worst-case scenarios. The avoided impacts achieved were assessed, together with an evaluation of the variables that can affect the environmental benefits: SRF biogenic carbon content (in percentage of paper and cardboard); transportation distances travelled from the treatment plant to the cement kiln; the renewable energy used in the mechanical facility. On average, about 35.6 kgCO2-eq are generated by the SRF transportation and production phase. These impacts are greatly compensated by coke substitution, obtaining a net value of about -1.1 tCO2-eq avoided per ton of SRF. On balance, the global warming potential due to SRF production and consumption ranges from about -542 kgCO2-eq to about -1729 kgCO2-eq. The research recommended the use of SRF to substitute coke in cement kilns also in low densely-populated areas to mitigate environmental impacts and achieve carbon neutrality at a global level.

Co-processing of solid recovered fuels from mixed municipal and commercial waste in the cement industry - A pathway to a circular economy.

With global municipal solid waste generation increasing steadily, the importance of high-quality, environmentally friendly waste valorization methods is rising, too. Most countries have set themselves ambitious recycling goals and follow a waste hierarchy in which recycling is more preferable than energy recovery. This article focuses on a waste treatment option that already is an integral part of waste management in some countries and enables the simultaneous recovery of energy and mineral constituents: the production of solid recovered fuels (SRFs) from mixed municipal and commercial waste and their use in the cement industry is often referred to as co-processing. The state of the art of SRF production is described and the first comprehensive dataset for SRF samples including major constituents, heavy metal and metalloid contents, energy- and CO2-emission-relevant parameters, ash constituents and the material-recyclable share of SRF is presented. Additionally, a comparison with fossil fuels is given. It is concluded that SRF from state-of-the-art production plants complies with strict limit values for heavy metals, has an average biogenic carbon content of 60%, and its application in the cement industry can be considered as partial recycling (14.5%) and partial energy recovery (85.5%). Leaving no residues to be dealt with, co-processing of waste in the cement industry therefore offers many benefits and can support the shift from a linear to a circular economy.

Pyrolysis of Solid Recovered Fuel Using Fixed and Fluidized Bed Reactors.

Currently, most plastic waste stems from packaging materials, with a large proportion of this waste either discarded by incineration or used to derive fuel. Accordingly, there is growing interest in the use of pyrolysis to chemically recycle non-recyclable (i.e., via mechanical means) plastic waste into petrochemical feedstock. This comparative study compared pyrolysis characteristics of two types of reactors, namely fixed and fluidized bed reactors. Kinetic analysis for pyrolysis of SRF was also performed. Based on the kinetic analysis of the pyrolytic reactions using differential and integral methods applied to the TGA results, it was seen that the activation energy was lower in the initial stage of pyrolysis. This trend can be mainly attributed to the initial decomposition of PP components, which was subsequently followed by the decomposition of PE. From the kinetic analysis, the activation energy corresponding to the rate of pyrolysis reaction conversion was obtained. In conclusion, pyrolysis carried out using the fluidized bed reactor resulted in a more active decomposition of SRF. The relatively superior performance of this reactor can be attributed to the increased mass and heat transfer effects caused by fluidizing gases, which result in greater gas yields. Regarding the characteristics of liquid products generated during pyrolysis, it was seen that the hydrogen content in the liquid products obtained from the fluidized bed reactor decreased, leading to the formation of oils with higher molecular weights and higher C/H ratios, because the pyrolysis of SRF in the fluidized bed reactor progressed more rapidly than that in the fixed bed reactor.

Atmospheric parameters play an important role in driving hydrogen sulphide concentrations in ambient air near waste management centres.

Emissions of odorous compounds are major contributors to public opposition when siting waste management facilities. Thus, it is essential to understand how to minimise the concentration of odour-causing chemicals in ambient air surrounding such facilities. Although the concentration of pollutants in the atmosphere is a function of meteorology, there is limited data on the atmospheric parameters that drive ambient air concentrations of odour-causing substances in settlements near waste management facilities. Here, we analysed how temperature, wind direction, wind speed, atmospheric pressure and humidity impact the concentrations of hydrogen sulphide (H2S) in the ambient air, a potentially toxic chemical and a chief contributor to noxious odours. The relative contribution of each variable was assessed using multivariate statistical analysis applied to an extensive data set of over 7,000 data points collected during 2021. Our results show that all tested atmospheric parameters significantly affected H2S concentrations in ambient air. Wind direction had the greatest impact on H2S concentrations, followed by temperature, humidity, atmospheric pressure and wind speed. Specifically, the concentration of H2S was positively correlated with humidity and atmospheric pressure and had a U-shaped correlation with temperature. Atmospheric variables were able to explain 15% of variation in H2S concentrations (R2 = 15%), indicating the presence of other factors affecting H2S ambient air concentrations. Our study shows that proper consideration of atmospheric parameters, especially wind direction and temperatures, is of uttermost importance when siting waste management facilities. The conclusions are broadly applicable to odorous compounds near waste management facilities, so adverse effects to human health and the environment can be minimised.

Upgrading of solid recovered fuel (SRF) by dechlorination and catalytic pyrolysis over nanocrystalline ZSM-5 zeolite.

Globally increasing concern related to municipal solid waste generation is encouraging research efforts on developing alternative routes to valorize mixed refused wastes. In this way, catalytic pyrolysis is emerging as an interesting and efficient technology due to its great flexibility in terms of feedstock. In the current work, upgrading of a Solid Recovered Fuel (SRF) has been investigated by catalytic pyrolysis over nanocrystalline ZSM-5 zeolite (n-ZSM-5), paying special attention to dechlorination effects due to the high Cl content of the raw waste. Thus, pretreatment of the SRF by water washing and mild thermal processing allows for a significant reduction of the Cl concentration. Regarding the catalytic pyrolysis step, the best conditions correspond with a temperature of 400 °C in the catalyst bed and 0.50 catalyst/SRF mass ratio, which lead to ca. 30 wt% oil yield (rich in aromatic hydrocarbons) together with about 40 wt% gas yield (rich in C3-C4 olefins). Accordingly, these products could find use as raw chemicals or for the production of advanced fuels. In addition, zeolite reutilization has been tested for several cycles, denoting a progressive modification of the products distribution because of coke deposition. However, an almost total recovery of the n-ZSM-5 zeolite catalytic performance is achieved after regeneration by air calcination, affording the production of an oil fraction with a Cl content as low as 40 ppm.

Evaluation of Fly Ash from Co-Combustion of Paper Mill Wastes and Coal as Supplementary Cementitious Materials.

The applications of waste-derived fuel from paper mills in industrial boilers benefit the reduction of carbon emissions. However, the co-combustion of waste-derived fuel and coal causes significant changes in the characteristics of the ash and brings about the need to find possible means of the utilization of the ash produced. In this work fly, ash samples were collected from circulating fluidized bed (CFB) boilers co-combusting paper mill wastes with coal and analyzed in detail. The chemical, physical, and thermal characteristics of two different co-combustion fly ashes (CCFA) were investigated using X-ray fluorescence (XRF), X-ray diffraction (XRD), thermogravimetry (TG), and scanning electron microscope (SEM). The chemical composition of CCFA is largely affected by the fuel source type. Thermal analyses of CCFA show that the type of desulfurization system used by the boiler influences the form of sulfate present in the fly ash. The presence of calcium sulfite hemihydrate can cause a high loss in the ignition of CCFA. By comparing the physical requirements specified in the ASTM standard for coal fly ash to be used in concrete, the CCFA produced from paper mill wastes was found to show good potential as supplementary cementitious materials.

Biodrying with the hot-air aeration system for kitchen food waste.

Biodrying is a promising method that produces bio-stabilized output with minimum pretreatment requirements. In this study, a hot-air supply system was added to the traditional biodrying process for kitchen waste, which showed significant reduction in moisture content in 5 days (maximum reduction of 37.45%). A series of experiments was conducted to optimize the hot-air biodrying system utilizing different aeration rates, temperatures, and mixing ratios of feedstock to bulking agents. The results showed that a 65 °C aeration temperature led to the highest water removal rate and low volatile solids consumption rate, with the biodrying index reaching 4.9 g water per gram of volatile solids. On the other hand, evaluation of the overall biodrying efficiency based on the weight loss and bio-stabilization showed that intermittent aeration temperature at 55 °C performed best, offering suitable conditions for water evaporation and bio-degradation. In combination with a flow rate of 0.8 L/kg*min and 1:1 mixing ratio, these conditions resulted in the maximum volatile solids consumption of 26.26% in 5 days. The volatile solids consumption and 34.47% water removal rate of the trial had contributed to a total of 64.13% weight loss. The weight loss was even higher than that of a conventional biodrying system which was conducted for more than 14 days.

Particle-specific characterisation of non-hazardous, coarse-shredded mixed waste for real-time quality assurance.

The development of a pre-treatment plant for non-hazardous, solid mixed waste into a smart waste factory for future involves the introduction of real-time characterisation of waste streams by applying sensor technology. First, research has been conducted on the application of near-infrared spectroscopy for quality assurance of solid recovered fuels (SRF) produced by the pre-treatment plant. The method is based on statistical analyses, thereby requiring a comprehensive database of detailed waste data. To ensure high-precision measurements, data must be gathered at the level of individual particles and must cover a broad spectrum of different particle types. In a previous study, the fine-shredded SRF (<30 mm) was investigated. The scope of this study includes coarse-shredded SRF (30-80 mm) and mixed commercial waste (pre-shredded to a maximum of 500 mm), which is used as input for the waste pre-treatment plant. For a total of 2346 particles, the projected particle area, particle mass, and particle height were measured with average values of 11.5 cm2, 1.2 g and 10.4 mm, respectively, for the coarse-shredded SRF. Data results regarding pre-shredded waste input were 115 cm2 area, 16.7 g mass and 33.9 mm height. Combined with previous results, the dataset covers a range of particle areas from 15.7 mm2 to 16.7 dm2 and a range of particle mass from 1.6 mg to 882.5 g. Additionally, selected fuel parameters (heating value, chlorine content, and ash content) were measured using laboratory analysis of composite samples from coarse-shredded SRF and mixed commercial waste. The physico-chemical results of the present study confirmed previous results; however, the variance of values increased, and more outliers were identified. Despite the provision of particle data, the major goal of this study was to determine the correlation between the projected area and particle mass, which was calculated using the Spearman's correlation coefficient (SCC). The calculations resulted in an SCC of 0.58 for coarse-shredded SRF and an SCC of 0.22 for pre-shredded waste input. Although the SCC of SRF was sufficient for establishing a quality assurance system, the SCC of input waste must be substantially improved.

Combustion of a Solid Recovered Fuel (SRF) Produced from the Polymeric Fraction of Automotive Shredder Residue (ASR).

The use of alternative fuels derived from residues in energy-intensive industries that rely on fossil fuels can cause considerable energy cost savings, but also significant environmental benefits by conserving non-renewable resources and reducing waste disposal. However, the switching from conventional to alternative fuels is challenging for industries, which require a sound understanding of the properties and combustion characteristics of the alternative fuel, in order to adequately adapt their industrial processes and equipment for its utilization. In this work, a solid recovered fuel (SRF) obtained from the polymeric fraction of an automotive shredder residue is tested for use as an alternative fuel for scrap preheating in an aluminium refinery. The material and chemical composition of the SRF has been extensively characterized using proximate and ultimate analyses, calorific values and thermal degradation studies. Considering the calorific value and the chlorine and mercury contents measured, the SRF can be designated as class code NCV 1; Cl 2; Hg 2 (EN ISO 21640:2021). The combustion of the SRF was studied in a laboratory-scale pilot plant, where the effects of temperature, flow, and an oxidizer were determined. The ash remaining after combustion, the collected liquid, and the generated gas phase were analysed in each test. It was observed that increasing the residence time of the gas at a high temperature allowed for a better combustion of the SRF. The oxidizer type was important for increasing the total combustion of the vapour compounds generated during the oxidation of the SRF and for avoiding uncontrolled combustion.

Real-time monitoring of volume flow, mass flow and shredder power consumption in mixed solid waste processing.

Real-time material flow monitoring is not yet implemented in mixed solid waste processing, but it is important for an efficient quality assured production and the development of the smart waste factory. The present paper shows results of practical investigation of the Real-Time Material Flow Monitoring in a large-scale Solid Recovered Fuel (SRF) production plant and a semi large-scale processing line (Technical line 4.0) using mixed solid waste. The investigations aimed to research the fundamentals for generating mass flow data from volume flow data and volume and mass flow data from shredder power consumption. It could be shown that a mass determination from volume flow data with the help of density determinations can be practically realized in a good approximation (deviation < 1%) to the gravimetrically determined mass in an SRF production plant. With R2 = 0.47, the power consumption of a shredder in the SRF plant shows a low to medium correlation to the corresponding volume flow. In the 31 tests with the Technical Line 4.0, both, the mass flow and the volume flow could be measured in real-time. Combining these data results in the temporal density curve and shows strong fluctuations for shredded commercial waste. Comparing the mean bulk densities for each test with those from the density determinations of taken samples shows a robust correlation (R2 = 0.82). Analyzes of the material composition of the shredded mixed solid waste show strong correlations to bulk density for the proportions of the fractions rest (positive correlation) and plastics (negative correlation).

Impact of utilizing solid recovered fuel on the global warming potential of cement production and waste management system: A life cycle assessment approach.

Cement production is responsible for a significant share of global greenhouse gas (GHG) emissions. A potential option to reduce the cement production emissions is to use alternative fuels which can have also an impact on emissions from the waste management sector. This work investigates the change in global warming potential (GWP) of ordinary Portland cement (OPC) production and affected waste management systems when conventional fuels are partially replaced by solid recovered fuel (SRF) made from commercial and industrial waste (C&IW). A life cycle assessment (LCA) was conducted with a functional unit of 1 metric tonne of OPC production and treatment of 194 kg of C&IW. Data from an existing cement plant have been used, where the share of SRF from total fuel energy demand increased from 0% to 53% between 2007 and 2016. Four scenarios were established with varying waste treatment methods and SRF share in the thermal energy mix of cement production. It was found that GHG emissions decreased by 20% from 1036 kg carbon dioxide (CO2), eq. (functional unit)-1 in Scenario 1 to 832 kg CO2, eq. (functional unit)-1 in Scenario 3. Furthermore, it is possible to reach a reduction of 30% to 725 kg CO2, eq. (functional unit)-1 in Scenario by increasing the share of SRF to 80%. In conclusion, significant GHG emissions reduction can be achieved by utilizing SRF in cement production. Especially in the middle-income and low-income countries where waste is dumped to the open landfills, emissions could be reduced without huge investments to waste incineration plants.

Establishing a sub-sampling plan for waste-derived solid recovered fuels (SRF): Effects of shredding on representative sample preparation based on theory of sampling (ToS).

The uncertainty arising from laboratory sampling (sub-sampling) can compromise the accuracy of analytical results in highly inherent heterogeneous materials, such as solid waste. Here, we aim at advancing our fundamental understanding on the possibility for relatively unbiased, yet affordable and practicable sub-sampling, benefiting from state of the art equipment, theoretical calculations by the theory of sampling (ToS) and implementation of best sub-sampling practices. Solid recovered fuel (SRF) was selected as a case of a solid waste sample with intermediate heterogeneity and chlorine (Cl) as an analyte with intermediate variability amongst waste properties. ToS nomographs were constructed for different sample preparation scenarios presenting the trend of uncertainty during sub-sampling. Nomographs showed that primary shredding (final d90 ≤ 0.4 cm) can reduce the uncertainty 11 times compared to an unshredded final sub-sample (d ≈ 3 cm), whereas cryogenic shredding in the final sub-sample can decrease the uncertainty more than three times compared to primary shredding (final d90 ≤ 0.015 cm). Practices that can introduce bias during sub-sampling, such as mass loss, moisture loss and insufficient Cl recovery were negligible. Experimental results indicated a substantial possibility to obtain a representative final sub-sample (uncertainty ≤ 15%) with the established sub-sampling plan (57-93%, with 95% confidence), although this possibility can be considerably improved by drawing two final sub-samples instead (91-98%, with 95% confidence). The applicability of ToS formula in waste-derived materials has to be investigated: theoretical ToS calculations assume a poorer performance of the sub-sampling plan than evidenced by the experimental results.

Steam gasification of lignite and solid recovered fuel (SRF) in a bench scale fluidized bed gasifier.

The reduction of CO2 emissions and solid waste disposal are critical issues with high importance for the environmental protection. Gasification is a promising process for sustainable energy production, because it can produce a versatile gaseous fuel starting from a wide range of organic feedstocks, and with reduced greenhouse gas emissions compared to combustion. Lignite is an abundant carbonaceous resource in Europe and in this work, gasification tests were carried out with lignite and a lignite and Solid Recovered Fuel (SRF) mixture, to evaluate the quality of gas produced from co-gasification of waste materials, in view of the final uses of the gas. Experimental gasification tests were carried out in a bench scale fluidized bed gasifier at different operating temperatures; the results were evaluated in terms of gas composition, tar content and conversion rates. In addition, characterization analyses were carried out on materials before and after the tests, and pressure fluctuation signals were analysed in order to evaluate the fluidization quality of the bed inventory.

Characterisation and composition identification of waste-derived fuels obtained from municipal solid waste using thermogravimetry: A review.

Thermogravimetric analysis (TGA) is the most widespread thermal analytical technique applied to waste materials. By way of critical review, we establish a theoretical framework for the use of TGA under non-isothermal conditions for compositional analysis of waste-derived fuels from municipal solid waste (MSW) (solid recovered fuel (SRF), or refuse-derived fuel (RDF)). Thermal behaviour of SRF/RDF is described as a complex mixture of several components at multiple levels (including an assembly of prevalent waste items, materials, and chemical compounds); and, operating conditions applied to TGA experiments of SRF/RDF are summarised. SRF/RDF mainly contains cellulose, hemicellulose, lignin, polyethylene, polypropylene, and polyethylene terephthalate. Polyvinyl chloride is also used in simulated samples, for its high chlorine content. We discuss the main limitations for TGA-based compositional analysis of SRF/RDF, due to inherently heterogeneous composition of MSW at multiple levels, overlapping degradation areas, and potential interaction effects among waste components and cross-contamination. Optimal generic TGA settings are highlighted (inert atmosphere and low heating rate (⩽10°C), sufficient temperature range for material degradation (⩾750°C), and representative amount of test portion). There is high potential to develop TGA-based composition identification and wider quality assurance and control methods using advanced thermo-analytical techniques (e.g. TGA with evolved gas analysis), coupled with statistical data analytics.

Methods for identifying the material-recyclable share of SRF during co-processing in the cement industry.

Solid Recovered Fuels (SRF) include non-combustible mineral components (e.g. CaCO3, SiO2, Al2O3) that are required as raw materials for producing clinker and are completely incorporated into the clinker during the thermal recovery of SRF. This paper discusses simple and practicable ways of finding the relative amount of SRF that may be utilised as raw material (given as the recycling index). For this purpose, the entire mineral content of SRF was determined as the ash content and its main components were identified using different analytical methods.•A fusion melt of the previously incinerated sample with subsequent measuring using ICP-OES and XRF as well as a total digestion of the incinerated and non-incinerated sample with subsequent measuring using ICP-OES/ICP-MS were applied.•The results showed a good agreement of all four analytical methods for the elementary oxides Al2O3, CaO, Fe2O3, SiO2, TiO2, P2O5 and MgO (relative deviation from 6.6 to 38.9%) and slightly higher deviations for K2O, Na2O and SO3 (14.2-96.0%).•It was also shown that different incineration temperatures (550 °C, 815 °C and 950 °C) have no effect on the result of the recycling index unless it is assumed that the recycling index equals the ash content.

Statistical quantification of sub-sampling representativeness and uncertainty for waste-derived solid recovered fuel (SRF): Comparison with theory of sampling (ToS).

The level of uncertainty during quantification of hazardous elements/properties of waste-derived products is affected by sub-sampling. Understanding sources of variability in sub-sampling can lead to more accurate risk quantification and effective compliance statistics. Here, we investigate a sub-sampling scheme for the characterisation of solid recovered fuel (SRF) - an example of an inherently heterogeneous mixture containing hazardous properties. We used statistically designed experiments (DoE) (nested balanced ANOVA) to quantify uncertainty arising from material properties, sub-sampling plan and analysis. This was compared with the theoretically estimated uncertainty via theory of sampling (ToS). The sub-sampling scheme derives representative analytical results for relatively uniformly dispersed properties (moisture, ash, and calorific content: RSD ≤ 6.1 %). Much higher uncertainty was recorded for the less uniformly dispersed chlorine (Cl) (RSD: 18.2 %), but not considerably affecting SRF classification. The ToS formula overestimates the uncertainty from sub-sampling stages without shredding, possibly due to considering uncertainty being proportional to the cube of particle size (FE ∝ d3), which may not always apply e.g. for flat waste fragments. The relative contribution of sub-sampling stages to the overall uncertainty differs by property, contrary to what ToS stipulates. Therefore, the ToS approach needs adaptation for quantitative application in sub-sampling of waste-derived materials.

Assessment of quality test methods for solid recovered fuel in South Korea.

Management of solid recovered fuel (SRF) in South Korea is unique from most other countries in that it is based on a single standard. All SRFs are distributed at the same price irrespective of their performance, resulting in utilization problems and a low degree of acceptance among consumers. Moreover, the difficulty of temperature maintenance during transportation, excessive ash content, and the use of inappropriate microwave acid digestion methods pose challenges to SRF reliability. To address these issues, we compared the relevant management statuses in South Korea with those of the international community and reviewed the effects of the transportation temperature, ash content, and microwave acid digestion technique. The moisture, ash, sulfur, and chlorine contents as well as the lower heating values (LHVs) of all the samples from South Korea were found to be below the standard [international] thresholds, and they were barely influenced by the transportation temperature. In addition, 5 g samples were found to be more appropriate for ash content analysis than the 20 g samples used in South Korea, with the former producing smaller standard deviations. The optimal microwave acid digestion conditions were also determined to be a reaction time with nitric acid of >10 min, temperature of 180 °C, and microwave power of 600 W. The results of this study highlight the need for revising the SRF test methods used in South Korea, to boost the market and enhance quality reliability.

Origins and carriers of Sb, As, Cd, Cl, Cr, Co, Pb, Hg, and Ni in mixed solid waste - A literature-based evaluation.

Antimony, arsenic, cadmium, chlorine, chromium, cobalt, lead, mercury, nickel and their compounds are commonly used in the industrial production of various goods. At the end of the product life cycle, these elements enter the waste system as constituents of the products. Mixed municipal and commercial wastes are landfilled, biologically treated, incinerated, and/or processed in mechanical treatment plants to yield solid recovered fuel (SRF). In all these cases, inorganic contaminants that are present in the input waste material play a significant role. In mechanical waste treatment, materials containing high concentrations of these elements (contaminant carriers) can be selectively removed (e.g. by infrared sorters) to improve the output quality, but prior knowledge about the contaminant carriers is required. This paper reviews several waste-related publications in order to identify carriers of Sb, As, Cd, Cl, Cr, Co, Pb, Hg, and Ni in mixed municipal and commercial waste. Identified contaminant carriers are listed alongside ranges for expected concentrations. Furthermore, the data are combined with information on industrial applications and contaminant concentrations in products in order to discuss the reasons for the presence of the respective elements in the carriers. Generally, besides inerts or metals, identified contaminant carriers often include plastics, composite materials, leather products, textiles, rubber, electronic waste, and batteries. Moreover, it is evaluated how individual contaminant carriers are reflected by chemical waste analyses. While the findings of the paper can be applied to different waste treatment options, the discussion focuses on SRF, which is the main output of mechanical treatment plants.

Interactive effect of the sorted components of solid recovered fuel manufactured from municipal solid waste by thermogravimetric and kinetic analysis.

Solid recovered fuel (SRF) has the characteristics of high calorific value and low chlorine and mercury content. The thermal decomposition of SRF collected from a municipal solid waste (MSW) incineration power plant in Hangzhou was investigated in this study. The study exhibits far-reaching significance for the design and commercial operation of SRF pyrolysis facilities and circulating fluidized bed (CFB) power plants. The pyrolysis behavior of SRF and its sorted components was evaluated by thermogravimetric analysis (TG). Five heating rates of 10, 15, 20, 25 and 30 °C·min-1 were conducted to analyze the effect of heating rate. The interactive effect of the sorted components was discussed by comparing the experimental and theoretical curves. Furthermore, the kinetic parameters were determined by using the Coats-Redfern (CR), Kissinger-Akahira-Sunose (KAS) and Flynn-Wall-Ozawa (FWO) methods. The activation energies of SRF and its sorted components in the pyrolysis process were obtained. The main reaction stages of the SRF and its sorted components were described by different mechanism functions. However, it was found that the KAS and FWO methods were not applicable for SRF according to the comparison results. The results provide useful information for the design and commercial operation of SRF pyrolysis facilities and CFB power plants.

Comparative analysis of wood and solid recovered fuels gasification in a downdraft fixed bed reactor.

This study aims to qualify air gasification performances of Solid Recovered Fuels (SRF) in a downdraft fixed bed gasifier. Five fuels have been studied: Wood, SRF wood, and three different mixtures of SRF wood and 20 %w of either SRF tire (mix A), SRF plastics (mix B) or SRF sewage sludge (mix C). The tests were carried out in a pilot scale reactor in a batch-fed mode using a fuel mass ranging from 5 to 8 kg, and an air inlet flow of 170-180 L/min, which led to an Equivalence Ratio (ER) ranging between 0.20 and 0.29. Considering Poplar wood as a reference, we observed a similar syngas quality for SRF wood, but SRF mixes led to a slight decrease of H2 and CO contents along with an increase of CO2, CH4, C2H4 and C2H6 contents. However syngas Low Heating Value (LHV) remained close and ranged between 4.9 and 5.4 MJ/m3 which led to a Cold Gas Efficiency (CGE) ranging from 38 to 52%. Wood and SRF wood had a similar condensate content (159-202 g/m3), but adding 20 %w of non-woody fuel led to an increased condensate content up to 369 g/m3 for mix A and 411 g/m3 for mix C. Tar analyses confirmed the similarity of Wood, SRF wood and mix C in air gasification, but highlighted large increases in aromatics and Polycyclic Aromatic Hydrocarbon (PAH) contents when adding 20 %w of tire. This study confirms the ability of downdraft gasifier to handle non-woody fuels, with an upper limit of 20%w share in a wood-based fuel.