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1.
PLoS One ; 19(5): e0303101, 2024.
Artículo en Inglés | MEDLINE | ID: mdl-38739642

RESUMEN

This research study aims to understand the application of Artificial Neural Networks (ANNs) to forecast the Self-Compacting Recycled Coarse Aggregate Concrete (SCRCAC) compressive strength. From different literature, 602 available data sets from SCRCAC mix designs are collected, and the data are rearranged, reconstructed, trained and tested for the ANN model development. The models were established using seven input variables: the mass of cementitious content, water, natural coarse aggregate content, natural fine aggregate content, recycled coarse aggregate content, chemical admixture and mineral admixture used in the SCRCAC mix designs. Two normalization techniques are used for data normalization to visualize the data distribution. For each normalization technique, three transfer functions are used for modelling. In total, six different types of models were run in MATLAB and used to estimate the 28th day SCRCAC compressive strength. Normalization technique 2 performs better than 1 and TANSING is the best transfer function. The best k-fold cross-validation fold is k = 7. The coefficient of determination for predicted and actual compressive strength is 0.78 for training and 0.86 for testing. The impact of the number of neurons and layers on the model was performed. Inputs from standards are used to forecast the 28th day compressive strength. Apart from ANN, Machine Learning (ML) techniques like random forest, extra trees, extreme boosting and light gradient boosting techniques are adopted to predict the 28th day compressive strength of SCRCAC. Compared to ML, ANN prediction shows better results in terms of sensitive analysis. The study also extended to determine 28th day compressive strength from experimental work and compared it with 28th day compressive strength from ANN best model. Standard and ANN mix designs have similar fresh and hardened properties. The average compressive strength from ANN model and experimental results are 39.067 and 38.36 MPa, respectively with correlation coefficient is 1. It appears that ANN can validly predict the compressive strength of concrete.


Asunto(s)
Fuerza Compresiva , Materiales de Construcción , Aprendizaje Automático , Redes Neurales de la Computación , Materiales de Construcción/análisis , Reciclaje
2.
PLoS One ; 19(5): e0303327, 2024.
Artículo en Inglés | MEDLINE | ID: mdl-38739645

RESUMEN

This study applied the pull-out test to examine the influence of freeze-thaw cycles and hybrid fiber incorporation on the bond performance between BFRP bars and hybrid fiber-reinforced concrete. The bond-slip curves were fitted by the existing bond-slip constitutive model, and then the bond strength was predicted by a BP neural network. The results indicated that the failure mode changed from pull-out to splitting for the BFRP bar ordinary concrete specimens when the freeze-thaw cycles exceeded 50, while only pull-out failure occurred for all BFRP bar hybrid fiber-reinforced concrete specimens. An increasing trend was shown on the peak slip, but a decreasing trend was shown on the bond stiffness and bond strength when freeze-thaw cycles increased. The bond strength could be increased significantly by the incorporation of basalt fiber (BF) and cellulose fiber (CF) under the same freezing and thawing conditions as compared to concrete specimens without fibers. The Malvar model and the Continuous Curve model performed best in fitting the ascending and descending sections of the bond-slip curves, respectively. The BP neural network also accurately predicted the bond strength, with relative errors of predicted bond strengths ranging from 3.75% to 13.7%, and 86% of them being less than 10%.


Asunto(s)
Materiales de Construcción , Congelación , Materiales de Construcción/análisis , Ensayo de Materiales , Redes Neurales de la Computación , Estrés Mecánico
3.
PLoS One ; 19(5): e0303645, 2024.
Artículo en Inglés | MEDLINE | ID: mdl-38771843

RESUMEN

The corrosion resistance of FRP-reinforced ordinary concrete members under the combined action of harsh environments (i.e., alkaline or acidic solutions, salt solutions) and freeze-thaw cycles is still unclear. To study the mechanical and apparent deterioration of carbon/basalt/glass/aramid fiber cloth reinforced concrete under chemical and freeze-thaw coupling. Plain concrete blocks and FRP-bonded concrete blocks were fabricated. The tensile properties of the FRP sheet and epoxy resin sheet before and after chemical freezing, the compressive strength of the FRP reinforced test block, and the bending capacity of the prismatic test block pasted with FRP on the prefabricated crack side were tested. The deterioration mechanism of the test block was analyzed through the change of surface photos. Based on the experimental data, the Lam-Teng constitutive model of concrete reinforced by alkali-freeze coupling FRP is modified. The results indicate that, in terms of apparent properties, with the increase in the duration of chemical freeze-thaw erosion, the surface of epoxy resin sheets exhibits an increase in pores, along with the emergence of small cracks and wrinkles. The texture of FRP sheets becomes blurred, and cracks and wrinkles appear on the surface. In terms of failure modes, as the number of chemical coupling erosion cycles increases, the location of failure in epoxy resin sheets becomes uncertain, and the failure plane tilts towards the direction of the applied load. The failure mode of FRP sheets remains unchanged. However, the bonding strength between FRP sheets and concrete decreases, resulting in a weakened reinforcement effect. In terms of mechanical properties, FRP sheets undergo the most severe degradation in the coupled environment of acid freeze-thaw cycles. Among them, GFRP experiences the largest degradation in tensile strength, reaching up to 30.17%. In terms of tensile performance, the sheets rank from highest to lowest as follows: CFRP, BFRP, AFRP, and GFRP.As the duration of chemical freeze-coupled erosion increases, the loss rate of compressive strength for specimens bonded with CFRP is the smallest (9.62% in salt freeze-thaw environment), while the loss rate of bearing capacity is higher for specimens reinforced with GFRP (33.8% in acid freeze-thaw environment). In contrast, the loss rate of bearing capacity is lower for specimens reinforced with CFRP (13.6% in salt freeze-thaw environment), but still higher for specimens reinforced with GFRP (25.8% in acid freeze-thaw environment).


Asunto(s)
Materiales de Construcción , Congelación , Ensayo de Materiales , Resistencia a la Tracción , Materiales de Construcción/análisis , Fuerza Compresiva
4.
PLoS One ; 19(5): e0300849, 2024.
Artículo en Inglés | MEDLINE | ID: mdl-38753707

RESUMEN

The improvement of sandy soils with poor seismic properties to modify their dynamic characteristics is of great importance in seismic design for engineering sites. In this study, a series of dynamic tests on sandy soils sandy soils with poor seismic conditions were conducted using the GCTS resonant column system to investigate the improvements effects of different cement contents on dynamic characteristic parameters. The research findings are as follows: The cement content has certain influences on the dynamic shear modulus, dynamic shear modulus ratio, the maximum dynamic shear modulus, and the damping ratio of sandy soils with poor seismic properties. Among them, the influence on dynamic shear modulus is limited, while the damping ratio is significantly affected. The addition of cement to seismic-poor sandy soils significantly enhances their dynamic characteristics. The most noticeable improvement is observed when the cement content is 8%. Through curve fitting analysis, a relationship equation is established between the maximum dynamic shear modulus and the cement content, and the relevant parameters are provided. A comparative test between the improved soils and the remolded soils reveals that the addition of cement significantly improves the seismic performance of the poor soils. The recommended values for the range of variation of the dynamic shear modulus ratio and damping ratio are provided, considering the effect of improvement. These research findings provide reference guidelines for seismic design and engineering sites.


Asunto(s)
Materiales de Construcción , Terremotos , Suelo , Suelo/química , Materiales de Construcción/análisis , Arena/química , Resistencia al Corte
5.
Waste Manag ; 182: 207-214, 2024 Jun 15.
Artículo en Inglés | MEDLINE | ID: mdl-38670004

RESUMEN

The objective of this paper is to evaluate the feasibility of co-processing wind turbine blade (WTB) material in cement manufacturing to provide an end-of-life means to divert the solid waste of decommissioned WTBs from landfills. Many WTBs consist primarily of glass fiber reinforced thermoset polymers that are difficult to recover or recycle. Portland cement is produced world-wide in large quantities, requiring immense quantities of raw materials (mostly calcium oxide and silicon oxide) and kiln temperatures approaching 1,450 °C. This work contributes analyses of WTB material composition, and predicts the energy provided through the combustible components of the WTBs and raw material contributions provided by incorporating the incombustible components of the WTBs to produce cement. Approximately 40 to 50 % of the WTB material will contribute as fuel to cement production, and approximately 50 to 60 % of the WTB material is expected to be incombustible. One tonne of WTB material can displace approximately 0.4 to 0.5 tonne of coal, while also contributing approximately 0.1 tonne of calcium oxide and 0.3 tonne of silicon oxide as raw material to the cement production process. The glass fiber WTB tested had an average boron content of 4.5 % in the ash. The effects of this high boron content on the cement and its production process should be evaluated. Co-processing WTBs in cement plants will slightly reduce combustion-related CO2 emissions due to avoided calcination. It seems feasible to co-process glass-fiber reinforced WTBs in cement production as WTBs provide suitable raw materials and compatible fuel for this process.


Asunto(s)
Materiales de Construcción , Materiales de Construcción/análisis , Reciclaje/métodos , Viento , Compuestos de Calcio/química , Administración de Residuos/métodos , Residuos Sólidos/análisis , Vidrio , Óxidos
6.
Waste Manag ; 182: 225-236, 2024 Jun 15.
Artículo en Inglés | MEDLINE | ID: mdl-38677140

RESUMEN

This article explores the impact of thermally treated asbestos-cement waste (ACWT) on metakaolin-based geopolymers, using liquid sodium silicate (LSS) and liquid potassium silicate (LKS) as alkali activators. Through statistical mixture design, various formulations were tested for rheological parameters, mineralogical composition, efflorescence mass, electrical conductivity, compressive strength, and CO2 emissions. Formulations with sodium silicate exhibited higher yield stress compared to those with potassium silicate, while flash setting occurred in LKS-activated mixtures with high ACWT content. Alkali activator content significantly affected mechanical strength and leachate electrical conductivity. CO2 emissions were higher for LKS-activated formulations but lower for those with more ACWT. Finally, by incorporating ACWT, it was possible to optimize the formulations, resulting in high compressive strength, reduced free ions, and reduced negative environmental impact.


Asunto(s)
Amianto , Dióxido de Carbono , Materiales de Construcción , Silicatos , Dióxido de Carbono/análisis , Silicatos/química , Materiales de Construcción/análisis , Amianto/análisis , Fuerza Compresiva , Residuos Industriales/análisis , Conductividad Eléctrica , Calor
7.
Artículo en Inglés | MEDLINE | ID: mdl-38541314

RESUMEN

This article reports the results of an investigation into the activity concentration of natural radionuclides in raw building materials for underground parking lots, together with the assessment of the radiation hazard for the public related to exposure to ionizing radiations. To this purpose, high-purity germanium (HPGe) γ-ray spectrometry was employed in order to quantify the average specific activity of 226Ra, 232Th, and 40K natural radioisotopes. With the aim to assess any possible radiological health risk for the population, the absorbed γ-dose rate (D), the annual effective dose equivalent outdoor (AEDEout) and indoor (AEDEin), the activity concentration index (I), and the alpha index (Iα) were also estimated, resulting in values that were lower than the maximum recommended ones for humans. Finally, the extent of the correlations existing between the observed radioactivity and radiological parameters and of these parameters with the analyzed samples was quantified through statistical analyses, including Pearson's correlation, a principal component analysis (PCA), and a hierarchical cluster analysis (HCA). As a result, three clusters of the investigated samples were recognized based on their chemical composition and mineralogical nature. Noteworthily, this paper covers a certain gap in science since its topic does not appear in literature in this form. Thus, the authors underline the importance of this work to global knowledge in the environmental research and public health fields.


Asunto(s)
Monitoreo de Radiación , Radiactividad , Radio (Elemento) , Contaminantes Radiactivos del Suelo , Humanos , Monitoreo de Radiación/métodos , Radioisótopos/análisis , Salud Radiológica , Espectrometría gamma , Materiales de Construcción/análisis , Torio/análisis , Radioisótopos de Potasio/análisis , Radio (Elemento)/análisis , Contaminantes Radiactivos del Suelo/análisis
8.
Appl Radiat Isot ; 207: 111266, 2024 May.
Artículo en Inglés | MEDLINE | ID: mdl-38461629

RESUMEN

Brazil is the fourth largest cement consumer in the world and the largest producer in Latin America, around 1.3% of global production. The main inputs in the manufacture of cement are limestone and clay. Few studies have been carried out in the country on the risk of these materials used in civil construction. Therefore, the objective of this present work is to evaluate the radiological danger that they can present to society. Gamma spectrometry analysis on 16 samples of different brands of cement used as construction material in Rio de Janeiro (Brazil) was performed in this study, using an HPGe detector and the Genie 2000 data acquisition software. Samples were set to count for an accumulation time of 14,400 s (4 h) and all measurements were corrected to eliminate background and backscattering. Activity concentrations are determined for 226Ra was from (41.2 ± 1.6 to 174.9 ± 3.9) Bq kg-1, 232Th was from (15.7 ± 0.5 to 43.1 ± 0.7) Bq kg-1 and 40K was from (82.6 ± 7.2 to 254 ± 17) Bq kg-1. To assess radiological health risks: mean values of Radium Activity Equivalent 150.0 ± 3.4 Bq kg-1, Annual Gonadal Dose Equivalent 468 ± 11 µSv year-1 and Lifetime Excess Cancer Risk (ELCR) 2.42 ± 0.06 were calculated. Total Absorbed Dose Rates ranged from 72.2 ± 1.7 to 225.1 ± 5.2 nGy h-1. The damage to collective health was also estimated from the annual effective dose rates with an estimated total cost of damage to health of US$ 130 million. Values are generally within global limits reported by UNSCEAR.


Asunto(s)
Monitoreo de Radiación , Radiactividad , Radio (Elemento) , Contaminantes Radiactivos del Suelo , Radioisótopos de Potasio/análisis , Torio/análisis , Monitoreo de Radiación/métodos , Brasil , Materiales de Construcción/análisis , Radio (Elemento)/análisis , Contaminantes Radiactivos del Suelo/análisis , Espectrometría gamma
9.
Ann Work Expo Health ; 68(4): 437-441, 2024 Apr 22.
Artículo en Inglés | MEDLINE | ID: mdl-38412287

RESUMEN

Personal air monitoring using a TSI SidePak AM520 personal aerosol monitor was performed on a northern Colorado construction site during five tasks from the OSHA Table 1: Specified Exposure Control Methods When Working With Materials Containing Crystalline Silica to estimate silica dust concentrations in real time. Photometric measurements were modified using a gravimetric correction factor and a % respirable crystalline silica adjustment. Each task was sampled once; sample time ranged from 14 min to 40 min, with a mean sample time of 27 min. The mean silica dust concentration estimates (µg/m3) (standard deviation [SD]) for the five tasks computed from the TSI SidePak AM520 respirable dust measurements were core drilling 12 µg/m3 [2.46], grinding 918 µg/m3 [1134.08], cutting with a walk-behind saw 36 µg/m3 [79.67], jackhammering 27 µg/m3 [23.24], and dowel drilling 66 µg/m3 [77.65]. Silica exposure estimates from real-time monitoring can be used to identify exposures that may be related to inadequate controls or worker behaviors that contribute to peak exposures. Respirable crystalline silica exposure estimates presented here are likely not generalizable to other construction sites or tasks.


Asunto(s)
Contaminantes Ocupacionales del Aire , Polvo , Monitoreo del Ambiente , Exposición por Inhalación , Exposición Profesional , Dióxido de Silicio , Exposición Profesional/análisis , Dióxido de Silicio/análisis , Contaminantes Ocupacionales del Aire/análisis , Exposición por Inhalación/análisis , Humanos , Polvo/análisis , Monitoreo del Ambiente/métodos , Industria de la Construcción , Colorado , Materiales de Construcción/análisis , Aerosoles/análisis , Factores de Tiempo
10.
Radiat Prot Dosimetry ; 200(3): 240-250, 2024 Mar 02.
Artículo en Inglés | MEDLINE | ID: mdl-38072679

RESUMEN

Natural radioactivity due to 238U, 232Th and 40K in brick samples from Tamil Nadu was determined using gamma-ray spectrometry. The mean activity concentrations of 238U, 232Th and 40K, 69 ± 6, 62 ± 6 and 462 ± 23 Bq kg-1, are slightly greater than the world recommended limits of 35, 45 and 420 Bq kg-1, respectively, and they are compared with a similar work carried out across the world. The radiological parameters such as radium equivalent activity, Raeq (193 ± 17 Bq kg-1), internal hazard index, Hin (0.71 ± 0.06), and activity utilisation index, AUI (1.43 ± 0.13), was lower, whilst absorbed dose rate, DRin (89 ± 8 nGy h-1), annual effective dose equivalent, AEDEin (0.43 ± 0.04 mSv y-1), and excess lifetime cancer risk, ELCRin (1.52 ± 0.13 mSv y-1), are slightly greater than the world's recommended limit. Bi-variate statistical analysis was performed to corroborate the relationship between radionuclides and radiological hazards.


Asunto(s)
Monitoreo de Radiación , Radio (Elemento) , Contaminantes Radiactivos del Suelo , Uranio , Torio/análisis , Radioisótopos de Potasio/análisis , Uranio/análisis , Dosis de Radiación , India , Materiales de Construcción/análisis , Radio (Elemento)/análisis , Monitoreo de Radiación/métodos , Contaminantes Radiactivos del Suelo/análisis
11.
Radiat Prot Dosimetry ; 200(2): 201-205, 2024 Feb 16.
Artículo en Inglés | MEDLINE | ID: mdl-38044801

RESUMEN

Natural radioactive materials in certain conditions can get to hazardous radiological level. The aim of the present work was to evaluate the natural activity concentration from sampled building materials collected from different locations in Babadogo Estate within Nairobi City County. The analysis done using gamma ray spectrometer, which was put into action for spectral data acquisition and then analysis. The activity concentration levels of 238U, 232Th and 40K for the selected samples of building materials was measured by the use of gamma ray spectrometry method. The analyzed data compared with the standard acceptable values. The activity concentration in 40K varied from 55 ± 3 to 2647 ± 132 Bq kg-1, giving an average (sum of all values divided by 33) value of 831 ± 42 Bq kg-1; 238U varied from 39 ± 2 to 3602 ± 180 Bq kg-1, giving average figures of 378 ± 19 Bq kg-1 and 232Th ranged from 5.000 ± 0.300 to 4213 ± 211 Bq kg-1, giving average figure of 290 ± 15 Bq kg-1. The calculated average figures for activity concentration surpassed the world average values of 420, 33 and 45 Bq kg-1 in 40K, 238U and 232Th, respectively.


Asunto(s)
Monitoreo de Radiación , Radiactividad , Radio (Elemento) , Uranio , Torio/análisis , Uranio/análisis , Kenia , Materiales de Construcción/análisis , Espectrometría gamma , Radioisótopos de Potasio/análisis , Radio (Elemento)/análisis
12.
Isotopes Environ Health Stud ; 60(1): 90-102, 2024 Mar.
Artículo en Inglés | MEDLINE | ID: mdl-37997342

RESUMEN

ABSTRACTEnvironmental and health risks posed by radionuclides in quarry pit soils are of great concern in environmental health monitoring. The current investigation was aimed at determining the natural radionuclide activity concentration (in Bq kg-1) of the understudied quarry pit granules used as construction materials. The collection and preparation of pit soil samples from Abeokuta quarry sites were done using standard methods, analysis of radiological parameters was carried out using hyperpure germanium (HPGe) spectrometer. Specific activity concentrations of 226Ra, 232Th, and 40K were measured. The values obtained were greater than the world weighted average of 35, 30, and 400 Bq kg-1 for 226Ra, 232Th, and 40K, respectively. The absorbed dose, the annual effective dose, and the radium equivalent were calculated and demonstrated significant values. The radionuclide content of the samples is relatively high and the use of pit soils as a building material, therefore, raises radiological concerns for dwellers in this area and requires periodic monitoring and undergoing a radiation protection program.


Asunto(s)
Monitoreo de Radiación , Radio (Elemento) , Contaminantes Radiactivos del Suelo , Dosis de Radiación , Monitoreo de Radiación/métodos , Radioisótopos de Potasio/análisis , Suelo , Nigeria , Salud Pública , Contaminantes Radiactivos del Suelo/análisis , Torio/análisis , Radioisótopos/análisis , Materiales de Construcción/análisis , Radio (Elemento)/análisis , Medición de Riesgo
13.
Environ Sci Pollut Res Int ; 30(60): 125965-125976, 2023 Dec.
Artículo en Inglés | MEDLINE | ID: mdl-38008831

RESUMEN

The main aim of this study is to investigate the material and monetary flows of CDW management and to characterize the distribution of illegally dumped CDW in Hanoi. Construction and demolition waste management has become a source of much concern to the urban authorities and citizens of big cities in Vietnam. It is estimated that 3000 t of CDW were generated per day from construction and demolition activities in Hanoi, but only 45% of the CDW was received at official landfills, while 55% of the CDW was disposed of elsewhere. The consequences of improper waste management are potentially alarming. The study conducted interviews to identify the material and cash flow associated with licensed and unlicensed contractors in CDW classification, transportation, treatment, and disposal, to characterize the distribution of illegally dumped CDW in two districts in Hanoi (urban and suburban districts), and to assess the composition of dumped CDW and environmental assessment of illegally dumped CDW by chemical analyses such as leaching and content tests. The study concluded that illegal dumping was performed mostly by unlicensed private companies. The illegally dumped CDW was mostly composed of mixed materials such as concrete, bricks, stones, and some hazardous materials such as asbestos and gypsum were found. The environmental concern of illegally dumped CDW was mostly dust, blockage of water ways, and inundation of increased suspended solids, whereas the heavy metal leaching concentration of all samples was below the environmental standards in Vietnam.


Asunto(s)
Industria de la Construcción , Metales Pesados , Administración de Residuos , Materiales de Construcción/análisis , Instalaciones de Eliminación de Residuos , Metales Pesados/análisis , Reciclaje , Residuos Industriales/análisis
14.
Environ Sci Pollut Res Int ; 30(47): 104408-104414, 2023 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-37704814

RESUMEN

Among the largest CO2 emission industries, the cement industry is ranked in 2nd place. A large volume of CO2 is emitted at the clinker production, which is a cement manufacturing intermediate product. Countries around the world were having difficulty reducing atmospheric emissions of greenhouse gases (GHG). Concrete is still being used more and more as the nation's infrastructure advances. The amount of CO2 emitted by concrete can be decreased by using less cement or substituting other materials for cement. In this study, the CO2 emission analysis is made on M40 grade, which is that metakaolin (MK) and alccofine (AL) are replaced to the cement in the manufacturing of concrete and is compared with the conventional concrete. The optimum cement replacement of MK and AL is 10% in the production of M40 grade concrete. MK and AL concrete have advantages and disadvantages. If proper safety precautions are taken during the manufacturing process, the toxicity level can be reduced, as well as the amount of CO2 released by the cement during the production of concrete. The LCA (life cycle analysis) is made for the concrete specimens, and the results were interpreted to know which concrete sample emits less and more carbon dioxide. The LCA study provided insights into the environmental aspects of metakaolin and alccofine concrete, including potential reductions in CO2 emissions, energy consumption and other environmental indicators. It helps identify areas of improvement and informs decision-making processes regarding sustainable material choices and construction practices. In M40 grade concrete, a 10% cement replacement with metakaolin and alccofine was found to be ideal. These results could also help in identifying the major cause of CO2 emission, and they can be used for further research purposes.


Asunto(s)
Materiales de Construcción , Gases de Efecto Invernadero , Materiales de Construcción/análisis , Dióxido de Carbono/análisis , Gases de Efecto Invernadero/análisis , Industrias
15.
Environ Sci Pollut Res Int ; 30(41): 93952-93969, 2023 Sep.
Artículo en Inglés | MEDLINE | ID: mdl-37518845

RESUMEN

The characteristics and potential for carbon dioxide capture and storage of the fifteenth-century lime mortar samples from City Palace, Udaipur, India, were studied. Physiochemical analysis followed by XRD, FTIR, TGA-DSC, and FE-SEM was performed. The findings demonstrate that calcium-rich eminently hydraulic mortars were used with a binder/aggregate (B/Ag) ratio of about 1:2.8±0.42. Mineralogy identified load-bearing phases: aragonite, vaterite, and calcite with 45±5% clay minerals. Absorption and stretching bands detected by FTIR at 1631 cm-1 and 2954 cm-1 corroborate the inclusion of plant organics. All samples showed aragonite around 870 cm-1, which can be traced back to bonded CO2 and the subsequent carbonation throughout the age of the structure. TGA-DSC validated XRD and FE-SEM analysis exhibited 18.66±3.40% weight loss at >600 °C, indicating calcite decomposition and CO2 release with CO2/H2O ratio of 3.31 to 3.66. From the historic example, a debate has been sparked about using lime mortars in contemporary construction to mitigate the carbon footprint with inherent attributes.


Asunto(s)
Dióxido de Carbono , Cambio Climático , Dióxido de Carbono/química , Carbonato de Calcio/química , Tecnología , Materiales de Construcción/análisis
16.
Environ Monit Assess ; 195(6): 673, 2023 May 16.
Artículo en Inglés | MEDLINE | ID: mdl-37188758

RESUMEN

The objective of this research is to assess the impact of radon concentration on workers at certain construction material industries in Erbil, Kurdistan Region of Iraq. The CR-39 solid-state track detector was used in this experiment to monitor radon levels and their daughters. For this purpose, as a case study group, 70 workers were divided into seven subgroups (gypsum, cement plant, lightweight block, marble, red brick 1, crusher stone, and concrete block 2), and 20 healthy volunteers were selected as a control group. The findings demonstrate that the mean concentrations of radon, radium, uranium, and radon daughters deposited on the detector face (POS) and chamber walls (POW) for the case study group were 9.61 ± 1.52 Bq/m3, 0.33 ± 0.05 Bq/Kg, 5.39 ± 0.86 mBq/Kg, 4 ± 0.63, and 16.62 ± 2.64 mBq/m3, whereas for the control group, they were 3.39 ± 0.58 Bq/m3, 0.117 ± 0.03 Bq/Kg, 1.91 ± 0.32 mBq/Kg, 1.41 ± 0.24, and 5.88 ± 1 mBq/m3, respectively. The statistical analysis revealed that radon, radium, uranium, and POW and POS concentrations were statistically significant (p ≤ 0.001) in the samples for the case study groups of cement, lightweight block, red brick 1, marble, and crusher stone factories in comparison to the control group; however, the results for gypsum and concrete block 2 factories were not statistically significant in comparison to the control group. Intriguingly, the radon levels in every blood sample examined were far lower than the 200 Bq/m3 limit established by the International Atomic Energy Agency. Hence, it may be argued that the blood is devoid of contaminants. These results are crucial for determining whether or not an individual is exposed to substantial quantities of radiation and for demonstrating a link between radon, its daughter, uranium, and the prevalence of cancer among workers in the Kurdish region of Iraq.


Asunto(s)
Contaminantes Radiactivos del Aire , Monitoreo de Radiación , Radio (Elemento) , Radón , Uranio , Humanos , Radio (Elemento)/análisis , Uranio/análisis , Sulfato de Calcio/análisis , Monitoreo del Ambiente , Radón/análisis , Contaminantes Radiactivos del Aire/análisis , Materiales de Construcción/análisis , Carbonato de Calcio/análisis , Monitoreo de Radiación/métodos
17.
Ann Work Expo Health ; 67(5): 609-621, 2023 06 06.
Artículo en Inglés | MEDLINE | ID: mdl-36866437

RESUMEN

OBJECTIVES: Cement belongs to the most used building materials. Clinker is the major constituent of cement, and it is believed that the strong increase of pH after hydration of clinker minerals is responsible for the observed decline in lung function of cement production workers. Information on clinker exposure at workplaces in the cement production industry is scarse. The aims of this study are to determine the chemical composition of thoracic dust and to quantify workplace exposure to clinker in cement production. METHODS: The elemental composition of 1250 personal thoracic samples collected at workplaces in 15 plants located in 8 different countries (Estonia, Greece, Italy, Norway, Sweden, Switzerland, Spain, Turkey) was determined by inductively coupled plasma optical emission spectrometry (ICP-OES), separately for water- and acid-soluble fraction. Positive matrix factorization (PMF) was used to determine the contribution of different sources to the dust composition and to quantify the clinker content in 1227 of the thoracic samples. In addition, 107 material samples were analysed to facilitate interpretation of the factors obtained by PMF. RESULTS: The median thoracic mass concentrations varied for individual plants between 0.28 and 3.5 mg/m3. PMF with 8 water-soluble and 10 insoluble (i.e., acid-soluble) element concentrations yielded a five-factor solution: Ca, K, Na sulfates; silicates; insoluble clinker; soluble clinker-rich; and soluble Ca-rich. The clinker content of the samples was calculated as sum of the insoluble clinker and soluble clinker-rich factors. The median clinker fraction of all samples was 45% (range 0-95%), and varied between 20% and 70% for individual plants. DISCUSSION: The 5-factor solution of PMF was selected on the basis of several mathematical parameters recommended in the literature as well as the mineralogical interpretability of the factors. In addition, interpretation of the factors was supported by the measured apparent solubility of Al, K, Si, Fe, and to a lesser extent Ca in material samples. The total clinker content obtained in the present study is considerably lower than estimates based on the Ca concentrations in a sample, and somewhat lower than estimates based on Si concentrations after selective leaching with a methanol/maleic acid mixture. The clinker abundance in workplace dust of one plant investigated in the present contribution was also estimated in a recent study by electron microscopy, and the good agreement between both studies gives confidence in the results of PMF. CONCLUSIONS: The clinker fraction in personal thoracic samples could be quantified from the chemical composition by positive matrix factorization. Our results allow for further epidemiological analyses of health effects in the cement production industry. As these estimates are more accurate for clinker exposure than aerosol mass, stronger associations with respiratory effects are expected if clinker is the main cause of these effects.


Asunto(s)
Exposición Profesional , Humanos , Exposición Profesional/análisis , Polvo/análisis , Materiales de Construcción/análisis , Lugar de Trabajo , Industrias
18.
Environ Sci Pollut Res Int ; 30(20): 58493-58515, 2023 Apr.
Artículo en Inglés | MEDLINE | ID: mdl-36988805

RESUMEN

This research incorporates sustainable materials such as ground granulated blast furnace slag (GGBS) and recycled waste glass (RWG) as cement and fine aggregate replacement respectively to produce green dry mix mortar paving blocks. The GGBS and RWG contents in the mortar paving block were optimised using the response surface methodology (RSM), considering the performances of the ultrasonic pulse velocity (UPV), flexural and compressive strengths, water absorption, and Cantabro loss. Life cycle assessment (LCA) was also conducted to evaluate the environmental impact of the optimised green mortar paving blocks. The RSM suggested that the paving block with optimum GGBS and RWG contents of 26.5% and 91.3%, respectively, could exhibit compressive strength of 36.5 MPa, which complied with the requirement for concrete segmental paving units (MA20). Excluding the mixes not fulfilling the MA20 requirement, the mix with 40% GGBS and 100% RWG exhibited the lowest values for the acidification potential (AP), global warming potential (GWP), photochemical oxidation (POCP), abiotic depletion potential for fossil fuel (ADPF), and water scarcity/strength ratio. Whereas, for eutrophication potential (EP) and abiotic depletion for elements (ADP (elements))/strength ratio, the mix with 100% RWG exhibited the lowest value. The optimised mix from RSM showed a similar performance as the two mixes.


Asunto(s)
Materiales de Construcción , Residuos Industriales , Residuos Industriales/análisis , Materiales de Construcción/análisis , Fuerza Compresiva , Agua/análisis , Ambiente
19.
Artículo en Inglés | MEDLINE | ID: mdl-36981845

RESUMEN

Policies have long been considered the essential driving force in promoting construction and demolition waste (CDW) recycling. However, the policy instruments adopted in different economies have varied greatly, which contributes to the difficulty in quantitative discernment of their effect. This study aims to examine whether the holistic employment of policy measures determines the development of CDW recycling around China. To accurately measure the holistic adoption of CDW policies, this study assessed policy strength via a proposed three-dimensional evaluation model. The spatiotemporal differences in policy strength among the 52 sample cities were further defined using K-means clustering and the Gini coefficient. Next, the driving effect of policy on the initial establishment of CDW recycling industry practices was examined by event history analysis (EHA). Finally, fuzzy set qualitative comparative analysis (fsQCA) was used to analyze the sufficiency and necessity of policy for the initial establishment of CDW recycling practices. The results indicated that the establishment of a first CDW recycling plant is only slightly correlated with policy measures, whereas it is highly correlated with the pilot city and per capita GDP. Furthermore, application of policy is neither a necessary nor sufficient condition for the establishment of a CDW recycling industry facility.


Asunto(s)
Industria de la Construcción , Administración de Residuos , Materiales de Construcción/análisis , Administración de Residuos/métodos , Industria de la Construcción/métodos , Ciudades , Reciclaje/métodos , China , Residuos Industriales/análisis
20.
Artículo en Inglés | MEDLINE | ID: mdl-36834185

RESUMEN

After a long decomposition process, organic matter turns into humic substances. In humus, carbon dioxide (CO2) bound in photosynthesis is brought back to the soil, where it should be used by its ecosystem. This is important because similar relationships are found in modern concretes and concretes designed with the use of geochemical modeling (possibility of the C-S-H phase for storing harmful substances). The aim of the article was to investigate the possibility of using humus (Humus Active-HA) and vermicompost (Biohumus Extra Universal-BEU), i.e., organic matter resulting from a long process of biological decomposition in the production of autoclaved bricks containing only ecological materials, i.e., sand, lime, and water. Tests of compressive strength, density, microstructure based on SEM, XRD, and micro-CT analysis were performed. The results of the research indicate that humus and vermicompost can be successfully used in their production. The paper compares traditional products and products made of raw material mass containing 3%, 7%, and 11% of humus and vermicompost, using the apparatus of mathematical experiment planning. Compressive strength, volumetric density, water absorption, and wicking, porosity, and material microstructure were tested. The best results were obtained for samples with the addition of 7% humus and 3% vermicompost. The compressive strength increased to 42.04 MPa (compared to standard bricks, whose strength is 15-20 MPa), and the bulk density increased by about 55%, to the value of 2.11 kg/dm3, which indicates the densification of the material's microstructure. They were characterized by the highest compressive strength, moderate water absorption, and a high proportion of closed pores in the sample.


Asunto(s)
Materiales de Construcción , Ecosistema , Materiales de Construcción/análisis , Suelo/química , Sustancias Húmicas/análisis , Agua/análisis
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