Impact of brick kilns industry on environment and human health in Pakistan.

The increase in population has led to the rise in the construction and manufacturing of bricks. Bricks are manufactured in brick kilns that emit very harmful gases which in turn affect the human health, environment and economy. In Pakistan, the diseases related to skin, and respiratory system have created a lot of problems for the humans and animals. According to experts and professionals, one of the main causes of the environment and health related problems is brick kiln. It is very important to identify the brick kilns and emissions that are extremely harmful for the environment and human health. Therefore, the objective of this research paper is threefold. Firstly, to identify and rank the emissions from brick kilns based on their harmful impact on human health and environment. Secondly, to rank the three types of brick kilns i.e. Traditional Brick Kilns (TBK) with coal as a fuel, Traditional Brick Kilns (TBK) with rubber as a fuel and Contemporary Brick Kilns (CBK) (technologically advanced brick kilns) based on their impact on human health and environment. Thirdly, to identify the relation of three alternative brick kilns with health and environmental problems, respectively. DEMATEL and Fuzzy-TOPSIS have used for achieving the objectives. The results show that CO2, CO and SO2 have the most harmful effects on the environment. Similarly, carcinogenic dioxin, SO2 and PM have the adverse effects on the human health. TBK in which rubber is used as a fuel is the most harmful and CBK is the safest types of brick kilns, respectively. In the light of the results, it is recommended to the government of Pakistan to formulate and implement the rules and regulations for minimizing the negative impacts of brick kilns on human health and environment. Moreover, new technologies should be used in order to reduce the harmful impacts.

Where did Roman masons get their material from? A preliminary DRIFTS/PCA investigation on mortar aggregates from X Regio buildings in the Veneto area (NE Italy) and their potential sources.

In this work, preliminary results are presented of an ongoing investigation aiming to identify the possible material sources employed by ancient Romans in their building activity in the X Regio, the European region corresponding to present north-eastern Italy and Istria (Croatia and Slovenia). The 63-420 µm fraction of the aggregate component recovered from eleven mortar fragments of buildings located in the Veneto area (in or close to Lio Piccolo, Vicenza, and Padua) is studied by diffuse reflection infrared Fourier transform spectroscopy and compared through principal component analysis to samples collected from local potential sources of raw materials. In this regard, the investigated samples from Lio Piccolo present a distinctive complexity, being this site located within the Venice lagoon, an area that has since been undergoing dramatic changes both due to natural and anthropic causes. The Vicenza and Padua sites were considered for comparison sake because they are or were located close to two rivers, the Bacchiglione and the Brenta, that in ancient times flowed into the Venice lagoon. As expected, from the exploratory investigation reported here, no firm conclusions can be obtained for the mortar samples collected in Lio Piccolo, whereas the likely provenance of the aggregate component of the samples from Vicenza and Padova from the Bacchiglione and the Brenta riverbeds, respectively, is confirmed.

Multivariate statistical analysis of radiological data of building materials used in Tiruvannamalai, Tamilnadu, India.

Using γ spectrometry, the concentration of the naturally occurring radionuclides (226)Ra, (232)Th and (40)K has been measured in soil, sand, cement, clay and bricks, which are used as building materials in Tiruvannamalai, Tamilnadu, India. The radium equivalent activity (Raeq), the criterion formula (CF), indoor gamma absorbed dose rate (DR), annual effective dose (HR), activity utilization index (AUI), alpha index (Iα), gamma index (Iγ), external radiation hazard index (Hex), internal radiation hazard index (Hin), representative level index (RLI), excess lifetime cancer risk (ELCR) and annual gonadal dose equivalent (AGDE) associated with the natural radionuclides are calculated to assess the radiation hazard of the natural radioactivity in the building materials. From the analysis, it is found that these materials used for the construction of dwellings are safe for the inhabitants. The radiological data were processed using multivariate statistical methods to determine the similarities and correlation among the various samples. The frequency distributions for all radionuclides were analyzed. The data set consisted of 15 measured variables. The Pearson correlation coefficient reveals that the (226)Ra distribution in building materials is controlled by the variation of the (40)K concentration. Principal component analysis (PCA) yields a two-component representation of the acquired data from the building materials in Tiruvannamalai, wherein 94.9% of the total variance is explained. The resulting dendrogram of hierarchical cluster analysis (HCA) classified the 30 building materials into four major groups using 15 variables.

Reliable classification of moving waste materials with LIBS in concrete recycling.

Effective discrimination between different waste materials is of paramount importance for inline quality inspection of recycle concrete aggregates from demolished buildings. The moving targeted materials in the concrete waste stream are wood, PVC, gypsum block, glass, brick, steel rebar, aggregate and cement paste. For each material, up to three different types were considered, while thirty particles of each material were selected. Proposed is a reliable classification methodology based on integration of the LIBS spectral emissions in a fixed time window, starting from the deployment of the laser shot. PLS-DA (multi class) and the hybrid combination PCA-Adaboost (binary class) were investigated as efficient classifiers. In addition, mean centre and auto scaling approaches were compared for both classifiers. Using 72 training spectra and 18 test spectra per material, each averaged by ten shots, only PLS-DA achieved full discrimination, and the mean centre approach made it slightly more robust. Continuing with PLS-DA, the relation between data averaging and convergence to 0.3% average error was investigated using 9-fold cross-validations. Single-shot PLS-DA presented the highest challenge and most desirable methodology, which converged with 59 PC. The degree of success in practical testing will depend on the quality of the training set and the implications of the possibly remaining false positives.

A wireless laser displacement sensor node for structural health monitoring.

This study describes a wireless laser displacement sensor node that measures displacement as a representative damage index for structural health monitoring (SHM). The proposed measurement system consists of a laser displacement sensor (LDS) and a customized wireless sensor node. Wireless communication is enabled by a sensor node that consists of a sensor module, a code division multiple access (CDMA) communication module, a processor, and a power module. An LDS with a long measurement distance is chosen to increase field applicability. For a wireless sensor node driven by a battery, we use a power control module with a low-power processor, which facilitates switching between the sleep and active modes, thus maximizing the power consumption efficiency during non-measurement and non-transfer periods. The CDMA mode is also used to overcome the limitation of communication distance, which is a challenge for wireless sensor networks and wireless communication. To evaluate the reliability and field applicability of the proposed wireless displacement measurement system, the system is tested onsite to obtain the required vertical displacement measurements during the construction of mega-trusses and an edge truss, which are the primary structural members in a large-scale irregular building currently under construction. The measurement values confirm the validity of the proposed wireless displacement measurement system and its potential for use in safety evaluations of structural elements.

How does the edge height of curb ramps obstruct bicycles?

The aim of this study is to recommend revisions, based on empirical data, to the current curb ramp standards for keeping bicyclists safe. Four types of curb ramps were tested: (1) concrete with a 50 mm edge height, (2) concrete reinforced by a metal plate with a 50 mm edge height, (3) plastic with a 20 mm edge height, and (4) recycled rubber with a 10 mm edge height. Twenty subjects aged 20-60 years ascended the curbs on a bicycle under various conditions. The angles of approach were 15 degrees, 30 degrees, 45 degrees, 60 degrees, 75 degrees and 90 degrees. Experiments were executed under both wet and dry conditions. We found that when approaching from an angle of 45 degrees or more, all subjects could ascend all ramps under both conditions. From a 15 degrees approach under wet conditions, no subjects ascended the concrete ramps. Some could not ascend at a 15 degrees approach on the concrete ramps in dry conditions, and some could not ascend from a 30 degrees approach on the reinforced concrete ramp in wet conditions. Bicyclists riding on roadways cannot easily ascend a curb ramp with a 50 mm edge, even in dry conditions. We thus recommend that curb ramp edge heights be lower than 50 mm. Keywords: friction coefficient; approach angle

Distribution of materials in construction and demolition waste in Portugal.

It may not be enough simply to know the global volume of construction and demolition waste (CDW) generated in a certain region or country if one wants to estimate, for instance, the revenue accruing from separating several types of materials from the input entering a given CDW recycling plant. A more detailed determination of the distribution of the materials within the generated CDW is needed and the present paper addresses this issue, distinguishing different buildings and types of operation (new construction, retrofitting and demolition). This has been achieved by measuring the materials from buildings of different ages within the Portuguese building stock, and by using direct data from demolition/retrofitting sites and new construction average values reported in the literature. An attempt to establish a benchmark with other countries is also presented. This knowledge may also benefit industry management, especially that related to CDW recycling, helping to optimize procedures, equipment size and operation and even industrial plant spatial distribution. In an extremely competitive market, where as in Portugal low-tech and high environmental impact procedures remain the norm in the construction industry (in particular, the construction waste industry), the introduction of a successful recycling industry is only possible with highly optimized processes and based on a knowledge-based approach to problems.

Framework for estimating potential wastes and secondary resources accumulated within an economy--a case study of construction minerals in Japan.

Material stocks in economic society are considered to represent a reserve for wastes and secondary resources. From the viewpoints of proper disposal and reutilization of stocked materials, accurate estimation of the amount of materials that will emerge as wastes or secondary resources in the future is important. We defined materials that have a high probability of emerging as wastes or secondary resources as "potential wastes and secondary resources" and estimated that amount for construction minerals in Japan as a case study. The following conclusions were drawn. (1) We classified materials that are input into economic society into four categories: potential wastes and secondary resources, potential dissipated materials, dissipatively used materials, and permanent structures. By clarifying the latter three non-potential wastes and secondary resources, we performed a more accurate assessment of the wastes and secondary resources that will emerge in the future. (2) The share of potential wastes and secondary resources was estimated to be about 30% of all construction minerals that have been input into and accumulated in Japanese economic society. (3) Information related to potential dissipated materials and dissipatively used materials will provide fundamental knowledge to support analyses of the environmental impacts and resource losses which these materials might generate.

A Spanish model for quantification and management of construction waste.

Currently, construction and demolition waste (C&D waste) is a worldwide issue that concerns not only governments but also the building actors involved in construction activity. In Spain, a new national decree has been regulating the production and management of C&D waste since February 2008. The present work describes the waste management model that has inspired this decree: the Alcores model implemented with good results in Los Alcores Community (Seville, Spain). A detailed model is also provided to estimate the volume of waste that is expected to be generated on the building site. The quantification of C&D waste volume, from the project stage, is essential for the building actors to properly plan and control its disposal. This quantification model has been developed by studying 100 dwelling projects, especially their bill of quantities, and defining three coefficients to estimate the demolished volume (CT), the wreckage volume (CR) and the packaging volume (CE). Finally, two case studies are included to illustrate the usefulness of the model to estimate C&D waste volume in both new construction and demolition projects.

Influence of recycled fine aggregates on the resistance of mortars to magnesium sulfate attack.

The influence of recycled fine aggregates, which had been reclaimed from field-demolished concretes, on the resistance of mortar specimens to magnesium sulfate attack was investigated. Mortar specimens were prepared with recycled fine aggregates at different replacement levels (0%, 25%, 50%, 75% and 100% of natural fine aggregate by mass). The mortar specimens were exposed to 4.24% magnesium sulfate solution for about 1 year at ambient temperature, and regularly monitored for visual appearance, compressive strength loss and expansion. Additionally, in order to identify products of magnesium sulfate attack, mortar samples incorporating 0%, 25% and 100% replacement levels of the recycled fine aggregates were examined by X-ray diffraction (XRD) technique. Experimental results confirmed that the use of recycled fine aggregates up to a maximum 50% replacement level is effective under severe magnesium sulfate environment, irrespective of type of recycled fine aggregates. However, the worse performance was observed in mortar specimens incorporating 100% replacement level. It was found that the water absorption of recycled fine aggregates affected deterioration of mortar specimens, especially at a higher replacement level. XRD results indicated that the main cause of deterioration of the mortar specimens was primarily due to the formation of gypsum and thaumasite by magnesium sulfate attack. In addition, it appeared that the conversion of C-S-H into M-S-H by the attack probably influenced mechanical deterioration of mortar specimens with recycled fine aggregates.

Properties of concrete blocks prepared with low grade recycled aggregates.

Low grade recycled aggregates obtained from a construction waste sorting facility were tested to assess the feasibility of using these in the production of concrete blocks. The characteristics of the sorted construction waste are significantly different from that of crushed concrete rubbles that are mostly derived from demolition waste streams. This is due to the presence of higher percentages of non-concrete components (e.g. >10% soil, brick, tiles etc.) in the sorted construction waste. In the study reported in this paper, three series of concrete block mixtures were prepared by using the low grade recycled aggregates to replace (i) natural coarse granite (10mm), and (ii) 0, 25, 50, 75 and 100% replacement levels of crushed stone fine (crushed natural granite <5mm) in the concrete blocks. Test results on properties such as density, compressive strength, transverse strength and drying shrinkage as well as strength reduction after exposure to 800 degrees C are presented below. The results show that the soil content in the recycled fine aggregate was an important factor in affecting the properties of the blocks produced and the mechanical strength deceased with increasing low grade recycled fine aggregate content. But the higher soil content in the recycled aggregates reduced the reduction of compressive strength of the blocks after exposure to high temperature due probably to the formation of a new crystalline phase. The results show that the low grade recycled aggregates obtained from the construction waste sorting facility has potential to be used as aggregates for making non-structural pre-cast concrete blocks.

Horizontal environmental assessment of building products in relation to the construction products directive (CPD).

According to the European Construction Products Directive (89/106/EC), construction products must satisfy specified essential requirements (ER). To comply with ER 3, on hygiene, health and environment, the construction works must be designed and built in such a way that they will not be a threat to the hygiene and health of the occupants and neighbours, nor to the environment. Standardised test methods for the release of substances that are hazardous to health and environment need to be developed at the European level. A horizontal approach is considered the best route for such test development and consists of the development of a test method applicable for different products used in a certain scenario (across the fields of different Technical Committees). The work presented here regards the emission of pollutants towards soil and water and has been carried out on monolith products, based on three types of matrices: concrete, wood and metal (zinc). The aim of the work is to study the parameters (nature of leachant, temperature, liquid-to-solid ratio) that could influence the release behaviour of substances in water. The knowledge acquired from these tests will allow the identification of some parameters needed for the development of a horizontal test.

Household risk factors for Trypanosoma cruzi seropositivity in two geographic regions of Ecuador.

Few studies on the relationship between environmental factors and Trypanosoma cruzi transmission have been conducted in Ecuador. We conducted a cross-sectional study of household risk factors for T. cruzi seropositivity in 2 distinct geographical regions of Ecuador. Exposure information was collected via household surveys, and subjects were tested for serological evidence of T. cruzi infection. In total, 3,286 subjects from 997 households were included. In the coastal region, factors associated with seropositivity were living in a house with a palm roof (odds ratio [OR] = 2.63, 95% confidence interval, [1.61. 4.27]), wood walls (OR = 5.75 [2.04, 16.18]), or cane walls (OR = 2.81 11.31, 6.04]), and the presence of firewood in the peridomicile (OR = 2.48 [1.54, 4.01]). Accumulation of trash outside the home was associated with a reduced risk of seropositivity (OR = 0.25 [0.12, 0.51]). In the Andean region, living in a house with adobe walls was the only factor predictive of T. cruzi seropositivity. In conclusion, risk factors for T. cruzi transmission in Ecuador varied by geographic region, probably because of differing behavior of the triatomine vector species in each region. An understanding of the transmission dynamics of T. cruzi in a particular area is necessary for the development of effective Chagas disease control strategies in those areas.

Near-infrared spectroscopic study of the physical and mechanical properties of wood with meso- and micro-scale anatomical observation.

Estimation of the density along with the tensile strength of wood within both the elastic and plastic deformation ranges, represented as modulus of elasticity (MOE) and ultimate tensile stress (UTS), respectively, were performed using near-infrared (NIR) spectroscopy. A partial least squares (PLS) analysis was applied to the measurements of density, MOE, and UTS, and resulted in a high accuracy of prediction, independent of wood species. The correlation coefficient between the NIR spectra and criterion variables, and the regression vector resulting from the PLS analysis, suggested that the characteristic absorption bands were strongly related to the predictability of each property. In the case of softwood, absorption bands due to intra-molecular hydrogen-bonded OH groups in the crystalline regions of cellulose, which are oriented preferentially in a direction parallel to the cellulose chain, might strongly affect the tensile strength of softwood. Hardwoods have much more complex and variable structures than softwoods; therefore, it was supposed that the key factor governing the tensile strength in hardwood would be the interaction between the three principal constituents (i. e., cellulose, hemicellulose, and lignin) of wood.

Radioactivity level in Chinese building ceramic tile.

The activity concentrations of (226)Ra, (232)Th and (40)K have been determined by gamma ray spectrometry. The concentrations of (226)Ra, (232)Th and (40)K range from 158.3 to 1087.6, 91.7 to 1218.4, and 473.8 to 1031.3 Bq kg(-1) for glaze, and from 63.5 to 131.4, 55.4 to 106.5, and 386.7 to 866.8 Bq kg(-1) for ceramic tile, respectively. The measured activity concentrations for these radionuclides were compared with the reported data of other countries and with the typical world values. The radium equivalent activities (Ra(eq)), external hazard index (H(ex)) and internal hazard index (H(in)) associated with the radionuclides were calculated. The Ra(eq) values of all ceramic tiles are lower than the limit of 370 Bq kg(-1). The values of H(ex) and H(in) calculated according to the Chinese criterion for ceramic tiles are less than unity. The Ra(eq) value for the glaze of glazed tile collected from some areas are >370 Bq kg(-1).

[Raman spectroscopic study of Ming Dynasty bar-tile from Heijing of Lufeng].

Ming dynasty bar-tile from the archaeological site of Heijing (Lufeng of Yunnan Province, China) was analyzed by Raman microscopy, X-ray diffraction and electron probe microscopy (EPMA). It was found that the major components of the tile are SiO2, besides moonstone(KAlSi3O8 var. of K-orthoclase), Na-orthoclase(NaAlSi3 O8 )and an unknown mineral (Al, Fe)3(PO4,VO4)2(OH)3.8H2O etc. The studies revealed that the agglomerant temperature of the bar-tile reached up to 1500 degrees C, indicating that the agglomerant technology of ceramics of Yunnan in the Ming dynasty (before 17 century) already attained a high level. Raman microscopyproves especially excellent in studing antiques. The results show that the facility and reliability of Raman spectroscopy, as anon-destructive unique technique, are suitable for the discrimination between moonstone and K-orthoclase within tile. No other technique tried was successful in its identification. This research demonstrates that only by combining several complementary techniques is possible to conduct comprehensive research on antiques.

Clasificación de los materiales de revestimiento interior de acuerdo a su comportamiento al fuego / Classification of heat insulation materials according to fire behaviour

Este trabajo tiene como objetivo analizar el alcance y las limitaciones del método utilizado actualmente en nuestro país para determinar la no combustibilidad de los materiales y presentar modificaciones tendientes a clasificar los materiales de revestimiento interior en diferentes escalas. Para ello, se describen algunos aspectos básicos sobre el comportamiento de los revestimientos interiores durante un incendio y dos metodologías extranjeras vigentes para clasificar y establecer limitantes de uso, en términos de comportamiento al fuego. Las dos metodologías descritas utilizan métodos de ensayo tendientes a determinar una clasificación de los materiales utilizados en la construcción, relacionados específicamente con el buen uso de los revestimientos interiores. Finalmente se entregan conclusiones y comentarios sobre los métodos presentados, así como las ventajas de su aplicación

Hospital construction materials: poor shielding capacity with respect to signals transmitted by mobile telephones.

Electromagnetic interference (EMI) with electronic medical equipment by the handsets of mobile telephones is a well documented problem in hospitals. To gain information about how to build an EMI-free hospital and how to make rooms safe for mobile telephone handset use in the hospital building the authors measured the shielding capacities of a concrete wall, concrete blocks, a steel door, and steel-surfaced partition panels. The shielding capacities of these materials were 2-7 dB for the concrete wall, 6-8 dB for the concrete blocks, 19-27 dB for the steel door, and 20-37 dB for the steel-surfaced partition panels. These results indicate that care should be taken to shield electronic equipment from signals coming from neighboring rooms and from those under and above any patient room in which such equipment is in use. Electricity-conductive paint, electricity-conductive wallpaper, and electricity-conductive cloth are examples of inexpensive materials that can increase shielding capacity.

Benzene emission from building and finishing materials.

The results for the determination of benzene air emissions from building and finishing materials are presented. The test chamber was used to ventilate sample materials at controlled air change rate, temperature and relative humidity. Charcoal sample cartridges were used and then CS2 was desorbed to a packed column gas chromatograph for analysis. The test chamber concentrations of benzene for adhesive were observed to diminish with time. Calculated emission rate for materials tested were determined from 0.4 micrograms/m2/h to 4.4 micrograms/m2/h.