Vegetation Dynamics and Growth Performance of Nitraria retusa among Different Habitats in Egypt.

<b>Background and Objective:</b> <i>Nitraria retusa</i> is a salt-tolerant and drought-resistant shrub located in the Nitrariaceae family. Floristic composition and soil characters in representative habitats of <i>Nitraria retusa</i> were analyzed in terms of habitat variations and vegetation dynamics. <b>Materials and Methods:</b> A total of 12 sites were surveyed and nineteen environmental factors were recognized in three main habitats: sandy dunes, salt marshes and wadi channel. Homogeneity of each stand was secured by visual judgment to comprise uniform habitat dominated by <i>Nitraria retusa</i>. A list of the accompanied species (inside and outside the studied quadrates) was made to give an idea about the plant diversity in the study area. <b>Results:</b> Four main vegetation groups were recorded and their controlling ecological factors were identified. Species diversity gradients in addition to the gradient of human interference were significantly higher in dunes habitat than the other habitats. The growth performance of <i>Nitraria retusa</i> was significantly higher in the sand dunes habitat than in the other habitats. <b>Conclusion:</b> The Egyptian desert's need for judicious utilization and sustainable development. For this, the influence of other environmental factors needs to be analyzed properly understood.

Effect of Growing Media Composition on the Growth of Areca Nut (Areca catechu L.).

<b>Background and Objective:</b> Every plant needs a suitable growing medium to grow and develop optimally. The growing media provide nutrients and an ideal place for roots to grow and take nutrients. This study aimed to obtain a suitable growing medium composition to increase the growth of areca nut. <b>Materials and Methods:</b> The research was carried out at the Agronomy Laboratory, Faculty of Agriculture, Halu Oleo University, Indonesia from March-September, 2020. Nine treatments of growing media composition in combination with the percentage of soil medium, rice husk charcoal and organic fertilizer used and arranged in a Randomized Block Design (RBD) with three replications. <b>Results:</b> The result showed that the composition of the growing medium has a significant effect on the growth of areca nuts. Growing media using the composition of 25% soil, 25% rice husk charcoal, 50% of organic plus fertilizer (M₅) is the best growing medium composition that can increase the growth of areca nut. Another growing media is composed of 50% soil, 0% rice husk charcoal, 50% organic plus fertilizer (M₂), 50% soil, 50% rice husk charcoal, 25% organic plus fertilizer (M₄), 25% soil, 50% rice husk charcoal, 25% organic plus fertilizer (M₇) and 0% soil, 50% rice husk charcoal, 50% organic plus fertilizer (M₈) can also be an alternative in increasing the growth of areca nut. <b>Conclusion:</b> The composition of the growing medium has a significant effect on the growth of areca nuts seedling. The growing media using the composition of 25% soil, 25% rice husk charcoal and 50% organic plus fertilizer is the best growing medium composition that can increase the growth of areca nut seedling.

Isolation, characterization and identification of pesticide degrading bacteria from contaminated soil for bioremediation.

In this study, malathion and chlorpyrifos degrading bacteria were isolated from agricultural soil samples taken from the Himachal region in India. A total of 52 organisms were isolated which were further screened for their efficiency for chlorpyrifos and malathion degradation. Screening was done by checking the growth on Nutrient Agar, Mineral Salt Medium and MacConkey agar plates containing chlorpyrifos and malathion; 37 isolates showed growth in these. Biomass assay and minimum inhibitory concentration (MIC) determination were carried out for the selection of most efficient bacterial isolates. Out of the seven isolates which showed good biomass assay and MIC, only three isolates (PDM-2, PDM-15 and PDM-20) were selected for further studies. These were characterized by various biochemical tests, Gram staining, indole test, methyl red test, Voges-Proskauer test, citrate utilization test and carbohydrate fermentation test. Out of three isolates, PDM-15 showed good resistance against the antibiotics such as erythromycin, chloramphenicol, ampicillin and penicillin and identified as Kocuria assamensis. Degradation of 71.3% of chlorpyrifos and 85% of malathion was observed by the gas chromatography. Therefore, the Kocuria assamensis can be used in the bioremediation of pesticide-contaminated soil.

Prediction of sediment transport capacity based on slope gradients and flow discharge.

Sediment transport capacity (Tc) is an essential parameter in the establishment of the slope soil erosion model. Slope type is an important crucial factor affecting sediment transport capacity of overland flow, and vegetation can effectively inhibit soil loss. Two new formulae of sediment transport capacity (Tc) are proposed of brown soil slope and vegetation slope in this study and evaluate the influence of slope gradient (S) and flow discharge (Q) on sediment transport capacity of different slope types. Laboratory experiments conducted using four flow discharges (0.35, 0.45, 0.55, and 0.65 L s-1), four slope gradients (3, 6, 9, and 12°), and two kinds of underlying surface (Brown soil slope, Vegetation slope). The soil particle size range is 0.05-0.5mm. The vegetation stems were 2mm in diameter and randomly arranged. The results show that the sediment transport capacity was positively correlated with the flow discharge and slope gradient. The vegetation slope's average sediment transport capacity is 11.80% higher than the brown soil slope that same discharge and slope gradient conditions. The sensitivity of sediment transport capacity to flow discharge on brown soil slope is higher than that of slope gradient. The sensitivity of sediment transport capacity of vegetation slope to slope gradient is more heightened than flow discharge. The sediment transport capacity was well predicted by discharge and slope gradient on brown soil slope (R2 = 0.982) and vegetation slope (R2 = 0.993). This method is helpful to promote the study of the sediment transport process on overland flow.

Derivation and validation of thresholds of cadmium, chromium, lead, mercury and arsenic for safe rice production in paddy soil.

Cadmium (Cd), chromium (Cr), lead (Pb), mercury (Hg) and arsenic (As) are potent toxicants to human health via dietary intake. It is imperative to establish accurate soil thresholds based on soil-plant transfer models and food safety standards for safe agricultural production. This study takes rice genotypes and soil properties into account to derive soil thresholds for five heavy metal(loid)s using the bioconcentration factors (BCF) and species sensitivity distribution (SSD) based on the food safety standard. The BCF generated from two paddy soils was calculated to investigate the sensitivity of heavy metal accumulation in nine rice cultivars in a greenhouse pot experiment. Then, empirical soil-plant transfer models were developed from a middle-sensitivity rice cultivar (Denong 2000, one selected from nine rice) grown in nineteen paddy soils with various soil properties under a proper exogenously metal(loid)s concentration gradient. After normalization, hazardous concentrations from the fifth percentile (HC5) were calculated from the SSD curves, and the derived soil thresholds were obtained from HC5 prediction models that based on the combination of pH and organic carbon (OC) or cation exchange capacity (CEC). The soil Cd threshold derived based on pH and organic carbon (pH < 7.5, OC ≥ 20 g kg-1) was 1.3-fold of those only considering pH, whereas the Pb threshold (pH > 6, CEC ≥ 20 cmolc kg-1) was 3.1 times lower than the current threshold. The derived thresholds for five elements were validated to be reliable through literature data and field experiments. The results suggested that deriving soil heavy metal(loid)s threshold using SSD method and local food safety standards is feasible and also applicable to other crops as well as other regions with potential health risks of toxic elements contamination in agricultural production.

Rice Straw Biochar Application and its Impact on Yield of Some Faba Bean Varieties in Sandy Soil.

<b>Background and Objective:</b> Biological fertilization in the development of agriculture became one new strategy in the increased production of field crops to decrease the costs of production input and environmental pollution. This study focused on the influence of biochar fertilization on the productivity of faba bean varieties under sandy soils. <b>Materials and Methods:</b> Appreciation of the yield and its components, in addition to measurement of grain protein content as well as carbohydrates (%) of faba bean. <b>Results:</b> The data obtained indicated that the biochar amendment affects plant production at different rates, where the best yield obtained is 90 kg fed¹. The grain yield increase is significant for the variety's types where, Mariout-2, followed by Nubaria-3 followed by Giza-716 for the addition of 90 kg fed¹ of biochar as referenced by the non-conditioning treatment. Likewise, the protein content was highest in the Mariout-2 variety, followed by Nubaria-3 variety and Giza-716 variety for the addition. This improvement may be regarded to the impact of biochar on the physic-chemical characteristics for the soils, in addition to the biological characteristics. Furthermore, the biochar itself add nutrient to the soil after decomposition. The best improvement happens by the long-term cropping for a long period could be reached up to years. <b>Conclusion:</b> The conclusion that plant growth was better at a high rate (90 kg fed¹) but the economy of this rate may be questioned, under the condition of the study. However, the validation for different soils may vary with different rates, which needs more research. Also, it is recommended to use Mariout-2 cultivars for their high production under these conditions.

Root exudates drive soil-microbe-nutrient feedbacks in response to plant growth.

Although interactions between plants and microbes at the plant-soil interface are known to be important for plant nutrient acquisition, relatively little is known about how root exudates contribute to nutrient exchange over the course of plant development. In this study, root exudates from slow- and fast-growing stages of Arabidopsis thaliana plants were collected, chemically analysed and then applied to a sandy nutrient-depleted soil. We then tracked the impacts of these exudates on soil bacterial communities, soil nutrients (ammonium, nitrate, available phosphorus and potassium) and plant growth. Both pools of exudates shifted bacterial community structure. GeoChip analyses revealed increases in the functional gene potential of both exudate-treated soils, with similar responses observed for slow-growing and fast-growing plant exudate treatments. The fast-growing stage root exudates induced higher nutrient mineralization and enhanced plant growth as compared to treatments with slow-growing stage exudates and the control. These results suggest that plants may adjust their exudation patterns over the course of their different growth phases to help tailor microbial recruitment to meet increased nutrient demands during periods demanding faster growth.

Assessment and source identification of As and Cd contamination in soil and plants in the vicinity of the Nui Phao Mine, Vietnam.

This study investigated the contamination levels and sources of As and Cd vicinity area from Nui Phao mine that is one of the largest tungsten (W) open pit mines in the world. Soil and plant samples were collected from the study area to identify the concentrations of As and Cd using aqua-regia or HNO3 digestion. According to the Vietnamese agricultural soil criteria, all soil samples were contaminated with As and Cd. The distribution of As concentration is related to the distance from the Nui Phao mine. The higher As concentrations were measured in the area close to the mine. However, the Cd distribution in the soil showed a different pattern from As. Enrichment factor and Geoaccumulation Index (Igeo) indicated that As in the soil is derived from the mining activities, while Cd could have other geogenic or anthropogenic sources. The ranges of As and Cd concentration in polished rice grains in the Nui Phao mine area exceeded the CODEX criteria (0.2 mg/kg), which indicated extreme contamination. The arsenic concentration between soil and plant samples was determined to be a positive correlation, while the Cd concentration showed a negative correlation, implying that As and Cd have different geochemical behavior based on their sources.

Alternative Evaluation to Earthworm Toxicity Test in Polychlorinated Biphenyls Spiked and Remediated Soils.

Polychlorinated biphenyls (PCBs) are a class of persistent organic pollutants that pose a threat to environment and human health. Aiming at predicting PCBs risk in actual soil ecosystem, this study was conducted by chemical and biological methods to assess the bioavailability of PCBs in spiked soil, and in field-contaminated soils before or after remediation. The three chemical methods were Soxhlet, n-butanol and hydroxypropyl-ß-cyclodextrin (HPCD). Results were compared to actual PCB bioaccumulation in earthworms (Eisenia fetida). HPCD extraction was the best to predict the actual PCB bioaccumulation in all soils. The results suggest that HPCD could be an effective alternative method to earthworm toxicity test. This study provides strategy to understand the toxicity assessment in contaminated soil and soil after remediation.

Using soil bacterial communities to predict physico-chemical variables and soil quality.

BACKGROUND: Soil ecosystems consist of complex interactions between biological communities and physico-chemical variables, all of which contribute to the overall quality of soils. Despite this, changes in bacterial communities are ignored by most soil monitoring programs, which are crucial to ensure the sustainability of land management practices. We applied 16S rRNA gene sequencing to determine the bacterial community composition of over 3000 soil samples from 606 sites in New Zealand. Sites were classified as indigenous forests, exotic forest plantations, horticulture, or pastoral grasslands; soil physico-chemical variables related to soil quality were also collected. The composition of soil bacterial communities was then used to predict the land use and soil physico-chemical variables of each site. RESULTS: Soil bacterial community composition was strongly linked to land use, to the extent where it could correctly determine the type of land use with 85% accuracy. Despite the inherent variation introduced by sampling across ~ 1300 km distance gradient, the bacterial communities could also be used to differentiate sites grouped by key physico-chemical properties with up to 83% accuracy. Further, individual soil variables such as soil pH, nutrient concentrations and bulk density could be predicted; the correlations between predicted and true values ranged from weak (R2 value = 0.35) to strong (R2 value = 0.79). These predictions were accurate enough to allow bacterial communities to assign the correct soil quality scores with 50-95% accuracy. CONCLUSIONS: The inclusion of biological information when monitoring soil quality is crucial if we wish to gain a better, more accurate understanding of how land management impacts the soil ecosystem. We have shown that soil bacterial communities can provide biologically relevant insights on the impacts of land use on soil ecosystems. Furthermore, their ability to indicate changes in individual soil parameters shows that analysing bacterial DNA data can be used to screen soil quality. Video Abstract.

Effects of Silver Nanoparticles and Ions Exposure on the Soil Invertebrates Folsomia candida and Enchytraeus crypticus.

The aim of the study was to assess the effects of silver nanoparticles (AgNPs1 = 2.7 d·nm, AgNPs2 = 6.5 d·nm) and silver nitrate (AgNO3) on Enchytraeus crypticus and Folsomia candida using toxicity tests (OECD Guideline 220, 232). A 28-day chronic toxicity study was performed to evaluate the reproduction and mortality rate. E. crypticus reproduction was more sensitive to AgNO3 with a 28dEC50 of 86.40 (62.52-119.4) mg·kg-1 dry weight (d.w.) compared to AgNPs1 (28dEC50 = 119.3 (60.4-235.6) mg·kg-1 d.w). Similarly, the reproduction of F. candida was inhibited the most by AgNO3 with a 28dEC50 of 126.2 (104.2-152.9) mg·kg-1 d.w. followed by AgNPs1 (28dEC50 = 158.7 (64.05-393.2) mg·kg-1 d.w.) and AgNPs2 (28dEC50 = 206.4 (181.9-234.1) mg·kg-1 d.w.). No mortalities were observed for tested soil invertebrates exposed to AgNPs at concentrations up to 166 mg·kg-1 d.w. of AgNPs1 and 300 mg·kg-1 d.w. of AgNPs2, respectively. It was found that silver ions are more toxic in comparison with AgNPs.

Ecological criteria for zinc in Chinese soil as affected by soil properties.

The increasing accumulation of zinc (Zn) in agricultural soils has led to the need to assess the potential risk of this element for terrestrial organisms. However, the soil ecological criteria in agricultural soil as a function of soil properties have been sparsely reported. In the present study, we derived the ecological criteria (expressed as predicted no effect concentration (PNEC)) for Zn in soils, based on ecotoxicity data for 19 terrestrial species in Chinese soils, the effect of soil properties on Zn ecotoxicity, differences in species sensitivity, and differences between laboratory and realistic field conditions. First, all ecotoxicity data of Zn for terrestrial organisms in Chinese soils were collected and filtered with given criteria to obtain reliable database. Second, the ecotoxicity data were normalized using Zn ecotoxicity predictive models to eliminate the effect of soil properties on Zn ecotoxicity, and corrected with leaching and aging factors to minimize the differences in Zn ecotoxicity under laboratory and field conditions. Then, species sensitivity distribution (SSD) curves were generated with a Burr Ⅲ function based on corrected ecotoxicity data. The concentration of Zn in soil that provides ecological safety for (100 - x)% of species (HCx), was calculated from the SSD curve and HC5 was used for estimation of PNEC. Finally, we developed the predictive models for HCx by quantifying the relationship between the Zn HCx and soil properties. Results showed that soil pH was the most crucial factor affecting Zn HCx values, with HC5 values varying from 38.3 mg/kg in an acidic soil to 263.3 mg/kg in an alkaline calcareous soil. Both the two-factor (soil pH and OC) and the three-factor (soil pH, OC and CEC) models predicted HCx values well, with determination coefficients (R2) of 0.941-0.959 and 0.978-0.982, respectively. This study provides a scientific and reliable basis for the improvement of ecological risk assessment and the establishment of soil environmental quality standards.

Phosphorus sorption and availability in an andosol after a decade of organic or mineral fertilizer applications: Importance of pH and organic carbon modifications in soil as compared to phosphorus accumulation.

The effect of organic fertilizers on soil phosphorus (P) availability is usually mainly associated with the rate and forms of P applied, while they also alter the soil physical-chemical properties, able to change P availability. We aimed to highlight the impact of pH and organic C modifications in soil on the inorganic P (Pi) sorption capacity and availability as compared to the effect of P accumulation after mineral or organic fertilizers. We conducted a 10-years-old field experiment on an andosol and compared fields that had been amended with mineral or organic (dairy slurry and manure compost) fertilizers against a non-fertilized control. Water and Olsen extractions and Pi sorption experiments were realized on soils sampled after 6 and 10 years of trial. We also realized an artificial and ex situ alkalization of the control soil to isolate the effect of pH on Pi sorption capacity. Organic fertilizer application increased total P, pH, and organic C in soil. Pi-Olsen increased mainly with soil total P (r2 adj = 0.79), while Pi-water increased jointly with soil total P and pH (r2 adj = 0.85). The Pi sorption capacity decreased with organic fertilizer application. Artificial and ex situ alkalization of the control soil showed that Pi sorption capacity decreased with increasing pH. Our study demonstrated that, beyond the P fertilization rate, the increase in organic C content and even more so in pH induced by a decade of organic fertilizer applications in soil decreased the Pi sorption capacity and consequently increased Pi-water in soil.

Cropland acidification increases risk of yield losses and food insecurity in China.

Distinct cropland acidification has been reported in China due to nitrogen (N) fertilizer overuse. However, the impacts on food production and thereby on food security are largely unknown. Yield losses in the period 1980-2050 were therefore assessed by simulating soil pH changes combined with derived pH-yield relationships for wheat, maize and rice. If the N fertilizer input continues to increase at 1% annually, the predicted average soil pH decline is about one unit and relative yield losses are expected to increase from approximately 4%-24% during 2010-2050. If the N fertilizer increase stops in 2020 (N2020), the expected losses are approximately 16% in 2050, which is comparable to a scenario of 100% crop residue return (100%RR). However, if 30% of the N fertilizer is replaced by manure N (30%MR), the losses reduce to near 5% in 2050. Soil acidification was predicted to reverse and expected losses are only 2.5% in 2050 in a combined scenario of N2020, 100%RR and 30%MR. Our results illustrate the potential food insecurity induced by cropland acidification and address the necessity of mitigation.

A comparison of different solarisation systems and their impacts on soil thermal characteristics-an application in cultivated soils close to Baghdad, a highly populated city in Iraq.

Solarisation application by mulching the soil with a polyethene plastic film has a significant influence on soil thermal characteristics (TCs), which, in turn, show a strong impact on soil energy balance and agricultural productivity. In countries like Iraq with highly populated cities, such as Baghdad, that need large quantities of agriproducts, this kind of clean energy should play a key role in sustainable agricultural production. However, little is known about the effects of different soil solarisation systems in specific cultivated fields for this country characterised by an arid climate and silty clay soils. Therefore, an experimental study was conducted to investigate changes in soil TCs under different soil solarisation systems (black and clear plastics) at three different soil depths in a two-factor factorial design. Also, both the black and clear plastic plots were compared with a control (without mulch) plot treatment. Three different soil TCs were assessed, namely soil thermal flux (qℎ), soil thermal conductivity (k), and soil volumetric heat capacity (Cv). The results of this study indicated that the soil solarisation application had a significant influence on soil TCs. Soil qℎ decreased with increasing soil depth, while k and Cv exhibited an opposite trend. The black plastic mulch treatment produced higher soil qℎ, k, and Cv values than both the clear plastic and the control treatments. Moreover, high diurnal variability of the TCs was also registered, and the clear plastic conserved a higher temperature than the black one during the night hours. During daylight, the black mulch reached a maximum temperature of 70 °C. It is recommended that more research should be conducted to get new insights on the interplay of the different seasons, and different crops and soil types.

Major factors dominating the fate of dibutyl phthalate in agricultural soils.

Dibutyl phthalate (DBP) is a ubiquitous soil contaminant. We have investigated the sorption, degradation and residue of DBP in 20 types of agricultural soils and aimed to identify the major soil properties that dominate the fate of DBP. Sorption isotherms of DBP in all soils were fitted well with the Freundlich model. The sorption coefficient (Kf) varied between 3.99 and 36.1 mg1-1/nL1/n/kg. Path analysis indicated that 59.9% of variation in Kf could be explained by the combination of pH, organic carbon (OC) and clay content. Degradation of DBP in the 20 soils was well described by the first-order kinetic model, with half-lives (t1/2) ranging from 0.430 to 4.99 d. The residual DBP concentration after 60 d of incubation (R60) ranged from 0.756 to 2.15 mg/kg and the residual rates ranged from 3.97% to 9.63%. The Kf value was significantly positively correlated with t1/2 and R60. Moreover, soil pH, microbial biomass carbon (Cmic) and OC were identified as dominating factors that explained 84.4% of variation in t1/2. The R60 data indicated 72.2% of its variability attributable to the combination of OC and Cmic. The orders of the relative importance of dominating factors on the Kf, t1/2 and R60 were OC > pH > clay, Cmic > pH > OC and OC > Cmic, respectively. This work contributes to better understand the fate of DBP in soils and make scientific decisions about accelerating its dissipation in different soils.

Mycorrhizal types differ in ecophysiology and alter plant nutrition and soil processes.

Mycorrhizal fungi benefit plants by improved mineral nutrition and protection against stress, yet information about fundamental differences among mycorrhizal types in fungi and trees and their relative importance in biogeochemical processes is only beginning to accumulate. We critically review and synthesize the ecophysiological differences in ectomycorrhizal, ericoid mycorrhizal and arbuscular mycorrhizal symbioses and the effect of these mycorrhizal types on soil processes from local to global scales. We demonstrate that guilds of mycorrhizal fungi display substantial differences in genome-encoded capacity for mineral nutrition, particularly acquisition of nitrogen and phosphorus from organic material. Mycorrhizal associations alter the trade-off between allocation to roots or mycelium, ecophysiological traits such as root exudation, weathering, enzyme production, plant protection, and community assembly as well as response to climate change. Mycorrhizal types exhibit differential effects on ecosystem carbon and nutrient cycling that affect global elemental fluxes and may mediate biome shifts in response to global change. We also note that most studies performed to date have not been properly replicated and collectively suffer from strong geographical sampling bias towards temperate biomes. We advocate that combining carefully replicated field experiments and controlled laboratory experiments with isotope labelling and -omics techniques offers great promise towards understanding differences in ecophysiology and ecosystem services among mycorrhizal types.

Disposición inadecuada de medicamentos por pacientes o consumidores en su hogar; una revisión sistematica / Inadequate disposal of medications by patients or consumers in your home; a systematic review

Introducción: Cada año se incrementan los volúmenes de medicamentos utilizados, ocasionando una acumulación en los hogares de pacientes y clientes, que luego son desechados de manera inadecuada, convirtiéndose en un riesgo para el ambiente y la salud pública. Se han encontrado residuos en pequeñas cantidades de productos farmacéuticos en medios acuáticos y suelos, los cuales se acumulan en tejidos de seres vivos y producen efectos tóxicos que promueven enfermedades. Objetivo: Realizar una revisión sistemática de estudios basados en encuestas de hogares sobre la disposición de medicamentos en el hogar, así como del conocimiento sobre el daño potencial al ambiente, con un aporte para la reducción o remediación del problema. Método: Fueron revisados 442 estudios que investigaron la disposición de medicamentos vencidos, dañados o sin uso, por pacientes o consumidores en sus casas. Se utilizó la metodología de Campbell Collaboration con búsquedas en bases de datos y mediante palabras claves, se identificaron 47 publicaciones que por un proceso de inclusión y exclusión, fueron seleccionados 20 trabajos que contienen un análisis estadístico de resultados de encuestas en hogares. Resultados: Se presentan resultados de encuestas a 8 267 hogares, donde en promedio el 87,7 % mantienen medicamentos en sus casas, siendo el 57,4 % sin uso o vencidos, y 74,6 % son dispuestos inadecuadamente. Conclusiones: Existe un desconocimiento del impacto ambiental de la disposición inapropiada de medicinas en el hogar, sin embargo, al tomar conciencia del peligro, hay interés de participar en programas para reducir el problema.

Legal measures to prevent and manage soil contamination and to increase food safety for consumer health: The case of Spain.

This article contains a brief overview of the European and Spanish environmental law framework for the prevention of soil contamination, for the management of contaminated soils and for consumers health protection in relation to agricultural crops. Some important aspects of the legislative framework for the prevention and management of soil contamination include recognising the possible risk to both human health and ecosystems that certain agricultural and industrial activities pose given the use of organic and inorganic chemical substances of a hazardous nature and pathogenic microorganisms. It is worth highlighting the milestone that many national constitutions include about the right to the environment. This right entails the obligation to protect it and to, therefore, protect soil from any degradation, including contamination. Legislation that protects soil from contamination and, consequently human health and ecosystems, is related mainly to agricultural activities (use of sewage sludge on farmlands, use of wastewater for irrigation, use of organic fertilisers and pesticides), and to industrial and commercial soil-contaminating activities. Consumer protection may be achieved through a legal system of environmental liability, specific measures to prevent contaminants entering soil, managing contaminated soils and a food traceability system. It is crucial to make the penalties for soil contamination offenses, and for violators of protective prohibitions, effective, proportionate and dissuasive. Global standards and guidelines on soil contamination could provide national legislative systems with substantive and procedural legal mechanisms to help prevent and manage soil contamination.

Effect of sodium concentration on mobilization and fate of trace metals in standard OECD soil.

The effect of different Na concentrations on the fate of trace metals (Cd, Cu, Ni, Zn) in standard OECD soil was evaluated by performing soil leaching column experiments. Five Na concentrations added in synthetic irrigation water (0, 1, 5, 10, 50 mM) were studied in order to evaluate the fate of the metals contained in both the irrigation water leachate and the soil layer. In all experiments, metals mostly accumulated on the top soil layer (0-0.5 cm), at variable concentrations according to the Na content in the artificial irrigation water. Nevertheless, concentration peaks of metal contamination occurred at different sampling time in the soil leachates depending on the metal and on influent water sodicity. Peaks of metals in the leachate appeared simultaneously with the release of organic matter and/or release of Al, suggesting significant involvement of colloids in metals transport. Sodium concentration (10-50 mM) was demonstrated to highly reduce colloidal mobilization leading to the accumulation of more than 95% of the influent metal in the top soil layer. Conversely, low Na concentrations (1-5 mM) favored colloidal transport leading to the recovery of metals in the soil leachates.