Preparation of amphiphilic polyquaternium nanofiber films with antibacterial activity via environmentally friendly microfluidic-blow-spinning for green food packaging applications.

Green food packaging plays an important role in environmental protection and sustainable development. Therefore, it is advisable to employ low-energy consumption manufacturing techniques, select environmentally friendly materials, and focus on cost-effectiveness with high production yields during the production process. In this study, an amphiphilic polyquaternium called PBzCl was proposed and synthesized by free radical polymerization of cost-efficient quaternary ammonium salts and methacrylate monomers. Then, biodegradable PCL and PVP were used to rapidly prepare the PBzCl@PCL/PVP nanofiber films via environmentally friendly microfluidic-blow-spinning (MBS). The best antibacterial effect was observed at a PBzCl loading concentration of 13.5%, and the PBzCl@PCL/PVP nanofiber films had 91% and 100% antibacterial rates against Escherichia coli and Staphylococcus aureus, respectively. Besides, the loading of PBzCl improved the water stability of the PCL/PVP nanofiber films, and the films also showed excellent biocompatibility. Overall, PBzCl@PCL/PVP nanofibre films have promising food packaging potential.

Fabrication of antimicrobial PCL/EC nanofibrous films containing natamycin and trans-cinnamic acid by microfluidic blow spinning for fruit preservation.

Fruit is susceptible to various postharvest pathogens; thus, the development of multifunctional preservation materials that can achieve the broad-spectrum inhibition of different pathogens is a current research hotspot. Here, microfluidic blow spinning was used to create a biodegradable polycaprolactone/ethyl cellulose (PCL/EC) nanofibrous film that incorporated two naturally-sourced compounds, natamycin and trans-cinnamic acid, resulting in multi-microbial inhibition. The PCL/EC-based film had a smooth and even morphology, indicating the favorable integration of PCL and EC. After the incorporation of ingredients, the film exhibited good inhibitory activity against Escherichia coli, Staphylococcus aureus, and Botrytis cinerea, and it had finer fiber diameters, higher permeability, and antioxidant properties. We further demonstrated that strawberries that were padded with the film had good resistance to Botrytis cinerea. Also, the film did not interference with the qualities of the strawberries during storage. The study demonstrates a promising application for multi-antimicrobial and bio-friendly packaging materials in postharvest fruit preservation.