A novel recycling way of blast furnace dust from steelworks: Electrocoagulation coupled micro-electrolysis system in indigo wastewater treatment.

In this study, a novel electrocoagulation electrode, based on blast furnace dust (BFD) from steelworks waste, was prepared for indigo wastewater treatment, and the performance was compared with different ratios of Fe-C composite electrodes. The BFD electrode exhibited great electrochemical performance and removal effect. The presence of Fe-C micro-electrolysis in the electrocoagulation system of the BFD electrode was demonstrated by FT-IR, Raman, ESR, and quenching experiments. Density Functional Theory (DFT) calculations further demonstrated that the iron-carbon ratio could influence the degree of O-O breaking and enhance ·OH generation. Finally, the BFD electrode's operating parameters were perfected, and the COD removal and decolorization could reach 75.7% and 95.8% within 60 min, respectively. Fe-C composite electrodes reduce energy consumption compared with the traditional Fe/Al electrode and have a lower production cost, which provides a potential way to recycle and reuse the resources of solid waste in steelworks, the concept of "waste controlled by waste" is realized.

Electrochemical methods for landfill leachate treatment: A review on electrocoagulation and electrooxidation.

Landfill leachate is a kind of difficult-to-degrade wastewater with complex water qualities. Waste filtrate cannot be thoroughly treated by traditional biological, physical and chemical methods. In the past five years, electrochemical methods have attracted widespread attention in the treatment of landfill leachate. The article pointed out that for the colloidal/suspended particles in the landfill leachate, using of electrocoagulation can achieve a good treatment effect. Aiming at the characteristics of the dissolved organic matter in the landfill leachate and the high concentration of chloride ions, a more efficient removal can be available by using of electrooxidation. In this review, the latest achievements and basic principles of electrocoagulation and electrooxidation have been introduced. Meanwhile, the influence of different process parameters on these two electrochemical methods was summarized. It also reviewed the effect of electrochemical technology as an independent system or combined with biological and physical chemical processes on the treatment of landfill leachate, as well as the cost of various laboratory scales. Finally, several main problems and challenges encountered by electrochemical methods were briefly discussed, and the prospects for new development and future research were also provided.