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1.
Carbohydr Polym ; 337: 122112, 2024 Aug 01.
Article En | MEDLINE | ID: mdl-38710545

The growing concerns on environmental pollution and sustainability have raised the interest on the development of functional biobased materials for different applications, including food packaging, as an alternative to the fossil resources-based counterparts, currently available in the market. In this work, functional wood inspired biopolymeric nanocomposite films were prepared by solvent casting of suspensions containing commercial beechwood xylans, cellulose nanofibers (CNF) and lignosulfonates (magnesium or sodium), in a proportion of 2:5:3 wt%, respectively. All films presented good homogeneity, translucency, and thermal stability up to 153 °C. The incorporation of CNF into the xylan/lignosulfonates matrix provided good mechanical properties to the films (Young's modulus between 1.08 and 3.79 GPa and tensile strength between 12.75 and 14.02 MPa). The presence of lignosulfonates imparted the films with antioxidant capacity (DPPH radical scavenging activity from 71.6 to 82.4 %) and UV barrier properties (transmittance ≤19.1 % (200-400 nm)). Moreover, the films obtained are able to successfully delay the browning of packaged fruit stored over 7 days at 4 °C. Overall, the obtained results show the potential of using low-cost and eco-friendly resources for the development of sustainable active food packaging materials.


Cellulose , Food Packaging , Lignin , Lignin/analogs & derivatives , Nanocomposites , Nanofibers , Tensile Strength , Wood , Xylans , Food Packaging/methods , Lignin/chemistry , Nanocomposites/chemistry , Cellulose/chemistry , Cellulose/analogs & derivatives , Wood/chemistry , Nanofibers/chemistry , Xylans/chemistry , Antioxidants/chemistry , Fruit/chemistry
2.
Food Res Int ; 186: 114340, 2024 Jun.
Article En | MEDLINE | ID: mdl-38729695

Fruits are essential sources of nutrients in our daily diet; however, their spoilage is often intensified by mechanical damage and the ethylene phytohormone, resulting in significant economic losses and exacerbating hunger issues. To address these challenges, this study presented a straightforward in situ synthesis protocol for producing Z/SOPPU foam, a 3D porous-structured fruit packaging. This innovative packaging material offered advanced ethylene-adsorbing and cushioning capabilities achieved through stirring, heating, and standing treatments. The results demonstrated that the Z/SOPPU foam, with its porous structure, served as an excellent packaging material for fruits, maintaining the intact appearance of tomatoes even after being thrown 72 times from a height of 1.5 m. Additionally, it exhibited desirable hydrophobicity (contact angle of 114.31 ± 0.82°), degradability (2.73 ± 0.88 % per 4 weeks), and efficient ethylene adsorption (adsorption rate of 13.2 ± 1.7 mg/m3/h). These remarkable characteristics could be attributed to the unique 3D micron-porous configuration, consisting of soybean oil polyol polyurethane foam for mechanical strain cushioning and zein for enhanced ethylene adsorption efficiency. Overall, this research offers an effective and original approach to the rational design and fabrication of advanced bio-based fruit packaging.


Ethylenes , Food Packaging , Fruit , Polyurethanes , Soybean Oil , Zein , Ethylenes/chemistry , Polyurethanes/chemistry , Food Packaging/methods , Porosity , Fruit/chemistry , Soybean Oil/chemistry , Zein/chemistry , Adsorption , Polymers/chemistry , Solanum lycopersicum/chemistry , Hydrophobic and Hydrophilic Interactions
3.
Food Res Int ; 187: 114390, 2024 Jul.
Article En | MEDLINE | ID: mdl-38763652

In light of the commendable advantages inherent in natural polymers such as biocompatibility, biodegradability, and cost-effectiveness, researchers are actively engaged in the development of biopolymer-based biodegradable food packaging films (BFPF). However, a notable limitation is that most biopolymers lack intrinsic antimicrobial activity, thereby restricting their efficacy in food preservation. To address this challenge, various active substances with antibacterial properties have been explored as additives to BFPF. Among these, ε-polylysine has garnered significant attention in BFPF applications owing to its outstanding antibacterial properties. This study provides a brief overview of the synthesis method and chemical properties of ε-polylysine, and comprehensively examines its impact as an additive on the properties of BFPF derived from diverse biopolymers, including polysaccharides, proteins, aliphatic polyesters, etc. Furthermore, the practical applications of various BFPF functionalized with ε-polylysine in different food preservation scenarios are summarized. The findings underscore that ε-polylysine, functioning as an antibacterial agent, not only directly enhances the antimicrobial activity of BFPF but also serves as a cross-linking agent, interacting with biopolymer molecules to influence the physical and mechanical properties of BFPF, thereby enhancing their efficacy in food preservation.


Anti-Bacterial Agents , Food Packaging , Food Preservation , Polylysine , Polylysine/chemistry , Food Packaging/methods , Biopolymers/chemistry , Food Preservation/methods , Anti-Bacterial Agents/pharmacology , Anti-Bacterial Agents/chemistry , Edible Films
4.
Carbohydr Polym ; 338: 122218, 2024 Aug 15.
Article En | MEDLINE | ID: mdl-38763705

Here, biogenic and multifunctional active food coatings and packaging with UV shielding and antimicrobial properties were structured from the aqueous dispersion of an industrial byproduct, suberin, which was stabilized with amphiphilic cellulose nanofibers (CNF). The dual-functioning CNF, synthesized in a deep eutectic solvent, functioned as an efficient suberin dispersant and reinforcing agent in the packaging design. The nanofibrillar percolation network of CNF provided a steric hindrance against the coalescence of the suberin particles. The low CNF dosage of 0.5 wt% resulted in dispersion with optimal viscosity (208.70 Pa.s), enhanced stability (instability index of <0.001), and reduced particle size (9.37 ± 2.43 µm). The dispersion of suberin and CNF was further converted into self-standing films with superior UV-blocking capability, good thermal stability, improved hydrophobicity (increase in water contact angle from 61° ± 0.15 to 83° ± 5.11), and antimicrobial properties against gram-negative bacteria. Finally, the synergistic bicomponent dispersions were demonstrated as fruit coatings for bananas and packaging for strawberries to promote their self-life. The coatings and packaging considerably mitigated fruit deterioration and improved their freshness by preventing moisture loss and microbial attack. This sustainable approach is expected to pave the way toward advanced, biogenic, and active food packaging based on widely available bioresources.


Cellulose , Food Packaging , Lipids , Nanofibers , Wood , Nanofibers/chemistry , Cellulose/chemistry , Food Packaging/methods , Wood/chemistry , Lipids/chemistry , Hydrophobic and Hydrophilic Interactions , Anti-Bacterial Agents/chemistry , Anti-Bacterial Agents/pharmacology , Viscosity , Musa/chemistry , Water/chemistry , Gram-Negative Bacteria/drug effects , Fruit/chemistry
5.
Carbohydr Polym ; 338: 122205, 2024 Aug 15.
Article En | MEDLINE | ID: mdl-38763727

Developing multifunctional films with antibacterial, antioxidant, and sustained-release properties is a robust strategy for preventing contamination of perishable fruits by foodborne microorganisms. This study engineered a sustained-release biodegradable antibacterial film loaded with EGCG (Pickering emulsion (PE)/α-Cyclodextrin (α-CD)/Konjac glucomannan (KGM)) through multi-strategy cross-linking for fruit preservation. EGCG is stabilized using PE and incorporated into the α-CD/KGM inclusion compound; the unique structure of α-CD enhances EGCG encapsulation, while KGM provides the film toughness and surface adhesion. The composite film's physicochemical properties, antioxidant, bacteriostatic and biodegradability were studied. Results showed that Pickering emulsions with 3 % oil phase exhibited excellent stability. Moreover, α-CD introduction increased the loading and sustained release of EGCG from the film, and its concentration significantly affected the light transmission, thermal stability, mechanical strength, mechanical characteristics and antioxidant capacity of the composite membrane. Antioxidant and antimicrobial activities of the composite film increased significantly with increasing α-CD concentration. Application of the film to tomatoes and strawberries effectively inhibited Escherichia coli and Staphylococcus aureus growth, prolonging the shelf-life of the fruits. Notably, the composite film exhibits superior biodegradability in soil. This EGCG-loaded PE/α-CD/KGM composite film is anticipated to be a multifunctional antimicrobial preservation material with sustained-release properties and biodegradable for perishable food applications.


Anti-Bacterial Agents , Antioxidants , Catechin , Emulsions , Escherichia coli , Fruit , Mannans , alpha-Cyclodextrins , alpha-Cyclodextrins/chemistry , Catechin/analogs & derivatives , Catechin/chemistry , Catechin/pharmacology , Mannans/chemistry , Mannans/pharmacology , Anti-Bacterial Agents/pharmacology , Anti-Bacterial Agents/chemistry , Fruit/chemistry , Emulsions/chemistry , Antioxidants/chemistry , Antioxidants/pharmacology , Escherichia coli/drug effects , Food Preservation/methods , Staphylococcus aureus/drug effects , Food Packaging/methods , Microbial Sensitivity Tests , Cross-Linking Reagents/chemistry , Drug Liberation
6.
Compr Rev Food Sci Food Saf ; 23(3): e13373, 2024 May.
Article En | MEDLINE | ID: mdl-38778547

The environmental challenges posed by plastic pollution have prompted the exploration of eco-friendly alternatives to disposable plastic packaging and utensils. Paper-based materials, derived from renewable resources such as wood pulp, non-wood pulp (bamboo pulp, straw pulp, reed pulp, etc.), and recycled paper fibers, are distinguished by their recyclability and biodegradability, making them promising substitutes in the field of plastic food packaging. Despite their merits, challenges like porosity, hydrophilicity, limited barrier properties, and a lack of functionality have restricted their packaging potential. To address these constraints, researchers have introduced antimicrobial agents, hydrophobic substances, and other functional components to improve both physical and functional properties. This enhancement has resulted in notable improvements in food preservation outcomes in real-world scenarios. This paper offers a comprehensive review of recent progress in hydrophobic antimicrobial paper-based materials. In addition to outlining the characteristics and functions of commonly used antimicrobial substances in food packaging, it consolidates the current research landscape and preparation techniques for hydrophobic paper. Furthermore, the paper explores the practical applications of hydrophobic antimicrobial paper-based materials in agricultural produce, meat, and seafood, as well as ready-to-eat food packaging. Finally, challenges in production, application, and recycling processes are outlined to ensure safety and efficacy, and prospects for the future development of antimicrobial hydrophobic paper-based materials are discussed. Overall, the emergence of hydrophobic antimicrobial paper-based materials stands out as a robust alternative to plastic food packaging, offering a compelling solution with superior food preservation capabilities. In the future, paper-based materials with antimicrobial and hydrophobic functionalities are expected to further enhance food safety as promising packaging materials.


Anti-Infective Agents , Food Packaging , Hydrophobic and Hydrophilic Interactions , Paper , Food Packaging/methods , Anti-Infective Agents/chemistry , Anti-Infective Agents/pharmacology , Food Preservation/methods
7.
Int J Biol Macromol ; 268(Pt 2): 131936, 2024 May.
Article En | MEDLINE | ID: mdl-38692533

With the increasing environmental and ecological problems caused by petroleum-based packaging materials, the focus has gradually shifted to natural resources for the preparation of functional food packaging materials. In addition to biodegradable properties, nanocellulose (NC) mechanical properties, and rich surface chemistry are also fascinating and desired to be one of the most probable green packaging materials. In this review, we firstly introduce the recent progress of novel applications of NC in food packaging, including intelligent packaging, nano(bio)sensors, and nano-paper; secondly, we focus on the modification techniques of NC to summarize the properties (antimicrobial, mechanical, hydrophobic, antioxidant, and so on) that are required for food packaging, to expand the new synthetic methods and application areas. After presenting all the latest advances related to material design and sustainable applications, an overview summarizing the safety of NC is presented to promote a continuous and healthy movement of NC toward the field of truly sustainable packaging.


Cellulose , Food Packaging , Food Packaging/methods , Cellulose/chemistry , Nanostructures/chemistry , Antioxidants/chemistry , Anti-Infective Agents/chemistry , Anti-Infective Agents/pharmacology , Hydrophobic and Hydrophilic Interactions
8.
Int J Biol Macromol ; 268(Pt 2): 131940, 2024 May.
Article En | MEDLINE | ID: mdl-38692554

Composite edible films were developed by casting method using sunnhemp protein isolate (SHPI) and potato starch (PS) at various proportions (100:0, 90:10, 80:20; 70:30, 60:40, and 50:50) containing glycerol as a plasticizer and clove oil. All the edible films were evaluated for thickness, moisture content, solubility, swelling ratio, water activity. Further characterization of edible films was done on the basis of mechanical, optical, thermal and structural attributes along with morphology. Among all the films, composite film containing 50 % SHPI, 50 % PS and 1 % clove oil were having better characteristics. The solubility and WVP decreased, while the tensile strength and elongation at break of composite film increased with the inclusion of potato starch and clove oil. Intermolecular interactions in the composite film matrix were confirmed by FTIR and XRD analysis. SEM images confirmed the structural compactness and integrity of all the developed films. The amino acid composition of edible films indicated presence of most of the essential amino acids. The present finding of this research work shows that the utilization of sunnhemp protein in the development of biocomposite edible films represents an alternative opportunity of sustainable edible food packaging.


Amino Acids , Clove Oil , Edible Films , Solanum tuberosum , Solubility , Starch , Starch/chemistry , Solanum tuberosum/chemistry , Clove Oil/chemistry , Amino Acids/chemistry , Amino Acids/analysis , Food Packaging/methods , Plant Proteins/chemistry , Tensile Strength , Biopolymers/chemistry , Water/chemistry
9.
Molecules ; 29(9)2024 Apr 27.
Article En | MEDLINE | ID: mdl-38731511

Alginate films plasticized with glycerol and enriched in raspberry and/or black currant seed oils were prepared via casting solution techniques. The intention was to create active films for food packaging where antioxidants in a film would deactivate oxidants in a packed product or its surroundings, improving conditions inside packaging and extending the shelf life of such a product. The prepared materials were characterized by physicochemical, spectroscopic, mechanical, water vapor transmission (WVTR), and antioxidant activity analysis. Infrared spectra of the alginate films with oils were similar to those without the additive; the band with a maximum at about 1740 cm-1 stood out. The prepared materials with oils were thicker, contained less water, were more yellow, and were less permeable to water vapor. Moreover, the presence of the oil in the films resulted in a slightly lower Young's modulus and lower stress at break values but higher strain at break. The antioxidant capacity of raspberry seed oil itself was about five times higher than that of black currant seed oil, and a similar trend was noticed for films modified with these oils. The results indicated that both oils could be used as active substances with antioxidant properties in food packaging.


Alginates , Antioxidants , Food Packaging , Plant Oils , Ribes , Rubus , Seeds , Food Packaging/methods , Alginates/chemistry , Antioxidants/chemistry , Antioxidants/pharmacology , Plant Oils/chemistry , Seeds/chemistry , Rubus/chemistry , Ribes/chemistry , Steam
10.
Sci Rep ; 14(1): 10825, 2024 05 11.
Article En | MEDLINE | ID: mdl-38734808

This study developed a kind of PEG-crosslinked O-carboxymethyl chitosan (O-CMC-PEG) with various PEG content for food packaging. The crosslinking agent of isocyanate-terminated PEG was firstly synthesized by a simple condensation reaction between PEG and excess diisocyanate, then the crosslink between O-carboxymethyl chitosan (O-CMC) and crosslinking agent occurred under mild conditions to produce O-CMC-PEG with a crosslinked structure linked by urea bonds. FT-IR and 1H NMR techniques were utilized to confirm the chemical structures of the crosslinking agent and O-CMC-PEGs. Extensive research was conducted to investigate the impact of the PEG content (or crosslinking degree) on the physicochemical characteristics of the casted O-CMC-PEG films. The results illuminated that crosslinking and components compatibility could improve their tensile features and water vapor barrier performance, while high PEG content played the inverse effects due to the microphase separation between PEG and O-CMC segments. The in vitro degradation rate and water sensitivity primarily depended on the crosslinking degree in comparison with the PEG content. Furthermore, caused by the remaining -NH2 groups of O-CMC, the films demonstrated antibacterial activity against Escherichia coli and Staphylococcus aureus. When the PEG content was 6% (medium crosslinking degree), the prepared O-CMC-PEG-6% film possessed optimal tensile features, high water resistance, appropriate degradation rate, low water vapor transmission rate and fine broad-spectrum antibacterial capacity, manifesting a great potential for application in food packaging to extend the shelf life.


Anti-Bacterial Agents , Chitosan , Escherichia coli , Food Packaging , Polyethylene Glycols , Chitosan/chemistry , Chitosan/analogs & derivatives , Chitosan/pharmacology , Food Packaging/methods , Anti-Bacterial Agents/chemistry , Anti-Bacterial Agents/pharmacology , Polyethylene Glycols/chemistry , Escherichia coli/drug effects , Cross-Linking Reagents/chemistry , Spectroscopy, Fourier Transform Infrared , Staphylococcus aureus/drug effects , Microbial Sensitivity Tests , Tensile Strength
11.
Int J Mol Sci ; 25(9)2024 Apr 26.
Article En | MEDLINE | ID: mdl-38731949

To enrich the properties of polylactic acid (PLA)-based composite films and improve the base degradability, in this study, a certain amount of poly(propylene carbonate) (PPC) was added to PLA-based composite films, and PLA/PPC-based composite films were prepared by melt blending and hot-press molding. The effects of the introduction of PPC on the composite films were analyzed through in-depth studies on mechanical properties, water vapor and oxygen transmission rates, thermal analysis, compost degradability, and bacterial inhibition properties of the composite films. When the introduction ratio coefficient of PPC was 30%, the tensile strength of the composite film increased by 19.68%, the water vapor transmission coefficient decreased by 14.43%, and the oxygen transmission coefficient decreased by 18.31% compared to that of the composite film without PPC, the cold crystallization temperature of the composite film increased gradually from 96.9 °C to 104.8 °C, and PPC improved the crystallization ability of composite film. The degradation rate of the composite film with PPC increased significantly compared to the previous one, and the degradation rate increased with the increase in the PPC content. The degradation rate was 49.85% and 46.22% faster on average than that of the composite film without PPC when the degradation was carried out over 40 and 80 days; the composite film had certain inhibition, and the maximum diameter of the inhibition circle was 2.42 cm. This study provides a strategy for the development of PLA-based biodegradable laminates, which can promote the application of PLA-based laminates in food packaging.


Polyesters , Propane/analogs & derivatives , Tensile Strength , Polyesters/chemistry , Polypropylenes/chemistry , Food Packaging/methods , Steam , Polymers/chemistry , Anti-Bacterial Agents/chemistry , Anti-Bacterial Agents/pharmacology , Temperature
12.
Int J Biol Macromol ; 268(Pt 1): 131464, 2024 May.
Article En | MEDLINE | ID: mdl-38702248

Global concerns over environmental damage caused by non-biodegradable single-use packaging have sparked interest in developing biomaterials. The food packaging industry is a major contributor to non-degradable plastic waste. This study investigates the impact of incorporating different concentrations of polyvinyl alcohol (PVA) and yerba mate extract as a natural antioxidant into carboxymethyl cassava starch films to possibly use as active degradable packaging to enhance food shelf life. Films with starch and PVA blends (SP) at different ratios (SP radios of 100:0, 90:10, 80:20 and 70:30) with and without yerba mate extract (Y) were successfully produced through extrusion and thermoforming. The incorporation of up to 20 wt% PVA improved starch extrusion processing and enhanced film transparency. PVA played a crucial role in improving the hydrophobicity, tensile strength and flexibility of the starch films but led to a slight deceleration in their degradation in compost. In contrast, yerba mate extract contributed to better compost degradation of the blend films. Additionally, it provided antioxidant activity, particularly in hydrophilic and lipophilic food simulants, suggesting its potential to extend the shelf life of food products. Starch-PVA blend films with yerba mate extract emerged as a promising alternative for mechanically resistant and active food packaging.


Antioxidants , Food Packaging , Manihot , Plant Extracts , Polyvinyl Alcohol , Starch , Food Packaging/methods , Polyvinyl Alcohol/chemistry , Starch/chemistry , Starch/analogs & derivatives , Antioxidants/chemistry , Manihot/chemistry , Plant Extracts/chemistry , Ilex paraguariensis/chemistry , Tensile Strength , Hydrophobic and Hydrophilic Interactions , Mechanical Phenomena
13.
Molecules ; 29(10)2024 May 15.
Article En | MEDLINE | ID: mdl-38792175

Anthocyanin-rich steamed purple sweet potato (SPSP) is a suitable raw material to produce smart packaging films. However, the application of SPSP-based films is restricted by the low antimicrobial activity of anthocyanins. In this study, SPSP-based smart packaging films were produced by adding mandarin essential oil (MEO) as an antimicrobial agent. The impact of MEO content (3%, 6%, and 9%) on the structures, properties, and application of SPSP-based films was measured. The results showed that MEO created several pores within films and reduced the hydrogen bonding system and crystallinity of films. The dark purple color of the SPSP films was almost unchanged by MEO. MEO significantly decreased the light transmittance, water vapor permeability, and tensile strength of the films, but remarkably increased the oxygen permeability, thermal stability, and antioxidant and antimicrobial properties of the films. The SPSP-MEO films showed intuitive color changes at different acid-base conditions. The purple-colored SPSP-MEO films turned blue when chilled shrimp and pork were not fresh. The MEO content greatly influenced the structures, physical properties, and antioxidant and antimicrobial activities of the films. However, the MEO content had no impact on the color change ability of the films. The results suggested that SPSP-MEO films have potential in the smart packaging of protein-rich foods.


Food Packaging , Ipomoea batatas , Oils, Volatile , Permeability , Ipomoea batatas/chemistry , Oils, Volatile/chemistry , Oils, Volatile/pharmacology , Food Packaging/methods , Antioxidants/chemistry , Antioxidants/pharmacology , Anti-Infective Agents/chemistry , Anti-Infective Agents/pharmacology , Steam , Tensile Strength , Anthocyanins/chemistry , Anthocyanins/pharmacology , Color
14.
Int J Food Microbiol ; 418: 110713, 2024 Jun 16.
Article En | MEDLINE | ID: mdl-38718617

This research aimed to assess the potential of active food packaging as an innovative approach to enhance the quality of fresh food products. Specifically, our focus was on developing chitosan edible films combined with rosemary nanoemulsion (Ch-RNE) and carvacrol nano-emulsion (Ch-CNE) as effective antibacterial food packaging solutions. The efficacy of these films against artificially inoculated L. monocytogenes (NCTC 13372\ ATCC® 7644) as a Gram-positive bacterium, and S. enterica serovar Typhimurium (ATCC 14028) as a Gram-negative bacterium, in ground meat was investigated. The size of the prepared nano-emulsions was characterized using zeta sizer, FTIR and HRTEM. The MIC of both nano-emulsions against both pathogens was found to be 0.78 % and 1.56 %. Filmogenic mixtures were casted using these concentrations, which were then dried and evaluated for their physical and mechanical properties.


Anti-Bacterial Agents , Chitosan , Cymenes , Edible Films , Emulsions , Food Packaging , Listeria monocytogenes , Monoterpenes , Salmonella typhimurium , Cymenes/pharmacology , Chitosan/pharmacology , Chitosan/chemistry , Listeria monocytogenes/drug effects , Listeria monocytogenes/growth & development , Salmonella typhimurium/drug effects , Salmonella typhimurium/growth & development , Emulsions/pharmacology , Anti-Bacterial Agents/pharmacology , Anti-Bacterial Agents/chemistry , Food Packaging/methods , Monoterpenes/pharmacology , Rosmarinus/chemistry , Microbial Sensitivity Tests , Food Microbiology , Meat Products/microbiology , Food Preservation/methods
15.
Meat Sci ; 214: 109532, 2024 Aug.
Article En | MEDLINE | ID: mdl-38733667

This study aimed to clarify the effect of electrostatic spraying of lactic acid (LE) and ascorbic acid (AE) on vacuum-packaged beef aged at 10 °C. The physicochemical attributes, flavor profiles, and microbial diversities were evaluated. Beef steaks were electrostatically sprayed twice with 4% LE, 0.5% AE, or a mixture of them (LAE). Afterward, the beef was vacuum-packaged and aged. All treated beef exhibited a decrease in quality and sensory scores over time. At the end of the study period, the total viable count (TVC) and the total volatile basic nitrogen values in the control group (7.34 log CFU/g and 15.52 mg/100 g, respectively) were higher than those in the acid-treated groups. The LAE group exhibited the best color stability and the lowest TVC and Enterobacteriaceae counts after aging. High-throughput sequencing analysis revealed that acid types and electrostatic spray could change the microbiota structure. Leuconostoc was the dominant bacteria in the AE and LAE groups, while Enterococcus became the predominant bacteria in the NLE and LE groups with aging. This indicates that electrostatic spray combined with acid treatment can ensure beef quality and microbiological safety at mild temperatures.


Ascorbic Acid , Lactic Acid , Red Meat , Animals , Cattle , Red Meat/microbiology , Red Meat/analysis , Ascorbic Acid/pharmacology , Lactic Acid/pharmacology , Vacuum , Food Packaging/methods , Taste , Humans , Temperature , Color , Food Microbiology , Microbiota/drug effects , Bacteria/drug effects , Static Electricity , Food Storage
16.
Int J Food Microbiol ; 418: 110733, 2024 Jun 16.
Article En | MEDLINE | ID: mdl-38754173

This research aimed to evaluate the effects of the addition of active essential oil components (linalool and/or eugenol) to a pickle-based marinade on controlling spoilage and extending the shelf life of fresh beef stored under vacuum packaging at 4 °C. Linalool and eugenol were used either separately at a concentration of 0.2 % (w/w) or together (1:1 ratio) to preserve marinated beef under vacuum packaging for 15 days. Samples were assessed for pH, color, texture, oxidative degradation, and microbiological parameters. All marinades exhibited significantly lower TBARS values than the control sample. The addition of linalool or eugenol to the marinate showed a significant antibacterial effect on total aerobic mesophilic bacteria (TAMB), lactic acid bacteria (LAB), Pseudomonas spp., and total coliform, and the reductions in microbial counts are as follows: TAMB: 1.563 log CFU/g and 1.46 log CFU/g; Pseudomonas spp.: 1.303 log CFU/g and 1.08 log CFU/g; LAB: 0.323 log CFU/g and 0.357 log CFU/g. Marinated beef with linalool and/or eugenol was found to be effective against the growth of yeast and mold. The use of eugenol presented the most effective inhibition activity against yeast and mold by reducing the number of yeast and molds to an uncountable level on the 12th and 15th days of storage. Physicochemical analysis also showed that the addition of active essential oils to marinade did not cause any undesirable effects on the color and texture properties of beef samples. Therefore, the findings revealed that eugenol and linalool could be suitable alternatives for beef marination.


Eugenol , Food Packaging , Food Preservation , Oils, Volatile , Red Meat , Oils, Volatile/pharmacology , Food Packaging/methods , Cattle , Vacuum , Eugenol/pharmacology , Food Preservation/methods , Animals , Red Meat/microbiology , Food Microbiology , Acyclic Monoterpenes/pharmacology , Bacteria/drug effects , Bacteria/growth & development , Colony Count, Microbial , Food Storage , Monoterpenes/pharmacology
17.
Int J Biol Macromol ; 269(Pt 1): 132005, 2024 Jun.
Article En | MEDLINE | ID: mdl-38777686

To enhance the mechanics performance, sensitivity and response range of multi-responsive photonic films, herein, a facile method for fabricating multi-responsive films is demonstrated using the evaporative self-assembly of a mixture of grape skin red (GSR), cellulose nanocrystal (CNC), polyvinyl alcohol (PVA) and deep eutectic solvent (DES). The prepared materials exhibited excellent thermal stability, strain properties, solvent resistance, ultraviolet (UV) resistance and antioxidant activity. Compared to a pure PVA film, the presence of GSR strengthened the antioxidant property of the film by 240.1 % and provided excellent UV barrier capability. The additional cross-linking of DES and CNC promoted more efficient phase fusion, yielding a film strain of 41.5 %. The addition of hydrophilic compound GSR, wetting and swelling due to the DES and the surface inhomogeneity of the films rendered the multi-responsive films high sensitivity, wide response range and multi-cyclic stability in environments with varying pH and humidity. A sample application showed that a PVA/CNC/DES film has the potential to differentiate between fresh, sub-fresh and fully spoiled shrimps. The above results help in designing intelligent thin film materials that integrate antioxidant properties, which help in monitoring the changes in food freshness and food packaging.


Antioxidants , Cellulose , Nanoparticles , Polyvinyl Alcohol , Polyvinyl Alcohol/chemistry , Cellulose/chemistry , Nanoparticles/chemistry , Antioxidants/chemistry , Deep Eutectic Solvents/chemistry , Food Packaging/methods , Vitis/chemistry , Food Analysis/methods , Hydrogen-Ion Concentration
18.
Int J Biol Macromol ; 269(Pt 1): 132067, 2024 Jun.
Article En | MEDLINE | ID: mdl-38710257

Nowadays food safety and protection are a growing concern for food producers and food industry. The stability of food-grade materials is key in food processing and shelf life. Pickering emulsions (PEs) have gained significant attention in food regimes owing to their stability enhancement of food specimens. PE can be developed by high and low-energy methods. The use of PE in the food sector is completely safe as it uses solid biodegradable particles to stabilize the oil in water and it also acts as an excellent carrier of essential oils (EOs). EOs are useful functional ingredients, the inclusion of EOs in the packaging film or coating formulation significantly helps in the improvement of the shelf life of the packed food item. The highly volatile nature, limited solubility and ease of oxidation in light of EOs restricts their direct use in packaging. In this context, the use of PEs of EOs is suitable to overcome most of the challenges, Therefore, recently there have been many papers published on PEs of EOs including active packaging film and coatings and the obtained results are promising. The current review amalgamates these studies to inform about the chemistry of PEs followed by types of stabilizers, factors affecting the stability and different high and low-energy manufacturing methods. Finally, the review summarizes the recent advancement in PEs-added packaging film and their application in the enhancement of shelf life of food.


Emulsions , Food Packaging , Oils, Volatile , Food Packaging/methods , Oils, Volatile/chemistry , Emulsions/chemistry , Biopolymers/chemistry
19.
Int J Biol Macromol ; 269(Pt 2): 132129, 2024 Jun.
Article En | MEDLINE | ID: mdl-38718994

This Review presents an overview of all-organic nanocomposites, a sustainable alternative to organic-inorganic hybrids. All-organic nanocomposites contain nanocellulose, nanochitin, and aramid nanofibers as highly rigid reinforcing fillers. They offer superior mechanical properties and lightweight characteristics suitable for diverse applications. The Review discusses various methods for preparing the organic nanofillers, including top-down and bottom-up approaches. It highlights in situ polymerization as the preferred method for incorporating these nanomaterials into polymer matrices to achieve homogeneous filler dispersion, a crucial factor for realizing desired performance. Furthermore, the Review explores several applications of all-organic nanocomposites in diverse fields including food packaging, performance-advantaged plastics, and electronic materials. Future research directions-developing sustainable production methods, expanding biomedical applications, and enhancing resistance against heat, chemicals, and radiation of all-organic nanocomposites to permit their use in extreme environments-are explored. This Review offers insights into the potential of all-organic nanocomposites to drive sustainable growth while meeting the demand for high-performance materials across various industries.


Nanocomposites , Nanocomposites/chemistry , Polymers/chemistry , Organic Chemicals/chemistry , Food Packaging/methods , Nanofibers/chemistry , Inorganic Chemicals/chemistry
20.
Int J Biol Macromol ; 269(Pt 2): 132219, 2024 Jun.
Article En | MEDLINE | ID: mdl-38729475

The use of plant gum-based biodegradable bioplastic films as a packaging material is limited due to their poor physicochemical properties. However, combining plant gum with synthetic degradable polymer and some additives can improve these properties. Keeping in view, the present study aimed to synthesize a series of bioplastic films using Moringa oleifera gum, polyvinyl alcohol, glycerol, and citric acid via thermal treatment followed by a solution casting method. The films were characterized using analytical techniques such as FTIR, XRD, SEM, AFM, TGA, and DSC. The study examined properties such as water sensitivity, gas barrier attributes, tensile strength, the shelf life of food, and biodegradability. The films containing higher citric acid amounts showed appreciable %elongation without compromising tensile strength, good oxygen barrier properties, and biodegradation rates (>95%). Varying the amounts of glycerol and citric acid in the films broadened their physicochemical properties ranging from hydrophilicity to hydrophobicity and rigidity to flexibility. As all the films were synthesized using economical and environmentally safe materials, and showed better physicochemical and barrier properties, this study suggests that these bioplastic films can prove to be a potential alternative for various packaging applications.


Food Packaging , Moringa oleifera , Plant Gums , Polyvinyl Alcohol , Tensile Strength , Polyvinyl Alcohol/chemistry , Moringa oleifera/chemistry , Plant Gums/chemistry , Food Packaging/methods , Biodegradable Plastics/chemistry , Citric Acid/chemistry , Glycerol/chemistry , Biodegradation, Environmental , Hydrophobic and Hydrophilic Interactions
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