Degradation and environmental assessment of compostable packaging mixed with biowaste in full-scale industrial composting conditions.

The incorporation of representative commercial compostable materials into a full-scale open-air windrow composting process in an industrial site using household-separated biowaste was investigated. Two batches out of the same initial biowaste mixture were studied, one as control and the other containing initially 1.28 wt% of certified compostable plastics. No significant differences in the composting process were revealed. Compostable plastics exhibited a 98 wt% mass loss after 4 months, aligning with industrial composting times. The evolution of the morphology of the materials unveiled polymer specific degradation mechanisms. Both Safety requirements for organic farming were met. Ecotoxicity tests showed no adverse effects, agronomic fertilizing and amending quality was high, the materials compost even enhancing barley growth. The ecological impact assessment demonstrated an advantage for composting over incineration for seven of the eight indicators. In conclusion, this study shows the successful integration of compostable materials into industrial composting, upholding product safety and quality.

The informative value and design of orthodontic practice websites in The Netherlands.

BACKGROUND: The aims of this cross-sectional study were to investigate the regulatory compliance of Dutch practice websites offering orthodontic services, readability of the available treatment information, website design as well as possible relationship with practice location and professional qualification of practitioners. METHODS: A comprehensive Internet search was performed using the Google search engine and five relevant terms in Dutch. Eligibility screening of the first 50 results of each search led to the final inclusion of 111 websites. The content of the selected websites was evaluated in terms of compliance to international regulations on ethical advertising guidelines (CED), treatment information text readability using Flesch Reading Ease Score (FRES), and website design using the BDC assessment tool. RESULTS: Reporting of websites according to CED guidelines covered on average 85% of the mandatory items. No significant differences were observed between dental and orthodontic practices, and between practices located in densely and sparsely populated regions (P > 0.05). The mean FRES of the displayed information indicated difficult-to-understand text. BDC scores of multi-location practices were significantly higher than the rest (P < 0.006). CONCLUSIONS: The websites of orthodontic practices in The Netherlands do not fully comply with CED guidelines on ethical advertising. Readability of the displayed information and website technical performance needs to be further optimized.

Microplastics elutriation system: Part B: Insight of the next generation.

Elutriation is an efficient process for extracting microplastics. The development of a numerical model has shown the need for optimizing aspects of the design of the actual elutriation protocol as well as the dimensioning of the column to increase its efficiency. The study aims to propose new dimensioning data and protocol elements for designing an efficient column. Using a numerical model, the filling velocity was calculated as a function of the size and the density of the particles to prevent sand suspension. The sieving protocol was adapted to increase the density limit for the extraction of plastic particles from 1460 to >1800 kg·m-3. The durations of the elutriation and the column height were calculated to improve the control of the particle suspension. These results contribute to the development of the next generation of elutriation system and will accelerate the study of plasticome in the context of sandy sediments.

Threat of plastic ageing in marine environment. Adsorption/desorption of micropollutants.

Ageing of various plastics in marine environment was monitored after immersion of two synthetic (polyvinylchloride, PVC, and polyethylene terephthalate, PET) and one biodegradable (poly(butylene adipate co-terephtalate), PBAT) plastics for 502days in the bay of Lorient (Brittany, France). Data analysis indicates that aged PVC rapidly releases estrogenic compounds in seawater with a later adsorption of heavy metals; PET undergoes a low weakening of the surface whereas no estrogenic activity is detected; PBAT ages faster in marine environment than PVC. Aged PBAT exhibits heterogeneous surface with some cavities likely containing clay minerals from the chlorite group. Besides, this degraded material occasionally shows a high estrogenic activity. Overall, this study reports, for the first time, that some aged plastics, without being cytotoxic, can release estrogenic compounds in marine environment.

Microplastics elutriation system. Part A: Numerical modeling.

The elutriation process has shown its efficiency to extract microplastics from sand and began to spread in the scientific community. This extraction technic requires knowing with accuracy the extraction velocities of particles. This study aims to test whether numerical modeling could help to calculate these velocities. From hydrodynamic equations, a numerical model has been developed and the outputs are compared to experimental extraction data. The results show, for the calculated velocities, the experimental plastic extraction yields will be higher than 90% for <10% of sand contamination. The model also allows determining that, with the actual protocol, the maximum plastic density which can be extracted is about 1450kg·m-3 whereas the detrimental resuspension, which may occur during the column filling step, is highlighted. From model calculations, it arises that changes in the column dimensioning and the protocol operations need to be considered.

Efficient microplastics extraction from sand. A cost effective methodology based on sodium iodide recycling.

Evaluating the microplastics pollution on the shores requires overcoming the technological and economical challenge of efficient plastic extraction from sand. The recovery of dense microplastics requires the use of NaI solutions, a costly process. The aim of this study is to decrease this cost by recycling the NaI solutions and to determine the impact of NaI storage. For studying the NaI recyclability, the solution density and the salt mass have been monitored during ten life cycles. Density, pH and salt mass have been measured for 40days to assess the storage effect. The results show that NaI solutions are recyclable without any density alterations with a total loss of 35.9% after the 10cycles of use. During storage, chemical reactions may appear but are reversible. Consequently, the use of recycling methods allows for a significant cost reduction. How far the plastic extraction by dense solutions is representative is discussed.

Microplastics elutriation from sandy sediments: A granulometric approach.

Although relatively easy to extract in the marine environment, microplastics are very difficult to recover when they are trapped in sediments. The elutriation column is one of the best tools currently available for extracting plastics from sediment, but with a high sand recovery yield. This study aims to address the following questions: (i) is it possible to use a sedimentological approach to limit the sand recovery? (ii) does the extraction velocity of the sand and plastic particles vary according to density and granulometry? (iii) what is the relative recovery efficiency obtained for dense polymer particles mixed with marine sand? Based on a new granulometric classification, different plastic particle-size fractions are defined. Their extraction velocities are experimentally determined on particles of sediment and different plastics (PA, PVC). The particle recovery experiments indicate that it is possible to extract >90% of dense plastic particles in cases of negligible sand recovery.

Performance and environmental impact of biodegradable polymers as agricultural mulching films.

In the aim of resolving environmental key issues such as irreversible soil pollution by non-biodegradable and non-recoverable polyethylene (PE) fragments, a full-scale field experiment was set up to evaluate the suitability of four biodegradable materials based on poly(butylene adipate-co-terephtalate) (PBAT) to be used as sustainable alternatives to PE for mulching application in vineyard. Initial ultimate tensile properties, functional properties during field ageing (water vapour permeability and radiometric properties), biodegradability and agronomical performance of the mulched vines (wood production and fruiting yield) were studied. In spite of their early loss of physical integrity that occurred only five months after vine planting, the four materials satisfied all the requested functional properties and led to agronomic performance as high as polyethylene. In the light of the obtained results, the mulching material lifespan was questioned in the case of long-term perennial crop such as grapevine. Taking into account their mulching efficiency and biodegradability, the four PBAT-based studied materials are proven to constitute suitable alternatives to the excessively resistant PE material.