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1.
Materials (Basel) ; 17(16)2024 Aug 19.
Article de Anglais | MEDLINE | ID: mdl-39203278

RÉSUMÉ

The galvanic corrosion performance of AM60B coupled to DC01 was characterized in simulated environments with varying water salinity. The results showed that the coupled DC01 effectively accelerated the corrosion rate of AM60B, and the increased salt concentration had a significant effect on the deterioration process. The corrosion of AM60B mainly exhibits metal dissolution, and the formed Mg(OH)2 has weak a protective effect on the alloy substrate. Furthermore, the distributions of the corrosion potential and the corrosion current density of the AM60B/DC01 couple were simulated and intensively discussed.

2.
Environ Sci Pollut Res Int ; 31(10): 15837-15850, 2024 Feb.
Article de Anglais | MEDLINE | ID: mdl-38305971

RÉSUMÉ

In this study, a scandium concentrate with Sc2O3 content of 66.24 g/t was obtained from V-Ti magnetite tailings by physical concentration, and the main Sc-bearing minerals were augite and hornblende. A novel process of roasting and leaching was proposed to extract scandium from scandium concentrate with titanium dioxide wastewater. Scandium concentrate was pretreated by roasting, and titanium dioxide wastewater was used to directly leach scandium from the roasted ore. The effects of roasting and leaching parameters such as roasting temperature, roasting time, roasting agents, leaching temperature, leaching time, liquid-to-solid ratio, and leaching agents on scandium separation were thoroughly researched in the experimental procedure. The results show that a scandium leaching efficiency of 85.89% was obtained, and the scandium content of leaching residue decreased to 9.31 g/t under the optimal conditions: a roasting temperature of 1123 K, a roasting time of 120 min, a leaching temperature of 343 K, a leaching time of 120 min, and a m (titanium dioxide wastewater)∶m (roasted ore)∶m (ammonium fluoride) ratio of 8∶1∶0.09. The main findings of the scandium separation mechanism show that Sc-bearing minerals can effectively decompose and release scandium element after roasting, and created favorable conditions for scandium leaching with titanium dioxide wastewater to achieve the purpose of scandium recovery.


Sujet(s)
Scandium , Eaux usées , Minéraux , Titane/composition chimique
3.
RSC Adv ; 8(24): 13083-13088, 2018 Apr 09.
Article de Anglais | MEDLINE | ID: mdl-35542504

RÉSUMÉ

Recently, solid-state electrolyte lithium lanthanum zirconium oxide garnet (Li7La3Zr2O12, LLZO) has attracted great attention due to its high room temperature conductivity of lithium ions and stability against lithium metal electrodes. The Al-doped cubic garnet Li6.4Al0.2La3Zr2O12 was synthesized by a conventional solid-state method at different sintering temperatures. The influence of the sintering process on the structure and ionic conductivity was investigated by X-ray diffraction, electrochemical impedance spectroscopy, and scanning electron microscopy. The results showed that Li vaporization and relative density were affected by the sintering process. The synergistic effects of Li concentration and relative density determined the Li+ ionic conductivity. Compared with the relative density, the Li concentration plays a more important role in determining the ionic conductivity via the solid-state method.

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