Cyclometalated luminescent platinum(II) complexes of dissymmetrical 2,2':4',2''-terpyridine and its self-assembled dimer presenting Pt-Ag dative bonds.

A series of cyclometalated (N^C^N) Pt(II)-platinum complexes featuring a terpyridine ligand with a non-coordinating nitrogen atom and a Pt-C bond was synthesized. In the presence of Ag+, the bis(isonitrile)Pt(II) complex formed a remarkable self-assembled helicoidal dimer stabilized by coordination of Ag(I) and metallophilic Pt-Ag interactions. Its assembly was observed in the solid state and maintained in solution. All complexes show strong luminescence and multiple emitting states, which could be rationalized based on solid state X-ray structures and coordinating environment.

Switchable molecular tweezers: design and applications.

Switchable molecular tweezers are a unique class of molecular switches that, like their macroscopic analogs, exhibit mechanical motion between an open and closed conformation in response to stimuli. Such systems constitute an essential component of artificial molecular machines. This review will present selected examples of switchable molecular tweezers and their potential applications. The first part will be devoted to chemically responsive tweezers, including stimuli such as pH, metal coordination, and anion binding. Then, redox-active and photochemical tweezers will be presented.