Effects of Cu(II)-DOM complexation on DOM degradation: Insights from spectroscopic evidence.

The fate of dissolved organic matter (DOM) is primarily governed by its sources, degradation, and transformation processes within the environment. However, the influence of metal-DOM complexation on DOM degradation remains ambiguous. In this study, controlled laboratory experiments were conducted using Cu(II) and natural water from the Duliujian River and the Beidagang Wetland to examine the effects of metal-DOM binding on the degradation pathway of DOM. Our results showed that Cu(II)-DOM complexation affected the distribution of DOM molecular weight with elevated Mw after complexed with Cu(II). Nevertheless, the concentration of DOM decreased over the incubation period due to degradation. In the absence of Cu(II) binding, both wetland and river DOM followed similar degradation pathways, transforming from high to low molecular weight with changes predominantly in the 1-10 kDa size-fraction during DOM degradation. In contrast, in the presence of Cu(II) and thus Cu(II)-DOM binding, the degradation of DOM was enhanced, resulting in higher kinetic rate constants for both wetland and river DOM. The results of differential spectra further confirmed the degradation of DOM with a decrease in bulk spectroscopic properties and an increase in the degree of DOM-Cu(II) complexation. These findings imply a mutually reinforcing relationship between metal-DOM complexation and the degradation of DOM in aquatic environments, providing new insights into the biogeochemical behavior and environmental fate of DOM.

Multiple Sulfur Isotopic Evidence for Sulfate Formation in Haze Pollution.

The mechanism of sulfate formation during winter haze events in North China remains largely elusive. In this study, the multiple sulfur isotopic composition of sulfate in different grain-size aerosol fractions collected seasonally from sampling sites in rural, suburban, urban, industrial, and coastal areas of North China are used to constrain the mechanism of SO2 oxidation at different levels of air pollution. The Δ33S values of sulfate in aerosols show an obvious seasonal variation, except for those samples collected in the rural area. The positive Δ33S signatures (0‰ < Δ33S < 0.439‰) observed on clean days are mainly influenced by tropospheric SO2 oxidation and stratospheric SO2 photolysis. The negative Δ33S signatures (-0.236‰ < Δ33S < ∼0‰) observed during winter haze events (PM2.5 > 200 µg/m3) are mainly attributed to SO2 oxidation by H2O2 and transition metal ion catalysis (TMI) in the troposphere. These results reveal that both the H2O2 and TMI pathways play critical roles in sulfate formation during haze events in North China. Additionally, these new data provide evidence that the tropospheric oxidation of SO2 can produce significant negative Δ33S values in sulfate aerosols.

Dynamic N transport and N2O emission during rainfall events in the coastal river.

The coastal zone exhibited a high population density with highly impacted by anthropogenic activities, such as river impoundment to prevent saline intrusion, which resulted in weak hydrological conditions. Rainfall events can result in dramatic changes in hydrological and nutrient transportation conditions, especially in rivers with weak hydrological conditions. However, how the nitrogen transport and N2O emissions or biogeochemistry responds to the different types of rainfall events in the weak hydrodynamics rivers is poorly understood. In this study, the hydrological, nitrogenous characteristic, as well as N2O dynamics, were studied by high-frequency water sampling during two distinct rainfall events, high-intensity with short duration (E1) and low-intensity with long duration (E2). The results displayed that the hydrologic condition in E1 with a wider range of d-excess values (from -9.50 to 32.1 ‰), were more dynamic than those observed in E2. The N2O concentrations (0.01-3.33 µmol/L) were higher during E1 compared to E2 (0.03-1.11 µmol/L), which indicated that high-intensity rainfall has a greater potential for N2O emission. On the contrary, the concentrations of nitrogen (e.g., TN and NO3--N) were lower during E1 compared to E2. Additionally, hysteresis was observed in both water and nitrogen components, resulting in a prolonged recovery time for pre-rainfall levels during the long-duration event. Moreover, the results showed that the higher average N2O flux (78.3 µmol/m2/h) in the rainfall event period was much larger than that in the non-rainfall period (1.63 µmol/m2/h). The frequency dam regulation resulted in the water level fluctuation, which could enhance wet-dry alternation and simulated N2O emissions. This study highlighted the characteristic of N dynamic and hydrological responses to diverse rainfall events occurrences in the coastal river. Rainfall could increase the N2O emission, especially during high-intensity rainfall events, which cannot be ignored in the context of annual N2O release.

Organic carbon preservation in wetlands: Iron oxide protection vs. thermodynamic limitation.

The sequestration of organic carbon (OC) in wetland sediments is influenced by the presence of oxygen or lack thereof. The mechanisms of OC sequestration under redox fluctuations, particularly by the co-mediation of reactive iron (Fe) protection and thermodynamic limitation by the energetics of the OC itself, remain unclear. Over the past 26 years, a combination of field surveys and remote sensing images had revealed a strong decline in both natural and constructed wetland areas in Tianjin. This decline could be attributed to anthropogenic landfill practices and agricultural reclamation efforts, which may have significant impacts on the oxidation-reduction conditions for sedimentary OC. The Fe-bound OC (CBD extraction) decreased by 2 to 10-fold (from 8.3 to 10% to 0.7-4.5%) with increasing sediment depth at three sites with varying water depths (WD). The high-resolution spectro-microscopy analysis demonstrated that Fe (oxyhydr)oxides were colocalized with sedimentary OC. Corresponding to lower redox potential, the nominal oxidation state of C (NOSC), which corresponds to the energy content in OC, became more negative (energy content increased) with increasing sediment depth. Taken together, the preservation of sedimentary OC is contingent on the prevailing redox conditions: In environments where oxygen availability is high, reactive Fe provides protection for OC, while in anoxic environments, thermodynamic constraints (i.e., energetic constraints) limit the oxidation of OC.

Size distributions of molecular markers for biogenic secondary organic aerosol in urban Beijing.

To understand the source, formation, and seasonality of biogenic secondary organic aerosol (BSOA), a nine-stage cascade impactor was utilized to collect size-segregated particulate samples from April 2017 to January 2018 in Beijing, China. BSOA tracers derived from isoprene, monoterpene, and sesquiterpene were measured with gas chromatography-mass spectrometry. Isoprene and monoterpene SOA tracers exhibited significant seasonal variations, with a summer maximum and a winter minimum. Dominance of 2-methyltetrols (isoprene SOA tracers) with a good correlation with levoglucosan (a biomass burning tracer), which was combined with the detection of methyltartaric acids (possible indicators for aged isoprene) in summer, implies possible biomass burning and long-range transport. In contrast, sesquiterpene SOA tracer (ß-caryophyllinic acid) was dominant in winter and was probably associated with the local burning of biomass. Bimodal size distributions were observed for most isoprene SOA tracers, consistent with previous laboratory experiments and field studies showing that they can be formed not only in the aerosol phase but also in the gas phase. Monoterpene SOA tracers cis-pinonic acid and pinic acid showed a coarse-mode peak (5.8-9.0 µm) in four seasons due to their volatile nature. Sesquiterpene SOA tracer ß-caryophyllinic acid showed a unimodal pattern with a major fine-mode peak (1.1-2.1 µm), which is linked to local biomass burning. The tracer-yield method was used to quantify the contributions of isoprene, monoterpene, and sesquiterpene to secondary organic carbon (SOC) and SOA. The highest isoprene SOC and SOA concentrations occurred in summer (2.00 µgC m-3 and 4.93 µg m-3, respectively), contributing to 1.61% of OC and 5.22% of PM2.5, respectively. These results suggest that BSOA tracers are promising tracers for understanding the source, formation, and seasonality of BSOA.

Differences in the spectral characteristics of dissolved organic matter binding to Cu(II) in wetland soils with moisture gradients.

The environmental behavior of heavy metals in soil is significantly regulated by their binding with dissolved organic matter (DOM), which is affected by soil moisture contents. However, the mechanism of this interaction in soils with varying moisture is still not well understood. Using a combination of ultrafiltration, Cu(II) titration, and multispectral (ultraviolet-visible absorption, 3D fluorescence, Fourier transform infrared) analysis techniques, we studied the differences in the spectral characteristics and Cu(II) binding properties of soil dissolved organic matter (DOM) and its different molecular weight (MW) fractions with moisture gradients. We found that the abundance and spectral characters of soil DOM changed with increasing soil moisture, i.e., the increase in abundance while the decrease in aromaticity and humification index. The components of DOM, shown by Fluorescence region-integration (FRI) analysis, also changed, with an increase in the proportion of protein-like substances and a decrease of humic-like and fulvic-like substances. The overall Cu(II) binding potential of soil DOM diminished with increasing soil moisture, as indicated by the fluorescence parallel factor (PARAFAC) analysis. This is aligns with the changes in DOM composition, as the humic-like and fulvic-like fractions exhibited higher Cu(II) binding potential compared to the protein-like fractions. The low MW fraction of the MW-fractionated samples showed a stronger binding potential for Cu(II) compared to the high MW fraction. Finally, the active binding site of Cu(II) in DOM, as revealed by UV-difference spectroscopy and 2D-FTIR-COS analysis, decreased with increasing soil moisture, with the order of preferentially functional groups shifting from OH, NH, and CO to CN and CO. This study emphasizes the impact of moisture variations on the characteristics of DOM and its interaction with Cu(II), providing insight into the environmental fate of heavy metal contaminants in soil in areas with alternating land and water conditions.

Risk assessment and binding mechanisms of potentially toxic metals in sediments from different water levels in a coastal wetland.

The excessive accumulation of potentially toxic metals (Pb and Cd) in coastal wetlands is among the main factors threatening wetland ecosystems. However, the effects of water table depth (WTD) on the risk and binding mechanisms of potentially toxic metals in sediments remain unclear. Here, sediments from different WTD obtained from a typical coastal wetland were evaluated using a newly developed strategy based on chemical extraction methods coupled with high-resolution spectroscopy. Our findings indicated that the WTD of the coastal wetland fluctuates frequently and the average enrichment factor for Pb was categorized as minor, whereas Cd enrichment was categorized as moderate. High-resolution spectroscopy techniques also demonstrated that organic functional groups and partly inorganic compounds (e.g., Fe-O/Si-O) played a vital role in the binding of Pb and Cd to surface sediments. Additionally, mineral components rather than organic groups were mainly bound to these metals in the bottom sediments. Collectively, our findings provide key insights into the potential health effects and binding characteristics of potentially toxic metals in sediments, as well as their dynamic behavior under varying sediment depths at a microscale.

Slight transition in Chinese atmospheric Pb isotopic fingerprinting due to increasing foreign Pb.

Atmospheric lead (Pb) pollution negatively affects human health and ecosystem, and extensive research is required to identify its sources and develop robust mitigation methods. In this study, the concentration and isotopic composition of Pb in fine particulate matter (PM2.5) at five sites in the China's Beijing-Tianjin-Hebei (BTH) region were analyzed. The results showed that the Pb concentration in the BTH region declined along the northwest direction in winter owing to the East Asian monsoon. Pb isotopic signatures confirmed that anthropogenic activities significantly contributed to Pb pollution, compared with natural sources. With the increasing import of foreign Pb (with a relatively lower 208Pb/206Pb ratio) to China, we hypothesized that the unique isotopic signature of Pb in Chinese aerosols may decline over time. Therefore, the application of the isotopic approach for quantifying Pb transported from China should be carefully appraised in future research to provide a realistic estimate of the contribution of local sources and the transboundary effect consistent with air mass trajectories analysis. This study provides a theoretical reference for supporting the utilization of Δ208Pb values for better clarify the transboundary impact of Pb pollution and to reduce international disputes.

Role of molecular weight-dependent spectral properties in regulating Cu(II) binding by dissolved organic matter from different sources.

The complexation of metals with dissolved organic matter (DOM) under different compositions and molecular weights (MWs) will result in different environmental fate and toxicity, but the specific role and impact of DOM MWs remain less well understood. This study explored the metal binding characteristics by DOM with different MWs from different sources, including sea, river, and wetland waters. The results of fluorescence characterization showed that the >1 kDa high-molecular-weight (HMW)-DOM were mainly from terrestrial sources while the low-molecular-weight (LMW)-DOM fractions were mostly from microbial sources. Based on UV-Vis spectroscopic characterization, the LMW-DOM contained more unsaturated bonds than its HMW counterpart, and the substituents are generally dominated by polar functional groups. Summer DOM had more unsaturated bonds and a higher metal binding capacity than winter DOM. Furthermore, DOM with different MWs had significantly different Cu binding properties. In addition, Cu binding with microbially derived LMW-DOM mainly caused the change in the peak at 280 nm, while binding with terrigenous HMW-DOM resulted in the change of the 210 nm peak. Compared with the HMW-DOM, most of the LMW-DOM had stronger Cu-binding ability. Correlation analysis indicates that metal binding ability of DOM mainly depends on its concentration, number of unsaturated bonds and benzene rings, and types of substituents during interactions. This work provides an improved understanding of the metal-DOM binding mechanism, the role of composition- and MW-dependent DOM from different sources, and thus the transformation and environmental/ecological role of metals in aquatic systems.

Sulfate concentrations affect sulfate reduction pathways and methane consumption in coastal wetlands.

Coastal wetlands are an important source of methane emissions, and understanding the mechanisms that control methane emissions from coastal wetlands is of great significance to global warming. Anaerobic oxidation of methane driven by sulfate is an important process to prevent methane emissions from coastal wetlands. The effects of environmental changes on this process and the function of the sulfate-methane transition zone (SMTZ) are poorly understood. In this study, spatiotemporal variations in pore-water geochemistry (concentrations of SO42-, CH4 and DIC as well as δ13C-DIC and δ13C-CH4) in the Beidagang wetland, Tianjin, China, were investigated to unravel factors controlling the role of anaerobic oxidation of methane in coastal wetlands. Results show that the geochemical profile of pore-water is characterized by significant spatial and temporal variability, which may be related to changes in sulfate concentration, temperature and dissolved oxygen. The carbon isotope fractionation factors (εC) during methane oxidation range from 8.9‰ to 12.5‰, indicating that the sulfate-driven anaerobic oxidation of methane (S-AOM) dominates the methane oxidation in the Beidagang coastal wetland in both winter and summer, in both high and low salinity wetlands, and in both open water and littoral areas. However, sulfate concentration has a strong influence on the sulfate reduction pathways and methane consumption. The consumption of methane and sulfate by S-AOM is more significant in coastal wetlands with high sulfate concentrations, with S-AOM consuming nearly all of the upward-diffusing methane (96%) and downward-diffusing sulfate (96%). In addition, the dissolved inorganic carbon (DIC) produced in the pore-water mainly comes from methanogenesis, accounting for more than 80% of the total DIC pool, but in the areas with high sulfate concentrations in water column, the contribution of S-AOM to the DIC pool is greater, although only a small fraction of the total DIC pool (9%). The depth and width of the SMTZ show a clear spatial and temporal pattern, with active methanogenesis activity and upward high methane flux shoaling the SMTZ and increasing the risk of high methane emissions from coastal wetlands with low sulfate concentrations. Our findings highlight the importance of sulfate-driven anaerobic oxidation of methane in coastal wetlands and the effect of sulfate concentration on it. It contributes to our understanding of the mechanism of methane production and emissions from the coastal wetland system, particularly in light of the increased demand for coastal wetland restoration under global warming.

Differences in the spectroscopic characteristics of wetland dissolved organic matter binding with Fe3+, Cu2+, Cd2+, Cr3+ and Zn2.

Understanding of the binding characteristics of wetland dissolved organic matter (DOM) and different metals is important for the quantitative assessment of the environmental behavior of metals in wetlands. In this study, different types of spectroscopy including ultraviolet-visible absorption, Fourier transform infrared, and fluorescence spectroscopy was used to investigate the binding characteristics of Fe3+, Cu2+, Cr3+, Cd2+, and Zn2+ with DOM from wetland water. Differential absorption spectra identified binding sites for these five metals in this wetland DOM at 210 nm, 280 nm, 335 nm, and > 400 nm regions. The low binding capacity of DOM in this wetland with Cd and Zn indicated that the toxicity and environmental effects of these metals in this wetland warrant further study. The calculated △EEM combined with fluorescence regional integration (FRI) analysis clearly revealed that Fe and Cu preferred to bind with humic-like DOM while Cd and Zn preferred to bind with protein-like DOM in this wetland. △EEM successfully demonstrated the characteristics of DOM complexing with different metals and could be a compelling tool in evaluating metal-DOM interactions. In addition, 2D-FTIR-COS identified the binding sites and the dynamic processes of binding at the functional group level. Metals preferentially bind with the CO, CO functional group, and then binds to the OH functional group. This study revealed that different DOM components will facilitate the migration of different metals in the environment and provided new slights into an improved understanding of migration and transformation of metals in aquatic environments.

Linking deeply-sourced volatile emissions to plateau growth dynamics in southeastern Tibetan Plateau.

The episodic growth of high-elevation orogenic plateaux is controlled by a series of geodynamic processes. However, determining the underlying mechanisms that drive plateau growth dynamics over geological history and constraining the depths at which growth originates, remains challenging. Here we present He-CO2-N2 systematics of hydrothermal fluids that reveal the existence of a lithospheric-scale fault system in the southeastern Tibetan Plateau, whereby multi-stage plateau growth occurred in the geological past and continues to the present. He isotopes provide unambiguous evidence for the involvement of mantle-scale dynamics in lateral expansion and localized surface uplift of the Tibetan Plateau. The excellent correlation between 3He/4He values and strain rates, along the strike of Indian indentation into Asia, suggests non-uniform distribution of stresses between the plateau boundary and interior, which modulate southeastward growth of the Tibetan Plateau within the context of India-Asia convergence. Our results demonstrate that deeply-sourced volatile geochemistry can be used to constrain deep dynamic processes involved in orogenic plateau growth.

High Molecular Diversity of Organic Nitrogen in Urban Snow in North China.

Snow serves as a vital scavenging mechanism to gas-phase and particle-phase organic nitrogen substances in the atmosphere, providing a significant link between land-atmosphere flux of nitrogen in the surface-earth system. Here, we used optical instruments (UV-vis and excitation-emission matrix fluorescence) and a Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS) to elucidate the molecular composition and potential precursors of snow samples collected simultaneously at four megacities in North China. The elemental O/N ratio (≥3), together with the preference in the negative ionization mode, indicates that the one and two nitrogen atom-containing organics (CHON1 and CHON2) in snow were largely in the oxidized form (as organic nitrates, -ONO2). This study assumed that scavenging of particle-phase and gas-phase organic nitrates might be significant sources of CHON in precipitation. A gas-phase oxidation process and a particle-phase hydrolysis process, at a molecular level, were used to trace the potential precursors of CHON. Results show that more than half of the snow CHON molecules may be related to the oxidized and hydrolyzed processes of atmospheric organics. Potential formation processes of atmospheric organics on a molecular level provide a new concept to better understand the sources and scavenging mechanisms of organic nitrogen species in the atmosphere.

Temporal and spatial variations in stable isotopic compositions of precipitation during the typhoon Lekima (2019), China.

A clear understanding of factors governing stable isotopic variations in precipitation of tropical cyclones is critical for constraining atmospheric hydrological model simulations. The temporal and spatial variations in stable isotopic compositions of precipitation during the typhoon Lekima (2019) were investigated, based on rainwater samples collected at four sampling sites along its track between August 10 and August 12, 2019. Results showed that the δ18O and δD values of rainwater samples varied from -15.5‰ to -2.9‰ and from -112.4‰ to -17.3‰, respectively. The large ranges of δ18O and δD values in rainwater from the typhoon Lekima were most likely caused by the changes in rainfall intensity and its complex interaction with local water vapor. In addition, it was observed that the δ18O and δD values gradually decreased from the outer rainbands to the inner rainbands, and their values were more depleted of heavy isotopes than those of local rain. We speculated that both the high stratiform precipitation fractions and the deep convection system may be responsible for the isotopic depletion of rainwater related with the typhoon Lekima. It reveals that the rain type fractions and the intensity of convection should be considered in the elucidation of δ18O signals in extreme precipitation events. This study also has important implications for understanding atmospheric moisture cycles in tropical cyclones.

The abatement of acid rain in Guizhou province, southwestern China: Implication from sulfur and oxygen isotopes.

The high frequency of acid rain in southern China has captured public and official concern since 1980s. Subsequently, gas emission reduction measures have been implemented to improve the air quality. Variations in SO2 emission intensities can influence the sulfur and oxygen isotopic compositions of sulfate in rainwater, since atmospheric sulfate is mainly formed via the oxidation of sulfur gases from natural and anthropogenic sources. To evaluate the impacts of emission reduction measures on atmospheric sulfate, the seasonal and long-term trends in stable isotopic compositions of sulfate in rainwater in Guizhou province, southwestern China have been investigated based on rainwater samples collected from June 2016 to June 2018 and literature investigation (2000-2010).The results reveal that coal combustion remains a major contributor to sulfate in rainwater, although its SO2 emission has significantly decreased over the past two decades. The δ34Ssulfate and δ18Osulfate values in rainwater are negatively correlated and have significant seasonal changes. The seasonality in δ34Ssulfate has been interpreted as due to the changes in contributions of dimethyl sulfide and coal combustion, while the seasonal pattern of δ18Osulfate is consistent with that of δ18Owater values, indicating sulfate in rainwater is mainly formed by heterogeneous oxidation of SO2. Combined with the data from previous studies (Xiao and Liu, 2002; Liu, 2007; Xiao et al., 2009; Xiao et al., 2014), we found that the volume weighted mean δ34S values of sulfate in rainwater in Guizhou province show a marked increase between 2001 and 2018, indicating that the 34S-depleted SO2 emission from coal combustion has declined during this period. Furthermore, the synchronous changes in δ34S values, sulfate concentration and pH values of rainwater suggest that the frequency of acid rain in Guizhou province has dropped over the past two decades, which is likely to result from the emission reduction measures taken in Guizhou province.

Seasonal and long-term trends of sulfate, nitrate, and ammonium in PM2.5 in Beijing: implication for air pollution control.

Particulate matter pollution in Beijing is a serious environmental problem. In response to this, the Beijing government has implemented comprehensive emission reduction measures in recent years. To assess the effectiveness of these measures, the seasonal and long-term trends in chemical compositions of PM2.5 in Beijing have been studied based on daily samples collected from July 2015 to April 2016 and literature investigation (2000-2014). Results show that the concentrations of sulfate, nitrate, and ammonium in PM2.5 have significant seasonal variations, which are related to the changes in meteorological conditions and emission intensities. In addition, the long-term data display that the concentrations of sulfate, nitrate, and ammonium have significantly decreased between 2013 and 2016, which are consistent with the reduction in PM2.5 levels (~ 11.2 µg/m3 per year). The declines could not be interpreted by the meteorological factors. It suggests that the air pollution control measures in Beijing (2013-2016), especially the decreasing consumption of coal, can effectively decrease the mass concentration of fine particles. To further improve the air quality, similar measures should be adopted in the areas around Beijing. These air pollution control measures taken in Beijing can provide invaluable guidance for mega-cities in China and other developing countries to decrease their PM2.5 concentration and reduce health risk from particulate pollution.

Accumulation of organic carbon in a large canyon reservoir in Karstic area, Southwest China.

Artificial reservoirs play an important role in intercepting organic carbon (OC), which affects the carbon cycle of inland waters. However, limited by the methods of field observations, studies on the potential carbon sink of sediment in reservoirs are not accurate enough. In this study, we investigated OC accumulation in the Wujiangdu Reservoir (WJDR), a canyon reservoir located in a karst area of Southwest China, by coupling seismic survey data with physicochemical data of sediment cores. The results showed that irregular underwater topography resulted in spatial heterogeneity of the sediment deposition. The mean OC accumulation rate in the WJDR was 579.2 g C m-2 year-1, and the OC accumulation flux of the WJDR was 1.4 × 1010 g C year-1. δ13C values coupled with a mixing model indicated that the autochthonous OC ranged from 14.2 to 97.0% of the total OC in the sediment, with an average of 48.4%. The significantly positive relationship between autochthonous OC and TN indicated that the autochthonous OC generated in the reservoir was associated with nutrient input. The autochthonous OC accumulation flux was 6.6 × 109 g C year-1, which was equal to 2.3 times the carbon emission from the reservoir surface to the atmosphere as CO2-C, indicating that the autochthonous OC produced within the reservoir is a large carbon sink.

Phosphorus fractions and oxygen isotope composition of inorganic phosphate in typical agricultural soils.

Phosphorus (P), despite being an essential nutrient element for plants growth in agricultural ecosystem, the low utilization rate of soil P and the environmental problems caused by soil P losses are serious. Therefore, scoping knowledge of the possible sources and utilization extent of soil P by microorganisms is very helpful for better understanding of promoting P utilization for sustainable agriculture. Oxygen isotope of phosphate technology is an effective tool to trace the sources of P. In this study, P contents and oxygen isotope composition of inorganic phosphate (δ18OP) of different pools (H2O-P, NaHCO3-P, NaOH-P, and HCl-P) in typical agricultural soil from Northeast China and Central China were analyzed and quantified. The results showed that fertilizer and land use were important factors influencing the contents of H2O-Pt and NaHCO3-Pt and the soil TP contents from different types of soils were greatly affected by soil weathering degree. The δ18OP of different P pools indicated that the difference in utilization extent of different P fractions by microorganisms and the δ18OP values of different P fractions could be due to accumulation of multiple factors. The results will provide effective information for further study on sources and effective utilization of different P fractions in soil.

Flux of organic carbon burial and carbon emission from a large reservoir: implications for the cleanliness assessment of hydropower.

Accurately quantifying the budget of carbon sources and sinks in hydropower reservoirs is important for evaluating the cleanliness of hydroelectricity. However, current research on carbon emissions from reservoirs has rarely taken into account the organic carbon (OC) buried in sediment. Only greenhouse gas emissions from the water-air interface at reservoirs have been examined, which would result in an overestimation of the greenhouse effect of reservoirs. In November 2017, this study investigated the distribution of sediment in the Hongfeng Reservoir (HFR) in southwest China, a typical large hydropower reservoir, by using an underwater seismology monitoring system. We estimated the flux of OC into sediment using the results of a sediment survey and a dataset compiled from references. Our results show that, the HFR retained 200,715 t of OC in the sediment since its impounding after dam construction to the sampling year of 2017, when the average burial flux was 3,521 t-C a-1 (106 g C a-1) and the modern burial flux was 5,449 t-C a-1. After excluding the exogenous OC, the modern valid carbon sink of the sediment was 4,632 t per year. Under the current state of the reservoir, taking the modern valid carbon sink value, the carbon emissions from the reservoir's surface, and the discharge water from the dam into consideration, the net carbon sink of the HFR is found to be 1,098.9 t-C a-1. If the hydroelectricity generated by the reservoir is converted to a carbon sink, then the total net carbon sink becomes 12,972.9 t-C a-1. This work argues that both reservoir sediment and hydroelectricity are important carbon sinks and both should be included in assessments of the greenhouse effects of reservoirs.