Photocatalytic oxidation of diuron using nickel organic xerogel under simulated solar irradiation.

In this study, a nickel organic xerogel (X-Ni) was used as semiconductor photocatalyst for the degradation of the herbicide diuron (DRN) in aqueous solution. The main objective of this work was to analyze and compare the effectiveness of solar irradiation to remove DRN from water both by direct photolysis and photocatalytic degradation. We examined the influence of the initial concentration of the herbicide, the solution pH, the presence of different ions in the medium, the chemical composition of the water, and the presence of a photocatalyst, after 240 min of irradiation. Direct photolysis achieved a low percentage of DRN degradation but was favored: i) by a reduction in the initial concentration of the herbicide (from 35.6% to 79.0% for 0.150 × 10-3 mol/L and 0.021 × 10-3 mol/L of DRN, respectively) and ii) at solution pHs at which diuron is positively charged (78.6% for pH 2 and 50.4% for pH 7), as suggested by DFT calculations carried out for DRN and its protonated form (DRN-H+). The corresponding mono-demethylated DRN derivative, 1-(3,4-dichlorophenyl)-3-methylurea (DCPU), was identified as a DRN degradation byproduct. In addition, the presence of certain anions in the medium significantly affected the overall degradation process by direct photolysis, due to the additional generation of HO radicals. We highlight that the presence of X-Ni considerably improved the photodegradation process under solar irradiation. The photocatalytic degradation rate constant was directly proportional to the xerogel concentration, because an increase in catalyst dose produced an increase in surface active sites for the photodegradation of DRN, enhancing the overall efficiency of the process. Thus, when 4167 mg/g of X-Ni was added, the DRN removal rate was 3-fold higher and both percentage of degradation and mineralization increased 88.5% with respect to the results obtained by direct photolysis.

Nitroimidazoles adsorption on activated carbon cloth from aqueous solution.

The objective of this study was to analyze the equilibrium and adsorption kinetics of nitroimidazoles on activated carbon cloth (ACC), determining the main interactions responsible for the adsorption process and the diffusion mechanism of these compounds on this material. The influence of the different operational variables, such as ionic strength, pH, temperature, and type of water (ultrapure, surface, and waste), was also studied. The results obtained show that the ACC has a high capacity to adsorb nitroimidazoles in aqueous solution. Electrostatic interactions play an important role at pH<3, which favors the repulsive forces between dimetridazole or metronidazole and the ACC surface. The formation of hydrogen bonds and dispersive interactions play the predominant role at higher pH values. Modifications of the ACC with NH3, K2S2O8, and O3 demonstrated that its surface chemistry plays a predominant role in nitroimidazole adsorption on this material. The adsorption capacity of ACC is considerably high in surface waters and reduced in urban wastewater, due to the levels of alkalinity and dissolved organic matter present in the different types of water. Finally, the results of applying kinetic models revealed that the global adsorption rate of dimetridazole and metronidazole is controlled by intraparticle diffusion.