Rice husk-derived nano-SiO2 assembled on reduced graphene oxide distributed on conductive flexible polyaniline frameworks towards high-performance lithium-ion batteries.

By combining rice husk-derived nano-silica and reduced graphene oxide and then polymerizing PANI by in situ polymerization, we created polyaniline-coated rice husk-derived nano-silica@reduced graphene oxide (PANI-SiO2@rGO) composites with excellent electrochemical performance. ATR-FTIR and XRD analyses confirm the formation of PANI-SiO2@rGO, implying that SiO2@rGO served as a template in the formation of composites. The morphology of PANI-SiO2@rGO was characterized by SEM, HRTEM, and STEM, in which SiO2 nanoparticles were homogeneously loaded on graphene sheets and the PANI fibrous network uniformly covers the SiO2@rGO composites. The structure can withstand the large volume change as well as retain electronic conductivity during Li-ion insertion/extraction. Over 400 cycles, the assembled composite retains a high reversible specific capacity of 680 mA h g-1 at a current density of 0.4 A g-1, whereas the SiO2@rGO retains only 414 mA h g-1 at 0.4 A g-1 after 215 cycles. The enhanced electrochemical performance of PANI-SiO2@rGO was a result of the dual protection provided by the PANI flexible layer and graphene sheets. PANI-SiO2@rGO composites may pave the way for the development of advanced anode materials for high-performance lithium-ion batteries.

Fast-Charging Anode Materials and Novel Nanocomposite Design of Rice Husk-Derived SiO2 and Sn Nanoparticles Self-Assembled on TiO2(B) Nanorods for Lithium-Ion Storage Applications.

A novel microstructure of anode materials for lithium-ion batteries with ternary components, comprising tin (Sn), rice husk-derived silica (SiO2), and bronze-titanium dioxide (TiO2(B)), has been developed. The goal of this research is to utilize the nanocomposite design of rice husk-derived SiO2 and Sn nanoparticles self-assembled on TiO2(B) nanorods, Sn-SiO2@TiO2(B), through simple chemical route methods. Following that, the microstructure and electrochemical performance of as-prepared products were investigated. The major patterns of the X-ray diffraction technique can be precisely indexed as monoclinic TiO2(B). The patterns of SiO2 and Sn were found to be low in intensity since the particles were amorphous and in the nanoscale range, respectively. Small spherical particles, Sn and SiO2, attached to TiO2(B) nanorods were discovered. Therefore, the influence mechanism of Sn-SiO2@TiO2(B) fabrication was proposed. The Sn-SiO2@TiO2(B) anode material performed exceptionally well in terms of electrochemical and battery performance. The as-prepared electrode demonstrated outstanding stability over 500 cycles, with a high discharge capacity of ∼150 mA h g-1 at a fast-charging current of 5000 mA g-1 and a low internal resistance of around 250.0 Ω. The synthesized Sn-SiO2@TiO2(B) nanocomposites have a distinct structure, the potential for fast charging, safety in use, and good stability, indicating their use as promising and effective anode materials in better power batteries for the next-generation applications.

Ultrafast-charging and long cycle-life anode materials of TiO2-bronze/nitrogen-doped graphene nanocomposites for high-performance lithium-ion batteries.

Emerging technologies demand a new generation of lithium-ion batteries that are high in power density, fast-charging, safe to use, and have long cycle lives. This work reports charging rates and specific capacities of TiO2(B)/N-doped graphene (TNG) composites. The TNG composites were prepared by the hydrothermal method in various reaction times (3, 6, 9, 12, and 24 h), while the N-doped graphene was synthesized using the modified Hummer's method followed by a heat-treatment process. The different morphologies of TiO2 dispersed on the N-doped graphene sheet were confirmed as anatase-nanoparticles (3, 6 h), TiO2(B)-nanotubes (9 h), and TiO2(B)-nanorods (12, 24 h) by XRD, TEM, and EELS. In electrochemical studies, the best battery performance was obtained with the nanorods TiO2(B)/N-doped graphene (TNG-24h) electrode, with a relatively high specific capacity of 500 mA h g-1 at 1C (539.5 mA g-1). In long-term cycling, excellent stability was observed. The capacity retention of 150 mA h g-1 was observed after 7000 cycles, at an ultrahigh current of 50C (27.0 A g-1). The synthesized composites have the potential for fast-charging and have high stability, showing potential as an anode material in advanced power batteries for next-generation applications.

Investigation and control of a Plasmodium falciparum malaria outbreak in Shan Special Region II of Myanmar along the China-Myanmar Border from June to December 2014.

BACKGROUND: From 2007 to 2013, intensive control measures reduced malaria burden by 90 % along the China-Myanmar border. However, despite these measures a P. falciparum malaria outbreak was reported in the Shan Special Region II of Myanmar in June of 2014. METHODS: Epidemiological, parasitological and entomological investigations were performed. Dihydroartemisinin piperaquine (DAPQ) was immediately administered to treat parasite positive individuals. Long lasting insecticidal nets (LLIN), indoor residual spraying (IRS) with insecticides and behavior change communication (BCC) were also provided for outbreak control. An embedded efficacy study was conducted evaluating DP. Molecular genotyping via polymerase chain reaction (PCR) was performed on the Kelch gene on chromosome 13. RESULTS: All infections were identified as Plasmodium falciparum by RDT and microscopy. Two fatalities resulted from the outbreak. The attack rate was 72.8 % (67/92) and the incidence density rate was 14.2 per 100 person-weeks. The positive rate of rapid diagnostic test (RDT) was 72.2 % (65/90) and microscopically-determine parasite rate 42.2 % (38/90). Adjusted odds ratio (OR) of multivariate logistic regression analysis for aged <15 years, 15-45 years, inappropriate treatment from a private healer and lack of bed nets were 13.51 (95 % confidence interval, 2.21-105.89), 7.75 (1.48-44.97), 3.78 (1.30-46.18) and 3.21(1.21-15.19) respectively. In the six surrounding communities of the outbreak site, positive RDT rate was 1.2 % (4/328) and microscopically-determine parasite rate 0.6 % (2/328). Two light traps collected a total of 110 anopheline mosquitoes including local vectors, An. minimus, An. sinensis and An. maculates. After intensive control, the detection of malaria attacks, parasites and antigen were reduced to zero between July 1 and December 1, 2014. The cure rate of P. falciparum patients at day 42 was 94.3 % (95 % CI, 80.8-99.3 %). The PCR did not detect K13-propeller mutations. CONCLUSION: Imported P. falciparum caused the outbreak. Age, seeking inappropriate treatment and lack of bed nets were risk factors for infection during the outbreak. P. falciparum was sensitive to treatment with DAPQ. The integrated measures controlled the outbreak and prevented the spread of P. falciparum effectively. The results of this study indicate that malaria control on the China-Myanmar border, especially among special populations, needs further collaboration between China, Myanmar and international societies.