Electrochemical Nitrate Reduction to Ammonia on AuCu Single-atom Alloy Aerogels under Wide Potential Window.

Electrocatalytic nitrate reduction to ammonia (NO3RR) is very attractive for nitrate removal and ammonia production in industrial processes. However, the nitrate reduction reaction is characterized by intense hydrogen competition at strong reduction potentials, which greatly limits the Faraday efficiency at strong reduction potentials. Herein, we reported an AuxCu single-atom alloy aerogels (AuxCu SAAs) with three-dimensional network structure with significant nitrate reduction performance of Faraday efficiency (FE) higher than 90% over a wide potential range (0 ~ -1 VRHE). The FE of the catalyst was close to 100% at a high reduction potential of -0.8 VRHE, accompanying with NH3 yield reaching 6.21 mmol h-1 cm-2. More importantly, the catalyst maintained a long-term operation over 400 h at 400 mA cm-2 for the NO3RR using a continuous flow system in a H-cell. Experimental and theoretical analysis demonstrate that the catalyst can lower the energy barrier for the hydrogenation reaction of *NO2, leading to a rapid consumption of the generated *H, facilitate the hydrogenation process of NO3RR, and inhibit the competitive HER at high overpotentials, which efficiently promotes the nitrate reduction reaction, especially in industrial applications.

Superhydrophobic Cellulose Nanofiber Aerogels for Efficient Hemostasis with Minimal Blood Loss.

Reducing unnecessary blood loss in hemostasis is a major challenge for traditional hemostatic materials due to uncontrolled blood absorption. Tuning the hydrophilic and hydrophobic properties of hemostatic materials provides a road to reduce blood loss. Here, we developed a superhydrophobic aerogel that enabled remarkably reduced blood loss. The aerogel was fabricated with polydopamine-coated and fluoroalkyl chain-modified bacterial cellulose via a directional freeze-drying method. Primarily, the hydrophobic feature prevented blood from uncontrolled absorption by the material and overflowing laterally. Additionally, the aerogel had a dense network of channels that allowed it to absorb water from blood due to the capillary effect, and fluoroalkyl chains trapped the blood cells entering the channels to form a compact barrier via hydrophobic interaction at the bottom of the aerogel, causing quick fibrin generation and blood coagulation. The animal experiments reveal that the aerogel reduced the hemostatic time by 68% and blood loss by 87 wt % compared with QuikClot combat gauze. The study demonstrates the superiority of superhydrophobic aerogels for hemostasis and provides new insights into the development of hemostatic materials.

Bioinspired hierarchical and dual-morphology humic-acid/pectin/chitosan composite aerogels for efficient removal of pollutants from wastewater.

How to solve the contradiction between the efficiency and adsorption rate of porous materials in adsorbing pollutants has always been one of the focus issues. In this study, the small landscape cypress trees structure like biomimetic of a hierarchical and dual morphology 3D porous HA-based aerogel was designed and synthesized to use humic acid (HA), pectin (PE) and chitosan (CTS) as raw materials, which it was formed by the disorderly overlapping of lamella composed of fiber networks in 3D space. Due to its special microstructure, it can be used like separation membrane, which allowing for rapid adsorption of pollutants in the water while the water flow passes through quick. In general, this work provides a new concept for owning fast adsorption rate and efficient adsorption of porous materials of preparation to use green method.

Aerogels for Phase-Change Materials in Functional and Multifunctional Composites: A Review.

Phase-change materials (PCMs) have gained more attention during the last few decades. As the main function of these materials is to store and release energy in the form of latent heat during phase transitions, they perfectly fulfill the direction of modern research focused on energy-related topics. Although they have basic energy-related properties, recent research shows a need to upgrade those materials in terms of improving their common drawbacks like shape stability, leakage, and poor conductivity. The research related to PCM-based composites leads to imparting some additional functional properties such as different types of conversion abilities or extra performance such as shape memory and thermal protection. Together with a new emerging material group-aerogels (AGs), extra-light and highly porous matrices-PCMs could become functional and multifunctional materials. AG-PCM composites could be implemented in a large variety of applications in different sectors like energy, buildings, medical, defense, space technologies, and more. This study aims to help summarize current trends, methods, and works on PCM-aerogel composites in terms of developing new functional materials, especially for energy conversion purposes but also for improved conductivity, mechanical properties, and flame retardancy.

Lignin Nanofiber Flexible Carbon Aerogels for self-standing supercapacitors.

Renewable feedstocks are sought for clean technology applications, including energy storage applications. In this study, LignoForce™ lignin, a biobased aromatic polymer commercially isolated from wood, was fractioned into two parts using acetone, and the resulting lignin fractions had distinct thermo-rheological behavior. These two fractionated lignins were combined in various ratios and transformed into nanofibers by electrospinning. Subsequently, electrospun fiber materials were disrupted by agitating the mats in water, and the materials were transformed into ultralight 3D aerogels through lyophilization and post-process controlled heating. Using only this combination of two fractions, the morphology of lignin nanofibers was tailored by heat treatment, resulting in lignin aerogels with high flexibility and significant shape recovery properties. Various microscale structures of lignin fibers impacted the resulting physical properties of the elastic aerogel materials, such as resilience, compressive strength, and electrical conductivity for the corresponding carbonized samples. By exploiting lignin's sensitivity to heat and tailoring the thermal properties of the lignin through fractionation, the work provided an interesting path to form robust lignin-derived functional materials without any toxic chemical additives and significant ability to serve as free-standing electrodes with specific capacitance values better than some graphene-based supercapacitors.

Current insights and future prospects of graphene aerogel-enhanced supercapacitors: A systematic review.

Supercapacitors present a compelling alternative to conventional batteries, offering rapid energy storage and high power density. Despite their advantages, they typically fall short in energy density compared to traditional batteries, primarily due to limitations in electrode materials. Graphene Aerogels (GA) have emerged as a promising solution to enhance supercapacitor performance because of their unique properties, such as high surface area and excellent conductivity. This systematic review provides a comprehensive analysis of recent advancements in GA technology, focusing on their synthesis methods and applications in supercapacitors. It highlights significant improvements that GA can bring to Electric Double-Layer Capacitors (EDLCs), pseudocapacitors, and hybrid supercapacitors. Additionally, the review explores GA's potential for enhancing electric generators and integrating into flexible, wearable technologies. Future research directions are emphasised, particularly regarding GA's potential applications in waste management and environmental protection. The review was conducted through a thorough literature search, prioritising peer-reviewed sources related to GA synthesis and supercapacitor applications. Methodological quality and potential biases of the included studies were assessed using principles similar to the Cochrane Risk of Bias tool. Thematic analysis was employed to synthesise findings and identify key trends and challenges. Limitations such as potential biases and methodological variations are discussed. Overall, this review highlights the technological prospects of GA and provides guidance for future research in supercapacitor development and applications.

3D-printed aerogels as theranostic implants monitored by fluorescence bioimaging.

Aerogel scaffolds are nanostructured materials with beneficial properties for tissue engineering applications. The tracing of the state of the aerogels after their implantation is challenging due to their variable biodegradation rate and the lack of suitable strategies capable of in vivo monitoring the scaffolds. Upconversion nanoparticles (UCNPs) have emerged as advanced tools for in vitro bioimaging because of their fluorescence properties. In this work, highly fluorescent UCNPs were loaded into aerogels to obtain theranostic implants for tissue engineering and bioimaging applications. 3D-printed alginate-hydroxyapatite aerogels labeled with UCNPs were manufactured by 3D-printing and supercritical CO2 drying to generate personalize-to-patient aerogels. The physicochemical performance of the resulting structures was evaluated by printing fidelity measurements, nitrogen adsorption-desorption analysis, and different microscopies (confocal, transmission and scanning electron microscopies). Stability of the aerogels in terms of physicochemical properties was also tested after 3 years of storage. Biocompatibility was evaluated in vitro by different cell and hemocompatibility assays, in ovo and in vivo by safety and bioimaging studies using different murine models. Cytokines profile, tissue index and histological evaluations of the main organs unveiled an in vivo downregulation of the inflammation after implantation of the scaffolds. UCNPs-decorated aerogels were first-time manufactured and long-term traceable by fluorescence-based bioimaging until 3 weeks post-implantation, thereby endorsing their suitability as tissue engineering and theranostic nanodevices (i.e. bifunctional implants).

Emulsion-Based Multiscale Structural Design Realizes Lightweight and Superelastic Graphene Aerogels for Electromagnetic Interference Shielding.

Ultralight graphene aerogels with high electrical conductivity and superelasticity are demanded yet difficult to produce. A versatile emulsion-based approach is demonstrate to optimize multiscale structure of lightweight, elastic, and conductive graphene aerogels. By constructing Pickering emulsion using graphene oxide (GO), poly (amic acid) (PAA), and octadeyl amine (ODA), micron-level close-pore structure is realized while thermal shrinkage mismatch between GO and PAA creates numerous nanowrinkles during thermal annealing. GO nanosheets are bridged by PAA-derived carbon, enhancing the structural integrity at molecular level. These multiscale structural features facilitate rapid electron transport and efficient load transfer, conferring graphene aerogels with intriguing mechanical and electromagnetic interference (EMI) shielding properties. The emulsion-based graphene aerogel with an ultralow density of ≈3.0 mg cm-3 integrates outstanding electrical conductivity, air-caliber thermal insulation, high EMI shielding effectiveness of 75.0 dB, and 90% strain compressibility with superb fatigue resistance. Intriguingly, thanks to the gel-like rheological behavior of the emulsion, ultralight graphene scaffolds with programmable geometries are obtained by 3D printing. This work provides a general approach for the preparation of ultralight and superelastic graphene aerogels with excellent EMI shielding properties, showing broad application prospects in various fields.

Integrated processes (HPSE+scCO2) to prepare sterilized alginate-gelatine-based aerogel.

Biopolymers application in biomedical areas has been limited due to the physicochemical degradation that occurs using conventional processing/sterilization methods (e.g., steam heat, γ-radiation, ethylene oxide). Aiming to avoid/minimize degradation and preserve their properties, supercritical carbon dioxide (scCO2) has been proposed as an alternative sterilization method for such materials. ScCO2 can simultaneously be used as a drying method to produce aerogels (i) and sterilize them (ii). However, a solvent exchange is required to prepare the alcogel from hydrogel, achievable through high-pressure solvent exchange (HPSE) (iii). This study integrated three processes: HPSE, scCO2 drying, and sterilization to prepare alginate-gelatine sterilized aerogels. Two scCO2 sterilization methods were tested. Results showed that sterilization did not compromise the aerogels' chemical, thermal and swelling properties. Conversely, Young's Modulus increased, and BET surface area decreased, due to the structural changes caused by the fast pressurization/depressurization rates applied during sterilization. Regarding the sterilization efficiency, results showed a reduction in contamination throughout the process, achieving a SAL of 10-4. The sterilized aerogels were non-cytotoxic in vitro and showed improved wound-healing properties. The innovative integrated process produced decontaminated/sterile and ready-to-use aerogels reducing process time by 75 %, from 2 days up to 12 h without compromising the aerogel's properties.

High-Performance Organic Aerogels Tailored for Versatile Recycling Approaches: Recycling-Reforming-Upcycling.

Organic aerogels are emerging as promising materials due to their versatile properties, rendering them excellent candidates for a variety of applications in the fields of thermal insulation, energy storage, pharmaceuticals, chemical adsorption, and catalysis. However, current aerogel designs rely on cross-linked polymer networks, which lack efficient end-of-use solutions, thereby hindering their overall sustainability. In this study, a facile synthesis of organic aerogels with a unique combination of imine and cyanurate moieties is presented, resulting in high-performance, lightweight insulating materials. The aerogels' structure, ensures mechanical robustness, thermal resistance, and hydrophobicity without additional treatments, crucial for long-term performance. Additionally, in response to the currently unsustainable use of cross-linked polymer materials, the molecular design offers diverse avenues of chemical recycling. These include full depolymerization back into the original monomers, partial network fragmentation producing soluble oligomers that can be promptly employed to fabricate new aerogels, and upcycling of aerogel waste into useful building blocks. This work pioneers a novel approach to material design, emphasizing recyclability as a core feature while maintaining high-performance excellence.

Customized Pore Creation Strategies for Hyperelastic, Robust, Insulating Multifunctional MXene Aerogels for Microwave Absorption.

The construction of heterogeneous microstructure and the selection of multicomponents have turned into a research hotspot in developing ultralight, multifunctional, high-efficiency electromagnetic wave absorbing (EMA) materials. Although aerogels are promising materials to fulfill the above requirements, the increase in functional fillers inevitably leads to the deterioration of intrinsic properties. Tuning the electromagnetic properties from the structural design point of view remains a difficult challenge. Herein, we design customized pore creation strategies via introducing sacrificial templates to optimize the conductive path and construct the discontinuous dielectric medium, increasing dielectric loss and achieving efficient microwave absorption properties. A 3D porous composite (MEM) was crafted, which encapsulated an EVA/FeCoNi (EVA/MNPs) framework with Ti3C2Tx MXene coating by employing a direct heated cross-linking and immersion method. Controllable adjustment of the conductive network inside the porous structure and regulation of the dielectric character are achieved by porosity variation. Eventually, the MEM-5 with a porosity of 66.67% realizes RLmin of -39.2 dB (2.2 mm) and can cover the entire X band. Moreover, through off-axis electronic holography and the calculation of conduction loss and polarization loss, the dielectric property is deeply investigated, and the inner mechanism of optimization is pointed out. Thanks to the inherent characteristic of EVA and the porous structure, MEM-5 showed excellent thermal insulating and superior compressibility, which can maintain 60 °C on a 90-100 °C continuous heating stage and reached a maximum compressive strength of 60.12 kPa at 50% strain. Conceivably, this work provides a facile method for the fabrication of highly efficient microwave absorbers applied under complex conditions.

3D-Printed Interfacially Jammed Emulsion Aerogels.

3D printing ultralightweight porous structures using direct ink writing (DIW) while maintaining their mechanical robustness is highly challenging. This difficulty is amplified when low ink concentrations are used to create complex geometries. Herein, this shortfall was addressed by interfacially jammed emulsion gels. The gel emerged from the electrostatic interaction among synergized nanomaterials (graphene oxide (GO) and cellulose nanocrystals (CNCs)) in the aqueous phase and a ligand in the oil phase. This interaction led to the jamming of the nanoparticles and the creation of stable emulsion gels. The formed interfacial assemblies were further treated by post-jamming ionic cross-linking with NaHCO3, which dictated the emulsion gels' rheological characteristics, enhancing the ink's viscoelastic properties for high-resolution 3D printing. The customizable emulsion system allows control over porosity from the macro- to the micro-scale and generates complex geometries with desired compositions. By manipulating post-annealing processes and varying concentrations, it is possible to achieve aerogels that feature a remarkably low density (∼2.63 mg/cm3) and adjustable mechanical robustness (elastic modulus of 0.45 MPa). Additionally, this method allows for producing aerogels with flexible or stiff characteristics as required, alongside the capability to tailor specific electromagnetic shielding effectiveness (ranging from 6791 to 19615 dB cm2/g), showcasing the technique's versatility and engineerability.

Wide-temperature-range pressure sensing by an aramid nanofibers/reduced graphene oxide flakes composite aerogel.

Aerogel-based conductive materials have emerged as a major candidate for piezoresistive pressure sensors due to their excellent mechanical and electrical performance besides light-weighted and low-cost characteristics, showing great potential for applications in electronic skins, biomedicine, robot controlling and intelligent recognition. However, it remains a grand challenge for these piezoresistive sensors to achieve a high sensitivity across a wide working temperature range. Herein, we report a highly flexible and ultra-light composite aerogel consisting of aramid nanofibers (ANFs) and reduced graphene oxide flakes (rGOFs) for application as a high-performance pressure sensing material in a wide temperature range. By controlling the orientations of pores in the composite framework, the aerogel promotes pressure transfer by aligning its conductive channels. As a result, the ANFs/rGOFs aerogel-based piezoresistive sensor exhibits a high sensitivity of up to 7.10 kPa-1, an excellent stability over 12,000 cycles, and an ultra-wide working temperature range from -196 to 200 °C. It is anticipated that the ANFs/rGOFs composite aerogel can be used as reliable sensing materials in extreme environments.

Electrothermally-Driven Ultrafast Chemical Modulation of Multifunctional Nanocarbon Aerogels.

Ultrahigh-temperature Joule-heating of carbon nanostructures opens up unique opportunities for property enhancements and expanded applications. This study employs rapid electrical Joule-heating at ultrahigh temperatures (up to 3000 K within 60 s) to induce a transformation in nanocarbon aerogels, resulting in highly graphitic structures. These aerogels function as versatile platforms for synthesizing customizable metal oxide nanoparticles while significantly reducing carbon emissions compared to conventional furnace heating methods. The thermal conductivity of the aerogel, characterized by Umklapp scattering, can be precisely adjusted by tuning the heating temperature. Utilizing the aerogel's superhydrophobic properties enables its practical application in filtration systems for efficiently separating toxic halogenated solvents from water. The hierarchically porous aerogel, featuring a high surface area of 607 m2 g-1, ensures the uniform distribution and spacing of embedded metal oxide nanoparticles, offering considerable advantages for catalytic applications. These findings demonstrate exceptional catalytic performance in oxidative desulfurization, achieving a 98.9% conversion of dibenzothiophene in the model fuel. These results are corroborated by theoretical calculations, surpassing many high-performance catalysts. This work highlights the pragmatic and highly efficient use of nanocarbon structures in nanoparticle synthesis under ultrahigh temperatures, with short heating durations. Its broad implications extend to the fields of electrochemistry, energy storage, and high-temperature sensing.

Mullite-Fibers-Reinforced Bagasse Cellulose Aerogels with Excellent Mechanical, Flame Retardant, and Thermal Insulation Properties.

Cellulose aerogels are considered as ideal thermal insulation materials owing to their excellent properties such as a low density, high porosity, and low thermal conductivity. However, they still suffer from poor mechanical properties and low flame retardancy. In this study, mullite-fibers-reinforced bagasse cellulose (Mubce) aerogels are designed using bagasse cellulose as the raw material, mullite fibers as the reinforcing agent, glutaraldehyde as the cross-linking agent, and chitosan as the additive. The resulted Mubce aerogels exhibit a low density of 0.085 g/cm3, a high porosity of 93.2%, a low thermal conductivity of 0.0276 W/(m∙K), superior mechanical performances, and an enhanced flame retardancy. The present work offers a novel and straightforward strategy for creating high-performance aerogels, aiming to broaden the application of cellulose aerogels in thermal insulation.

A novel three-dimensional porous Ag/TiO2 hybrid aerogels with high dense hot spot as effective SERS substrate for ultrasensitive detection.

This research focuses on preparing a series of new TiO2/Ag hybrid aerogels with varying TiO2 contents, and demonstrates their application as ultrasensitive SERS substrates. The synthesized TiO2/Ag hybrid aerogels exhibited excellent SERS behavior when detecting 4-Mercaptobenzoic acid (4-MBA), and the calculated SERS enhancement factor (EF) was 6.34 × 106. 3D structured aerogels can create more hot spots and adsorption sites, and multiple interband chemical transfer (CT) pathways emerged and enhanced CT efficiency because of the large number of surface oxygen vacancies of meso-TiO2 NPs. Therefore, the synergy of electromagnetic field enhancement and chemical enhancement leads to SERS enhancement. In addition, the composite SERS substrate has high sensitivity, and the detection limit of adsorbed 4-MBA probe molecules reaches 10-11 M. Furthermore, the TiO2/Ag hybrid aerogels demonstrate good reproducibility with minimal standard deviation in terms of SERS signals. In addition, even after standing for 6 months, there is almost no attenuation in the SERS signal intensity, which highlights the excellent stability of this substrate. Therefore, these highly sensitive TiO2/Ag hybrid aerogels SERS substrates have important practical value in environmental monitoring, medical inspection and food supervision.

Coaxial nanofibrous aerogel featuring porous network-structured channels for ovarian cancer treatment by sustained release of chitosan oligosaccharide.

Ovarian cancer, the deadliest gynecological malignancy, primarily treated with chemotherapy. However, systemic chemotherapy often leads to severe toxic side effects and chemoresistance. Drug-loaded aerogels have emerged as a promising method for drug delivery, as they can improve drug solubility and bioavailability, control drug release, and reduce drug distribution in non-targeted tissues, thereby minimizing side effects. In this research, chitosan oligosaccharide (COS)-loaded nanofibers composite chitosan (CS) aerogels (COS-NFs/CS) with a porous network structure were created using nanofiber recombination and freeze-drying techniques. The core layer of the aerogel has a COS loading rate of 60 %, enabling the COS-NFs/CS aerogel to significantly inhibit the migration and proliferation of ovarian cancer cells (resulting in a decrease in the survival rate of ovarian cancer cells to 33.70 % after 48 h). The coaxial fiber's unique shell-core structure and the aerogel's porous network structure enable the COS-NFs/CS aerogels to release COS steadily and slowly over 30 days, effectively reducing the initial burst release of COS. Additionally, the COS-NFs/CS aerogels exhibit good biocompatibility, degradability (only retaining 18.52 % of their weight after 6 weeks of implantation), and promote angiogenesis, thus promoting wound healing post-oophorectomy. In conclusion, COS-NFs/CS aerogels show great potential for application in the treatment of ovarian cancer.

Intelligent and biocompatible cellulose aerogels featured with high-elastic and fast-hemostatic for epistaxis and wound healing.

Nasal tamponade is a commonly employed and highly effective treatment method for preventing nasal bleeding. However, the current nasal packing hemostatic materials exhibit some limitations, such as low hemostatic efficiency, the potential for causing secondary injury when removed from the nasal cavity, limited intelligence in their design, and an inability to promote the healing of nasal mucosa wounds. Herein, we report the fabrication of a smart cellulose aerogel through the covalent cross-linking of carboxymethyl cellulose (CMC) macromolecules, while incorporating one-dimensional cellulose nanofibers (CNF) and two-dimensional MXene as reinforcing network scaffolds and conductive fillers. The abundant hydrogen and ether bonds in aerogels make them possess high elasticity in both dry and wet states, which can be compressed 100 times at 90 % deformation with a stress loss of <10 % under water. The highly elastic aerogels can be filled into the narrow nasal passages, pressuring the capillaries and reducing the amount of bleeding. Moreover, the strong interface between aerogels and blood can promote red blood cell aggregation, platelet adhesion and activation, activate intrinsic coagulation pathway and accelerate blood coagulation, resulting in excellent hemostatic ability. Furthermore, the aerogels exhibit excellent hemocompatibility and cytocompatibility, making them suitable for wound healing and capable of fully healing wounds within 15 days. Notably, the presence of MXene causes the aerogels to form a conductive network when exposed to blood, enabling them to perform real-time hemostatic monitoring without removing the dressing. This innovative biomedical aerogel, prepared from natural materials, shows excellent potential for applications in rapid nasal hemostasis.

Enhancing cellulose-stabilized multiphase/Pickering emulsions systems: A molecular dynamics perspective.

Cellulose stabilized multiphase systems (CSMS) have garnered significant attention due to their ultra-stabilization mechanism and vast potential across different fields. CSMS have found valuable applications in scientific disciplines, including Food Science, Pharmaceutical Science, Material Science, and related fields, owing to their beneficial attributes such as sustainability, safety, renewability, and non-toxicity. Furthermore, MPS exhibit novel characteristics that enable multiple mechanisms to produce HIPEs, aerogels, and oleogels revealing undiscovered information. Therefore, to explore the undiscovered phenomena of MPS, molecular level insights using advanced simulation/computational approaches are essential. The molecular dynamics simulation (MDS), play a valuable role in analyzing the interactions of ternary interphase. The MDS have successfully quantified the interactions of MPS by generating, visualizing, and analyzing trajectories. Through MDS, researchers have explored CSMS at the molecular level and advanced their applications in 3D printing, packaging, preparation, drug delivery, encapsulation, biosensors, electronic devices, biomaterials, and energy conservation. This review highlights the remarkable advancements in CSMS over the past five years, along with contributions of MDS in evaluating the relationships that dictate the functionality and properties of CSMS. By integrating experimental and computational methods, we underscore the potential to innovate and optimize these multiphase systems for groundbreaking applications.

Bidirectional, Multilayer MXene/Polyimide Aerogels for Ultra-Broadband Microwave Absorption.

To obtain high-performance electromagnetic microwave (EM) absorption materials with broad effective absorption bandwidth (EAB) and reduced thickness, designing structures has proved to be a promising way. Herein, ultra-broadband multilayer bidirectional MXene/polyimide EM absorption aerogels containing multi-structures on scales ranging from the micro- to the macroscale are produced with the aid of electric and temperature fields. On the microscale, under the action of electric force and temperature gradient, the ordered structures made of aligned Ti3C2Tx MXene nanosheets and the microscale layered aerogel walls enable the bidirectional aerogel to achieve a wide EAB of 8.58 GHz at a thickness of 2.1 mm. This is ascribed to the numerous aligned nanosheets and layered aerogel walls perpendicular to the incident EMs, facilitating the conversion of electromagnetic energy into electrical energy. Furthermore, on the macroscale, the multilayer bidirectional aerogel with non-gradient structures effectively resolves the conflict between impedance matching and energy loss, resulting in an ultrawide EAB of 9.41 GHz at a thickness of 3 mm. This innovative design of electric-field-assisted multilayer bidirectional aerogels with multiscale structural coupling may provide feasible and effective pathways for the development of advanced EM absorption materials.