Wetting transitions in adhesive surfaces of polystyrene: The petal effect.

HYPOTHESIS: The petal effect is a well-known natural phenomenon in surface science and has served as inspiration for the creation of several materials with superhydrophobic qualities and high adhesion. As surface roughness has a crucial role in these properties, being able to modulate it could help us design materials at will. Capillary penetration frustrates diffusion and promotes large contact angles as well as high adhesion. EXPERIMENTS: Polystyrene surfaces were created using the spin-coating technique. By varying the polymer concentration, the surface roughness was modified. To determine the roughness parameters, atomic force microscopy was used. We recorded advancing and receding contact angles using water and glycerol as test liquids to study contact angle hysteresis, the work of adhesion and the apparent surface energy, which was determined with the Chibowski and Perea-Carpio method. For the purpose of elucidating the wetting states, captive bubble experiments were conducted. FINDINGS: Using an easy method, we create polystyrene surfaces with both superhydrophobicity and strong adhesion, where the roughness area factor regulates wetting transitions from Cassie-Baxter to Wenzel. The receding contact angle suggests capillary penetration, which we demonstrate by captive bubble experiments. In addition, a link was found between the surface roughness and apparent surface energy.

Novel Apoplastic Antifreeze Proteins of Deschampsia antarctica as Enhancer of Common Cell Freezing Media for Cryobanking of Genetic Resources, a Preliminary Study.

Antifreeze proteins (AFPs) are natural biomolecules found in cold-adapted organisms that lower the freezing point of water, allowing survival in icy conditions. These proteins have the potential to improve cryopreservation techniques by enhancing the quality of genetic material postthaw. Deschampsia antarctica, a freezing-tolerant plant, possesses AFPs and is a promising candidate for cryopreservation applications. In this study, we investigated the cryoprotective properties of AFPs from D. antarctica extracts on Atlantic salmon spermatozoa. Apoplastic extracts were used to determine ice recrystallization inhibition (IRI), thermal hysteresis (TH) activities and ice crystal morphology. Spermatozoa were cryopreserved using a standard cryoprotectant medium (C+) and three alternative media supplemented with apoplastic extracts. Flow cytometry was employed to measure plasma membrane integrity (PMI) and mitochondrial membrane potential (MMP) postthaw. Results showed that a low concentration of AFPs (0.05 mg/mL) provided significant IRI activity. Apoplastic extracts from D. antarctica demonstrated a cryoprotective effect on salmon spermatozoa, with PMI comparable to the standard medium. Moreover, samples treated with apoplastic extracts exhibited a higher percentage of cells with high MMP. These findings represent the first and preliminary report that suggests that AFPs derived from apoplastic extracts of D. antarctica have the potential to serve as cryoprotectants and could allow the development of novel freezing media.

Tunable Magnetic Properties of Interconnected Permalloy Nanowire Networks.

In this study, we investigate the magnetic properties of interconnected permalloy nanowire networks using micromagnetic simulations. The effects of interconnectivity on the hysteresis curves, coercivity, and remanence of the nanowire networks are analyzed. Our results reveal intriguing characteristics of the hysteresis curves, including nonmonotonic behaviors of coercivity as a function of the position of horizontal nanowires relative to vertical nanowires. By introducing horizontal nanowires at specific positions, the coercivity of the nanowire networks can be enhanced without altering the material composition. The normalized remanence remains relatively constant regardless of the position of the horizontal wires, although it is lower in the interconnected nanowire arrays compared to nonconnected arrays. These findings provide valuable insights into the design and optimization of nanowire networks for applications requiring tailored magnetic properties.

Ocular Biomechanics and Glaucoma.

Biomechanics is a branch of biophysics that deals with mechanics applied to biology. Corneal biomechanics have an important role in managing patients with glaucoma. While evidence suggests that patients with thin and stiffer corneas have a higher risk of developing glaucoma, it also influences the accurate measurement of intraocular pressure. We reviewed the pertinent literature to help increase our understanding of the biomechanics of the cornea and other ocular structures and how they can help optimize clinical and surgical treatments, taking into consideration individual variabilities, improve the diagnosis of suspected patients, and help monitor the response to treatment.

Static and Dynamic Magnetic Properties of Fe3O4 Nanotubes.

In this paper, our objective was to investigate the static and dynamic magnetic properties of Fe3O4 nanotubes that are 1000 nm long, by varying the external radius and the thickness of the tube wall. We performed a detailed numerical analysis by simulating hysteresis curves with an external magnetic field applied parallel to the axis of the tubes (along the z-axis). Our findings indicate that nanotubes with an external radius of 30 nm exhibit non-monotonic behavior in their coercivity due to a change in the magnetization reversal mechanism, which was not observed in nanotubes with external radii of 80 nm. Additionally, we explored the dynamic susceptibility of these nanotubes and found that the position and number of resonance peaks can be controlled by manipulating the nanotube geometry. Overall, our study provides valuable insights into the behavior of Fe3O4 nanotubes, which can aid in the design and improvement in pseudo-one-dimensional technological devices.

Utilização de caneca de alumínio como material alternativo para temperatura de globo de Vernon / Use of aluminum mug as alternative material for Vernon globe temperature

Diversos estudos relacionados à viabilidade e eficiência do uso de materiais alternativos ao globo de Vernon têm sido realizados, principalmente em decorrência ao preço elevado do cobre, componente do instrumento padrão. O objetivo foi avaliar a eficiência da utilização de caneca de alumínio como material alternativo para substituição do globo de Vernon. Para a confecção do protótipo empregou-se uma caneca de alumínio, utilizada em pistola de pintura, com capacidade de 50 ml. A caneca foi pintada com tinta preto-fosca, em duas camadas e um termômetro de mercúrio foi inserido ao centro. Para realização dos testes foram utilizados quatro equipamentos (dois globos de Vernon e dois globos negros alternativos). Foram efetuados testes prévios de comportamento temporal. Estabelecido o tempo, as temperaturas dos globos foram coletadas durante sete dias consecutivos, em três períodos, de 15 minutos cada. Os registros de temperatura foram realizados a cada cinco minutos, num total de 84 por equipamento. Os dados foram submetidos a análise de correlação de Pearson. Os resultados indicaram correlação positiva com o r2 de 0,9927, estabelecendo uma forte correlação entre os resultados de temperatura média do globo negro alternativo e globo de Vernon. Conclui-se que o globo negro alternativo do tipo caneca de alumínio mostrou-se eficiente para aferição da temperatura de globo negro em estudos de ambiência em substituição ao Globo de Vernon.(AU)

Several studies related to the feasibility and efficiency of using alternative materials to Vernon's globe have been carried out, mainly due to the high price of copper, a component of the standard instrument. The objective was to evaluate the efficiency of using an aluminum mug as an alternative material for replacing Vernon's globe. To make the prototype, an aluminum mug was used, used in a paint gun, with a capacity of 50 ml. The mug was painted with matte black paint, in two layers and a mercury thermometer was inserted in the center. Four pieces of equipment were used to carry out the tests (two Vernon globes and two alternative black globes). Previous temporal behavior tests were carried out. Once the time was established, the globes' temperatures were collected for seven consecutive days, in three periods of 15 minutes each. Temperature records were taken every five minutes, a total of 84 per equipment. Data were subjected to Pearson's correlation analysis. The results indicated a positive correlation with the r2 of 0.9927, establishing a strong correlation between the mean temperature results of the alternative black globe and Vernon's globe. It is concluded that the alternative black globe of the aluminum mug type proved tobe efficient for measuring the temperature of the black globe in ambience studies, replacing the Vernon Globe.(AU)

Effect of antifreeze proteins on the freeze-thaw cycle of foods: fundamentals, mechanisms of action, current challenges and recommendations for future work.

Freezing is widely used in food preservation, but if not carried out properly, ice crystals can multiply (nucleation) or grow (recrystallization) rapidly. This also affects thawing, causing structural damage and affecting overall quality. The objective of this review is to comprehensively study the cryoprotective effect of antifreeze proteins (AFPs), highlighting their role in the freeze-thaw process of food. The properties of AFPs are based on their thermal hysteresis capacity (THC), on the modification of crystal morphology and on the inhibition of ice recrystallization. The mechanism of action of AFPs is based on the adsorption-inhibition theory, but the specific role of hydrogen and hydrophobic bonds/residues and structural characteristics is also detailed. Because of the properties of AFPs, they have been successfully used to preserve the quality of a wide variety of refrigerated and frozen foods. Among the limitations of the use of AFPs, the high cost of production stands out, but currently there are solutions such as the use the production of recombinant proteins, cloning and chemical synthesis. Although in vitro, in vivo and human studies have shown that AFPs are non-toxic, their safety remains a matter of debate. Further studies are recommended to expand knowledge about AFPs, to reduce costs in their large-scale production, to understand their interaction with other food compounds and their possible effects on the consumer.

SMM Behaviour of the Butterfly {CrIII 2 DyIII 2 } Pivalate Complex and Magneto-structurally Correlated Relaxation Thermal Barrier.

We are reporting the synthesis, single-crystal X-ray structure characterization, and magnetic property investigations of the pivalate butterfly {CrIII 2 LnIII 2 } complexes with Ln= Gd and Dy and the isostructural Y(III) sample. We found an anti-ferromagnetic Cr(III)-Ln(III) exchange interaction, which, as previously observed in related Cr(III)/Ln(III) systems, plays a key role in suppressing quantum tunnelling of magnetization and enhances the SMM performance in the Dy(III) complex. In fact, a pure Orbach relaxation mechanism, with absence of QT regime, is observed with a thermal barrier of 50 cm-1 , leading to magnetization hysteresis opening, measured with a commercial magnetometer, up to 3.6 K with a coercive field of 2.9 T. Analysis of SMM behaviour in literature-known butterfly {CrIII 2 DyIII 2 } complexes, reveals the existence of a magneto-structural correlation between Ueff , the thermal barrier size, and the mean Cr-Dy bond distances. Moreover, a clear correlation is found for the thermal barrier magnitude and the maximum temperature hysteresis opening and coercive field.

Catalytic behavior of gold nanoparticles supported on a TiO2-Al2O3 mixed oxide for CO oxidation at low temperature.

The present work highlights the versatility of a TiO2-Al2O3 mixed oxide bearing highly dispersed gold nanoparticles that was applied in the CO oxidation reaction at room temperature. The TiO2, Al2O3, and TiO2-Al2O3 supports were synthesized by the sol-gel method, while gold nanoparticles were added by the deposition-precipitation with urea method using a theoretical Au loading of 2 wt.%. A promotional effect of the TiO2-Al2O3 support on the activity of gold catalysts with respect to TiO2 and Al2O3 was observed; Au/TiO2-Al2O3 showed outstanding CO oxidation, being active from 0 °C and stable throughout a 24-h test. As for the alumina content (5, 10, and 15 wt.%) in TiO2, it improved the textural properties by retarding the crystal growth and anatase-rutile phase transformation of TiO2, suppressing the deposition of carbon on the catalyst surface and stabilizing the Au nanoparticles even at high temperatures. Gold was highly dispersed with nanoparticle sizes ranging from 1 to 2 nm when H2 was used to treat thermally the Au/TiO2-Al2O3, Au/TiO2, and Au/Al2O3 materials. In addition, the XPS technique helped elicit that Au0 and Au1+ boosted their interaction with the TiO2, Al2O3, and TiO2-Al2O3 supports by means of charge transfer, which resulted in outstanding CO oxidation activity from 0 °C. Likewise, the key factors that control the peculiar catalytic performance in the CO oxidation reaction are discussed, which represents a step forward in the versatility behavior of gold catalysts supported on mixed oxide catalysts.

Shaking Table Attached to Magnetorheological Damper: Simulation and Experiments for Structural Engineering.

This paper details how to construct a small-scale shaking table attached to a magnetorheological (MR) damper. The motivation for this construction relies on the increasing interest in modeling the dynamics of MR dampers-MR dampers have been used in structures for safety reasons. To model the MR damper, we use the so-called 'Dahl model', which is useful to represent systems with a hysteresis. The Dahl model, validated through experimental data collected in a laboratory, was combined with a linear model to represent a two-story building. This two-story building model allows us to simulate the dynamics of that building when its floors are attached to MR dampers. By doing so, we can assess-through simulation-to what extent MR dampers can protect structures from vibrations. Using data from the 'El Centro' earthquake (1940), we can conclude that MR dampers have the potential to reduce the impact of earthquakes upon structures. This finding emphasizes the potential benefits of MR dampers for the safety of structures, which is a conclusion taken from the apparatus detailed in this paper.

Comparison of Carotid Intima-Media Thickness in Children and Adults With and Without Obesity: A Hysteresis Model.

OBJECTIVE: To describe a third-degree polynomial function (hysteresis) of the effect size of age, obesity, and insulin sensitivity over the carotid intima-media thickness (c-IMT), in the pediatric and adult groups. METHODS: A quasi-experimental study with fixed factor analysis of age (children aged 8-12 years, n = 73; adults aged 21-45 years, n = 82) and obesity (yes, n = 76; no, n = 79) was conducted to analyze the effect on the c-IMT and Matsuda insulin sensitivity index values. This quasi-experimental design was analyzed with robust regression modeling. RESULTS: The additive effect of obesity, independent of age, was evident in the case of the c-IMT values. There was no interaction effect, but a significant difference between participants with normal weight and those with obesity was found (P < .0001). The difference between adults and children was also significant, but the effect size was smaller. A model was created based on age, Tanner stage, and obesity using the c-IMT and Matsuda insulin sensitivity index values. A linear function fit as R2, and the cubic function estimated parameters like a polynomial model. CONCLUSION: This practical study design showed that children with obesity displayed the same levels of carotid intima-media abnormalities as adults with obesity. The polynomial shape of the model suggests potentially poor outcomes that resemble the hysteresis process and may predict chronic cardiometabolic events during early adulthood.

Corneal biomechanics and glaucoma beyond the bidirectional impact of intraocular pressure and corneal deformation response / Biomecânica corneana e glaucoma além do impacto bididirecional da pressão intraocular e da resposta da deformação corneana

ABSTRACT The purpose of this study was to highlight the impact of biomechanical corneal response in available in vivo tonometry methods for glaucoma management. Systematic review of non-contact air-puff tonometers that analyzes the corneal deformation response, with special focus on the investigation of the correlation of derived parameters with intraocular pressure measurements. The two actual and commercially available in vivo corneal tonometers provide promising information about biomechanical characteristics of the cornea and its relation to glaucoma, allowing the development of new protocols to evaluate, diagnose, and manage this disease.

RESUMO O objetivo deste estudo é destacar o impacto da resposta biomecânica corneana em métodos de tonometria in vivo disponíveis para o manejo do glaucoma. Trata-se de revisão sistemática de tonômetros de ar que analisa a resposta à deformação corneana, com foco especial na investigação da correlação dos parâmetros derivados com as medições da pressão intraocular. Os dois tonômetros mais recentes e comercialmente disponíveis fornecem informações promissoras sobre as características biomecânicas da córnea e sua relação com o glaucoma, permitindo o desenvolvimento de novos protocolos para avaliar, diagnosticar e controlar a doença.

Design, Simulation, and Fabrication of a Copper-Chrome-Based Glass Heater Integrated into a PMMA Microfluidic System.

In this paper, the development of a copper-chrome-based glass microheater and its integration into a Polymethylmethacrylate (PMMA) microfluidic system are presented. The process highlights the importance of an appropriate characterization, taking advantage of computer-simulated physical methods in the heat transfer process. The presented system architecture allows the integration for the development of a thermal flow sensor, in which the fluid flows through a 1 mm width × 1 mm length microchannel across a 5 mm width × 13 mm length heating surface. Using an electrothermal analysis, based on a simulation and design process, the surface heating behavior curve was analyzed to choose a heating reference point, primarily used to control the temperature point within the fluidic microsystem. The heater was characterized using the theory of electrical instrumentation, with a 7.22% error for the heating characterization and a 5.42% error for the power consumption, measured at 0.69 W at a temperature of 70 °C. Further tests, at a temperature of 115 °C, were used to observe the effects of the heat transfer through convection on the fluid and the heater surface for different flow rates, which can be used for the development of thermal flowmeters using the configuration presented in this work.

Effect of Calcination Temperature and Chemical Composition of PAN-Derived Carbon Microfibers on N2, CO2, and CH4 Adsorption.

This work investigates the interplay of carbonization temperature and the chemical composition of carbon microfibers (CMFs), and their impact on the equilibration time and adsorption of three molecules (N2, CO2, and CH4). PAN derived CMFs were synthesized by electrospinning and calcined at three distinct temperatures (600, 700 and 800 °C), which led to samples with different textural and chemical properties assessed by FTIR, TGA/DTA, XRD, Raman, TEM, XPS, and N2 adsorption. We examine why samples calcined at low/moderate temperatures (600 and 700 °C) show an open hysteresis loop in nitrogen adsorption/desorption isotherms at -196.15 °C. The equilibrium time in adsorption measurements is nearly the same for these samples, despite their distinct chemical compositions. Increasing the equilibrium time did not allow for the closure of the hysteresis loop, but by rising the analysis temperature this was achieved. By means of the isosteric enthalpy of adsorption measurements and ab initio calculations, adsorbent/adsorbate interactions for CO2, CH4 and N2 were found to be inversely proportional to the temperature of carbonization of the samples (CMF-600 > CMF-700 > CMF-800). The enhancement of adsorbent/adsorbate interaction at lower carbonization temperatures is directly related to the presence of nitrogen and oxygen functional groups on the surface of CMFs. Nonetheless, a higher concentration of heteroatoms also causes: (i) a reduction in the adsorption capacity of CO2 and CH4 and (ii) open hysteresis loops in N2 adsorption at cryogenic temperatures. Therefore, the calcination of PAN derived microfibers at temperatures above 800 °C is recommended, which results in materials with suitable micropore volume and a low content of surface heteroatoms, leading to high CO2 uptake while keeping acceptable selectivity with regards to CH4 and moderate adsorption enthalpies.

Immuno-pharmacokinetics of Meglumine Antimoniate in Patients With Cutaneous Leishmaniasis Caused by Leishmania (Viannia).

BACKGROUND: Control of cutaneous leishmaniasis (CL) relies on chemotherapy, yet gaps in our understanding of the determinants of therapeutic outcome impede optimization of antileishmanial drug regimens. Pharmacodynamic (PD) parameters of antimicrobials are based on the relationship between drug concentrations/exposure and microbial kill. However, viable Leishmania persist in a high proportion of individuals despite clinical resolution, indicating that determinants other than parasite clearance are involved in drug efficacy. METHODS: In this study, the profiles of expression of neutrophils, monocytes, Th1 and Th17 gene signatures were characterized in peripheral blood mononuclear cells (PBMCs) during treatment with meglumine antimoniate (MA) and clinical cure of human CL caused by Leishmania (Viannia). We explored relationships of immune gene expression with plasma and intracellular antimony (Sb) concentrations. RESULTS: Our findings show a rapid and orchestrated modulation of gene expression networks upon exposure to MA. We report nonlinear pharmacokinetic/pharmacodynamic (PK/PD) relationships of Sb and gene expression dynamics in PBMCs , concurring with a time lag in the detection of intracellular drug concentrations and with PK evidence of intracellular Sb accumulation. CONCLUSIONS: Our results quantitatively portray the immune dynamics of therapeutic healing, and provide the knowledge base for optimization of antimonial drug treatments, guiding the selection and/or design of targeted drug delivery systems and strategies for targeted immunomodulation.

Hysteresis of pyruvate phosphate dikinase from Trypanosoma cruzi.

Trypanosoma cruzi, the causative agent of Chagas' disease, belongs to the Trypanosomatidae family. The parasite undergoes multiple morphological and metabolic changes during its life cycle, in which it can use both glucose and amino acids as carbon and energy sources. The glycolytic pathway is peculiar in that its first six or seven steps are compartmentalized in glycosomes, and has a two-branched auxiliary glycosomal system functioning beyond the intermediate phosphoenolpyruvate (PEP) that is also used in the cytosol as substrate by pyruvate kinase. The pyruvate phosphate dikinase (PPDK) is the first enzyme of one branch, converting PEP, PPi, and AMP into pyruvate, Pi, and ATP. Here we present a kinetic study of PPDK from T. cruzi that reveals its hysteretic behavior. The length of the lag phase, and therefore the time for reaching higher specific activity values is affected by the concentration of the enzyme, the presence of hydrogen ions and the concentrations of the enzyme's substrates. Additionally, the formation of a more active PPDK with more complex structure is promoted by it substrates and the cation ammonium, indicating that this enzyme equilibrates between the monomeric (less active) and a more complex (more active) form depending on the medium. These results confirm the hysteretic behavior of PPDK and are suggestive for its functioning as a regulatory mechanism of this auxiliary pathway. Such a regulation could serve to distribute the glycolytic flux over the two auxiliary branches as a response to the different environments that the parasite encounters during its life cycle.

Fisiología respiratoria mecánica de la respiración / Mechanics breathing

El trabajo respiratorio se ejerce en una estructura cerrada donde se encuentran los pulmones, estos son sometidos a cambios de presiones determinados por la musculatura pulmonar en las diferentes fases del ciclo respiratorio, lo que generará gradientes y permite la entrada y salida de aire. Se suman a ello el calibre de las vías aéreas, el tipo de flujo, las características de las vías aéreas y del surfactante pulmonar, que determinan un menor o mayor trabajo respiratorio según la condición fisiológica.

The work of breathing is exerted in a closed structure where the lungs are located. These are subjected to pressure changes determined by the pulmonary musculature in the different phases of the respiratory cycle, which will generate gradients and allow the entry and exit of air. In addition to the aforesaid, airway calibre, type of flow, airway characteristics and pulmonary surfactant determine less or more work of breathing depending on the physiological condition.

Monitoring sediment yield for soil and water conservation planning in rural catchments.

Sediment yield in river catchments can cause siltation of reservoirs and channels, carries contaminants adhered to sediment particles, and represents water erosion at the catchment scale, leading to decreased agricultural productivity. Hydrological monitoring enables the understanding of overland flow and soil erosion dynamics. In this study, we analyzed whether the relationship between precipitation (P), water flow (Q), and suspended sediment concentration (SSC) during rainfall events shows the usefulness of hydrological and sedimentological monitoring in soil and water conservation projects to river catchments. We conducted a study in the Lajeado Ferreira catchment in southern Brazil. This catchment is characterized by high soil fragility and erosion rates because of relief and intense tobacco cultivation. The small size of the catchment (120 ha) allowed a better understanding of the processes that occurred between hillslope and watercourses. We analyzed 43 rainfall-runoff events (P-Q), and we selected characteristic variables of each event and related them to independent variables (climate, land use, and soil management) and their seasonality using regression techniques. We also conducted a hysteresis analysis to understand the behavior of SSC in relation to runoff. The results showed a high relation of sediment yield (SY) with maximum water flow of the event (Qmax), and linear regression models showed the best performance between characteristic variables. In addition, the seasonal variability of the land coverage presented greater influence on the SY than the precipitation itself.

Effect of in vitro cold acclimation of Deschampsia antarctica on the accumulation of proteins with antifreeze activity.

Deschampsia antarctica has managed to colonize the maritime Antarctic. One of the main factors associated with its tolerance to low temperatures is the presence of apoplastic proteins with antifreeze activity. This work focuses on the effect of cold acclimation of D. antarctica on the accumulation of apoplastic proteins with antifreeze activity. Antifreeze proteins present in apoplastic extracts were purified by ice affinity purification, and their identity was determined by protein sequencing. D. antarctica plants were subjected to 22 days of cold acclimation at 4 °C. The highest content of apoplastic proteins with antifreeze activity was obtained at between 12 and 16 days of acclimation. Protein sequencing allowed their identification with >95% probability. Percentage coverage was 74% with D. antarctica ice recrystallization inhibition protein 1 (DaIRIP1) and 55% with DaIRIP3. Cold acclimation of D. antarctica improved the yield of apoplastic proteins, and resulted in an increase in the antifreeze activity of apoplastic extracts. An in silico analysis suggested that the fluctuations presented by the three-dimensional structures of DaIRIPs help to explain the presence of certain DaIRIPs in apoplastic extracts under the cold acclimation conditions evaluated.

Sorption and desorption of diuron on Typic Argiudoll, Oxic Argiudoll and on their clay fractions: environmental aspects.

The sorption and desorption of diuron by soil samples from Horizons A and B (HA and HB) and by their different clay fractions were investigated, using two soil samples, classified as Typic Argiudoll and Oxic Argiudoll. The sorption and desorption curves were adjusted to the Freundlich model and evaluated by parameters Kf, Kd and Koc. Based on the data of groundwater ubiquity score (GUS), leachability index (LIX) and hysteresis index (HI), the risk of groundwater pollution was evaluated. The Kd values obtained for soil samples were between 4.5 mL g-1 (Oxic Argiudoll - HB) and 15.9 mL g-1 (Typic Argiudoll - HA) and between 1.13 and 14.0 mL g-1 for the different mineral fractions, whereas the Koc values varied between 276 (Oxic Argiudoll - HB) and 462 (Typic Argiudoll - HA). According to the parameter GUS, only Oxic Argiudoll - HB presented leaching potential, and based on the LIX index this same soil presented the highest leaching potential. Some samples presented low LIX and GUS values, indicating no leaching potential, but none presented HI results indicative of hysteresis, suggesting weak bonds between diuron and the soil samples and, hence, the risk of groundwater pollution by diuron.