End-of-life vehicle dismantling activity emits large quantities of phthalates and their alternatives: New insights on environmental sources and co-exposure risks.

Automotive interiors have been identified as significant sources of various chemicals, yet their occupational hazards for end-of-life vehicle (ELV) dismantlers remain poorly characterized. Herein, eight classes of plasticizers, including 11 phthalates esters (PAEs) and 16 non-phthalates esters (NPAEs), were detected in dust samples from inside and outside ELV dismantling workshops. Moreover, indoor dust from ordinary households and university dormitories was compared. The indoor dust from the ELV dismantling workshops contained the highest concentrations of plasticizers (median: 594 µg/g), followed by ordinary households (296 µg/g), university dormitories (186 µg/g), and outdoor dust (157 µg/g). PAEs remained the dominant plasticizers, averaging 11.7-fold higher than their NPAE alternatives. Specifically, diisononyl phthalate and trioctyl trimellitate were notably elevated in workshop dust, being 15.5 and 4.78 times higher, respectively, than in ordinary household dust, potentially indicating their association with ELV dismantling activities. The estimated daily intake of occupational ELV dismantling workers was up to five times higher than that of the general population. Moreover, certain dominant NPAEs demonstrated nuclear receptor interference abilities comparable to typical PAEs, suggesting potential toxic effects. This study is the first to demonstrate that ELV dismantling activities contribute to the co-emission of PAEs and NPAEs, posing a substantial risk of exposure to workers, which warrants further investigation.

Occurrence, spatial distribution and ecological risk assessment of Organophosphate Esters in surface water and sediments from the Ravi River and its tributaries.

Organophosphate esters (OPEs) are widely used as substitutes for brominated flame retardants and characterized as emerging contaminants. Due to their toxicity and persistent nature, OPEs are becoming a matter of greater concern worldwide. However, information about the pollution profile of OPEs and associated ecological risks is still scarce in environmental matrices of the South Asian region, particularly Pakistan. Hence, the current study was conducted to investigate the occurrence, spatial distribution patterns, ecological risks and riverine flux of 10 organophosphate esters in surface water and sediments of Ravi River and its four tributaries. The concentrations of ∑10OPEs were in the range of 19.2 - 105 ng/L, with the dominance of chlorinated-OPEs (51 %) in surface water, whereas in case of sediments, the ∑10OPEs concentrations ranged from 20.7 to 149 ng/g dw, with high abundance of non - chlorinated alkyl-OPEs, which contributed about 56 % to total OPE concentration. The correlation analysis signified a strong positive relation of OPEs with TOC (p < 0.05, R = 0.76) in sediments; and in addition to this, field-based LogKoc values were estimated to be higher than predicted LogKoc. Moreover, a significantly positive correlation (p < 0.05, R = 0.88) was observed between LogKoc and LogKow, implying that hydrophobicity plays a significant role in OPE distribution in different environmental matrices. The global comparison revealed that contamination status of OPEs in the present study was comparatively lower than other regional findings, furthermore, principal component analysis suggested vehicular emissions, industrial discharges, household supplies and atmospheric deposition as main sources of OPEs occurrence in current study region. Furthermore, the riverine flux of ∑10OPEs was estimated to be 0.68 tons/yr and the ecological risk assessment indicated that all OPEs, except EHDPP and TCrP, showed negligible or insignificant ecological risks for aquatic organisms.

Fluorotelomer betaines and sulfonic acid in aerobic wetland soil: Stability, biotransformation, and bacterial community response.

The microbial degradation of 6:2 fluorotelomer sulfonic acid (6:2 FTSA), fluorotelomer sulfonamide alkylbetaine (6:2 FTAB), and fluorotelomer betaines (5:3 and 5:1:2 FTB) in aerobic wetland soil was investigated during a 100-day incubation. The half-lives of 6:2 FTSA in the treatments with diethylene glycol butyl ether as the sole carbon source (NA treatment) and with additional supplementation of sodium acetate (ED treatment) were determined to be 26.2 and 16.7 days, respectively. By day 100, ∼20 mol% of 6:2 FTAB was degraded in the NA and ED treatments. The potential transformation products of 6:2 FTSA and 6:2 FTAB were identified using liquid/gas chromatography-high resolution mass spectrometry, and their biotransformation pathways were proposed. In contrast, 5:3 and 5:1:2 FTB exhibited high persistence under two carbon source conditions. There was no intense alteration in the diversity of soil bacterial communities under the stress of fluorotelomer compounds at the level of ∼150 µg/L. The supplementation of sodium acetate led to an enrichment of bacterial species within the genera Hydrogenophaga (phylum Proteobacteria) and Rhodococcus (phylum Actinobacteria), promoting the biodegradation of 6:2 FTSA and 6:2 FTAB and the formation of transformation products. Species from the genus Rhodococcus were potentially crucial functional microorganisms involved in the degradation of 6:2 FTSA.

Multimedia distribution and release characteristics of emerging PFAS in wastewater treatment plants in Tianjin, China.

Legacy and emerging PFAS in the air, wastewater, and sludge from two wastewater treatment plants (WWTPs) in Tianjin were investigated in this study. The semi-quantified nontarget PFAS accounted for up to 99 % of Æ©PFAS in the gas phase, and aqueous film-forming foam (AFFF)-related PFAS were predominant in wastewater (up to 2250 ng/L, 79 % of Æ©PFAS) and sludge (up to 4690 ng/g, 95 % of Æ©PFAS). Furthermore, field-derived air particle-gas, air-wastewater, and wastewater particle-wastewater distribution coefficients of emerging PFAS are characterized, which have rarely been reported. The emerging substitute p-perfluorous nonenoxybenzenesulfonate (OBS) and AFFF-related cationic and zwitterionic PFAS show a stronger tendency to partition into particle phase in air and wastewater than perfluorooctane sulfonic acid (PFOS). The estimated total PFAS emissions from the effluent and sludge of WWTP A were 202 kg/y and 351 kg/y, respectively. While the target PFAS only accounted for 20-33 % of the total emissions, suggesting a significant underestimation of environmental releases of the nontarget PFAS and unknown perfluoroalkyl acid precursors through the wastewater and sludge disposal. Overall, this study highlights the importance of comprehensive monitoring and understanding the behavior of legacy and emerging PFAS in wastewater systems, and fills a critical gap in our understanding of PFAS exposure.

Informal E-waste dismantling activities accelerated the releasing of liquid crystal monomers (LCMs) in Pakistan: Occurrence, distribution, and exposure assessment.

Liquid crystal monomers (LCMs) are emerging contaminants characterized by their persistence, bioaccumulation potential, and toxicity. They have been observed in several environmental matrices associated with electronic waste (e-waste) dismantling activities, particularly in China. However, there is currently no information on the pollution caused by LCMs in other developing countries, such as Pakistan. In this study, we collected soil samples (n = 59) from e-waste dismantling areas with different functions in Pakistan for quantification analysis of 52 target LCMs. Thirty out of 52 LCMs were detected in the soil samples, with the concentrations ranging from 2.14 to 191 ng/g (median: 16.3 ng/g), suggesting widespread contamination by these emerging contaminants. Fluorinated LCMs (median: 10.4 ng/g, range: 1.27-116 ng/g) were frequently detected and their levels were significantly (P < 0.05) higher than those of non-fluorinated LCMs (median: 6.11 ng/g, range: not detected (ND)-76.7 ng/g). The concentrations and profiles of the observed LCMs in the soil samples from the four functional areas varied. The informal dismantling of e-waste poses a potential exposure risk to adults and infants, with median estimated daily intake (EDI, ng/kg bw/day) values of 0.0420 and 0.1013, respectively. Calculation of the hazard quotient (HQ) suggested that some LCMs (e.g., ETFMBC (1.374) and EDFPB (1.257)) may pose potential health risks to occupational workers and their families. Considering the widespread contamination and risks associated with LCMs, we strongly recommend enhancing e-waste management and regulation in Pakistan.

Aromatic amine antioxidants (AAs) and p-phenylenediamines-quinones (PPD-Qs) in e-waste recycling industry park: Occupational exposure and liver X receptors (LXRs) disruption potential.

Recently, evidence of aromatic amine antioxidants (AAs) existence in the dust of the electronic waste (e-waste) dismantling area has been exposed. However, there are limited studies investigating occupational exposure and toxicity associated with AAs and their transformation products (p-phenylenediamines-quinones, i.e., PPD-Qs). In this study, 115 dust and 42 hand wipe samples collected from an e-waste recycling industrial park in central China were analyzed for 19 AAs and 6 PPD-Qs. Notably, the median concentration of ∑6PPD-Qs (1,110 ng/g and 1,970 ng/m2) was significantly higher (p < 0.05, Mann-Whitney U test) than that of ∑6PPDs (147 ng/g and 34.0 ng/m2) in dust and hand wipes. Among the detected analytes, 4-phenylaminodiphenylamine quinone (DPPD-Q) (median: 781 ng/g) and 1,4-Bis(2-naphthylamino) benzene quinone (DNPD-Q) (median: 156 ng/g), were particularly prominent, which were first detected in the e-waste dismantling area. Occupational exposure assessments and nuclear receptor interference ability, conducted through estimated daily intake (EDI) and molecular docking analysis, respectively, indicated significant occupational exposure to PPD-Qs and suggested prioritized Liver X receptors (LXRs) disruption potential of PPDs and PPD-Qs. The study provides the first evidence of considerable levels of AAs and PPD-Qs in the e-waste-related hand wipe samples and underscores the importance of assessing occupational exposure and associated toxicity effects.

Spatial distribution and ecological risk assessment of short and medium chain chlorinated paraffins in water and sediments of river Ravi, Pakistan.

Short (SCCPs) and medium (MCCPs) chain chlorinated paraffins being the emerging organic pollutants have raised serious concerns due to their widespread use and related human health risks. However, their occurrence in aquatic bodies like rivers and associated damage to ecological integrity is yet unknown in some regions of the world. The current study is the first ever assessment of SCCPs and MCCPs in sediment and water of river Ravi, Pakistan. Spatial occurrence and associated ecological risks were investigated from sediments (n = 16) and composite water samples (n = 8) collected at eight locations along the stretch of river Ravi. The concentrations of SCCPs and MCCPs varied from below limit of detection (