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1.
Cryobiology ; 115: 104890, 2024 Jun.
Article En | MEDLINE | ID: mdl-38555012

In the 1970s, sperm cryopreservation was presented as a unique route to fertility preservation. The ability to cryopreserve sperm from all species is challenging. The sperm cryopreservation process encompasses various cellular stresses such as increased osmotic pressure, ice crystal formation, and thermal shock, therefore decreasing the quality of sperm. The nanostructures due to their inherent features such as reactivity, high uptake, active surface area, and antioxidant activity, have contributed to modifying freezing protocols. In this review, the current state of the art with regards to emerging applications of nanotechnology in sperm cryopreservation are reviewed, some of the most promising advances are summarized, and the limitations and advantages are comprehensively discussed.


Cryopreservation , Cryoprotective Agents , Nanostructures , Semen Preservation , Spermatozoa , Cryopreservation/methods , Male , Nanostructures/chemistry , Humans , Spermatozoa/drug effects , Semen Preservation/methods , Cryoprotective Agents/pharmacology , Cryoprotective Agents/chemistry , Animals , Nanotechnology/methods , Fertility Preservation/methods
2.
Eur J Dent Educ ; 28(1): 142-147, 2024 Feb.
Article En | MEDLINE | ID: mdl-37327204

INTRODUCTION: The aim of this study was to understand the trends of teaching Computer Aided Design/Computer Aided Manufacturing (CAD/CAM) in the undergraduate dental curriculum in the MENA region by conducting an online survey among the undergraduate dental colleges in this region. MATERIALS AND METHODS: An online survey was conducted using Google Forms consisting of 20 questions that could be answered by "yes" or "no" responses, multiple-choice answers or in a descriptive, "open" format. A total of 55 participants from the MENA region representing their dental college were requested to participate in this study. RESULTS: The response rate of the survey was 85.5% following the twofold follow-up reminders method. Although the vast majority of professors demonstrated vital knowledge in the practical use of CAD/CAM, the majority of them did not provide theoretical and practical training on CAD/CAM in their institutions. Among the schools with established levels of teaching CAD/CAM, nearly 50% of them provide both pre-clinical and clinical training on CAD/CAM. Despite the availability of extra-curricular training courses on CAD/CAM outside the university setting, there is a lack of advocating for students to enrol in those courses by the institutions. More than 80% of the participants agreed that CAD/CAM has a strong future in chair-side dental clinics and CAD/CAM needs to be incorporated within undergraduate studies. CONCLUSION: Based on the results of the current study, it is understandable that an intervention is required by the dental education providers to cope with the growing demand for CAD/CAM technology for the current and future dental practitioners of the MENA region.


Dentists , Education, Dental , Humans , Professional Role , Students , Technology , Computer-Aided Design
3.
J Biomol Struct Dyn ; : 1-14, 2023 Dec 27.
Article En | MEDLINE | ID: mdl-38149868

Fanconi anemia (FA) is a genetic disorder that occurs when certain genes responsible for repairing DNA replication and promoting homologous recombination fail to function properly. This leads to severe clinical symptoms and a wide range of cancer-related characteristics. Recent treatment approaches for FA involve hematopoietic stem cell transplantation (HSCT), which helps restore the population of stem cells. A survival study using p-values indicated that specific hub genes play a significant role in diagnosing and predicting the disease. To find potential medications that interact with the identified hub genes, researchers inferred drugs. Among hub genes, TP53 was found to be particularly promising through computational analysis. Further investigation focused on two drugs, Topiramate and Tocofersolan predicted based on drug bank database analysis. Molecular docking strategies were employed to assess the best binding pose of these drugs with TP53. Topiramate showed a binding affinity of -6.5 kcal/mol, while Tocofersolan showed -8.5 kcal/mol against the active residues within the binding pocket. Molecular dynamics (MD) simulations were conducted to observe the stability of each drug's interaction with the TP53 protein over time. Both drugs exhibited stable confirmation with only slight changes in the loop region of the TP53 protein during the simulation intervals. Results also shows that there was a high fluctuation observed during apo-sate simulation time intervals as compared to complex system. Hence, it is suggested that the exploration of structure-based drug design holds promising results to specific target. This could potentially lead to a breakthrough in future experimental approaches for FA treatment.Communicated by Ramaswamy H. Sarma.

4.
J Photochem Photobiol B ; 236: 112571, 2022 Nov.
Article En | MEDLINE | ID: mdl-36215792

The novel Ag0/Cu2MoO4 nanoparticles was simply synthesized via chemical method. Ag/Cu2MoO4 nanoparticles was characterized by FESEM image, XRD curve, UV-vis spectroscopy, BET analysis, and XPS spectrum. XRD pattern depicts that the cubic crystalline phase of particles. The band gap of Ag/Cu2MoO4 nanoparticles was achieved to 2.04 eV, which that depicted the best activity under visible light irradiation. Ag/Cu2MoO4 nanoparticles exhibits 99.74% degradation under light and persulfate ion which was higher response than Cu2MoO4 nanoparticles (83.56%) under this condition. The scavenging test indicates the important reactive species in removal process were •OH, and •SO4-. The Ag/Cu2MoO4 nanoparticles was indicated highly photo-stability for the MG degradation after 5th cycle. Ag/Cu2MoO4 exhibits substantial antibacterial properties against P. aeruginosa and S. pneumoniae. Moreover, Ag/Cu2MoO4 nanoparticles was experimented to peroxidase-like performance for the colorimetric detection of glucose with the Limit of Detection about 52.23 nM.


Glucose , Nanoparticles , Catalysis , Anti-Bacterial Agents/pharmacology , Anti-Bacterial Agents/chemistry , Light
5.
Chemosphere ; 308(Pt 2): 136375, 2022 Dec.
Article En | MEDLINE | ID: mdl-36088970

In this work, the fabrication of the CuO on ZnCdS as a heterojunction nanocomposites were conducted by hydrothermal method and the synthesis method was confirmed by the XRD, XPS, EDS, UV-vis spectrum analysis. The CuO/ZnCdS was used as a photocathode in the bio-photoelectrochemical system (BPES) for tetracycline (TC) degradation under solar irradiation. The CuO/ZnCdS photocathode indicated substantial photocatalytic efficiency for TC degradation, due to the fast separation and transfer of photogenerated carriers. The ESR test evaluates the mechanism of degradation, and shows that ·OH, and ·O2- were contributed to TC degradation. The TC degradation was 1.59 times higher than the unilluminated process (98.72% vs 61.71). The photocatalysis test shows that the TC was degraded about 90.5% in 1.5 h. Then, the synthesized CuO/ZnCdS nanocomposites were studied for the biological application such as antifungal activities. CuO/ZnCdS nanocomposites depicted substantial antimicrobial activity versus Candida-albicans by in vitro process. Therefore, this study suggests the novel system for the antibiotics degradation, and as antifungal application.


Microbiota , Nanocomposites , Zinc Oxide , Anti-Bacterial Agents/pharmacology , Antifungal Agents/pharmacology , Cadmium , Cadmium Compounds , Catalysis , Copper/pharmacology , Oxides , Sulfides , Tetracycline , Zinc , Zinc Compounds
6.
J Photochem Photobiol B ; 234: 112526, 2022 Sep.
Article En | MEDLINE | ID: mdl-35908358

In this study, the hydrothermal method was used to synthesis of silver indium sulfide/nickel molybdenum sulfide (AgInS2/NiMoS4) nanostructure and decorated on Palygorskite (Plg) as an excellent carrier of antibacterial materials. The performance of the prepared AgInS2/NiMoS4/Plg composites was investigated for light-driven antibacterial process and detection of uric acid from biological samples. The result shows the highest antibacterial activity of the AgInS2/NiMoS4/Plg with the minimum inhibitory concentrations about 0.2-0.3 mg/mL. The prepared AgInS2/NiMoS4/Plg as sensor depicted enhanced peroxidase-like activity for detection of acid uric. The detection limit of acid uric by AgInS2/NiMoS4/Plg was about 26.1 nM. Therefore, the AgInS2/NiMoS4/Plg can be developed in the bactericidal process and sensing in complex biological systems.


Gout , Nanostructures , Anti-Bacterial Agents/pharmacology , Clay , Disulfides , Humans , Indium/chemistry , Minerals , Molybdenum , Nanostructures/chemistry , Nickel , Silver/chemistry , Uric Acid
7.
J Photochem Photobiol B ; 228: 112393, 2022 Mar.
Article En | MEDLINE | ID: mdl-35144054

Ag doped Sn3O4 Nanostructure and immobilized on hyperbranched polypyrrole is investigated in this project. The product was synthesized by the hydrothermal synthesis method. The surface and structural characteristics of the product was studied by different instrumental analysis. The fabricated nanocomposites was utilized as a nano photocatalyst in the removal of methylene blue dye. The crystallography results depicts the triclinic phase of Sn3O4 with the crystallite size 36.3 nm. The band gap of the Ag-Sn3O4/hyperbranched polypyrrole was found 1.50 eV from kubelka-munk measurements. The specific surface area was increased in the presence of the hyperbranched polypyrrole as compared to Ag-Sn3O4 samples. The photo-catalytic activity of composites was found 100.0% degradation of CR in 30 min under visible light irradiation. The catalytic kinetic was followed from the first kinetic model. Moreover, the Ag/Sn3O4/hyperbranched polypyrrole was applied as a bactericidal agent against Streptococcus pneumoniae, and Pseudomonas aeruginosa bacteria. Determination of Streptococcus pyogenes as a pathogenic bacteria was investigated by using aptamer/Ag/Sn3O4/hyperbranched polypyrrole in peroxidase activity. The detection limit of S. pyogenes was 71.0 CFU/mL by using the nano-aptamer.


Anti-Bacterial Agents , Nanocomposites , Anti-Bacterial Agents/chemistry , Anti-Bacterial Agents/pharmacology , Catalysis , Light , Nanocomposites/chemistry , Polymers , Pyrroles , Silver/chemistry
8.
J Photochem Photobiol B ; 226: 112354, 2022 Jan.
Article En | MEDLINE | ID: mdl-34814013

In this study, the Cu2MoS4/WO3 supported on chitosan was prepared by precipitation method, and applied to photocatalyst, antibacterial agent and biosensor. The presence of WO3 and Cu2MoS4 crystals were confirmed by XRD analysis. The elemental information was investigated by EDS. FTIR spectra shows the presence of chitosan in nanocomposites. The as-synthesized Cu2MoS4/WO3/Chitosan nanocomposites has a bandgap of 2.18 eV and it is effective for visible light condition. The average particle size of the Cu2MoS4/WO3/Chitosan is 71 nm. The photocatalysis activity Cu2MoS4/WO3/Chitosan was higher than Cu2MoS4 or WO3.The Cu2MoS4/WO3/Chitosan nanocomposites shows the highest efficiency (100%) in photocatalysis degradation of dye under visible light irradiation in 80 min. The •O2- plays a main role in degradation process. The as-synthesized Cu2MoS4/WO3/Chitosan nanocomposites depicted the antibacterial activity toward G+/- bacteria. Determination of enterococcus faecalis is important for human health. The DNA template was used to the Cu2MoS4/WO3/Chitosan nanocomposites and applied in detection of enterococcus faecalis by H2O2 and 3,3',5,5' -tetramethylbenzidine in peroxidase like activity. The detection limit of enterococcus faecalis by DNA-Cu2MoS4/WO3/Chitosan in peroxidase-like catalysis was about 55 CFU/mL. Therefore, the Cu2MoS4/WO3/Chitosan can be applied in the photocatalysis, bactericidal and peroxidase process.


Chitosan
9.
Spectrochim Acta A Mol Biomol Spectrosc ; 268: 120636, 2022 Mar 05.
Article En | MEDLINE | ID: mdl-34890872

In this project, poly (citric acid) (PCA) functionalized on nano Ag/Cu was synthesized by chemical analysis method. The nano probe was applied to detection of cysteine by using the magnesium (II) ions as a cross linker. The characterization of Ag/Cu/PCA nano probe was studied by using the UV-visible, morphological microscopy, dynamic light scattering, and zeta potential analyzer. The zeta potential and size of Ag/Cu/PCA were -38.0 mV and 18.0 nm, respectively. The prepared nano probe shows rapid response for detection of cysteine. The detection limit of Ag/Cu/PCA nano probe was 0.07 nM. Additional, the Ag/Cu/PCA nanoparticles was applied to cysteine detection from real samples in the presence of amino acids compounds. Rapidly and sensitive determination of Streptococcus pneumoniae is substantial for food safety and human health. The DNA-Ag/Cu/PCA were prepared as a template in chemical method and experimented as a bio-receptor for the cell bacteria detection as peroxidase-like catalytic process. The DNA-Ag/Cu/PCA nano probe shows a linear dynamic concertation range of Streptococcus pneumoniae via detection limit about 65 CFU/mL. The project presents that the DNA-Ag/Cu/PCA could detect the biological and bacterial samples via high accuracy.


Colorimetry , Metal Nanoparticles , Amino Acids , Bacteria , Copper , Humans , Peroxidases , Silver
10.
J Photochem Photobiol B ; 219: 112201, 2021 Jun.
Article En | MEDLINE | ID: mdl-33962112

In this project, we studied the thermal and chemical method for the synthesis of carbon dots (CDs)/Hematite (α-Fe2O3) quantum dots and the preparation of hydroxypropyl cellulose cross-linked chitosan (HPCCS) and ulvan (UN) was performed by chemical method. Carbon dots/α-Fe2O3 quantum dots with size distribution of 3-5 nm were completely encapsulated in the HPCCS/UN NPs to obtain composites, which indicated unique characteristics with respect to antimicrobial, pH-responsive and optical properties. The CDs-HQDs/HPCCS/UN nanocomposites exhibited a single-excitation (440 nm), dual-emission fluorescence property (505 nm and 628 nm for green and red light from CDs-HQDs and HPCCS/UN NPs). The nanocomposites played as a pH-responsive drug delivery process to release ulvan at a fast rate in pH 7.4 buffer solution but at a slow rate in low pH solutions. The CDs-HQDs/HPCCS/UN nanocomposites gained the highest photocatalytic activity for degrading 4-chlorophenol (4-CPh) as a pollutant (>98% during 70 min under sunlight irradiation). Moreover, the nanocomposites indicated great inhibitory influences towards bacterial and fungal.


Anti-Infective Agents/chemistry , Cellulose/analogs & derivatives , Chitosan/chemistry , Nanocomposites/chemistry , Quantum Dots/chemistry , Sunlight , Anti-Infective Agents/pharmacology , Carbon/chemistry , Catalysis , Cell Line, Tumor , Cell Survival/drug effects , Cell Survival/radiation effects , Cellulose/chemistry , Chlorophenols/chemistry , Drug Carriers/chemistry , Drug Liberation/radiation effects , Escherichia coli/drug effects , Ferric Compounds/chemistry , Humans , Hydrogen-Ion Concentration , Nanocomposites/toxicity , Staphylococcus aureus/drug effects , Water Pollutants, Chemical/chemistry
11.
Spectrochim Acta A Mol Biomol Spectrosc ; 253: 119592, 2021 May 15.
Article En | MEDLINE | ID: mdl-33640626

In this project, Sn-Fe bimetallic nanoparticles were prepared by a facile method. The bimetallic nanoparticles of it could be well established by a field emission scanning electron microscope micrographs. Due to the excellent synergistic influence between Sn-Fe nanoparticles and leucine indicated a great performance for determination of Cr3+. The material was characterized using the XRD, DLS, and zetasizer for theevaluation of crystal structure and morphologyinformation.The potential and effective size of Sn-Fe NPs was -29.10 mV and 30 nm, respectively. Cr3+ ions interaction with the Sn-Fe NPs-leucine probe was carried out in 1 min as response time. The limit of detection of Sn-Fe NPs for Cr(III) colorimetric method was 0.25 nM. The prepared nanoparticles showed impressive photocatalysis efficiency for degradation of MO was about 95.1% in 35 min, thus the prepared nanoparticles may be developed for the detoxification of pollution. The prepared nanoparticles depicted effective antibacterial activity againstC. botulinum and, H. pylori bacteria.


Metal Nanoparticles , Nanoparticles , Anti-Bacterial Agents/pharmacology , Bacteria , Colorimetry , Leucine
12.
Spectrochim Acta A Mol Biomol Spectrosc ; 249: 119324, 2021 Mar 15.
Article En | MEDLINE | ID: mdl-33385971

In this project, bimetallic Au-Agnanoparticles/CuS nanoparticles were prepared via simple hydrothermal methods, which were used as highly efficient material for Cr (III) detection, photocatalytic, and biological process. The Au-Ag/CuS nanoparticles was studied via UV-visible spectroscopy, field-emission scanning electron microscopy, Dynamic light scattering, and X-ray diffraction. The zeta potential and effective size of Au-Ag/CuS nanoparticles was -32.1 mV and 25 nm respectively. The response time of Cr (III) ions interaction was 2 min. The lowest detection of Cr (III) by Au-Ag/CuS nanoparticles was 0.5 nM. The Au-Ag/CuS nano catalyst was applied to decomposition of drug under visible lamp irradiation. The photo degradation response of drug was 100.0% in 30 min irradiation. The particles exhibited excellent antibacterial activities.


Gold , Metal Nanoparticles , Anti-Bacterial Agents/pharmacology , Chromium , Copper , Silver , Sulfides
13.
Int J Biol Macromol ; 169: 436-442, 2021 Feb 01.
Article En | MEDLINE | ID: mdl-33309668

Recently, photo-degradation process under ultraviolet-light irradiation is being used as a substantial treatment method for the removal of environmental pollution. In this study, a silver phosphate-ilmenite (Ag3PO4-FeTiO3) hetero structure supported on glycol chitosan catalyst was completely prepared, also, and its structural, and optical properties were characterized. Meantime, scanning electron microscopy, X-ray diffraction, X-ray photoelectron, and UV-vis spectra were applied. The Ag3PO4-FeTiO3/glycol chitosan catalyst was used to degrade metronidazole under visible-light irradiation. The degradation rate of metronidazole in 25 min by Ag3PO4-FeTiO3/glycol chitosan nanocomposites was found to be 99.2% under UV light irradiation, which was higher than that by Ag3PO4-FeTiO3 (72.24%) and FeTiO3 (35.5%), respectively. The active species trapping test of Ag3PO4-FeTiO3/glycol chitosan indicated that ·OH and ·O2- participated during the reaction. The diffusion method was evaluated to appraise the bactericidal activity of the synthesized nanomaterials when tested against both Staphylococcus aureus and Escherichia coli bacteria, with or without LED-light irradiation. The antibacterial tests show higher inhibition zones under light illumination as compared to dark conditions. The antifungal properties of the prepared nanomaterials were analyzed by fungi (Aspergillus niger, and Fusarium solani) using disc diffusion analysis. It was confirmed that the prepared nanomaterials have the best antifungal agent as compared to the standard antibiotics. When the Ag3PO4-FeTiO3/glycol chitosan was used, the amount of inhibition zone was enhanced.


Environmental Restoration and Remediation/methods , Iron/chemistry , Phosphates/chemistry , Silver Compounds/chemistry , Titanium/chemistry , Anti-Bacterial Agents/pharmacology , Catalysis , Chitosan/chemistry , Environmental Pollutants/chemistry , Escherichia coli/drug effects , Fusarium/drug effects , Light , Metronidazole/adverse effects , Metronidazole/chemistry , Microbial Sensitivity Tests , Nanocomposites/chemistry , Staphylococcus aureus/drug effects
14.
Int J Biol Macromol ; 164: 4138-4145, 2020 Dec 01.
Article En | MEDLINE | ID: mdl-32896563

The application of nano materials for removal and detection of hazardous metal detection with nanoparticles is important for researcher. In this paper, the silver-manganese disulfide/chitosan-polyvinyl alcohol (Ag-MnS2/CSPVA) nanocomposites was prepared for the detection of toxic heavy metal. The synthesized nano materials was experimented through the various analysis methods to structural and morphological evaluation. The surface charge of the Ag-MnS2/CSPVA was -25.0 ± 0.1 mV. The various metal ions have not effect on detection of mercury (II). The result shows the excellent linearity was found the mercury concentrations changing with limit of detection of 9.0 nM (nano molar level). The condition of detection was conducted at pH 5 and room temperature. Moreover, the photocatalytic properties of the Ag-MnS2/CSPVA nanocomposites was analyzed for degradation of malachite green under visible light irradiation. The complete malachite green degradation reached up to 97.29% after 30 min of photocatalytic reaction. The antibacterial efficiency was studied versus both Escherichia coli and Staphylococcus aureus bacteria. The outcome depicts that the Ag-MnS2/CSPVA nanocomposites has an excellent property in antibacterial activity.


Anti-Bacterial Agents/chemistry , Anti-Bacterial Agents/pharmacology , Chitosan/chemistry , Colorimetry/methods , Mercury/chemistry , Photochemical Processes , Polyvinyl Alcohol/chemistry , Catalysis , Disulfides/chemistry , Ions/chemistry , Manganese/chemistry , Nanocomposites/chemistry , Nanocomposites/ultrastructure , Silver/chemistry , Spectrum Analysis
15.
J Photochem Photobiol B ; 212: 112025, 2020 Nov.
Article En | MEDLINE | ID: mdl-32977113

In this project, silver­platinum (AgPt) nanoparticles were prepared by using the Crocus sativus L. plant ethanolic extract. The AgPt nanoparticles were characterized by applying the various method as ultraviolet-visible and infrared spectroscopy, electron microscopy, and X-ray diffraction analysis. The morphology structural indicated that the AgPt nanoparticles were spherical particles with diameter about 36.0 nm. The FTIR spectroscopy shows the efficient stabilization of the AgPt nanoparticles by phytoconstituents. The Ag and AgPt nanoparticles have polyphenolic content, lower than the flavonoids and proanthocyanins contents. The AgPt nanoparticles depicted the highest antioxidant properties compared to the Ag nanoparticles and ascorbic acid. The results showed that the AgPt nanoparticles had a high antioxidant properties. In addition, the AgPt nanoparticles demonstrated the substantial antimicrobial and cytotoxic activities against pathogenic microbes and MCF-7 breast cancer cell line. The environmental chemistry analysis depicts that methyl orange can be degraded from water by catalytic degradation process with sodium borohydride. The AgPt nanoparticles were prosperous in catalytic degrading methyl orange following a first order kinetic model.


Alloys/chemistry , Alloys/pharmacology , Crocus/chemistry , Metal Nanoparticles/chemistry , Plant Extracts/chemistry , Platinum/chemistry , Silver/chemistry , Alloys/chemical synthesis , Anti-Infective Agents/chemical synthesis , Anti-Infective Agents/chemistry , Anti-Infective Agents/pharmacology , Antineoplastic Agents/chemical synthesis , Antineoplastic Agents/chemistry , Antineoplastic Agents/pharmacology , Antioxidants/chemical synthesis , Antioxidants/chemistry , Antioxidants/pharmacology , Catalysis , Chemistry Techniques, Synthetic , Humans , MCF-7 Cells
16.
Clinicoecon Outcomes Res ; 12: 459-472, 2020.
Article En | MEDLINE | ID: mdl-32922051

BACKGROUND: This study builds on previous successes of using tracer indicators in tracking progress towards Universal Health Coverage (UHC) and complements them by offering a more detailed tool that would allow us to identify potential process barriers and enablers towards such progress. PURPOSE: This tool was designed accounting for possibly available data in low- and middle-income counties. METHODOLOGY: A systematic review of relevant studies was carried out using PubMed, ISI Web of Science, Embase, Scopus, and ProQuest databases with no time restriction. The search was complemented by a scoping review of grey literature, using the World Bank and the World Health Organization (WHO) official reports depositories. Next, an inductive content analysis identified determinants influencing the progress towards UHC and its relevant indicators. The conceptual proximity between indicators and categorized themes was explored through three focus group discussion with 18 experts in UHC. Finally, a comprehensive list of indicators was converted into an assessment tool and refined following three consecutive expert panel discussions and two rounds of email surveys. RESULTS: A total of 416 themes (including indicators and determinants factors) were extracted from 166 eligible articles and documents. Based on conceptual proximity, the number of factors was reduced to 119. These were grouped into eight domains: social infrastructure and social sustainability, financial and economic infrastructures, population health status, service delivery, coverage, stewardship/governance, and global movements. The final assessment tool included 20 identified subcategories and 88 relevant indicators. CONCLUSION: Identified factors in progress towards UHC are interrelated. The developed tool can be adapted and used in whole or in part in any country. Periodical use of the tool is recommended to understand potential factors that impede or advance progress towards UHC.

17.
Int J Biol Macromol ; 164: 1584-1591, 2020 Dec 01.
Article En | MEDLINE | ID: mdl-32758601

A novel AgO-CoO-CdO/Poly(alanine)-chitosan-reduced graphene oxide (PACSGO) nanocomposite was developed to study the degradation efficiency under visible light irradiation. The AgO, CoO, CdO nanoparticles and AgO-CoO-CdO heterometal oxides were prepared by using the chemical method. The crystallite structure and phase studies were studied by the X-ray diffraction assay. The SEM images were evaluated to explore the morphology of the prepared materials. EDS analysis and FTIR spectra confirmed the formation of nano-materials with high purity. The optical bandgap values were measured via Kubelka-Munk plot showing that the metal oxides produced a new energy state in the electronic level for high photocatalysis efficiency. The incorporation of AgO-CoO-CdO in PACSGO showed a novel nano-photocatalyst for substantial degradation of dye in low process time. The catalysis data displayed that PACSGO based AgO-CoO-CdO nanocomposites ensured a strong potential to degradation of organic dye compounds from water in during photocatalysis reaction. The beneficial anti-pathogenic bacterial performance of the AgO-CoO-CdO/PACSGO nanocomposites was further demonstrated by a substantial reduction in the amount of Staphylococcus aureus, Escherichia coli, Pseudomonas aeruginosa, and B. cereus medium and increase in inhibition zone value with the addition of the AgO-CoO-CdO/PACSGO nanocomposites.


Alanine/chemistry , Anti-Bacterial Agents/chemistry , Antioxidants/chemistry , Chitosan/chemistry , Graphite/chemistry , Metal Nanoparticles/chemistry , Oxides/chemistry , Anti-Bacterial Agents/pharmacology , Antioxidants/pharmacology , Bacteria/drug effects , Cadmium Compounds/chemistry , Catalysis , Nanocomposites/chemistry , Polymers/chemistry , Water/chemistry , X-Ray Diffraction/methods
18.
Int J Biol Macromol ; 162: 220-228, 2020 Nov 01.
Article En | MEDLINE | ID: mdl-32544578

In this work, we present Co3S4-SnO2 supported polyvinylpyrrolidone-cellulose (PVPCS) nano-structure for Lidocaine degradation. The nanostructure was characterized by various techniques i.e. morphological and optical ones. The results have demonstrated that Co3S4-SnO2 nanocomposites were evenly supported on the PVPCS. Moreover, the photocatalysis performances of the catalysts were investigated under ultra-violet (UV) light irradiation. The nano-structure Co3S4-SnO2/PVPCS composite (98.72%) revealed the highest photocatalysis performance as compared to SnO2 nanoparticles, and Co3S4-SnO2 nanocomposites. The photo-stability of nano-structure Co3S4-SnO2/PVPCS composite was characterized using cyclic catalytic experimental. Results demonstrated a substantially stable performance of the nano-structure Co3S4-SnO2/PVPCS composite. The biological properties of Co3S4-SnO2/PVPCS composite were investigated through the antibacterial (versus Staphylococcus aureus, and Escherichia coli) and antifungal studies (Candida albicans). As the results declared, Co3S4-SnO2 nanocomposites have substantial biological properties as compared to SnO2 nanoparticles, and Co3S4-SnO2 nanocomposites.


Anti-Bacterial Agents/pharmacology , Antifungal Agents/pharmacology , Cellulose/chemistry , Cobalt/chemistry , Nanocomposites/chemistry , Povidone/analogs & derivatives , Tin Compounds/chemistry , Anti-Bacterial Agents/chemistry , Candida albicans/drug effects , Candida albicans/radiation effects , Catalysis , Cobalt/pharmacology , Cobalt/radiation effects , Drug Carriers/chemistry , Escherichia coli/drug effects , Escherichia coli/radiation effects , Microscopy, Electron, Scanning , Nanocomposites/ultrastructure , Nanoparticles/chemistry , Nanostructures/chemistry , Nanostructures/ultrastructure , Photochemical Processes , Povidone/chemistry , Staphylococcus aureus/drug effects , Staphylococcus aureus/radiation effects , Tin Compounds/pharmacology , Tin Compounds/radiation effects , Ultraviolet Rays , X-Ray Diffraction
19.
J Photochem Photobiol B ; 207: 111882, 2020 Jun.
Article En | MEDLINE | ID: mdl-32361282

Silver sulfide­magnesium oxide/graphene oxide (Ag2S-MgO/GO) nanocomposite was prepared via sol-gel/ultrasound method to modify the photo-degradation performance for rhodamine B decontamination under visible and UV light. Analytical studies were performed to distinguish the properties such as structure, morphology, and elements of prepared materials. The average crystallite size of MgO, Ag2S-MgO and Ag2S-MgO/GO is distinguished to be 24.2, 29.3 and 33.1 nm, respectively. The Band gap MgO, Ag2S-MgO and Ag2S-MgO/GO is 4.08, 3.25 and 2.82 eV, respectively. Ag2S-MgO/GO nanocomposites illustrated the highest photo-degradation rate of rhodamine B (RhB) under UV light (98.8%) and visible light (64.8%) during in 60 min. In this project, the process parameter of pH and time were investigated for RhB degradation activity influence. The suggested mechanisms for the enhanced photo-degradation of RhB by Ag2S-MgO/GO nanocomposites under light irradiation due to enhanced charge transfer efficiency via decreasing band gap amount; reduced e-/h+ recombination of MgO with the Ag2S crystal and an enhanced removal efficiency with the supported on graphene oxide. Examination of the antibacterial and antifungal properties of the prepared nano-materials were conducted with Bacillus vallismortis, Escherichia coli, Aspergillus flavus and Trichoderma viride. The beneficial antibacterial and antifungal performance of the Ag2S-MgO/GO nanocomposites was further tested by a great reduction in the number of bacteria and fungi medium with the addition of the Ag2S-MgO/GO nanocomposites.


Anti-Infective Agents/chemistry , Graphite/chemistry , Magnesium Oxide/chemistry , Nanocomposites/chemistry , Silver Compounds/chemistry , Bacillus/drug effects , Catalysis , Escherichia coli/drug effects , Light , Photochemical Processes , Rhodamines/chemistry , Structure-Activity Relationship , Surface Properties , Time Factors
20.
J Photochem Photobiol B ; 205: 111842, 2020 Apr.
Article En | MEDLINE | ID: mdl-32146274

Development of high responsive photocatalysts for the degradation of dye from water is a significance method to solve the difficulties of water contamination. In the present project, Cr2O3 nanoparticles were decorated onto cellulose through a facile synthesis method, which was exposed to characterization by XRD, FESEM, DLS, PL, and UV-vis spectroscopy. The structural attributes confirmed the presence of rhombohedral phase of Cr2O3 nanoparticles. The mean crystal size of Cr2O3, and Cr2O3/cellulose nanocomposites were 38.50 nm, and 50.11 nm, respectively. The band gap values (Eg) of Cr2O3, and Cr2O3/cellulose nanocomposites were was found 3.00, and 2.53 eV, respectively. Moreover, the morphological and optical studies have been showed the impressive photocatalytic properties of the prepared Cr2O3/cellulose nanocomposites. The photocatalytic efficiency of Cr2O3, and Cr2O3/cellulose nanocomposites has been investigated for the photo-degradation of crystal violet in the ultraviolet light region. The Cr2O3/cellulose indicated promising photocatalytic performance and up to 99.65% of the crystal violet was photo-degraded in 40 min. The obtained crystal violet degradation results were fitted onto a Langmuir-Hinshelwood (L-H) plot. The antioxidant performances of Cr2O3, and Cr2O3/cellulose were analyzed. The beneficial antibacterial performance of the Cr2O3/cellulose nanocomposites was tested by various bacteria as Escherichia coli, Pseudomonas aeruginosa, staphylococcus aurous, and Streptococcus pyogenes.


Anti-Bacterial Agents , Antioxidants , Cellulose , Chromium Compounds , Nanocomposites , Anti-Bacterial Agents/administration & dosage , Anti-Bacterial Agents/chemistry , Antioxidants/administration & dosage , Antioxidants/chemistry , Bacteria/drug effects , Bacteria/growth & development , Biphenyl Compounds/chemistry , Catalysis , Cellulose/administration & dosage , Cellulose/chemistry , Chromium Compounds/administration & dosage , Chromium Compounds/chemistry , Coloring Agents/chemistry , Gentian Violet/chemistry , Nanocomposites/administration & dosage , Nanocomposites/chemistry , Picrates/chemistry , Water Pollutants, Chemical/chemistry
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